Displaying publications 221 - 240 of 712 in total

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  1. Baiuitiar Ul Haq, Ahmed R, Shaari A, Afaq A, Hussain R
    Sains Malaysiana, 2014;43:813-817.
    The central theme of nanotechnology to miniaturize devices has stimulated interest in diluted magnetic semiconductors (DMS). DMS that simultaneously exhibit magnetic and semiconducting behavior are capable of parting properties of two different function devices into one. In this research we present our first principles investigations related to the structural and electronic properties of, Cr doped zinc-blende (zB) ZnO, DMS. These calculations are carried out using full potential linearized augmented plane wave plus local orbital (FP-L(APW+lo)) with generalized gradient approximations approach as implemented in WIEN2k code. In this study, the effect of Cr doping on lattice parameters, spin polarized electronic band structure, density of states (Dos) of ZnO is presented and analyzed in detail.
    Matched MeSH terms: Radiation
  2. Abdul Ghapor Hussin, Norli Anida Abdullah, Ibrahim Mohamed
    This paper gives a comprehensive discussion on complex regression model by extending the idea of regression model to circular variables. Various aspect have been considered such as the biasness of parameters, error assumptions and model checking. The advantage of this approach is that it allows the use of usual technique available in ordinary linear regression for the regression of circular variables. The quality of the estimates and the feasibility of the approach were illustrated via simulation. The model was then applied to the wave direction data.
    Matched MeSH terms: Radiation
  3. Samat S, Evans C
    Sains Malaysiana, 2011;40:1355-1358.
    Eleven different brands of mineral water available in Malaysia were assessed in comparison with two criteria for ingested radiation dose. It is concluded that mineral water can only contribute a very small fraction of the typical daily intake of potassium, and that the radiation dose acquired from any of the brands can never exceed a small fraction of the recommended limits.
    Matched MeSH terms: Radiation Dosage
  4. Hossain A, Islam MT, Almutairi AF, Singh MSJ, Mat K, Samsuzzaman M
    Sensors (Basel), 2020 Mar 01;20(5).
    PMID: 32121477 DOI: 10.3390/s20051354
    An Ultrawideband (UWB) octagonal ring-shaped parasitic resonator-based patch antenna for microwave imaging applications is presented in this study, which is constructed with a diamond-shaped radiating patch, three octagonal, rectangular slotted ring-shaped parasitic resonator elements, and partial slotting ground plane. The main goals of uses of parasitic ring-shaped elements are improving antenna performance. In the prototype, various kinds of slots on the ground plane were investigated, and especially rectangular slots and irregular zigzag slots are applied to enhance bandwidth, gain, efficiency, and radiation directivity. The optimized size of the antenna is 29 × 24 × 1.5 mm3 by using the FR-4 substrate. The overall results illustrate that the antenna has a bandwidth of 8.7 GHz (2.80 ̶ 11.50 GHz) for the reflection coefficient S11 < -10 dB with directional radiation pattern. The maximum gain of the proposed prototype is more than 5.7 dBi, and the average efficiency over the radiating bandwidth is 75%. Different design modifications are performed to attain the most favorable outcome of the proposed antenna. However, the prototype of the proposed antenna is designed and simulated in the 3D simulator CST Microwave Studio 2018 and then effectively fabricated and measured. The investigation throughout the study of the numerical as well as experimental data explicit that the proposed antenna is appropriate for the Ultrawideband-based microwave-imaging fields.
    Matched MeSH terms: Electromagnetic Radiation
  5. Alomari AH, Saleh MA, Hashim S, Alsayaheen A, Abdeldin I, Bani Khalaf R
    J Water Health, 2019 Dec;17(6):957-970.
