Displaying publications 1 - 20 of 369 in total

  1. Nor Rahafza Abdul Manap, Roslinda Shamsudin, Mohd Norhafsam MaghpoR, Muhammad Azmi Abdul Hamid, Azman Jalar
    Sains Malaysiana, 2017;46:953-965.
    Sifat isoterma dan kinetik penjerapan formaldehid ke atas komposit serbuk serat kelapa sawit-TiO2 yang melibatkan sistem gas-pepejal adalah dikaji. Komposit serbuk serat kelapa sawit-TiO2 dihasilkan dengan mencampurkan serbuk kelapa sawit dan serbuk TiO2 dengan nisbah 8:2 menggunakan teknik pengisaran mekanik. Pengujian dijalankan di dalam kebuk ujian dengan komposit serbuk kelapa sawit-TiO2 dibiarkan untuk menjerap dan mengurangkan nilai kepekatan formaldehid secara pasif. Didapati nilai penjerapan maksima dan sifat kinetik penjerapan bergantung kepada kepekatan awal formaldehid. Kepekatan awal, Ci, 2.1 ppm dan 0.5 ppm masing-masing diwakili oleh pseudo-tertib pertama dan pseudo tertib kedua, manakala Ci = 0.75 dan 0.9 ppm diwakili oleh model Elovich. Isoterma penjerapan formaldehid diwakili oleh isoterma Freundlich dengan nilai korelasi tertinggi R2 = 0.9397 berbanding nilai korelasi isoterma Langmuir (R2 = 0.8692) dan isoterma Temkin (R2 = 0.8756). Parameter keseimbangan, 0
    Matched MeSH terms: Titanium
  2. Matinmanesh A, Li Y, Nouhi A, Zalzal P, Schemitsch EH, Towler MR, et al.
    J Mech Behav Biomed Mater, 2018 02;78:273-281.
    PMID: 29190533 DOI: 10.1016/j.jmbbm.2017.11.015
    It has been reported that the adhesion of bioactive glass coatings to Ti6Al4V reduces after degradation, however, this effect has not been quantified. This paper uses bilayer double cantilever (DCB) specimens to determine GIC and GIIC, the critical mode I and mode II strain energy release rates, respectively, of bioactive coating/Ti6Al4V substrate systems degraded to different extents. Three borate-based bioactive glass coatings with increasing amounts of incorporated SrO (0, 15 and 25mol%) were enamelled onto Ti6Al4V substrates and then immersed in de-ionized water for 2, 6 and 24h. The weight loss of each glass composition was measured and it was found that the dissolution rate significantly decreased with increasing SrO content. The extent of dissolution was consistent with the hypothesis that the compressive residual stress tends to reduce the dissolution rate of bioactive glasses. After drying, the bilayer DCB specimens were created and subjected to nearly mode I and mode II fracture tests. The toughest coating/substrate system (one composed of the glass containing 25mol% SrO) lost 80% and 85% of its GIC and GIIC, respectively, in less than 24h of degradation. The drop in GIC and GIIC occurred even more rapidly for other coating/substrate systems. Therefore, degradation of borate bioactive glass coatings is inversely related to their fracture toughness when coated onto Ti6A4V substrates. Finally, roughening the substrate was found to be inconsequential in increasing the toughness of the system as the fracture toughness was limited by the cohesive toughness of the glass itself.
    Matched MeSH terms: Titanium/chemistry*
  3. Pang YL, Lim S, Lee RKL
    Environ Sci Pollut Res Int, 2020 Oct;27(28):34638-34652.
    PMID: 31102214 DOI: 10.1007/s11356-019-05373-x
    A novel titanium dioxide/activated carbon (TiO2/AC) composite where AC derived from oil palm empty fruit bunch (EFB) was synthesised by using sol-gel method. All the samples were characterised by using X-ray diffraction (XRD), scanning electron microscopy-energy dispersive X-ray (SEM-EDX), Fourier transformed infrared (FTIR), thermogravimetric analysis (TGA) and surface analyser. SEM analysis showed that TiO2 particles were successfully embedded and well distributed on the AC surface. The elemental composition analysis found that the TiO2/AC composite contained titanium (Ti), oxygen (O) and carbon (C) atoms. Meanwhile, the appearance of new band at about 960 cm-1 which assigned to the Ti-O stretching was observed in the FTIR spectra when the AC was incorporated into TiO2. TGA analysis showed that the weight loss of 32 wt.% from 150 to 550 °C was due to the decomposition of amorphous carbon layers and loss of hydroxyl groups on TiO2. It was found that the TiO2/AC composite had better performance in the sonocatalytic degradation of malachite green as compared to the individual AC and TiO2 because the TiO2/AC composite had dual functionality and huge number of active sites which could promote the mass transfer of dye molecules towards catalyst surface. By using 1.5 g/L of TiO2/AC composite which calcined at 700 °C on 100 mL of 200 mg/L of malachite green at solution pH of 7, a degradation efficiency of 87.11% had been achieved after 30 min of ultrasonic irradiation. A lower chemical oxygen demand (COD) removal (81.75%) was observed because the structured dye molecules underwent mineralisation process during the sonocatalytic degradation to generate intermediate compounds. The TiO2/AC composite was able to be recycled and still achieved a high degradation efficiency of 76.78% after second catalytic cycle as compared to the fresh TiO2/AC composite with degradation efficiency of 87.11%. In conclusion, the TiO2/AC composite had high reusability and promising for practical applications in textile industry.
    Matched MeSH terms: Titanium*
  4. Mat-Baharin NH, Razali M, Mohd-Said S, Syarif J, Muchtar A
    J Prosthodont Res, 2020 Oct;64(4):490-497.
    PMID: 32063537 DOI: 10.1016/j.jpor.2020.01.004
    PURPOSE: Not all elements with β-stabilizing properties in titanium alloys are suitable for biomaterial applications, because corrosion and wear processes release the alloying elements to the surrounding tissue. Chromium and molybdenum were selected as the alloying element in this work as to find balance between the strength and modulus of elasticity of β-titanium alloys. This study aimed to investigate the effect of Titanium-10Molybdenum-10Chromium (Ti-10Mo-10Cr), Titanium-10Chromium (Ti-10Cr) and Titanium-10Molybdenum (Ti-10Mo) on the elemental leachability in tissue culture environment and their effect on the viability of human gingival fibroblasts (HGFs).

    METHODS: Each alloy was immersed in growth medium for 0-21 days, and the elution was analyzed to detect the released metals. The elution was further used as the treatment medium and exposed to seeded HGFs overnight. The HGFs were also cultured directly to the titanium alloy for 1, 3 and 7 days. Cell viability was then determined.

    RESULTS: Six metal elements were detected in the immersion of titanium alloys. Among these elements, molybdenum released from Ti-10Mo-10Cr had the highest concentration throughout the immersion period. Significant difference in the viability of fibroblast cells treated with growth medium containing metals and with direct exposure technique was not observed. The duration of immersion did not significantly affect cell viability. Nevertheless, cell viability was significantly affected after 1 and 7 days of exposure, when the cells were grown directly onto the alloy surfaces.

    CONCLUSIONS: Within the limitation of this study, the newly developed β-titanium alloys are non-cytotoxic to human gingival fibroblasts.

    Matched MeSH terms: Titanium*
  5. Yan L, Yu J, Zhong Y, Gu Y, Ma Y, Li W, et al.
    J Nanosci Nanotechnol, 2020 03 01;20(3):1605-1612.
    PMID: 31492322 DOI: 10.1166/jnn.2020.17340
    The present study focuses on the microstructural and bioactive properties evolution in selective laser melting (SLM) β titanium alloys. We have applied cross-scan strategy for improving mechanical properties and lower elastic modulus of SLMed Ti-20Mg-5Ta alloys which has been shown to be altering the microstructure and refining the grain size. The cross-scan strategy can refine the microstructure and induce various deformation textures in contrast to the conventional scan strategy. The microstructures of Ti-20Mg-5Ta alloys indicate that the cross-scan strategy will yield the best mechanical properties and lower elastic modulus. The corrosion behavior of the Ti-20Mg-5Ta alloys was studied during immersion in an acellular simulated body fluid (SBF) at 37±0.50 °C for 28 days. Both the mechanical and bioactive properties showed that the novel Ti-20Mg-5Ta alloys should be ideal for bone implants.
    Matched MeSH terms: Titanium*
  6. Sahudin MA, Su'ait MS, Tan LL, Abd Karim NH
    PMID: 33281086 DOI: 10.1016/j.saa.2020.119129
    Histamine is one of the important biomarkers for food spoilage in the food sectors. In the present study, a rapid and simple analytical tool has been developed to detect histamine as an indirect strategy to monitor food freshness level. Optical histamine sensor with carboxyl-substituted Schiff base zinc(II) complex with hydroxypropoxy side chain deposited onto titanium dioxide nanoparticles was fabricated and was found to respond successfully to histamine. The Schiff base zinc(II) complex-histamine binding generated an enhancement of the fluorescent signal. Under the optimal reaction condition, the developed sensor can detect down to 2.53 × 10-10 M in the range of between 1.0 × 10-9 and 1.0 × 10-5 M (R2 = 0.9868). Selectivity performance of the sensor towards histamine over other amines was confirmed. The sensor also displayed good reproducibility performances with low relative standard deviation values (1.45%-4.95%). Shelf-life studies suggested that the developed sensor remains stable after 60 days in histamine detection. More importantly, the proposed sensor has been successfully applied to determine histamine in salmon fillet with good recoveries. This strategy has a promising potential in the food quality assurance sectors, especially in controlling the food safety for healthy consumption among consumers.
    Matched MeSH terms: Titanium*
  7. Mohd Fairul Sharin, Muhammad Azam
    Three types of binder PVA, PVC and PVA/PVC mixtures have been evaluated for PANi-TiO2 immobilized system. These binders have been varied to several weights of loading for optimization purposes. As a result, it shows that higher loading of binders improved the photodegradation of RR4 dye but the mechanical properties of each immobilized system started to decreases. This behavior occurs due to the immobilized particles coated on the plate easy to peel off despite weak attachment toward to the continuous photodegradation operation system. Therefore 4 times of dipping PVA and PVC layers was selected as the optimum loading of binders to the PANi/TiO2 system during photocatalytic degradation of Reactive Red 4 with the rate constant of 0.5568 K/min for PVA and 0.5742 K/min for PVC. Meanwhile for PVA/PVC mixture binder system at 4 times dipping showed the highest rate constant of photodegradation of RR4 dye with 0.6026 K/min. In addition, SEM analysis has also been carried out for further investigation.
    Matched MeSH terms: Titanium
  8. Apratim A, Eachempati P, Krishnappa Salian KK, Singh V, Chhabra S, Shah S
    J Int Soc Prev Community Dent, 2015 May-Jun;5(3):147-56.
    PMID: 26236672 DOI: 10.4103/2231-0762.158014
    Titanium has been the most popular material of choice for dental implantology over the past few decades. Its properties have been found to be most suitable for the success of implant treatment. But recently, zirconia is slowly emerging as one of the materials which might replace the gold standard of dental implant, i.e., titanium.
    Matched MeSH terms: Titanium
  9. Ahams ST, Shaari A, Ahmed R, Pattah NFA, Idris MC, Haq BU
    Sci Rep, 2021 Mar 02;11(1):4980.
    PMID: 33654175 DOI: 10.1038/s41598-021-84466-5
    The MAX phase materials such as layered ternary carbides that simultaneously exhibit characteristics of metallic and ceramic materials have received substantial interest in recent years. Here, we present a systematic investigation of the electronic, structural stabilities, and elastic properties of Ti3(Al1-nSin)C2 (n = 0,1) MAX phase materials using the ab initio method via a plane-wave pseudopotential approach within generalized-gradient-approximations. The computed electronic band structures and projected density of states show that both Ti3SiC2 and Ti3AlC2 are metallic materials with a high density of states at the Fermi level emanating mainly from Ti-3d. Using the calculated elastic constants, the mechanical stability of the compounds was confirmed following the Born stability criteria for hexagonal structures. The Cauchy pressure and the Pugh's ratio values establish the brittle nature of the Ti3SiC2 and Ti3AlC2 MAX phase materials. Due to their intriguing physical properties, these materials are expected to be suitable for applications such as thermal shock refractories and electrical contact coatings.
    Matched MeSH terms: Titanium
  10. Fayyaz O, Khan A, Shakoor RA, Hasan A, Yusuf MM, Montemor MF, et al.
    Sci Rep, 2021 Mar 05;11(1):5327.
    PMID: 33674680 DOI: 10.1038/s41598-021-84716-6
    In the present study, the effect of concentration of titanium carbide (TiC) particles on the structural, mechanical, and electrochemical properties of Ni-P composite coatings was investigated. Various amounts of TiC particles (0, 0.5, 1.0, 1.5, and 2.0 g L-1) were co-electrodeposited in the Ni-P matrix under optimized conditions and then characterized by employing various techniques. The structural analysis of prepared coatings indicates uniform, compact, and nodular structured coatings without any noticeable defects. Vickers microhardness and nanoindentation results demonstrate the increase in the hardness with an increasing amount of TiC particles attaining its terminal value (593HV100) at the concentration of 1.5 g L-1. Further increase in the concentration of TiC particles results in a decrease in hardness, which can be ascribed to their accumulation in the Ni-P matrix. The electrochemical results indicate the improvement in corrosion protection efficiency of coatings with an increasing amount of TiC particles reaching to ~ 92% at 2.0 g L-1, which can be ascribed to a reduction in the active area of the Ni-P matrix by the presence of inactive ceramic particles. The favorable structural, mechanical, and corrosion protection characteristics of Ni-P-TiC composite coatings suggest their potential applications in many industrial applications.
    Matched MeSH terms: Titanium
  11. Alias N, Ali Umar A, Malek NAA, Liu K, Li X, Abdullah NA, et al.
    ACS Appl Mater Interfaces, 2021 Jan 20;13(2):3051-3061.
    PMID: 33410652 DOI: 10.1021/acsami.0c20137
    A deficiency in the photoelectrical dynamics at the interface due to the surface traps of the TiO2 electron transport layer (ETL) has been the critical factor for the inferiority of the power conversion efficiency (PCE) in the perovskite solar cells. Despite its excellent energy level alignment with most perovskite materials, its large density of surface defect as a result of sub lattice vacancies has been the critical hurdle for an efficient photovoltaic process in the device. Here, we report that atoms thick 2D TiS2 layer grown on the surface of a (001) faceted and single-crystalline TiO2 nanograss (NG) ETL have effectively passivated the defects, boosting the charge extractability, carrier mobility, external quantum efficiency, and the device stability. These properties allow the perovskite solar cells (PSCs) to produce a PCE as high as 18.73% with short-circuit current density (Jsc), open-circuit voltage (Voc), and fill-factor (FF) values as high as 22.04 mA/cm2, 1.13 V, and 0.752, respectively, a 3.3% improvement from the pristine TiO2-NG-based PSCs. The present approach should find an extensive application for controlling the photoelectrical dynamic deficiency in perovskite solar cells.
    Matched MeSH terms: Titanium
  12. Ong WJ, Tan LL, Chai SP, Yong ST, Mohamed AR
    Nanoscale, 2014 Feb 21;6(4):1946-2008.
    PMID: 24384624 DOI: 10.1039/c3nr04655a
    Titanium dioxide (TiO2) is one of the most widely investigated metal oxides due to its extraordinary surface, electronic and catalytic properties. However, the large band gap of TiO2 and massive recombination of photogenerated electron-hole pairs limit its photocatalytic and photovoltaic efficiency. Therefore, increasing research attention is now being directed towards engineering the surface structure of TiO2 at the most fundamental and atomic level namely morphological control of {001} facets in the range of microscale and nanoscale to fine-tune its physicochemical properties, which could ultimately lead to the optimization of its selectivity and reactivity. The synthesis of {001}-faceted TiO2 is currently one of the most active interdisciplinary research areas and demonstrations of catalytic enhancement are abundant. Modifications such as metal and non-metal doping have also been extensively studied to extend its band gap to the visible light region. This steady progress has demonstrated that TiO2-based composites with {001} facets are playing and will continue to play an indispensable role in the environmental remediation and in the search for clean and renewable energy technologies. This review encompasses the state-of-the-art research activities and latest advancements in the design of highly reactive {001} facet-dominated TiO2via various strategies, including hydrothermal/solvothermal, high temperature gas phase reactions and non-hydrolytic alcoholysis methods. The stabilization of {001} facets using fluorine-containing species and fluorine-free capping agents is also critically discussed in this review. To overcome the large band gap of TiO2 and rapid recombination of photogenerated charge carriers, modifications are carried out to manipulate its electronic band structure, including transition metal doping, noble metal doping, non-metal doping and incorporating graphene as a two-dimensional (2D) catalyst support. The advancements made in these aspects are thoroughly examined, with additional insights related to the charge transfer events for each strategy of the modified-TiO2 composites. Finally, we offer a summary and some invigorating perspectives on the major challenges and new research directions for future exploitation in this emerging frontier, which we hope will advance us to rationally harness the outstanding structural and electronic properties of {001} facets for various environmental and energy-related applications.
    Matched MeSH terms: Titanium/chemistry*
  13. Mohamed MA, W Salleh WN, Jaafar J, Mohd Hir ZA, Rosmi MS, Abd Mutalib M, et al.
    Carbohydr Polym, 2016 08 01;146:166-73.
    PMID: 27112862 DOI: 10.1016/j.carbpol.2016.03.050
    Visible light driven C-doped mesoporous TiO2 (C-MTiO2) nanorods have been successfully synthesized through green, low cost, and facile approach by sol-gel bio-templating method using regenerated cellulose membrane (RCM) as nanoreactor. In this study, RCM was also responsible to provide in-situ carbon sources for resultant C-MTiO2 nanorods in acidified sol at low temperatures. The composition, crystallinity, surface area, morphological structure, and optical properties of C-MTiO2 nanorods, respectively, had been characterized using FTIR, XRD, N2 adsorption/desorption, TEM, UV-vis-NIR, and XPS spectroscopy. The results suggested that the growth of C-MTiO2 nanorods was promoted by the strong interaction between the hydroxyl groups of RCMs and titanium ion. Optical and XPS analysis confirmed that carbon presence in TiO2 nanorods were responsible for band-gap narrowing, which improved the visible light absorption capability. Photocatalytic activity measurements exhibited the capability of C-MTiO2 nanorods in degradation of methyl orange in aqueous solution, with 96.6% degradation percentage under visible light irradiation.
    Matched MeSH terms: Titanium/chemistry*
  14. Ng KH, Khan MR, Ng YH, Hossain SS, Cheng CK
    J Environ Manage, 2017 Jul 01;196:674-680.
    PMID: 28365553 DOI: 10.1016/j.jenvman.2017.03.078
    In this study, we have employed a photocatalytic method to restore the liquid effluent from a palm oil mill in Malaysia. Specifically, the performance of both TiO2 and ZnO was compared for the photocatalytic polishing of palm oil mill effluent (POME). The ZnO photocatalyst has irregular shape, bigger in particle size but smaller BET specific surface area (9.71 m2/g) compared to the spherical TiO2 photocatalysts (11.34 m2/g). Both scavenging study and post-reaction FTIR analysis suggest that the degradation of organic pollutant in the TiO2 system has occurred in the bulk solution. In contrast, it is necessary for organic pollutant to adsorb onto the surface of ZnO photocatalyst, before the degradation took place. In addition, the reactivity of both photocatalysts differed in terms of mechanisms, photocatalyst loading and also the density of photocatalysts. From the stability test, TiO2 was found to offer higher stability, as no significant deterioration in activity was observed after three consecutive cycles. On the other hand, ZnO lost around 30% of its activity after the 1st-cycle of photoreaction. The pH studies showed that acidic environment did not improve the photocatalytic degradation of the POME, whilst in the basic environment, the reaction media became cloudy. In addition, longevity study also showed that the TiO2 was a better photocatalyst compared to the ZnO (74.12%), with more than 80.0% organic removal after 22 h of UV irradiation.
    Matched MeSH terms: Titanium*
  15. Nagentrau M, Mohd Tobi AL, Jamian S, Otsuka Y, Hussin R
    J Mech Behav Biomed Mater, 2021 10;122:104657.
    PMID: 34246851 DOI: 10.1016/j.jmbbm.2021.104657
    Present research aims to develop a finite element computational model to examine delamination-fretting wear behaviour that can suitably mimic actual loading conditions at HAp-Ti-6Al-4V interface of uncemented hip implant femoral stem component. A simple finite element contact configuration model based on fretting fatigue experimental arrangement subjected to different mechanical and tribological properties consist of contact pad (bone), HAp coating and Ti-6Al-4V substrate are developed using adaptive wear modelling approach adopting modified Archard wear equation to be examined under static simulation. The developed finite element model is validated and verified with reported literatures. The findings revealed that significant delamination-fretting wear is recorded at contact edge (leading edge) as a result of substantial contact pressure and contact slip driven by stress singularity effect. The delamination-fretting wear behaviour is promoted under higher delamination length, lower normal loading with higher fatigue loading, increased porous (cancellous) and cortical bone elastic modulus with higher cycle number due to significant relative slip amplitude as the result of reduced interface rigidity. Tensile-compressive condition (R=-1) experiences most significant delamination-fretting wear behaviour (8 times higher) compared to stress ratio R=0.1 and R=10.
