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Fulltext Structural, Electromagnetic and Microwave Properties of Magnetite Extracted from Mill Scale Waste via Conventional Ball Milling and Mechanical Alloying Techniques

Elmahaishi MF, Azis RS, Ismail I, Mustaffa MS, Abbas Z, Matori KA, et al.

Materials (Basel), 2021 Nov 22;14(22).
PMID: 34832475 DOI: 10.3390/ma14227075

This study presents the utilization of mill scale waste, which has attracted much attention due to its high content of magnetite (Fe3O4). This work focuses on the extraction of Fe3O4 from mill scale waste via magnetic separation, and ball milling was used to fabricate a microwave absorber. The extracted magnetic powder was ground-milled using two different techniques: (i) a conventional milling technique (CM) and (ii) mechanical alloying (MM) process. The Fe3O4/CM samples were prepared by a conventional milling process using steel pot ball milling, while the Fe3O4/MM samples were prepared using a high-energy ball milling (HEBM) method. The effect of milling time on the structural, phase composition, and electromagnetic properties were examined using X-ray diffraction (XRD) and a vector network analyzer (VNA). XRD confirmed the formation of magnetite after both the magnetic separation and milling processes. The results revealed that Fe3O4 exhibited excellent microwave absorption properties because of the synergistic characteristics of its dielectric and magnetic loss. The results showed that the Fe3O4/CM particle powder had a greater absorption power (reflection loss:
Fulltext Effects of Petroleum-Based Oils as Dispersing Aids on Physicochemical Characteristics of Magnetorheological Elastomers

Muhammad Zaki N, Yunus NA, Yusoff MS, Mazlan SA, Abdul Aziz SA, Izni NA, et al.

Materials (Basel), 2021 Nov 19;14(22).
PMID: 34832425 DOI: 10.3390/ma14227026

This paper investigated the effects of petroleum-based oils (PBOs) as a dispersing aid on the physicochemical characteristics of natural rubber (NR)-based magnetorheological elastomers (MREs). The addition of PBOs was expected to overcome the low performance of magnetorheological (MR) elastomers due to their inhomogeneous dispersion and the mobility of magnetic particles within the elastomer matrix. The NR-based MREs were firstly fabricated by mixing the NR compounds homogeneously with different ratios of naphthenic oil (NO), light mineral oil (LMO), and paraffin oil (PO) to aromatic oil (AO), with weight percentage ratios of 100:0, 70:30, 50:50, and 30:70, respectively. From the obtained results, the ratios of NO mixed with low amounts of AO improved the material physicochemical characteristics, such as thermal properties. Meanwhile, LMO mixed the AO led to the best results for curing characteristics, microstructure observation, and magnetic properties of the MREs. We found that the LMO mixed with a high content of AO could provide good compatibility between the rubber molecular and magnetic particles due to similar chemical structures, which apparently enhance the physicochemical characteristics of MREs. In conclusion, the 30:70 ratio of LMO:AO is considered the preferable dispersing aid for MREs due to structural compounds present in the oil that enhance the physicochemical characteristics of the NR-based MREs.
Fulltext Structural and Optical Modifications in the BaO-ZnO-LiF-B2O3-Yb2O3 Glass System after γ-Irradiation

Prabhu NS, Somashekarappa HM, Sayyed MI, Osman H, Alamri S, Khandaker MU, et al.

Materials (Basel), 2021 Nov 17;14(22).
PMID: 34832355 DOI: 10.3390/ma14226955

A Yb3+-doped borate glass system was examined for the structural and optical modifications after γ-irradiation. Among the studied 10BaO-20ZnO-20LiF-(50-x)B2O3-xYb2O3 (x = 0.1, 0.5, 0.7, and 1.0 mol%) glasses, the 10BaO-20ZnO-20LiF-49.9B2O3-0.1Yb2O3 glass showed the highest thermoluminescence intensity, trap density, and trap depth. The glass was irradiated with the optimum γ-dose of 1 kGy towards the analysis of radiation-induced defects. The amorphous nature was preserved before and after irradiation. The glass density slightly increased after irradiation. The structural rearrangement was evident from the Fourier transform infrared spectroscopy by the appearance and disappearance of some bonds after γ-irradiation. The transformation of [BO4] units into [BO3] units and non-bridging oxygens was deduced. The color of the glass darkened after irradiation and the optical absorption intensity enhanced between 250 and 700 nm. The optical bandgap reduced and Urbach energy increased upon γ-dose exposure. The electron spin resonance of the irradiated glass exhibited two signals at g = 2.0167 and g = 1.9938, corresponding to the non-bridging oxygen hole center and Boron E'-center, respectively.
Fulltext Push-Out Bond Strength of Resin-Modified Glass Ionomer Cement and Flowable Composite Luting Systems on Glass Fiber Post of Root Canal

Cheruvathoor JJ, Thomas LR, Thomas LA, Shivanna MM, Machani P, Naik S, et al.

Materials (Basel), 2021 Nov 16;14(22).
PMID: 34832308 DOI: 10.3390/ma14226908

BACKGROUND: Posts that have been properly fitted can withstand torsion forces and so provide better retention. The push-out bonding strength of glass fiber posts to the root canal was evaluated using resin-modified glass ionomer cement (RMGIC) and flowable composite (FC).
METHOD: Forty single-rooted maxillary central incisors were used in the study. The samples were randomly divided into two groups of 20 teeth each. The crown-down procedure was used to clean and shape the pulp area. A Tenax fiber trans Coltene whaletene post was used by both groups. The first group utilized FC (Filtek Z 350 3M ESPE) to coat the post, whereas the second group used RMGIC (Rely X 3M ESPE). The specimens were cross-sectioned after 24 h. Specimens were cross-sectioned four millimeters thick into coronal and middle parts using a sectioning machine, yielding 40 specimens per group. The strength of the bond between the luting cement and the posts was measured using push-out bond strength testing. We loaded the components at a cross speed of 0.5 mm/min on a universal testing machine until the bond failed.
RESULTS: The FC group had a 4.80 N push-out bond strength, whereas the RMGIC group had a 7.11 N push-out bond strength.
CONCLUSION: FC's mean push-out bond strength score is lower than RMGIC's.
Fulltext Mechanical and Microstructural Characterization of Quarry Rock Dust Incorporated Steel Fiber Reinforced Geopolymer Concrete and Residual Properties after Exposure to Elevated Temperatures

Ibraheem M, Butt F, Waqas RM, Hussain K, Tufail RF, Ahmad N, et al.

Materials (Basel), 2021 Nov 15;14(22).
PMID: 34832298 DOI: 10.3390/ma14226890

The purpose of this research is to study the effects of quarry rock dust (QRD) and steel fibers (SF) inclusion on the fresh, mechanical, and microstructural properties of fly ash (FA) and ground granulated blast furnace slag (SG)-based geopolymer concrete (GPC) exposed to elevated temperatures. Such types of ternary mixes were prepared by blending waste materials from different industries, including QRD, SG, and FA, with alkaline activator solutions. The multiphysical models show that the inclusion of steel fibers and binders can enhance the mechanical properties of GPC. In this study, a total of 18 different mix proportions were designed with different proportions of QRD (0%, 5%, 10%, 15%, and 20%) and steel fibers (0.75% and 1.5%). The slag was replaced by different proportions of QRD in fly ash, and SG-based GPC mixes to study the effect of QRD incorporation. The mechanical properties of specimens, i.e., compressive strength, splitting tensile strength, and flexural strength, were determined by testing cubes, cylinders, and prisms, respectively, at different ages (7, 28, and 56 days). The specimens were also heated up to 800 °C to evaluate the resistance of specimens to elevated temperature in terms of residual compressive strength and weight loss. The test results showed that the mechanical strength of GPC mixes (without steel fibers) increased by 6-11%, with an increase in QRD content up to 15% at the age of 28 days. In contrast, more than 15% of QRD contents resulted in decreasing the mechanical strength properties. Incorporating steel fibers in a fraction of 0.75% by volume increased the compressive, tensile, and flexural strength of GPC mixes by 15%, 23%, and 34%, respectively. However, further addition of steel fibers at 1.5% by volume lowered the mechanical strength properties. The optimal mixture of QRD incorporated FA-SG-based GPC (QFS-GPC) was observed with 15% QRD and 0.75% steel fibers contents considering the performance in workability and mechanical properties. The results also showed that under elevated temperatures up to 800 °C, the weight loss of QFS-GPC specimens persistently increased with a consistent decrease in the residual compressive strength for increasing QRD content and temperature. Furthermore, the microstructure characterization of QRD blended GPC mixes were also carried out by performing scanning electron microscopy (SEM), X-ray diffraction (XRD), and energy dispersive spectroscopy (EDS).
Fulltext Behavior of Alkali-Activated Fly Ash through Underwater Placement

Yahya Z, Abdullah MMAB, Li LY, Burduhos Nergis DD, Hakimi MAAZ, Sandu AV, et al.

