Optical Properties of Azo-Benzothiazole Side Chain Liquid Crystalline Polymers: Effect of Solvents, Substituents and Temperatures

Dzulkharnien NSF 1 , Karim MR 2 , Zahid NI 1 , Rahman NMMA 1 , Abdullah I 1 , Salleh NM 3

Affiliations 

  • 1 Department of Chemistry, Faculty of Science, University of Malaya, 50603, Kuala Lumpur, Malaysia
  • 2 Department of Chemistry, Rajshahi University, Rajshahi, 6205, Bangladesh
  • 3 Department of Chemistry, Faculty of Science, University of Malaya, 50603, Kuala Lumpur, Malaysia. dini@um.edu.my
J Fluoresc, 2019 Jul;29(4):1049-1056.
PMID: 31338718 DOI: 10.1007/s10895-019-02418-9

Abstract

The optical properties of a series of side chain liquid crystalline polymers (P1-P3) containing azo-benzothiazole mesogen with different terminal substituents (-H, -CH3 and -OCH2CH3) in four organic solvents of varying polarity have been investigated by absorption and fluorescence spectral analysis. Solvatochromic studies of P1-P3 did not show any regular variation on the absorption and emission intensities with changing the polarity of solvent. Theoretical studies were performed based on different solvent correlation methods such as Dimroth-Reichardt and Kamlet-Taft methods to investigate the solute-solvent interactions. Both absorption and emission maxima of investigated polymers were bathochromically shifted with the replacement of sixth position hydrogen atom by electron donating groups in benzothiazole moiety. The emission intensities of the studied polymers showed decreasing trend with increasing temperature.

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