Effect of pyrolysis temperature on characteristics and chloramphenicol adsorption performance of NH2-MIL-53(Al)-derived amine-functionalized porous carbons

Tran TV 1 , Jalil AA 2 , Nguyen DTC 1 , Nguyen TTT 3 , Nguyen LTT 4 , Nguyen CV 5 Show all authors , Alhassan M 6

Affiliations 

  • 1 Faculty of Chemical and Energy Engineering, Universiti Teknologi Malaysia, 81310, UTM Johor, Bahru, Johor, Malaysia; Institute of Applied Technology and Sustainable Development, Nguyen Tat Thanh University, 298-300A Nguyen Tat Thanh, District 4, Ho Chi Minh City, 755414, Viet Nam
  • 2 Faculty of Chemical and Energy Engineering, Universiti Teknologi Malaysia, 81310, UTM Johor, Bahru, Johor, Malaysia; Centre of Hydrogen Energy, Institute of Future Energy, 81310, UTM Johor Bahru, Johor, Malaysia. Electronic address: aishahaj@utm.my
  • 3 Nong Lam University Ho Chi Minh City, Ho Chi Minh City, 700000, Viet Nam
  • 4 Faculty of Chemistry, Thai Nguyen University of Education, Thai Nguyen, 240000, Viet Nam
  • 5 Faculty of Applied Technology, School of Engineering and Technology, Van Lang University, 69/68 Dang Thuy Tram, Ward 13, Binh Thanh District, Ho Chi Minh City, 700000, Viet Nam
  • 6 Faculty of Chemical and Energy Engineering, Universiti Teknologi Malaysia, 81310, UTM Johor, Bahru, Johor, Malaysia; Department of Chemistry, Sokoto State University, PMB, 2134, Airport Road, Sokoto, Nigeria
Chemosphere, 2024 May;355:141599.
PMID: 38548079 DOI: 10.1016/j.chemosphere.2024.141599

Abstract

Several activities such as aquaculture, human and feedstock therapies can directly release antibiotics into water. Due to high stability, low hydrolysis and non-biodegradation, they can accumulate in the aqueous environment and transport to aquatic species. Here, we synthesized amine-functionalized porous carbons (ANC) by a direct-pyrolysis process of NH2-MIL-53(Al) as a sacrificial template at between 600 and 900 °C and utilized them to eliminate chloramphenicol antibiotic from water. The NH2-MIL-53(Al)-derived porous carbons obtained high surface areas (304.7-1600 m2 g-1) and chloramphenicol adsorption capacities (148.3-261.5 mg g-1). Several factors such as hydrogen bonding, Yoshida hydrogen bonding, and π-π interaction, hydrophobic interaction possibly controlled adsorption mechanisms. The ANC800 could be reused four cycles along with high stability in structure. As a result, NH2-MIL-53(Al)-derived porous carbons are recommended as recyclable and efficient adsorbents to the treatment of antibiotics in water.

* Title and MeSH Headings from MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine.

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