Materials (Basel), 2021 Nov 14;14(22).
PMID: 34832267 DOI: 10.3390/ma14226865

Underwater concrete is a cohesive self-consolidated concrete used for concreting underwater structures such as bridge piers. Conventional concrete used anti-washout admixture (AWA) to form a high-viscosity underwater concrete to minimise the dispersion of concrete material into the surrounding water. The reduction of quality for conventional concrete is mainly due to the washing out of cement and fine particles upon casting in the water. This research focused on the detailed investigations into the setting time, washout effect, compressive strength, and chemical composition analysis of alkali-activated fly ash (AAFA) paste through underwater placement in seawater and freshwater. Class C fly ash as source materials, sodium silicate, and sodium hydroxide solution as alkaline activator were used for this study. Specimens produced through underwater placement in seawater showed impressive performance with strength 71.10 MPa on 28 days. According to the Standard of the Japan Society of Civil Engineers (JSCE), the strength of specimens for underwater placement must not be lower than 80% of the specimen's strength prepared in dry conditions. As result, the AAFA specimens only showed 12.11% reduction in strength compared to the specimen prepared in dry conditions, thus proving that AAFA paste has high potential to be applied in seawater and freshwater applications.
Fulltext Tin Whiskers' Behavior under Stress Load and the Mitigation Method for Immersion Tin Surface Finish

Fadil NA, Yusof SZ, Abu Bakar TA, Ghazali H, Mat Yajid MA, Osman SA, et al.

Materials (Basel), 2021 Nov 11;14(22).
PMID: 34832218 DOI: 10.3390/ma14226817

Since the use of the most stable Pb-based materials in the electronic industry has been banned due to human health concerns, numerous research studies have focused on Pb-free materials such as pure tin and its alloys for electronic applications. Pure tin, however, suffers from tin whiskers' formation, which tends to endanger the efficiency of electronic circuits, and even worse, may cause short circuits to the electronic components. This research aims to investigate the effects of stress on tin whiskers' formation and growth and the mitigation method for the immersion of the tin surface's finish deposited on a copper substrate. The coated surface was subjected to external stress by micro-hardness indenters with a 2N load in order to simulate external stress applied to the coating layer, prior to storage in the humidity chamber with environmental conditions of 30 °C/60% RH up to 52 weeks. A nickel underlayer was deposited between the tin surface finish and copper substrate to mitigate the formation and growth of tin whiskers. FESEM was used to observe the whiskers and EDX was used for measuring the chemical composition of the surface finish, tin whiskers, and oxides formed after a certain period of storage. An image analyzer was used to measure the whiskers' length using the JEDEC Standard (JESD22-A121A). The results showed that the tin whiskers increased directly proportional to the storage time, and they formed and grew longer on the thicker tin coating (2.3 μm) than the thin coating (1.5 μm). This is due to greater internal stress being generated by the thicker intermetallic compounds identified as the Cu5Sn6 phase, formed on a thicker tin coating. In addition, the formation and growth of CuO flowers on the 1.5 μm-thick tin coating suppressed the growth of tin whiskers. However, the addition of external stress by an indentation on the tin coating surface showed that the tin whiskers' growth discontinued after week 4 in the indented area. Instead, the whiskers that formed were greater and longer at a distance farther from the indented area due to Sn atom migration from a high stress concentration to a lower stress concentration. Nonetheless, the length of the whisker for the indented surface was shorter than the non-indented surface because the whiskers' growth was suppressed by the formation of CuO flowers. On the other hand, a nickel underlayer successfully mitigated the formation of tin whiskers upon the immersion of a tin surface finish.
Fulltext The Effect of Solid-State Processes and Heat Treatment on the Properties of AA7075 Aluminum Waste Recycling Nanocomposite

Sabbar HM, Leman Z, Shamsudin S, Tahir SM, Jaafar CNA, Ariff AHM, et al.

Materials (Basel), 2021 Nov 05;14(21).
PMID: 34772193 DOI: 10.3390/ma14216667

Direct solid-states, such as hot extrusion and equal channel angular pressing (ECAP), are alternative and efficient solid-state processes for use in recycling aluminium scrap. These processes utilise less energy and are eco-friendly. Ceramic particles such as ZrO2 are suggested as alternatives in the production of metal composites. This study investigated and optimised the effects of various parameters of reinforced ZrO2 nanoparticles on the mechanical and physical properties via response surface methodology (RSM). These parameters were the volume fraction (VF), preheating temperature (T), and preheating time (t). The effects of these parameters were examined before and after the heat treatment condition and ECAP. Each parameter was evaluated at varying magnitudes, i.e., 450, 500, and 550 °C for T, 1, 2, and 3 h for t, and 1, 3, and 5% for VF. The effect that process variables had on responses was elucidated using the factorial design with centre point analysis. T and VF were crucial for attaining the optimum ultimate tensile strength (UTS) and microhardness. Reducing VF increased the mechanical properties to 1 vol% of oxide. The maximum hardness of 95 HV was attained at 550 °C, 1.6 h, and 1 vol% ZrO2 with a density of 2.85 g/cm3 and tensile strength of 487 MPa. UTS, density, and microhardness were enhanced by 14%, 1%, and 9.5%, respectively. Additionally, the hot extrusion parameters and ECAP followed by heat treatment strengthened the microhardness by 64% and density by 3%. Compression pressure and extrusion stress produced in these stages were sufficient to eliminate voids that increased the mechanical properties.
Fulltext Adoption of the Wet Surface Treatment Technique for the Improvement of Device Performance of Enhancement-Mode AlGaN/GaN MOSHEMTs for Millimeter-Wave Applications

Wang C, Chen YC, Hsu HT, Tsao YF, Lin YC, Dee CF, et al.

Materials (Basel), 2021 Nov 01;14(21).
PMID: 34772078 DOI: 10.3390/ma14216558

In this work, a low-power plasma oxidation surface treatment followed by Al2O3 gate dielectric deposition technique is adopted to improve device performance of the enhancement-mode (E-mode) AlGaN/GaN metal-oxide-semiconductor high-electron-mobility transistors (MOSHEMTs) intended for applications at millimeter-wave frequencies. The fabricated device exhibited a threshold voltage (Vth) of 0.13 V and a maximum transconductance (gm) of 484 (mS/mm). At 38 GHz, an output power density of 3.22 W/mm with a power-added efficiency (PAE) of 34.83% were achieved. Such superior performance was mainly attributed to the high-quality Al2O3 layer with a smooth surface which also suppressed the current collapse phenomenon.
Fulltext Understanding the Effect of Introducing Micro- and Nanoparticle Bismuth Oxide (Bi2O3) on the Gamma Ray Shielding Performance of Novel Concrete

El-Nahal MA, Elsafi M, Sayyed MI, Khandaker MU, Osman H, Elesawy BH, et al.

Materials (Basel), 2021 Oct 28;14(21).
PMID: 34772013 DOI: 10.3390/ma14216487

The aim of this study is to investigate the radiation shielding properties of novel concrete samples with bulk Bi2O3 and Bi2O3 nanoparticles (Bi2O3 NP) incorporated into its composition. The mass attenuation coefficient of the concrete samples without Bi2O3 and with 5 and 7 wt% bulk Bi2O3 were experimentally determined and were compared against values obtained using the XCOM and Geant4 simulations. Both methods greatly agree with the experimental values. The linear attenuation coefficients (LAC) of blank concrete (C-0), concrete with 5% bulk Bi2O3 (C-B5), and concrete with 5% nanoparticle Bi2O3 (C-N5) were determined and compared at a wide energy range. We found that the LAC follows the trend of C-0 < C-B5 < C-N5 at all the tested energies. Since both C-B5 and C-N5 have a greater LAC than C-0, these results indicate that the addition of Bi2O3 improves the shielding ability of the concretes. In addition, we investigated the influence of nanoparticle Bi2O3 on the LAC of the concretes. The half-value layer (HVL) for the concretes with bulk Bi2O3 and Bi2O3 nanoparticles is also investigated. At all energies, the C-0 has the greatest HVL, while C-N15 has the least. Thus, C-N15 concrete is the most space efficient, while C-0 is the least space efficient. The radiation protection efficiency (RPE) of the prepared concretes was found to decrease with increasing energy for all five samples. For C-0, the RPE decreased from 63.3% at 0.060 MeV to 13.48% at 1.408 MeV, while for C-N15, the RPE decreased from 87.9 to 15.09% for the same respective energies. Additionally, C-N5 had a greater RPE than C-B5, this result demonstrates that Bi2O3 NP are more efficient at shielding radiation than bulk Bi2O3.
Fulltext Deposition, Characterization, and Modeling of Scandium-Doped Aluminum Nitride Thin Film for Piezoelectric Devices

Zhang Q, Chen M, Liu H, Zhao X, Qin X, Wang F, et al.

Materials (Basel), 2021 Oct 27;14(21).
PMID: 34771961 DOI: 10.3390/ma14216437

In this work, we systematically studied the deposition, characterization, and crystal structure modeling of ScAlN thin film. Measurements of the piezoelectric device's relevant material properties, such as crystal structure, crystallographic orientation, and piezoelectric response, were performed to characterize the Sc0.29Al0.71N thin film grown using pulsed DC magnetron sputtering. Crystal structure modeling of the ScAlN thin film is proposed and validated, and the structure-property relations are discussed. The investigation results indicated that the sputtered thin film using seed layer technique had a good crystalline quality and a clear grain boundary. In addition, the effective piezoelectric coefficient d33 was up to 12.6 pC/N, and there was no wurtzite-to-rocksalt phase transition under high pressure. These good features demonstrated that the sputtered ScAlN is promising for application in high-coupling piezoelectric devices with high-pressure stability.
Fulltext Declining Performance of Silicone-Based Magnetorheological Elastomers after Accelerated Weathering

Wibowo W, Lenggana BW, Ubaidillah U, Ariawan D, Imaduddin F, Mazlan SA, et al.

Materials (Basel), 2021 Oct 25;14(21).
PMID: 34771915 DOI: 10.3390/ma14216389

Magnetorheological elastomers (MRE)-based products are usually located in an area directly exposed to sunlight and rain. However, there is no specific research on the behavior of MRE after accelerated weathering. Therefore, in this study, the changes to the chemical and rheological properties of both isotropic and anisotropic MRE after accelerated weathering were examined. Treated and untreated specimens were compared. MRE specimens with 40% by weight CIP were prepared with no current excitation and another sample was prepared with 1.5 T of magnetic flux density. Each specimen was treated in an accelerated weathering machine, Q-Sun Xe-1 Xenon Test Chamber, under a UV light exposure cycle and water spray. A material characterization was carried out using FTIR and a rheometer to determine the changes to the chemical and rheological properties. The morphological analysis results showed that after the weather treatment, the surface was rough and more cavities occurred. The rheometer test results showed a significant decrease in the storage modulus of each treated MRE specimen, unlike the untreated MRE specimens. The decrease in the storage modulus value with currents of 0, 1, 2, and 3 Amperes was 66.67%, 78.9%, 85.2%, and 80.5%, respectively. Meanwhile, FTIR testing showed a change in the wave peak between the untreated and treated MRE specimens. Thermogravimetric analysis (TGA) also showed a decrease in MRE weight for each specimen. However, for both treated and untreated MRE specimens, the decrease in TGA was not significantly different. In all the tests carried out on the MRE samples, weather acceleration treatment caused significant changes. This is an important consideration for developers who choose silicone as the MRE matrix.
Fulltext Muntingia calabura Leaves Mediated Green Synthesis of CuO Nanorods: Exploiting Phytochemicals for Unique Morphology

Selvanathan V, Aminuzzaman M, Tey LH, Razali SA, Althubeiti K, Alkhammash HI, et al.

