Affiliations 

  • 1 Department of Chemistry, College of Natural and Applied Science, Al-Qalam University Katsina, Katsina City, 2137, Katsina, Nigeria. zakariyyazango@auk.edu.ng
  • 2 Department of Chemical Engineering and Materials Science, Yuan Ze University, Taoyuan, Taiwan
  • 3 Department of Chemistry, College of Natural and Applied Science, Al-Qalam University Katsina, Katsina City, 2137, Katsina, Nigeria
  • 4 Department of Chemistry, Ahmadu Bello University, P.M.B 1044, Zaria, Kaduna, Nigeria
  • 5 Department of Chemistry and Biology, Centre for Defense Foundation Studies, Universiti Pertahanan Nasional Malaysia, Kem Perdana Sungai Besi, 57000, Kuala Lumpur, Malaysia
  • 6 Basic Science Unit, Prince Sattam Bin Abdulaziz University, 16278, Alkharj, Alkharj, Saudi Arabia
  • 7 Department of Physics, College of Science, Imam Mohammad Ibn Saud Islamic University (IMSIU), 13318, Riyadh, Riyadh, Saudi Arabia
  • 8 Department of Physics, College of Science, Imam Mohammad Ibn Saud Islamic University (IMSIU), 13318, Riyadh, Riyadh, Saudi Arabia. khiahmed@imamu.edu.sa
  • 9 HICoE-Centre for Biofuel and Biochemical Research, Institute of Self-Sustainable Building, Department of Fundamental and Applied Sciences, Universiti Teknologi PETRONAS, 32610, Seri Iskandar, Perak Darul Ridzuan, Malaysia
  • 10 School of Chemical Sciences, Universiti Sains Malaysia, 11800, Gelugor, Penang, Malaysia
Environ Geochem Health, 2024 Apr 03;46(4):145.
PMID: 38568460 DOI: 10.1007/s10653-024-01936-1

Abstract

Frequent detection of sulfonamides (SAs) pharmaceuticals in wastewater has necessitated the discovery of suitable technology for their sustainable remediation. Adsorption has been widely investigated due to its effectiveness, simplicity, and availability of various adsorbent materials from natural and artificial sources. This review highlighted the potentials of carbon-based adsorbents derived from agricultural wastes such as lignocellulose, biochar, activated carbon, carbon nanotubes graphene materials as well as organic polymers such as chitosan, molecularly imprinted polymers, metal, and covalent frameworks for SAs removal from wastewater. The promising features of these materials including higher porosity, rich carbon-content, robustness, good stability as well as ease of modification have been emphasized. Thus, the materials have demonstrated excellent performance towards the SAs removal, attributed to their porous nature that provided sufficient active sites for the adsorption of SAs molecules. The modification of physico-chemical features of the materials have been discussed as efficient means for enhancing their adsorption and reusable performance. The article also proposed various interactive mechanisms for the SAs adsorption. Lastly, the prospects and challenges have been highlighted to expand the knowledge gap on the application of the materials for the sustainable removal of the SAs.

* Title and MeSH Headings from MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine.