Affiliations 

  • 1 Department of Chemistry, Division of Science and Technology, University of Education, Lahore, 54000, Lahore, Pakistan. Electronic address: salman.shafqat@ue.edu.pk
  • 2 Department of Chemistry, The University of Lahore, 54000, Lahore, Pakistan; Department of Chemistry, University of Malaya, Kuala Lumpur, 50603, Malaysia. Electronic address: Muhammad.rizwan@chem.uol.edu.pk
  • 3 Department of Chemistry, University of Gujrat, 50700, Gujrat, Pakistan
  • 4 Department of Chemistry, University of Sialkot, Sialkot, Pakistan
  • 5 Department of Chemistry, The University of Lahore, 54000, Lahore, Pakistan
  • 6 Interdisciplinary Research Center for Advanced Materials, King Fahd University of Petroleum and Minerals (KFUPM), Dhahran, 31261, Saudi Arabia. Electronic address: tahir.rasheed@kfupm.edu.sa
  • 7 Department of Chemistry, University of Gujrat, 50700, Gujrat, Pakistan. Electronic address: nadeem.zafar@uog.edu.pk
Chemosphere, 2023 Mar;318:137920.
PMID: 36690256 DOI: 10.1016/j.chemosphere.2023.137920

Abstract

Water bodies are being polluted rapidly by disposal of toxic chemicals with their huge entrance into drinking water supply chain. Among these pollutants, heavy metal ions (HMIs) are the most challenging one due to their non-biodegradability, toxicity, and ability to biologically hoard in ecological systems, thus posing a foremost danger to human health. This can be addressed by robust, sensitive, selective, and reliable sensing of metal ions which can be achieved by Metal organic frameworks (MOF) based electrochemical sensors. In the present era, MOFs have caught greater interest in a variety of applications including sensing of hazardous pollutants such as heavy metal ions. So, in this review article, types, synthesis and working mechanism of MOF based sensors is explained to give general overview with updated literature. First time, detailed study is done for sensing of metal ions such as chromium, mercury, zinc, copper, manganese, palladium, lead, iron, cadmium and lanthanide by MOFs based electrochemical sensors. The use of MOFs as electrochemical sensors has attractive success story along with some challenges of the area. Considering these challenges, we attempted to highlight the milestone achieved and shortcomings along with future prospective of the MOFs for employing it in electrochemical sensing devices for HMIs. Finally, challenges and future prospects have been discussed to promote the development of MOFs-based sensors in future.

* Title and MeSH Headings from MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine.