Fabrication, characterization, and application of BiOI@ZIF-8 nanocomposite for enhanced photocatalytic degradation of acetaminophen from aqueous solutions under UV-vis irradiation

Mengting Z 1 , Duan L 2 , Zhao Y 3 , Song Y 4 , Xia S 5 , Gikas P 6 Show all authors , Othman MHD 7 , Kurniawan TA 8

Affiliations 

  • 1 State Key Laboratory of Environmental Criteria and Risk Assessment, Chinese Research Academy of Environmental Science, Beijing, 100012, China; State Key Laboratory of Pollution Control and Resource Reuse, College of Environmental Science and Engineering, Tongji University, Shanghai, 200092, China
  • 2 State Key Laboratory of Environmental Criteria and Risk Assessment, Chinese Research Academy of Environmental Science, Beijing, 100012, China. Electronic address: duanliang@craes.org.cn
  • 3 State Key Laboratory of Environmental Criteria and Risk Assessment, Chinese Research Academy of Environmental Science, Beijing, 100012, China; State Key Joint Laboratory of Environment Simulation and Pollution Control, School of Environment, Tsinghua University, Beijing, 100084, China
  • 4 State Key Laboratory of Environmental Criteria and Risk Assessment, Chinese Research Academy of Environmental Science, Beijing, 100012, China
  • 5 State Key Laboratory of Pollution Control and Resource Reuse, College of Environmental Science and Engineering, Tongji University, Shanghai, 200092, China
  • 6 Technical University of Crete, School of Chemical and Environmental Engineering, Chania, 73100, Greece
  • 7 Advanced Membrane Technology Research Centre (AMTEC), Faculty of Chemical and Energy Engineering, Universiti Teknologi Malaysia, 81310, Skudai, Johor Bahru, Malaysia
  • 8 College of Ecology and the Environment, Xiamen University, Xiamen, 361102, China. Electronic address: tonni@xmu.edu.cn
J Environ Manage, 2023 Nov 01;345:118772.
PMID: 37597373 DOI: 10.1016/j.jenvman.2023.118772

Abstract

This work investigates the use of novel BiOI@ZIF-8 nanocomposite for the removal of acetaminophen (Ace) from synthetic wastewater. The samples were analyzed using FTIR, XRD, XPS, DRS, PL, FESEM-EDS, and ESR techniques. The effects of the loading capacity of ZIF-8 on the photocatalytic oxidation performance of bismuth oxyiodide (BiOI) were studied. The photocatalytic degradation of Ace was maximized by optimizing pH, reaction time and the amount of photocatalyst. On this basis, the removal mechanisms of the target pollutant by the nanocomposite and its photodegradation pathways were elucidated. Under optimized conditions of 1 g/L of composite, pH 6.8, and 4 h of reaction time, it was found that the BiOI@ZIF-8 (w/w = 1:0.01) nanocomposite exhibited the highest Ace removal (94%), as compared to that of other loading ratios at the same Ace concentration of 25 mg/L. Although this result was encouraging, the treated wastewater still did not satisfy the required statutory of 0.2 mg/L. It is suggested that the further biological processes need to be adopted to complement Ace removal in the samples. To sustain its economic viability for wastewater treatment, the spent composite still could be reused for consecutive five cycles with 82% of regeneration efficiency. Overall, this series of work shows that the nanocomposite was a promising photocatalyst for Ace removal from wastewater samples.

* Title and MeSH Headings from MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine.

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