    PMID: 31850902 DOI: 10.2166/wh.2019.158
    The current study was conducted to measure the activity concentration of the gross alpha and beta in 87 groundwater samples collected from the productive aquifers that constitute a major source of groundwater to evaluate the annual effective dose and the corresponding health impact on the population and to investigate the quality of groundwater in Jordan. The mean activity concentration of gross alpha and beta in groundwater ranges from 0.26 ± 0.03 to 3.58 ± 0.55 Bq L-1 and from 0.51 ± 0.07 to 3.43 ± 0.46 Bq L-1, respectively. A very strong relationship was found between gross alpha and beta activity concentrations. The annual effective dose for alpha and beta was found in the range of 0.32-2.40 mSv with a mean value of 0.89 mSv, which is nine times higher than the World Health Organization (WHO) recommended limit and one and half times higher than the national regulation limit. The mean lifetime risk was found to be 45.47 × 10-4 higher than the Jordanian estimated upper-bound lifetime risk of 25 × 10-4. The data obtained in the study would be the baseline for further epidemiological studies on health effects related to the exposure to natural radioactivity in Jordan.
    Matched MeSH terms: Background Radiation; Radiation Dosage; Radiation Monitoring*
  6. Sabarudin A, Siong TW, Chin AW, Hoong NK, Karim MKA
    Sci Rep, 2019 03 13;9(1):4374.
    PMID: 30867480 DOI: 10.1038/s41598-019-40758-5
    In this report we have evaluated radiation effective dose received by patients during ECG-gated CCTA examinations based on gender, heart rate, tube voltage protocol and body mass index (BMI). A total of 1,824 patients were retrospectively recruited (1,139 men and 685 women) and they were divided into Group 1 (CCTA with calcium scoring), Group 2 (CCTA without calcium scoring) and Group 3 (only calcium scoring), where the association between gender, heart rate, tube voltage protocol and body mass index (BMI) were analysed. Examinations were performed using a retrospective ECG-gated CCTA protocol and the effective doses were calculated from the dose length product with a conversion coefficient of 0.026 mSv.mGy-1cm-1. No significant differences were observed in the mean effective dose between gender in all groups. The mean estimated dose was significantly higher when the heart rate was lower in Group 1 (p 
    Matched MeSH terms: Radiation Exposure; Dose-Response Relationship, Radiation; Radiation Dosage*
  7. Iqbal A, Smida A, Mallat NK, Islam MT, Kim S
    Sensors (Basel), 2019 Mar 22;19(6).
    PMID: 30909414 DOI: 10.3390/s19061411
    A minimally-sized, triple-notched band ultra-wideband (UWB) antenna, useful for many applications, is designed, analyzed, and experimentally validated in this paper. A modified maple leaf-shaped main radiating element with partial ground is used in the proposed design. An E-shaped resonator, meandered slot, and U-shaped slot are implemented in the proposed design to block the co-existing bands. The E-shaped resonator stops frequencies ranging from 1.8⁻2.3 GHz (Advanced Wireless System (AWS1⁻AWS2) band), while the meandered slot blocks frequencies from 3.2⁻3.8 GHz (WiMAX band). The co-existing band ranging from 5.6⁻6.1 GHz (IEEE 802.11/HIPERLANband) is blocked by utilizing the U-shaped section in the feeding network. The notched bands can be independently controlled over a wide range of frequencies using specific parameters. The proposed antenna is suitable for many applications because of its flat gain, good radiation characteristics at both principal planes, uniform group delay, and non-varying transfer function ( S 21 ) for the entire UWB frequency range.
    Matched MeSH terms: Electromagnetic Radiation
  8. Ali I, Jamaluddin MH, Gaya A, Rahim HA
    Sensors (Basel), 2020 Jan 26;20(3).
    PMID: 31991889 DOI: 10.3390/s20030675
    In this paper, a dielectric resonator antenna (DRA) with high gain and wide impedance bandwidth for fifth-generation (5G) wireless communication applications is proposed. The dielectric resonator antenna is designed to operate at higher-order TEδ15x mode to achieve high antenna gain, while a hollow cylinder at the center of the DRA is introduced to improve bandwidth by reducing the quality factor. The DRA is excited by a 50Ω microstrip line with a narrow aperture slot. The reflection coefficient, antenna gain, and radiation pattern of the proposed DRAs are analyzed using the commercially available full-wave electromagnetic simulation tool CST Microwave Studio (CST MWS). In order to verify the simulation results, the proposed antenna structures were fabricated and experimentally validated. Measured results of the fabricated prototypes show a 10-dB return loss impedance bandwidth of 10.7% (14.3-15.9GHz) and 16.1% (14.1-16.5 GHz) for DRA1 and DRA2, respectively, at the operating frequency of 15 GHz. The results show that the designed antenna structure can be used in the Internet of things (IoT) for device-to-device (D2D) communication in 5G systems.
