Displaying publications 1 - 20 of 44 in total

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  1. Lee KT, Du JT, Chen WH, Ubando AT, Lee KT
    Environ Pollut, 2021 Sep 15;285:117244.
    PMID: 33965857 DOI: 10.1016/j.envpol.2021.117244
    A green approach using hydrogen peroxide (H2O2) to intensify the fuel properties of spent coffee grounds (SCGs) through torrefaction is developed in this study to minimize environmental pollution. Meanwhile, a neural network (NN) is used to minimize bulk density at different combinations of operating conditions to show the accurate and reliable model of NN (R2 = 0.9994). The biochar produced from SCGs torrefied at temperatures of 200-300 °C, duration of 30-60 min, and H2O2 concentrations of 0-100 wt% is examined. The results reveal that the higher heating value (HHV) of biochar increases with rising temperature, duration, or H2O2 concentration, whereas the bulk density has an opposite trend. The HHV, ignition temperature, and bulk density of biochar from torrefaction at 230 °C for 30 min with a 100 wt% H2O2 solution (230-100%-TSCG) are 27.00 MJ∙kg-1, 292 °C, and 120 kg∙m-3, respectively. This HHV accounts for a 29% improvement compared to that of untorrefied SCG. The contact angle (126°), water activity (0.51 aw), and moisture content (7.69%) of the optimized biochar indicate that it has higher resistance against biodegradation, and thereby can be stored longer. Overall, H2O2 is a green treatment additive for SCGs solid fuel. This study has successfully produced biochar with greater HHV and low bulk density at low temperatures. The green additive development can effectively reduce environmental pollutants and upgrade wastes into resources, and achieve "3E", namely, environmental (non-polluting green additives), energy (biofuel), and circular economy (waste upgrade). In addition, the produced biochar has great potential in the fields of bioadsorbents and soil amendments.
  2. Sankaran R, Parra Cruz RA, Pakalapati H, Show PL, Ling TC, Chen WH, et al.
    Bioresour Technol, 2020 Feb;298:122476.
    PMID: 31810736 DOI: 10.1016/j.biortech.2019.122476
    Microalgal and lignocellulosic biomass is the most sumptuous renewable bioresource raw material existing on earth. Recently, the bioconversion of biomass into biofuels have received significant attention replacing fossil fuels. Pretreatment of biomass is a critical process in the conversion due to the nature and structure of the biomass cell wall that is complex. Although green technologies for biofuel production are advancing, the productivity and yield from these techniques are low. Over the past years, various pretreatment techniques have been developed and successfully employed to improve the technology. This paper presents an in-depth review of the recent advancement of pretreatment methods focusing on microalgal and lignocellulosic biomass. The technological approaches involving physical, chemical, biological and other latest pretreatment methods are reviewed.
  3. Teh YY, Lee KT, Chen WH, Lin SC, Sheen HK, Tan IS
    Bioresour Technol, 2017 Dec;246:20-27.
    PMID: 28781203 DOI: 10.1016/j.biortech.2017.07.101
    This study aims to produce biochar and sugars from a macroalga Eucheuma denticulatum using dilute sulfuric acid hydrolysis along with microwave-assisted heating. The reactions were operated at sulfuric acid concentrations of 0.1 and 0.2M, reaction temperatures of 150-170°C and a heating time of 10min. Compared to the raw macroalga, biochar qualities were improved with increased carbon content and lower ash and moisture contents. The calorific value of the biochar could be intensified up to 45%, and 39% of energy yield was recovered. Apart from producing biochar, the highest total reducing sugars were 51.47g/L (74.84% yield) along with a low by-product 5-HMF of 0.20g/L, when the biomass was treated under the optimum conditions at 160°C with 0.1M H2SO4. Thus, this study demonstrated that macroalgae could be potentially used as biomass feedstock under microwave-assisted acid hydrolysis for the production of biofuel and value-added products.
  4. Suresh R, Rajendran S, Gnanasekaran L, Show PL, Chen WH, Soto-Moscoso M
    Chemosphere, 2023 May;322:138152.
    PMID: 36791812 DOI: 10.1016/j.chemosphere.2023.138152
    Water contamination due to soluble synthetic dyes has serious concerns. Membrane-based wastewater treatments are emerging as a preferred choice for removing dyes from water. Poly(vinylidene fluoride) (PVDF)-based nanomembranes have gained much popularity due to their favorable features. This review explores the application of PVDF-based nanomembranes in synthetic dye removal through various treatments. Different fabrication methods to obtain high performance PVDF-based nanomembranes were discussed under surface coating and blending methods. Studies related to use of PVDF-based nanomembranes in adsorption, filtration, catalysis (oxidant activation, ozonation, Fenton process and photocatalysis) and membrane distillation have been elaborately discussed. Nanomaterials including metal compounds, metals, (synthetic/bio)polymers, metal organic frameworks, carbon materials and their composites were incorporated in PVDF membrane to enhance its performance. The advantages and limitations of incorporating nanomaterials in PVDF-based membranes have been highlighted. The influence of nanomaterials on the surface features, mechanical strength, hydrophilicity, crystallinity and catalytic ability of PVDF membrane was discussed. The conclusion of this literature review was given along with future research.
  5. Leong YK, Chew KW, Chen WH, Chang JS, Show PL
    Trends Plant Sci, 2021 07;26(7):729-740.
    PMID: 33461869 DOI: 10.1016/j.tplants.2020.12.010
    Given their advantages of high photosynthetic efficiency and non-competition with land-based crops, algae, that are carbon-hungry and sunlight-driven microbial factories, are a promising solution to resolve energy crisis, food security, and pollution problems. The ability to recycle nutrient and CO2 fixation from waste sources makes algae a valuable feedstock for biofuels, food and feeds, biochemicals, and biomaterials. Innovative technologies such as the bicarbonate-based integrated carbon capture and algae production system (BICCAPS), integrated algal bioenergy carbon capture and storage (BECCS), as well as ocean macroalgal afforestation (OMA), can be used to realize a low-carbon algal bioeconomy. We review how algae can be applied in the framework of integrated low-carbon circular bioeconomy models, focusing on sustainable biofuels, low-carbon feedstocks, carbon capture, and advances in algal biotechnology.
  6. Yew GY, Chew KW, Malek MA, Ho YC, Chen WH, Ling TC, et al.
    Biotechnol Biofuels, 2019;12:252.
    PMID: 31666807 DOI: 10.1186/s13068-019-1591-8
    Background: The extraction of lipids from microalgae requires a pretreatment process to break the cell wall and subsequent extraction processes to obtain the lipids for biofuels production. The multistep operation tends to incur high costs and are energy intensive due to longer process operations. This research work applies the combination of radicals from hydrogen peroxide with an organic solvent as a chemical pretreatment method for disrupting the cell wall of microalgae and simultaneously extracting lipids from the biomass in a one-step biphasic solution.

    Result: Several parameters which can affect the biphasic system were analyzed: contact time, volume of solvent, volume ratio, type of organic solvent, biomass amount and concentration of solvents, to extract the highest amount of lipids from microalgae. The results were optimized and up to 83.5% of lipid recovery yield and 94.6% of enhancement was successfully achieved. The results obtain from GC-FID were similar to the analysis of triglyceride lipid standard.

    Conclusion: The profound hybrid biphasic system shows great potential to radically disrupt the cell wall of microalgae and instantaneously extract lipids in a single-step approach. The lipids extracted were tested to for its comparability to biodiesel performance.

  7. Lin BJ, Chen WH, Lin YY, Chang JS, Farooq A, Singh Y, et al.
    Bioresour Technol, 2020 Apr;301:122774.
    PMID: 31954973 DOI: 10.1016/j.biortech.2020.122774
    The thermal characteristics of Actinobacillus succinogenes (AS) from pyrolysis, torrefaction, and combustion are analyzed to evaluate the potential of this biomass as a renewable fuel. AS pyrolysis can be classified into four stages, and its main decomposition zone is at 200-500 °C. The solid yield of AS after 60 min torrefaction is over 60 wt%, and the torrefaction severity index map indicates that a high torrefaction temperature with a short duration has a more profound influence on its decomposition. The Py-GC/MS analysis of AS suggests that the volatile products from 500 °C pyrolysis are similar to microalgae-derived pyrolysis bio-oils. The combustibility index (S) of AS is 4.07 × 10-7 which is much higher than that of lignite coal (0.39 × 10-7) and bituminous coal (0.18 × 10-7), and close to those of biochar and bio-oil. The obtained results are conducive to the development of microorganisms as fuel to achieve a circular bioeconomy.
