Solution-enhanced dispersion by supercritical carbon dioxide (SEDS) and spray drying (SD) were used to microencapsulate red palm oil (RPO) to prolong the functionality of carotenes and vitamin E. The protective effects provided by SEDS and SD were evaluated in terms of the oxidative stability (65 °C for 35 days), fatty acid compositions, color change and degradation kinetics of carotenes and vitamin E (25 °C, 45 °C, 65 °C, and 85 °C for up to 198 days). SEDS microcapsules (SEDS-M) were the most oxidatively stable (total oxidation (Totox): 26.5), followed by SD microcapsules (SD-M) (34.9) and RPO (56.7). Degradation of carotenes and vitamin E fitted well a first-order kinetic model (average absolute relative deviation = 2-16%). SEDS-M offered better protection to vitamin E (Ea = 36 kJ/mol), whereas SD-M provided better protection for α + β carotene (Ea = 29 kJ/mol). Overall, encapsulation protected RPO during storage, with SEDS-microencapsulated RPO performing better than SD-microencapsulated RPO.
Dissolved oxygen is an ecologically critical variable with the prevalence of hypoxia one of the key global anthropogenic issues. A study was carried out to understand the causes of low dissolved oxygen in Brunei Bay, northwest Borneo. Hypoxia was widespread in bottom waters in the monsoonal dry season with dissolved oxygen
Atmospheric microplastic transport is an important delivery pathway with the deposition of microplastics to ecologically important regions raising environmental concerns. Investigating atmospheric delivery pathways and their deposition rates in different ecosystems is necessary to understanding its global impact. In this study, atmospheric deposition was collected at three sites in Malaysia, two urban and one pristine, covering the Northeast and Southwest monsoons to quantify the role of this pathway in Southeast Asia. Air mass back trajectories showed long-range atmospheric transport of microplastics to all sites with atmospheric deposition varying from 114 to 689 MP/m2/day. For the east coast of Peninsular Malaysia, monsoonal season influenced microplastic transport and deposition rate with peak microplastic deposition during the Northeast monsoon due to higher wind speed. MP morphology combined with size fractionation and plastic type at the coastal sites indicated a role for long-range marine transport of MPs that subsequently provided a local marine source to the atmosphere at the coastal sites.