    Matched MeSH terms: Electromagnetic Radiation
  9. Hoque A, Islam MT, Almutairi AF
    Sensors (Basel), 2020 Jun 11;20(11).
    PMID: 32545228 DOI: 10.3390/s20113323
    A low-profile high-directivity, and double-negative (DNG) metamaterial-loaded antenna with a slotted patch is proposed for the 5G application. The radiated slotted arm as a V shape has been extended to provide a low-profile feature with a two-isometric view square patch structure, which accelerates the electromagnetic (EM) resonance. Besides, the tapered patch with two vertically split parabolic horns and the unit cell metamaterial expedite achieve more directive radiation. Two adjacent splits with meta units enhance the surface current to modify the actual electric current, which is induced by a substrate-isolated EM field. As a result, the slotted antenna shows a 7.14 dBi realized gain with 80% radiation efficiency, which is quite significant. The operation bandwidth is 4.27-4.40 GHz, and characteristic impedance approximately remains the same (50 Ω) to give a VSWR (voltage Standing wave ratio) of less than 2, which is ideal for the expected application field. The overall size of the antenna is 60 × 40 × 1.52 mm. Hence, it has potential for future 5G applications, like Internet of Things (IoT), healthcare systems, smart homes, etc.
    Matched MeSH terms: Electromagnetic Radiation
  10. Sulieman A, Mayhoub F, Ibrahim HS, Omer H, Alkhorayef M, Abolaban FA, et al.
    Radiat Prot Dosimetry, 2021 Oct 12;195(3-4):314-318.
    PMID: 34265851 DOI: 10.1093/rpd/ncab107
    The objective of this study is to estimate the annual effective dose for cardiologists and nurses by measuring Hp(10) and Hp(0.07) during cardiac catheterization procedures. A total of 16 staffs members were working in interventional cardiology during 1 year at a tertiary hospital. The occupational dose was measured using calibrated thermo-luminescent dosemeters (TLD-100, LiF:Mg,Ti). The overall mean and range of the annual Hp(10) and Hp(0.07) (mSv) for cardiologists were 3.7 (0.13-14.5) and 3.2 (0.21-14.7), respectively. Cardiologists were frequently exposed to higher doses compared with nurses and technologists. The exposure showed wide variations, which depend on occupation and workload. Staff is adhered to radiation protection guidelines regarding shielding the trunk, thyroid shield, thus appropriately protected. Lens dose measurement is recommended to ensure that dose limit is not exceeded.
    Matched MeSH terms: Radiation Dosage
  11. Wong TW, Wahab S, Anthony Y
    Drug Dev Ind Pharm, 2007 Jul;33(7):737-46.
    PMID: 17654022
    The drug release behavior of beads made of poly(methyl vinyl ether-co-maleic acid) was investigated with respect to the influence of microwave irradiation. The beads were prepared by an extrusion method with sodium diclofenac as a model water-soluble drug. The beads were subjected to microwave irradiation at 80 W for 5 and 20 min, and at 300 W for 1 min 20 s and 5 min 20 s. The profiles of drug dissolution, drug content, drug-polymer interaction, and polymer-polymer interaction were determined by using dissolution testing, drug content assay, differential scanning calorimetry, and Fourier transform infra-red spectroscopy. Keeping the level of supplied irradiation energy identical, treatment of beads by microwave at varying intensities of irradiation did not bring about similar drug release profiles. The extent and rate of drug released from beads were markedly enhanced through treating the samples by microwave at 80 W as a result of loss of polymer-polymer interaction via the (CH(2))(n) moiety, but decreased upon treating the beads by microwave at 300 W following polymer-polymer interaction via the O-H, COOH, and COO(-) moieties as well as drug-polymer interaction via the N-H, O-H, COO(-), and C-O moieties. The beads treated by microwave at 300 W exhibited a higher level of drug release retardation capacity than those that were treated by microwave at 80 W in spite of polymer-polymer interaction via the (CH(2))(n) moiety was similarly reduced in the matrix. The mechanism of drug release of both microwave-treated and untreated beads tended to follow zero order kinetics. The drug release was markedly governed by the state of polymer relaxation of the matrix and was in turn affected by the state of polymer-polymer and/or drug-polymer interaction in beads.