  8. Selvarajoo A, Wong YL, Khoo KS, Chen WH, Show PL
    Chemosphere, 2022 Jan 26;294:133671.
    PMID: 35092753 DOI: 10.1016/j.chemosphere.2022.133671
    Renewable energy sources such as biomass have been proven to be one of the promising sustainable alternatives to fossil fuels. However, using biomass directly as a fuel is less attractive due to its high moisture content, poor grindability, low bulk density, and low energy density nature. Hence biomass can be converted into biochar to overcome these challenges. In this study, biochar was derived from citrus peels biomass by slow pyrolysis over the temperature range of 300-700 °C. The effect of pyrolysis temperature on the quality of citrus peels-derived biochar was examined based on the physical and chemical properties obtained from various analyses. The citrus peels biomass and biochar were characterized by means of higher heating value (HHV) analysis, field emission scanning electron microscopy with energy dispersive X-ray spectroscopy (FESEM-EDX), Fourier transform infrared ray (FTIR) analysis, proximate and thermogravimetric analysis. Based on the characterization results, the potential usage of the derived biochar as a solid fuel was discussed. Results obtained from the pyrolysis experiments indicated that a lower pyrolysis temperature produced a higher char yield. The carbon content and energy content of biochar were found to be increasing with pyrolysis temperature. Biochar produced at 500 °C presented the best fuel properties by having the highest value of HHV and carbon content. The results from this study provided great insights into biomass waste reutilisation to generate value-added biochar for renewable energy production in Malaysia.
  9. Chen WH, Lo HJ, Yu KL, Ong HC, Sheen HK
    Environ Pollut, 2021 Sep 15;285:117196.
    PMID: 33962308 DOI: 10.1016/j.envpol.2021.117196
    This research aims to study the wet torrefaction (WT) and saccharification of sorghum distillery residue (SDR) towards hydrochar and bioethanol production. The experiments are designed by Box-Behnken design from response surface methodology where the operating conditions include sulfuric acid concentration (0, 0.01, and 0.02 M), amyloglucosidase concentration (36, 51, and 66 IU), and saccharification time (120, 180, and 240 min). Compared to conventional dry torrefaction, the hydrochar yield is between 13.24 and 14.73%, which is much lower than dry torrefaction biochar (yield >50%). The calorific value of the raw SDR is 17.15 MJ/kg, which is significantly enhanced to 22.36-23.37 MJ/kg after WT. When the sulfuric acid concentration increases from 0 to 0.02 M, the glucose concentration in the product increases from 5.59 g/L to 13.05 g/L. The prediction of analysis of variance suggests that the best combination to maximum glucose production is 0.02 M H2SO4, 66 IU enzyme concentration, and 120 min saccharification time, and the glucose concentration is 30.85 g/L. The maximum bioethanol concentration of 19.21 g/L is obtained, which is higher than those from wheat straw (18.1 g/L) and sweet sorghum residue (16.2 g/L). A large amount of SDR is generated in the kaoliang liquor production process, which may cause environmental problems if it is not appropriately treated. This study fulfills SDR valorization for hydrochar and bioenergy to lower environmental pollution and even achieve a circular economy.
  10. Moogi S, Lam SS, Chen WH, Ko CH, Jung SC, Park YK
    Bioresour Technol, 2022 Oct 30;366:128209.
    PMID: 36323373 DOI: 10.1016/j.biortech.2022.128209
    Household food waste (FW) was converted into biohydrogen-rich gas via steam gasification over Ni and bimetallic Ni (Cu-Ni and Co-Ni) catalysts supported on mesoporous SBA-15. The effect of catalyst method on steam gasification efficiency of each catalyst was investigated using incipient wetness impregnation, deposition precipitation, and ethylenediaminetetraacetic acid metal complex impregnation methods. H2-TPR confirmed the synergistic interaction of the dopants (Co and Cu) and Ni. Furthermore, XRD and HR-TEM revealed that the size of the Ni particle varied depending on the method of catalyst synthesis, confirming the formation of solid solutions in Co- or Cu-doped Ni/SBA-15 catalysts due to dopant insertion into the Ni. Notably, the exceptional activity of the Cu-Ni/SBA-15-EMC catalyst in FW steam gasification was attributed to the fine distribution of the concise Ni nanoparticles (9 nm), which resulted in the highest hydrogen selectivity (62 vol%), gas yield (73.6 wt%). Likewise, Cu-Ni solid solution decreased coke to 0.08 wt%.
  11. Oh S, Lee J, Lam SS, Kwon EE, Ha JM, Tsang DCW, et al.
    Bioresour Technol, 2021 Dec;342:126067.
    PMID: 34601023 DOI: 10.1016/j.biortech.2021.126067
    Recent studies show that fast hydropyrolysis (i.e., pyrolysis under hydrogen atmosphere operating at a rapid heating rate) is a promising technology for the conversion of biomass into liquid fuels (e.g., bio-oil and C4+ hydrocarbons). This pyrolysis approach is reported to be more effective than conventional fast pyrolysis in producing aromatic hydrocarbons and also lowering the oxygen content of the bio-oil obtained compared to hydrodeoxygenation (a common bio-oil upgrading method). Based on current literature, various non-catalytic and catalytic fast hydropyrolysis processes are reviewed and discussed. Efforts to combine fast hydropyrolysis and hydrotreatment process are also highlighted. Points to be considered for future research into fast hydropyrolysis and pending challenges are also discussed.
  12. Seo J, Kim H, Jeon S, Valizadeh S, Khani Y, Jeon BH, et al.
    Bioresour Technol, 2023 Apr;373:128702.
    PMID: 36740100 DOI: 10.1016/j.biortech.2023.128702
    Air gasification of the Wood-Plastic Composite (WPC) was performed over Ni-loaded HZSM-5 catalysts to generate H2-rich gas. Increasing SiO2/Al2O3 ratio (SAR) of HZSM-5 adversely affected catalytic activity, where the highest gas yield (51.38 wt%) and H2 selectivity (27.01 vol%) were acquired using 20 %Ni/HZSM-5(30) than those produced over 20 %Ni/HZSM-5(80) and 20 %Ni/HZSM-5(280). Reducing SAR was also favorably conducive to increasing the acyclic at the expense of cyclic compounds in oil products. These phenomena are attributed to enhanced acid strength and Ni dispersion of 20 %Ni/HZSM-5(30) catalyst. Moreover, catalytic activity in the terms of gas yield and H2 selectivity enhanced with growing Ni loading to 20 %. Also, the addition of promoters (Cu and Ca) to 20 %Ni/HZSM-5(30) boosted the catalytic efficiency for H2-rich gas generation. Raising temperature indicated a positive relevance with the gas yield and H2 selectivity. WPC valorization via gasification technology would be an outstanding outlook in the terms of a waste-to-energy platform.
  13. Valizadeh S, Khani Y, Farooq A, Kumar G, Show PL, Chen WH, et al.
    Bioresour Technol, 2023 Jan 18;372:128638.
    PMID: 36669624 DOI: 10.1016/j.biortech.2023.128638
    Steam gasification of microalgae upon perovskite oxide-supported nickel (Ni) catalysts was carried out for H2-rich gas production. Ni-perovskite oxide catalysts with partial substitution of B in perovskite structures (Ni/CaZrO3, Ni/Ca(Zr0.8Ti0.2)O3, and Ni/Ca(Zr0.6Ti0.4)O3) were synthesized and compared with those of the Ni/Al2O3 catalyst. The perovskite oxide supports improved Ni dispersion by reducing the particle size and strengthening the Ni-support interaction. Higher gas yields and H2 selectivity were obtained using Ni-perovskite oxide catalysts rather than Ni/Al2O3. In particular, Ni/Ca(Zr0.8Ti0.2)O3 showed the highest activity and selectivity for H2 production because of the synergetic effect of metallic Ni and elements present in the perovskite structures caused by high catalytic activity coupled with enhanced oxygen mobility. Moreover, increasing the temperature promoted the yield of gas and H2 content. Overall, considering the outstanding advantages of perovskite oxides as supports for Ni catalysts is a promising prospect for H2 production via gasification technology.
  14. Zhang C, Ho SH, Chen WH, Wang R, Show PL, Ong HC
    J Biotechnol, 2021 Sep 10;338:81-90.
