The Yb(III) atom in the title complex, [Yb(C27H24Cl3N4O3)] [systematic name: (2,2',2''-{(nitrilo)-tris-[ethane-2,1-di-yl(nitrilo)-methylyl-idene]}tris-(4-chloro-phenolato)ytterbium(III)], is coordinated by a trinegative, hepta-dentate ligand and exists within an N4O3 donor set, which defines a capped octa-hedral geometry whereby the amine N atom caps the triangular face defined by the three imine N atoms. The packing features supra-molecular layers that stack along the a axis, sustained by a combination of aryl-C-H⋯O, imine-C-H⋯O, methyl-ene-C-H⋯π(ar-yl) and end-on C-Cl⋯π(ar-yl) inter-actions. A Hirshfeld surface analysis points to the major contributions of C⋯H/ H⋯C and Cl⋯H/H⋯Cl inter-actions (along with H⋯H) to the overall surface but the Cl⋯H contacts are at distances greater than the sum of their van der Waals radii.
This paper demonstrates an erbium/ytterbium co-doped fi bre amplifi er (EYDFA) which used a pumping wavelength of 1058 nm, whereby the amplifi cation was assisted by the energy transfer between Yb and Er ions. The energy transfer increased the erbium doping concentration limit that was imposed by concentration quenching in erbium-doped fi bre. The optimum length was obtained at 4m~6m for erbium/ytterbium co-doped fi bre with Er ion concentration of 1000 p.p.m. This enabled the development of a compact amplifi er with a shorter gain medium compared to erbium-doped fi bre amplifi ers which use a gain medium of up to 15 m. A 1058 nm pumping wave-length was used for the EYDFA, as 1480 nm pumping resulted in severely degraded gain and noise fi gures because the energy transfer could not be achieved. The use of the optical isolator improved the small signal gain and noise fi gure by about 4.8 dB and 1.6 dB, respectively. Without the isolator, gain saturation and a noise fi gure penalty were observed due to the oscillating laser which was created at around 1534 nm by spurious refl ection. This showed that the usage of optical isolators was an important aspect to consider when designing an EYDFA.
Heavy metal oxide glasses, containing bismuth and/or lead in their glass structure are new alternatives for rare eart (RE) doped hosts. Hence, the study of the structure of these vitreous systems is of great interest for science and technology. In this research work, GeO(2)-PbO-Bi(2)O(3) glass host doped with Er(3+)/Yb(3+) ions was synthesized by a conventional melt quenching method. The Fourier transform infrared (FTIR) results showed that PbO and Bi(2)O(3) participate with PbO(4) tetragonal pyramids and strongly distort BiO(6) octahedral units in the glass network, which subsequently act as modifiers in glass structure. These results also confirmed the existence of both four and six coordination of germanium oxide in glass matrix.
An efficient erbium/ytterbium co-doped fibre amplifier was demonstrated by using a dual-stage partial doublepass structure with a band-pass filter (BPF). The amplifier achieved the maximum small signal gain of 56 dB and the corresponding noise figure of 4.66 dB at 1536 nm with an input signal power and total pump power of –50 dBm and 140 mW, respectively. Compared with a conventional single-stage amplifier, the maximum gain enhancement of 16.99 dB was obtained at 1544 nm with the corresponding noise figure was improved by 2 dB. The proposed amplifier structure only used a single pump source with a partial double pass scheme to provide a high gain and dual-stage structure to provide the low noise figure.