Affiliations 

  • 1 Department of Chemistry, University of Management and Technology, Lahore, 54770, Pakistan
  • 2 Department of Chemistry, University of Management and Technology, Lahore, 54770, Pakistan. Electronic address: ayesha.mohyuddin@umt.edu.pk
  • 3 Advanced Membrane Technology Research Centre, Faculty of Chemical and Energy Engineering, Universiti Teknologi Malaysia, 81310, Skudai, Johor Bahru, Malaysia
  • 4 Technical University of Crete, School of Chemical and Environmental Engineering, Chania, Greece
  • 5 College of the Environment and Ecology, Xiamen University, Xiamen, 361102, Fujian, China. Electronic address: tonni@xmu.edu.cn
J Environ Manage, 2023 Dec 01;347:119129.
PMID: 37778073 DOI: 10.1016/j.jenvman.2023.119129

Abstract

Buffing dust, generated from tannery industries, is a source of air pollution in Pakistan. Valorization of the waste into another useful material is important to deal with the environmental pollution, while reducing waste disposal costs in landfills. To demonstrate its technological strength, this work fabricates a thermal insulation material made of plaster of Paris and the buffing dust (from tanning waste) in the form of a composite with superior mechanical properties and low thermal conductivity. Buffing dust with concentrations ranging from 5 to 20% (w/w) were loaded in the composite. The samples synthesized were made slurry of plaster of Paris, buffing dust, and water at ambient temperature. The physico-mechanical properties of composite were analyzed. It was found that the composite had better thermal insulation properties than the panels of the plaster of Paris. Its thermal conductivity was reduced to 15% after adding buffing dust (20% w/w). All the materials had physico-chemical properties like tensile strength (0.02 MPa and 0.06 MPa), density (700-400 kg/m3), water absorption (5.2-8.6%) and thermal conductivity (0.17000-0.09218 W/m-K). Thermogravimetric analysis showed that the material was thermally stable at temperatures ranging from 145 to 177 °C, while FT-IR results revealed that the composite contained O-H, N-H, and CO functional groups. SEM analysis displayed that the composite's homogeneity was reduced with low voids due to buffing dust addition, while EDX analysis showed that the composite contained 23.62% of S, 26.76% of Ca, 49.2% of O and 0.42% of C. This implies that buffing dust could be recycled to manufacture heat insulation materials for construction sector to reduce air pollution, while minimizing energy consumption. By integrating the buffing dust from tanning waste and the plaster of Paris as a composite for construction sector, this work promotes the recycling of unused waste, while saving public funds. Instead of paying landfill fees and polluting soil, the waste may be recycled at lower cost, while reducing environmental damage.

* Title and MeSH Headings from MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine.