Al/B4C composites with 0 wt.%, 5 wt.% and 10 wt.% of B4C were prepared by powder metallurgy and their properties were characterised successfully. Investigation of the effect of milling times (4, 8, 12, 16 hours) on microstructure, phase identification, hardness and neutron attenuation coefficient of composites has been studied. The results showed that hardness increased with increased of milling time, with maximum hardness obtained at 16 hours milling time. The increment is slower as the composition of B4C increased. The hardness of Al/10%B4C, Al/5%B4C and Al/0%B4C were 81.7, 78.7 and 61.2 HRB respectively. Morphology of scanning electron microscopy (SEM) showed that microstructures play important role in controlling the hardness. Meanwhile, x-ray diffraction (XRD) analysis showed the phases and crystalline present in composites with an indication that crystalline of the grain increased as the milling time increased. Neutron absorption of Al/10%B4C composites showed that this composite has the highest attenuation coefficient, thus indicating that it is the best composites for neutron shielding.
The composite polymer films of polyvinyl alcohol/polypyrrole/chloral hydrate (PVA-PPy-CH) had been prepared. Effects of J-rays on the electrical conductivity of the composite polymer films had
been investigated by using Inductance Capacitance Resistance meter (LCR) meter at a frequency
ranging from 20 Hz to 1 MHz. With the incorporation of chloral hydrate in the polymer sample, the conductivity increased indicates that it is capable to be used as dopant for polymerizing conjugated polymer. The electrical conductivity obtained increased as the dose increased, which is in the order of 10-5Scm-1 indicates that J-rays is capable to enhance the electrical conductivity of the composite polymer films. The parameter of s is in the range of 0.31 d s d 0.49 and obeyed simple power law dispersion Zs. The Scanning Electron Microscopy (SEM) micrographs reveal the formation of polypyrrole globules in polyvinyl alcohol matrix which increased as the irradiation dose was increased.
The experiment aims to investigate the effect of high energy milling to the crystallite size of α-alumina. The starting material used is α-alumina powder with starting crystal size of 86nm. This powder was milled at different time ranges from 0 to 60 minutes and milling speed ranges from 400 rpm to 1100 rpm using a wet milling technique in corundum abrasive materials. The wet milling technique involved the use of water with the alumina to water ratio of 1:6.1. Samples prepared were then examined using the X-Ray Diffraction (XRD) to calculate the crystallite size and scanning electron microscope (SEM) was also used to determine changes in the morphology. Results from these analysis showed that the crystallite size will get smaller when milling speed and time of more than 600rpm and 30 minutes respectively were used. Optimum conditions to achieve the smallest crystal size of 79.7nm are 1000 rpm and 60 minutes.
This paper investigates the effect of acid and silane treatment of Carbon Nanotubes (CNT) on wear properties of epoxy polymer composite. The wear test done was based on ASTM D3389 standard using the Abrasive Wear Tester (TR 600). Characterisation analysis was also done using Transmission Electron Microscopy (TEM) in order to study the dispersion of the CNT inside the epoxy matrix. When untreated CNT was added to the epoxy with amounts of 0.5, 0.75 and 1.0 wt%, the wear rates did not improve except for 0.5 wt% CNT filled epoxy. This was due to the lack of dispersion which causes larger chunks of material being dug out, thus contributing to a higher mass loss and wear rate. When treated with acid and silane, 0.75 wt% and 1.0 wt% CNT filled epoxy composites showed improvement. The TEM images of 0.5 wt%, 0.75 wt% and 1.0 wt% PCNT filled epoxy supported the claim of the lack of dispersion of PCNT inside the epoxy.
This paper presents a study on the effect of Arenga Pinnata fibre volume fraction on the tensile and compressive properties of Arenga Pinnata fibre reinforced epoxy composite (APREC). The composites were produced using four different Arenga Pinnata fibre volume contents, which were 10vol%, 15vol%, 20vol%, and 25vol%, in unidirectional (UD) fibre alignment. Tensile and compression tests were performed on all APREC specimens in order to investigate the effect of fibre volume fraction on modulus of elasticity, strength and strain to failure. The morphological structure of fractured specimens was observed using scanning electron microscopy (SEM) in order to evaluate the fracture mechanisms involved when the specimens were subjected to tensile or compressive loading. The results indicated that the higher the amount of Arenga Pinnata fibres, the higher the stiffness of the composites. This is shown by the increment of tensile and compressive modulus of the specimens when the fibre volume content was increased. Tensile modulus increased up to 180% when 25vol% Arenga Pinnata fibre was used in APREC compared to Pure Epoxy specimen. It can also be observed that the tensile strength of the specimens increased 28% from 53.820 MPa (for Pure Epoxy) to 68.692 MPa (for Epoxy with 25vol% APREC addition). Meanwhile, compressive modulus and strength increased up to 3.24% and 9.17%, respectively. These results suggest that the addition of Arenga Pinnata fibres significantly improved the tensile and compressive properties of APREC.
The objective of the study was to asses the adhesion of Streptococcus mutans on nanofilled and microfilled composite resin and glass ionomer cement restorative materials. Glass ionomer cements; KetacTM N100 (nanofilled) and Fuji IITM LC (microfilled) and composite resins; FiltekTM Z350 (nanofilled) and FiltekTM Z250 (microhybrid) were packed in acrylic mould of 2 mm thickness and 5 mm diameter. All samples were light-cured and polished with Sof-Lex discs. All materials were cultured with the exponential phase of S. mutans cultivation. Surface roughness values were assessed using Atomic Force Microscope (AFM, Ambios, USA) at time intervals (7hrs, 24 hrs, 7 days, 14 days and 21 days). The morphology of S. mutans on materials was observed after 24 hour incubation of S. mutan on materials under Scanning Electron Microscope (SEM, Quanta FEG 450). Within groups, results showed that both nanofilled materials had lower surface roughness and less adhesion of S. mutans compared to microfilled materials. This study would enhance the clinical knowledge especially in aesthetic area and improve the longevity of the dental restoration.
Silicon dioxide (SiO2) has been extensively studied due to their unique properties that make it desirable for many applications ranging from electronic, catalysis, pigment as well as sensors. Multitude of methods and processes are established with the ability to manipulate and control the key properties that can cater for specific applications. Stober method is a very simple and easy for up-scale production of SiO2. This paper presents the experimental study on the effect of synthesis parameter on the morphology of SiO2 synthesized via Stober method. Three parameters were investigated such as concentration of catalyst, concentration of precursor and percentage of water content. The obtained samples were characterized using scanning electron microscopy (SEM) analysis. The findings showed that the size of particles produced is dependent on the synthesis parameter. In this study, particles size ranging from 50 nm to >100 nm are easily produced. The sphere size of SiO2 can be increased by increasing the concentration of ammonia hydroxide catalyst, the concentration of TEOS, as well as the percentage of water content.
Melissopalynology (pollen analysis) allows the identification of floral sources, botanical and geographical origin of selected Kelulut honey samples. Therefore, the aim of this study is to determine the origin of selected Kelulut honey by Geniotrigona thoracica and Heterotrigona itama farmed and harvested at Lenggong (Perak). Briefly, the honey was diluted in ddH2O and filtered to obtain the pollens. Subsequently, the morphology of the pollens was observed under scanning electron microscope (SEM) and the frequency classes of species were determined. Based on qualitative and quantitative analysis, G. thoracica honey was demonstrated to be a uni-floral honey and H. Itama honey as a multi-floral honey. A total of 7 types of pollens were observed in G. thoracica honey while 9 types in H. Itama honey. Some of the pollen were identified with the aid of pollen atlas while some were unidentified. Furthermore, the results obtained in this study suggested that the pollens present in Kelulut honey are crucial in identifying botanical resource of stingless bee honey, which assist in preserving the ecosystem.
Data presented in this article focused on the application of Methyl Ester Sulphonate (MES) surfactant and nanopolystyrene in water based drilling fluid. Data from rheology study using Bingham and Power law models showed that the synergy of MES and nanopolystyrene improved the formulated drilling fluid. Filtration study under LPLT and HPHT conditions showed that MES and nanopolystyrene drilling fluid reduced filtration loss by 50.7% at LPLT and 61.1% at HPHT conditions. These filtration data were validated by filter cake permeability and scanning electron microscope images.
Siliceous mesoporous molecular sieve (Si-MCM-41) material with highly ordered hexagonal pore arrangement was synthesized at 373 K for 8-days duration by hydrothermal method, dried at 393 K and calcined at 823 K in N2 atmosphere. The calcined Si-MCM-41 was later functionalized with 10-50 wt. % monoethanolamine (MEA) by impregnation method and dried in vacuum at 343 K. The MEA-Si-MCM-41 samples were characterized for their physicochemical properties with FTIR, XRD, TGA, HRTEM, FESEM, BET and elemental analysis. XRD results showed that the intensity of the characteristic peaks of Si-MCM-41 reduces with increasing loading of MEA indicating that the MEA molecules are loaded in the pores as well as on the surface of Si-MCM-41. The appearance of FTIR peaks corresponding to N-H, C-N and C-H bonds suggested that Si-MCM-41 has been functionalized with MEA. The presence of Si-O-Si peaks in FTIR spectra of MEA-Si-MCM-41 samples indicates that the hexagonal pore arrangement remains intact and this is supported by HRTEM images. FESEM images show that MEA-Si-MCM-41 samples became agglomerated with increase loading of MEA. TGA analyses show that the MEA-Si-MCM-41 samples are thermally stable up to 528 K. N2 adsorption-desorption isotherms show that the textural properties of Si-MCM-41 material slowly change from a mesoporous material to non-porous material as the MEA loading increases due to pore filling effect during functionalization with MEA. Detection of N, C and H by elemental analysis confirms the presence of MEA in MEA-Si-MCM-41 samples.
This study utilized the incorporation of nanoparticle filler into an epoxy system to study the effect of different nanosized
montmorillonite (MMT) fillers on the thermal stability and mechanical properties of epoxy. The sample was prepared
using diglycidyl ether of bisphenol A (DGEBA) with different surface treatments of montmorillonite filler by mechanical
stirring. The results of thermal stability and mechanical properties of epoxy/clay system obtained from thermal gravimetric
analyzer (TGA), universal testing machine (UTM) and scanning electron microscopy (SEM) were discussed. With the same
amount of filler introduced into the system, different thermal stability of epoxy composite can be observed. Bentonite,
which contained other contaminant components, can downgrade the enhanced properties of the filler.
This article reports on the studies of structural and optical properties of nanoporous GaN prepared by Pt assisted electro chemical etching. The porous GaN samples were investigated by scanning electron microscopy (SEM), atomic force microscopy (AFM), and optical transmission (OT). SEM images liang indicated that the density of the pores increased with etching duration, however, the etching duration has no significant effect on the size and shape of the pores. AFM measurements exhibited that the surface roughness was increased with etching durations, however, for long etching duration, the increase of the surface roughness became insignificant. OT measurements revealed that the increase of pore density would lead to the reduction of light transmission. The studies showed that the porosity could influence the structural and optical properties of the GaN.
This paper presents the study of mechanical properties of short random oil palm fibre reinforced epoxy (OPF/epoxy) composites. Empty fruit bunch (EFB) was selected as the fibre and epoxy as the matrix. Composite plate with four different volume fractions of oil palm fibre was fabricated, (5 vol%, 10 vol%, 15 vol% and 20 vol%). The fabrication was made by hand-lay up techniques. The tensile and flexural properties showed a decreasing trend as the fibre loading was increased. The highest tensile properties was obtained for the composite with fibre loading of 5 vol% and there were no significant effect for addition of more than 5 vol% to the flexural properties. Interaction between fibre and matrix was observed from the scanning electron microscope (SEM) micrograph.
In this study TiO2 films have been prepared using two different techniques i.e. sol-gel and electron gun evaporation (e-gun) techniques. The films were annealed at 300, 350 and 400oC in air. The microstructure study using field emission scanning electron microscope and x-ray diffractometer showed nanometer grains size and only the film prepared by sol-gel and annealed at 400oC has anatase phase while others are amorphous. To study the effect of the films (as buffer layer) onto the dielectric bolometer Ba0.6Sr 0.4TiO3 as distance sensor, sensors with the configuration of Al/BST/TiO2/RuO2/SiO2/Si were built. Two different measurements i.e. with and without infrared source were carried out to measure the sensitivity and repeatability of the sensors. The sensors which contained sol-gel TiO2 films gave reading for both type of measurements, indicating that the sensor can act as active and passive sensors. However, the sensors which contained e-gun TiO2 films only gave responses when the IR source was used, indicating that they can only act as passive sensors. The most sensitive sensor was TiO2 film prepared by sol gel and annealed at 350oC. In general sensors which contained TiO2 films prepared by sol gel showed good repeatability.