    PMID: 34298023 DOI: 10.1016/j.jbiotec.2021.07.009
    Microalgae are a promising feedstock for carbon-neutral biofuel production due to their superior cellular composition. Alternatively, oxidative torrefaction has been recognized as a potential thermochemical technique for microalgal solid biofuel upgrading. Herein, by using microalga N. oceanica as a feedstock, several characterizations are adopted for evaluating the potential of oxidative torrefaction towards microalgal solid biofuel production. The oxidatively torrefied microalgae can be upgraded as lignite. After in-depth analysis, significant change in the surface microstructure of oxidatively torrefied microalgae is largely changed (via wrinkle and fragmentation) The hydrophobicity, thermal decomposition, thermal stability, and aromatization of oxidatively torrefied microalgae can be largely enhanced as the oxidative torrefaction severity increase. With the increasing torrefaction temperature, the hydrophobicity of oxidative torrefied microalgae gradually improved. The decomposition of C-2/3/5, and -OCH3, the CO bonds of CH3CO-, and the aromatization occurs via oxidative torrefaction according to the NMR analysis. For XPS analysis, torrefaction operation significantly decreases the carbide carbon and enhances the graphitization. As a result, the thermal stability of oxidatively torrefied microalgae is improved. Conclusively, the information obtained in this study can provide insights into the evaluation of oxidative torrefaction performance and fuel properties of microalgal solid biofuel, which may help accelerate the advancement of oxidative torrefaction industrialization.
  15. Chen WH, Hsu HJ, Kumar G, Budzianowski WM, Ong HC
    Bioresour Technol, 2017 Dec;246:12-19.
    PMID: 28803060 DOI: 10.1016/j.biortech.2017.07.184
    This study focuses on the biochar formation and torrefaction performance of sugarcane bagasse, and they are predicted using the bilinear interpolation (BLI), inverse distance weighting (IDW) interpolation, and regression analysis. It is found that the biomass torrefied at 275°C for 60min or at 300°C for 30min or longer is appropriate to produce biochar as alternative fuel to coal with low carbon footprint, but the energy yield from the torrefaction at 300°C is too low. From the biochar yield, enhancement factor of HHV, and energy yield, the results suggest that the three methods are all feasible for predicting the performance, especially for the enhancement factor. The power parameter of unity in the IDW method provides the best predictions and the error is below 5%. The second order in regression analysis gives a more reasonable approach than the first order, and is recommended for the predictions.
  16. Lee XJ, Ong HC, Ooi J, Yu KL, Tham TC, Chen WH, et al.
    J Hazard Mater, 2022 Feb 05;423(Pt A):126921.
    PMID: 34523506 DOI: 10.1016/j.jhazmat.2021.126921
    Colourants, micropollutants and heavy metals are regarded as the most notorious hazardous contaminants found in rivers, oceans and sewage treatment plants, with detrimental impacts on human health and environment. In recent development, algal biomass showed great potential for the synthesis of engineered algal adsorbents suitable for the adsorptive management of various pollutants. This review presents comprehensive investigations on the engineered synthesis routes focusing mainly on mechanical, thermochemical and activation processes to produce algal adsorbents. The adsorptive performances of engineered algal adsorbents are assessed in accordance with different categories of hazardous pollutants as well as in terms of their experimental and modelled adsorption capacities. Due to the unique physicochemical properties of macroalgae and microalgae in their adsorbent forms, the adsorption of hazardous pollutants was found to be highly effective, which involved different mechanisms such as physisorption, chemisorption, ion-exchange, complexation and others depending on the types of pollutants. Overall, both macroalgae and microalgae not only can be tailored into different forms of adsorbents based on the applications, their adsorption capacities are also far more superior compared to the conventional adsorbents.
  17. Su G, Ong HC, Gan YY, Chen WH, Chong CT, Ok YS
    Bioresour Technol, 2022 Jan;344(Pt B):126096.
    PMID: 34626763 DOI: 10.1016/j.biortech.2021.126096
    Microalgae are the most prospective raw materials for the production of biofuels, pyrolysis is an effective method to convert biomass into bioenergy. However, biofuels derived from the pyrolysis of microalgae exhibit poor fuel properties due to high content of moisture and protein. Co-pyrolysis is a simple and efficient method to produce high-quality bio-oil from two or more materials. Tires, plastics, and bamboo waste are the optimal co-feedstocks based on the improvement of yield and quality of bio-oil. Moreover, adding catalysts, especially CaO and Cu/HZSM-5, can enhance the quality of bio-oil by increasing aromatics content and decreasing oxygenated and nitrogenous compounds. Consequently, this paper provides a critical review of the production of bio-oil from co-pyrolysis of microalgae with other biomass wastes. Meanwhile, the underlying mechanism of synergistic effects and the catalytic effect on co-pyrolysis are discussed. Finally, the economic viability and prospects of microalgae co-pyrolysis are summarized.
  18. Dharmaraj S, Ashokkumar V, Pandiyan R, Halimatul Munawaroh HS, Chew KW, Chen WH, et al.
    Chemosphere, 2021 Jul;275:130092.
    PMID: 33984908 DOI: 10.1016/j.chemosphere.2021.130092
    COVID-19 has led to the enormous rise of medical wastes throughout the world, and these have mainly been generated from hospitals, clinics, and other healthcare establishments. This creates an additional challenge in medical waste management, particularly in developing countries. Improper managing of medical waste may have serious public health issues and a significant impact on the environment. There are currently three disinfection technologies, namely incineration, chemical and physical processes, that are available to treat COVID-19 medical waste (CMW). This study focuses on thermochemical process, particularly pyrolysis process to treat the medical waste. Pyrolysis is a process that utilizes the thermal instability of organic components in medical waste to convert them into valuable products. Besides, the technique is environmentally friendly, more efficient and cost-effective, requires less landfill capacity, and causes lower pollution. The current pandemic situation generates a large amount of plastic medical wastes, which mainly consists of polyethylene, polypropylene, polystyrene, polyethylene terephthalate, and nylon. These plastic wastes can be converted into valuable energy products like oil, gas and char through pyrolysis process. This review provides detailed information about CMW handling, treatment, valuable product generation, and proper discharge into the open environment.
  19. Zhang C, Chen WH, Ho SH, Zhang Y, Lim S
    Bioresour Technol, 2023 Oct;386:129531.
    PMID: 37473787 DOI: 10.1016/j.biortech.2023.129531
    This study performs the comparative advantage analysis of oxidative torrefaction of corn stalks to investigate the advantages of oxidative torrefaction for biochar fuel property upgrading. The obtained results indicate that oxidative torrefaction is more efficient in realizing mass loss and energy density improvement, as well as elemental carbon accumulation and surface functional groups removal, and thus leads to a better fuel property. The maximum values of relative mass loss, higher heating value, enhancement factor, and energy yield are 3.00, 1.10, 1.03, and 0.87, respectively. The relative elemental carbon, hydrogen, and oxygen content ranges are 1.30-3.10, 1.50-3.30, and 2.00-6.80, respectively. In addition, an excellent linear distribution is obtained between the comprehensive pyrolysis index and torrefaction severity index, with elemental carbon and oxygen component variation stemming from pyrolysis performance correlating to the elemental component and valance.
  20. Chen WH, Chang CM, Mutuku JK, Lam SS, Lee WJ
    Environ Res, 2021 06;197:110975.
    PMID: 33689824 DOI: 10.1016/j.envres.2021.110975
    The deposition phenomenon of microparticle and SAR-CoV-2 laced bioaerosol in human airways is studied by Taguchi methods and response surface methodology (RSM). The data used herein is obtained from simulations of airflow dynamics and deposition fractions of drug particle aerosols in the downstream airways of asthma patients using computational fluid dynamics (CFD) and discrete particle motion (DPM). Three main parameters, including airflow rate, drug dose, and particle size, affecting aerosol deposition in the lungs of asthma patients are examined. The highest deposition fraction (DF) is obtained at the flow rate of 45 L min-1, the drug dose of 200 μg·puff-1, and the particle diameter of 5 μm. The optimized combination of levels for the three parameters for maximum drug deposition is performed via the Taguchi method. The importance of the influencing factors rank as particle size > drug dose > flow rate. RSM reveals that the combination of 30 L min-1, 5 μm, 200 μg·puff- has the highest deposition fraction. In part, this research also studied the deposition of bioaerosols contaminated with the SAR-CoV-2 virus, and their lowest DF is 1.15%. The low DF of bioaerosols reduces the probability of the SAR-CoV-2 virus transmission.
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