Materials (Basel), 2021 Oct 25;14(21).
PMID: 34771914 DOI: 10.3390/ma14216379

In this study, phytochemical assisted nanoparticle synthesis was performed using Muntingia calabura leaf extracts to produce copper oxide nanoparticles (CuO NPs) with interesting morphology. Scanning electron microscope (SEM) and transmission electron microscope (TEM) analysis of the biosynthesized CuO NPs reveal formation of distinct, homogeneous, and uniform sized CuO nanorods structure with thickness and length of around 23 nm and 79 nm, respectively. Based on Fourier-transform infrared (FTIR) analysis, the unique combinations of secondary metabolites such as flavonoid and polyphenols in the plant extract are deduced to be effective capping agents to produce nanoparticles with unique morphologies similar to conventional chemical synthesis. X-ray diffraction (XRD) analysis verified the monoclinical, crystalline structure of the CuO NPs. The phase purity and chemical identity of the product was consolidated via X-Ray photoelectron spectroscopy (XPS) and Raman spectroscopic data which indicate the formation of a single phase CuO without the presence of other impurities. The direct and indirect optical band gap energies of the CuO nanorods were recorded to be 3.65 eV and 1.42 eV.
Fulltext Flexural Strength of Internally Stiffened Tubular Steel Beam Filled with Recycled Concrete Materials

Al Zand AW, Ali MM, Al-Ameri R, Badaruzzaman WHW, Tawfeeq WM, Hosseinpour E, et al.

Materials (Basel), 2021 Oct 23;14(21).
PMID: 34771860 DOI: 10.3390/ma14216334

The flexural strength of Slender steel tube sections is known to achieve significant improvements upon being filled with concrete material; however, this section is more likely to fail due to buckling under compression stresses. This study investigates the flexural behavior of a Slender steel tube beam that was produced by connecting two pieces of C-sections and was filled with recycled-aggregate concrete materials (CFST beam). The C-section's lips behaved as internal stiffeners for the CFST beam's cross-section. A static flexural test was conducted on five large scale specimens, including one specimen that was tested without concrete material (hollow specimen). The ABAQUS software was also employed for the simulation and non-linear analysis of an additional 20 CFST models in order to further investigate the effects of varied parameters that were not tested experimentally. The numerical model was able to adequately verify the flexural behavior and failure mode of the corresponding tested specimen, with an overestimation of the flexural strength capacity of about 3.1%. Generally, the study confirmed the validity of using the tubular C-sections in the CFST beam concept, and their lips (internal stiffeners) led to significant improvements in the flexural strength, stiffness, and energy absorption index. Moreover, a new analytical method was developed to specifically predict the bending (flexural) strength capacity of the internally stiffened CFST beams with steel stiffeners, which was well-aligned with the results derived from the current investigation and with those obtained by others.
Fulltext Optimized Rivastigmine Nanoparticles Coated with Eudragit for Intranasal Application to Brain Delivery: Evaluation and Nasal Ciliotoxicity Studies

Bhanderi M, Shah J, Gorain B, Nair AB, Jacob S, Asdaq SMB, et al.

Materials (Basel), 2021 Oct 22;14(21).
PMID: 34771817 DOI: 10.3390/ma14216291

Rivastigmine, a reversible cholinesterase inhibitor, is frequently indicated in the management of demented conditions associated with Alzheimer disease. The major hurdle of delivering this drug through the oral route is its poor bioavailability, which prompted the development of novel delivery approaches for improved efficacy. Due to numerous beneficial properties associated with nanocarriers in the drug delivery system, rivastigmine nanoparticles were fabricated to be administer through the intranasal route. During the development of the nanoparticles, preliminary optimization of processing and formulation parameters was done by the design of an experimental approach. The drug-polymer ratio, stirrer speed, and crosslinking time were fixed as independent variables, to analyze the effect on the entrapment efficiency (% EE) and in vitro drug release of the drug. The formulation (D8) obtained from 23 full factorial designs was further coated using Eudragit EPO to extend the release pattern of the entrapped drug. Furthermore, the 1:1 ratio of core to polymer depicted spherical particle size of ~175 nm, % EE of 64.83%, 97.59% cumulative drug release, and higher flux (40.39 ± 3.52 µg.h/cm2). Finally, the intranasal ciliotoxicity study on sheep nasal mucosa revealed that the exposure of developed nanoparticles was similar to the negative control group, while destruction of normal architecture was noticed in the positive control test group. Overall, from the in vitro results it could be summarized that the optimization of nanoparticles' formulation of rivastigmine for intranasal application would be retained at the application site for a prolonged duration to release the entrapped drug without producing any local toxicity at the mucosal region.
Fulltext Optimization of Cement-Based Mortar Containing Oily Sludge Ash by Response Surface Methodology

Kankia MU, Baloo L, Danlami N, Samahani WN, Mohammed BS, Haruna S, et al.

Materials (Basel), 2021 Oct 22;14(21).
PMID: 34771834 DOI: 10.3390/ma14216308

In the industries of petroleum extraction, a large volume of oily sludge is being generated. This waste is usually considered difficult to dispose of, causing environmental and economic issues. This study presented the novel experimental method of manufacturing mortar used in civil construction by cement and oily sludge ash (OSA). The defined method was described with a logical experimental study conducted to examine a feasible manufacturing method for casting cement-based mortars by partially replacing cement with OSA. Replacement concentrations for OSA ranged from 0 to 20 percent by cement weight, while the water-to-cement (w/c) ratio was varied from 0.4 to 0.8, and the amount of sand was kept constant. The strengths and absorption rate of the mortar were monitored for 28 days. The OSA contains a crystalline structure with packs of angular grains. Because of OSA in the cement-based mortar mixtures and water-to-cement ratios, the mechanical strength was improved significantly. However, the water absorption trend increased linearly. Using variance analysis, the influence of OSA and w/c ratio on the behavior of mortar was acquired. The developed models were significant for all p-value reactions of <5%. Numerical optimization results showed that the best mixture can be obtained by replacing 8.19 percent cement with OSA and 0.52 as a ratio of w/c.
Fulltext Detection and Quantification of Precious Elements in Astrophyllite Mineral by Optical Spectroscopy

Ahmad A, Abbasi SA, Hafeez M, Khan TM, Rafique M, Ahmed N, et al.

Materials (Basel), 2021 Oct 21;14(21).
PMID: 34771799 DOI: 10.3390/ma14216277

With many advantages over well-established methods, laser induced breakdown spectroscopy (LIBS) has emerged as a useful analytical technique for the compositional analysis of multi-elemental geological materials. In this study, LIBS was employed for qualitative and quantitative analysis of a rare mineral, astrophyllite, bearing precious elements of industrial and technological interest. The experiment was carried out using second harmonic generation of Nd:YAG laser of pulse width 5 ns and repetition rate of 10 Hz. Microplasma was produced by focusing laser beam on an astrophyllite target, and optical emissions from the generated plasma were recorded in the spectral range of 200-720 nm with the help of a LIBS2000+ detection system. On analyzing the optical spectra, existence of 15 elements in astrophyllite target were revealed. These elements include: Ti, W, Ag, Al, Ba, Ca, Cr, Cu, Fe, Li, Mg, Na, Ni, Si and H. For quantification, calibration-free method was used. Only ten elements, namely Ti, W, Fe, Cr, Cu, Ca, Mg, Ni, Si and Al, were quantified with relative weight concentrations of 55.39%, 18.79%, 18.30%, 4.05%, 2.66, 0.43%, 0.18%, 0.12%, 0.06% and 0.02%, respectively. To benchmark these results, XRF analysis was performed, which confirmed the presence of all the elements detected in the optical spectrum of the sample, except for Na, Li, and H. The concentrations of these ten elements as measured by XRF were in reasonable agreement, especially for the major elements. The presence of a significant amount of Ti and W in an astrophyllite sample, found in Pakistan, highlights the economic value of this mineral. This study may be of further interest in commissioning LIBS technology for exploration of minerals in the region.
Fulltext The Influence of Hydroxyapatite and Alumina Particles on the Mechanical Properties and Corrosion Behavior of Mg-Zn Hybrid Composites for Implants