    Matched MeSH terms: Titanium*
  16. Jukapli NM, Bagheri S
    J. Photochem. Photobiol. B, Biol., 2016 Oct;163:421-30.
    PMID: 27639172 DOI: 10.1016/j.jphotobiol.2016.08.046
    This review provides a background, fundamental and advanced application of titania nanoparticles (TiO2) on the disinfection and killing of cancer cell through photocatalytic chemistry. It starts with the characteristic properties focused on the surface, light sensitivity, crystallinity and toxicology of TiO2 as a photocatalyst. Consequently, outline and design of photocatalytic reactor has been figured out based on the target organisms, including bacteria, viruses, fungi and cancer cells. Despite a large number of studies undertaken, limited selectivity and efficacy of TiO2 photocatalyst are still widely accepted problems. An ideal TiO2 photocatalyst should have the combined properties of highly stable reactive oxygen species yield and a greater degree of selectivity towards cancerous cell without damaging the healthy tissues. Hybridization of TiO2 with metal, metal oxide and carbon nano materials significantly improved both of stability and selectivity of TiO2, whilst maintaining its high Photodynamic reactivity.
    Matched MeSH terms: Titanium/pharmacology*; Titanium/therapeutic use; Titanium/toxicity; Titanium/chemistry*
  17. Bagheri S, Muhd Julkapli N, Bee Abd Hamid S
    ScientificWorldJournal, 2014;2014:727496.
    PMID: 25383380 DOI: 10.1155/2014/727496
    The lack of stability is a challenge for most heterogeneous catalysts. During operations, the agglomeration of particles may block the active sites of the catalyst, which is believed to contribute to its instability. Recently, titanium oxide (TiO2) was introduced as an alternative support material for heterogeneous catalyst due to the effect of its high surface area stabilizing the catalysts in its mesoporous structure. TiO2 supported metal catalysts have attracted interest due to TiO2 nanoparticles high activity for various reduction and oxidation reactions at low pressures and temperatures. Furthermore, TiO2 was found to be a good metal oxide catalyst support due to the strong metal support interaction, chemical stability, and acid-base property. The aforementioned properties make heterogeneous TiO2 supported catalysts show a high potential in photocatalyst-related applications, electrodes for wet solar cells, synthesis of fine chemicals, and others. This review focuses on TiO2 as a support material for heterogeneous catalysts and its potential applications.
    Matched MeSH terms: Titanium/chemistry*
  18. Mahmoodian R, Hamdi M, Hassan MA, Akbari A
    PLoS One, 2015;10(6):e0130836.
    PMID: 26111217 DOI: 10.1371/journal.pone.0130836
    Titanium carbide-graphite (TiC/C) composite was successfully synthesized from Ti and C starting elemental powders using self-propagating high-temperature synthesis technique in an ultra-high plasma inert medium in a single stage. The TiC was exposed to a high-temperature inert medium to allow recrystallization. The product was then characterized using field emission scanning electron microscopy (FESEM) coupled with energy dispersive X-ray analysis (EDX), X-ray diffraction (XRD), Rietveld refinement, nanoindentation, and micro-hardness to determine the product's properties. The recorded micro-hardness of the product was 3660 HV, which is a 14% enhancement and makes is comparable to TiC materials.
    Matched MeSH terms: Titanium/chemistry*
  19. Matinmanesh A, Li Y, Clarkin O, Zalzal P, Schemitsch EH, Towler MR, et al.
    J Mech Behav Biomed Mater, 2017 11;75:212-221.
    PMID: 28756281 DOI: 10.1016/j.jmbbm.2017.07.030
    Bioactive glasses have been used as coatings for biomedical implants because they can be formulated to promote osseointegration, antibacterial behavior, bone formation, and tissue healing through the incorporation and subsequent release of certain ions. However, shear loading on coated implants has been reported to cause the delamination and loosening of such coatings. This work uses a recently developed fracture mechanics testing methodology to quantify the critical strain energy release rate under nearly pure mode II conditions, GIIC, of a series of borate-based glass coating/Ti6Al4V alloy substrate systems. Incorporating increasing amounts of SrCO3in the glass composition was found to increase the GIICalmost twofold, from 25.3 to 46.9J/m2. The magnitude and distribution of residual stresses in the coating were quantified, and it was found that the residual stresses in all cases distributed uniformly over the cross section of the coating. The crack was driven towards, but not into, the glass/Ti6Al4V substrate interface due to the shear loading. This implied that the interface had a higher fracture toughness than the coating itself.
    Matched MeSH terms: Titanium/analysis*
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