In this work, the preparation of ZnO, N-doped ZnO (NZO), Al-doped ZnO (AZO) and Al, N-doped ZnO (ANZO) thin films by the sol-gel spin-coating method is reported. The structural properties and surface morphologies of films were characterized by X-ray diffraction (XRD) and field emission scanning electron microscope (FE-SEM). The optical properties of the films were interpreted from their transmission spectra using UV-VIS spectrophotometer. The XRD and SEM results disclosed that the crystallization quality and grain size of as-prepared films were highly influenced by N and Al doping. UV-VIS spectrophotometer results indicated that Al and N additives could significantly enhance the optical transparency and induce the blue-shift in optical bandgap of ZnO films.
CaxZn(1_x)Al204thin films (x = 0.00; 0 .05 ; 0.10; 0.15 and 0.20) were prepared by sol-gel method with the substitution of Zn2+ by Ca" in the framework of ZnAl204. The effect of Ca addition on the structure and morphology of CaZnAl204thin films was investigated by x-ray diffraction (xRD), field-emission scanning electron microscope (FESEM), energy-dispersive x-ray spectroscopy (EDx), ultra-violet visible (uv-Vis) and atomic force microscope (AFM). The xRD patterns showed the characteristic peaks of face-centred cubic (fcc)ZnAl204and CaZnAl204. The addition of Ca increased the crystallite size from 8.9 to 302 nm. The bandgap of CaxZnuld204 thin film was found in the range of 3.40 to 3.84 eV. sEm micrograph shows the morphology of all thin films is sphere-like, with the grain size increased from 33 to 123 nm. The AFM images show the roughness of surface morphology increased. The substitution of Zn2+ by Ca" increased the crystallite size, grain size and surface roughness which evidently increased the density (4.59 to 4.64 glcm3) and dielectric constant (8.48 to 9.54). The composition of CaxZn(1_x)Al204is considered as suitable material for GPS patch antennas.
A clear understanding on the fundamental mechanism in solid state self-healing resin system might significantly improve the optimization of healing performance. The focus of this study was to prove the diffusion (through thermal inter-diffusion) of a linear healing agent within the network matrix resin. The results had demonstrated that 45 to 21 percentage recoveries in fracture toughness (K1C) were observed within the third healing cycles of the healable resin. Based on the optical microscopy, scanning electron microscopy (SEM) and time-of-flight secondary ion mass spectrometry (ToF-SIM) analyst; the diffusion of healing agent was also demonstrated by the change in the morphology and chemical images of the healing agent on the fracture surface specimen, before and after healing process.
Hybrid composites of polypropylene (PP)/nanoclay (NC)/glass fiber (GF) were prepared byextrusion and injection molding. Molded specimens were analyzed by transmission electron microscopy (TEM), thermogravimetric analysis (TGA), tensile and flexural tests. TEM results revealed NC particle intercalation. TGA results showed that the incorporation of clay into the GF composite improves the thermal stability of the material. The initial thermal decomposition temperatures also shifted to higher values. Incorporation of GF into PP lowers the tensile strength of the binary composite, indicating poor fiber-matrix interfacial adhesion. However, introducing NC increased the strength of the ternary composites. Tensile modulus was enhanced with the incorporation of GF and further increased with an introduction of NC. Flexural strength and flexural modulus are both enhanced with an increase in GF and NC loading.
Titanate nanotubes were prepared by a rapid hydrothermal method in the presence of triethanolamine (TEA) using TiO2 nanoparticles as a precursor. The addition of TEA significantly reduced the formation time of the titanate nanotubes from 24 to 6 h. The crystalline structure of the titanate nanotubes was revealed to be H2Ti2O5 through the X-ray diffraction (xRD) measurement. The morphology of the titanate nanotubes was confirmed using transmission electron microscopy (TEM) while the surface area was characterized using Brunauer-Emmett-Teller (BET) surface area analysis. The titanate nanotubes produced were several hundred nanometers in length and had an average outer diameter of - 11.5 nm, inner diameter of -5.0 nm, interlayer spacing of 0.93 nm and surface area of >250 m2Ig. The photocatalytic activity of the titanate nanotubes was studied using methylene blue as a model dye; the titanate nanotubes showed better photocatalytic performance as compared to TiO2 nanoparticles.