Nazirah R, Zuhailawati H, Siti Nur Hazwani MR, Abdullah TK, Azzura I, Dhindaw BK

Materials (Basel), 2021 Oct 20;14(21).
PMID: 34771772 DOI: 10.3390/ma14216246

Considering the necessity for a biodegradable implant alloy with good biocompatibility and mechanical strength, dual ceramic particles of HAP and Al2O3 were added to Mg-Zn alloy to produce a new hybrid composite using powder metallurgy. The paper reports the mechanical and corrosion behaviour of Mg-Zn/HAP/Al2O3 hybrid composites containing variable wt.% HAP and Al2O3 with 15 wt.% total ceramic content. The powders of Mg, Zn, Al2O3 and HAP were milled in a high-energy ball mill, and then compacted under 400 MPa and sintered at 300 °C. Density and compression strength increased with increasing Al2O3 content. HAP facilitated weight gain in Hanks balanced salt solution due to deposition of an apatite layer which promoted anodic behaviour with higher corrosion resistance. A hybrid composite of Mg alloy with 5 wt.% Al2O3 and 10 wt.% HAP displayed 153 MPa compressive strength, 1.37 mm/year corrosion resistance and bioactivity with a CA:P ratio of 1:1.55 and appears to be the most promising biodegradable implant material tested.
Fulltext Strength and Acid Resistance of Ceramic-Based Self-Compacting Alkali-Activated Concrete: Optimizing and Predicting Assessment

Algaifi HA, Khan MI, Shahidan S, Fares G, Abbas YM, Huseien GF, et al.

Materials (Basel), 2021 Oct 19;14(20).
PMID: 34683800 DOI: 10.3390/ma14206208

The development of self-compacting alkali-activated concrete (SCAAC) has become a hot topic in the scientific community; however, most of the existing literature focuses on the utilization of fly ash (FA), ground blast furnace slag (GBFS), silica fume (SF), and rice husk ash (RHA) as the binder. In this study, both the experimental and theoretical assessments using response surface methodology (RSM) were taken into account to optimize and predict the optimal content of ceramic waste powder (CWP) in GBFS-based self-compacting alkali-activated concrete, thus promoting the utilization of ceramic waste in construction engineering. Based on the suggested design array from the RSM model, experimental tests were first carried out to determine the optimum CWP content to achieve reasonable compressive, tensile, and flexural strengths in the SCAAC when exposed to ambient conditions, as well as to minimize its strength loss, weight loss, and UPVL upon exposure to acid attack. Based on the results, the optimum content of CWP that satisfied both the strength and durability aspects was 31%. In particular, a reasonable reduction in the compressive strength of 16% was recorded compared to that of the control specimen (without ceramic). Meanwhile, the compressive strength loss of SCAAC when exposed to acid attack minimized to 59.17%, which was lower than that of the control specimen (74.2%). Furthermore, the developed RSM models were found to be reliable and accurate, with minimum errors (RMSE < 1.337). In addition, a strong correlation (R > 0.99, R2 < 0.99, adj. R2 < 0.98) was observed between the predicted and actual data. Moreover, the significance of the models was also proven via ANOVA, in which p-values of less than 0.001 and high F-values were recorded for all equations.
Fulltext Development and Investigation of an Inexpensive Low Frequency Vibration Platform for Enhancing the Performance of Electrical Discharge Machining Process

Mertiya AS, Upadhyay A, Nirwan K, Harane PP, Abdul-Rani AM, Pruncu CI, et al.

Materials (Basel), 2021 Oct 18;14(20).
PMID: 34683784 DOI: 10.3390/ma14206192

Difficulty in debris removal and the transport of fresh dielectric into discharge gap hinders the process performance of electrical discharge machining (EDM) process. Therefore, in this work, an economical low frequency vibration platform was developed to improve the performance of EDM through vibration assistance. The developed vibratory platform functions on an eccentric weight principle and generates a low frequency vibration in the range of 0-100 Hz. The performance of EDM was evaluated in terms of the average surface roughness (Ra), material removal rate (MRR), and tool wear rate (TWR) whilst varying the input machining parameters viz. the pulse-on-time (Ton), peak current (Ip), vibration frequency (VF), and tool rotational speed (TRS). The peak current was found to be the most significant parameter and contributed by 78.16%, 65.86%, and 59.52% to the Ra, MRR, and TWR, respectively. The low frequency work piece vibration contributed to an enhanced surface finish owing to an improved flushing at the discharge gap and debris removal. However, VF range below 100 Hz was not found to be suitable for the satisfactory improvement of the MRR and reduction of the TWR in an electrical discharge drilling operation at selected machining conditions.

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