    Matched MeSH terms: Diclofenac/radiation effects; Maleates/radiation effects; Polyethylenes/radiation effects
  12. Rahman A, Islam MT, Samsuzzaman M, Singh MJ, Akhtaruzzaman M
    Materials (Basel), 2016 May 11;9(5).
    PMID: 28773479 DOI: 10.3390/ma9050358
    In this paper, a novel phenyl-thiophene-2-carbaldehyde compound-based flexible substrate material has been presented. Optical and microwave characterization of the proposed material are done to confirm the applicability of the proposed material as a substrate. The results obtained in this work show that the phenyl-thiophene-2-carbaldehyde consists of a dielectric constant of 3.03, loss tangent of 0.003, and an optical bandgap of 3.24 eV. The proposed material is analyzed using commercially available EM simulation software and validated by the experimental analysis of the flexible substrate. The fabricated substrate also shows significant mechanical flexibility and light weight. The radiating copper patch deposited on the proposed material substrate incorporated with partial ground plane and microstrip feeding technique shows an effective impedance bandwidth of 3.8 GHz. It also confirms an averaged radiation efficiency of 81% throughout the frequency band of 5.4-9.2 GHz.
    Matched MeSH terms: Electromagnetic Radiation
  13. Khandaker MU, Asaduzzaman K, Sulaiman AFB, Bradley DA, Isinkaye MO
    Mar Pollut Bull, 2018 Feb;127:654-663.
    PMID: 29475708 DOI: 10.1016/j.marpolbul.2017.12.055
    Study is made of the radioactivity in the beach sands of Langkawi island, a well-known tourist destination. Investigation is made of the relative presence of the naturally occurring radionuclide 40K and the natural-series indicator radionuclides 226Ra and 232Th, the gamma radiation exposure also being estimated. Sample quantities of black and white sand were collected for gamma ray spectrometry, yielding activity concentration in black sands of 226Ra, 232Th and 40K from 451±9 to 2411±65Bqkg-1 (mean of 1478Bqkg-1); 232±4 to 1272±35Bqkg-1 (mean of 718Bqkg-1) and 61±6 to 136±7Bqkg-1 (mean of 103Bqkg-1) respectively. Conversely, in white sands the respective values for 226Ra and 232Th were appreciably lower, at 8.3±0.5 to 13.7±1.4Bqkg-1 (mean of 9.8Bqkg-1) and 4.5±0.7 to 9.4±1.0Bqkg-1 (mean of 5.9Bqkg-1); 40K activities differed insubstantially from that in black sands, at 85±4 to 133±7Bqkg-1 with a mean of 102Bqkg-1. The mean activity concentrations of 226Ra and 232Th in black sands are comparable with that of high background areas elsewhere in the world. The heavy minerals content gives rise to elevated 226Ra and 232Th activity concentrations in all of black sand samples. Evaluation of the various radiological risk parameters points to values which in some cases could be in excess of recommendations providing for safe living and working. Statistical analysis examines correlations between the origins of the radionuclides, also identifying and classifying the radiological parameters. Present results may help to form an interest in rare-earth resources for the electronics industry, power generation and the viability of nuclear fuels cycle resources.
    Matched MeSH terms: Background Radiation*; Radiation Monitoring/methods*
  14. Norsuddin NM, Mei Sin JG, Ravintaran R, Arasaratnam S, Abdul Karim MK
    Appl Radiat Isot, 2023 Feb;192:110525.
    PMID: 36436228 DOI: 10.1016/j.apradiso.2022.110525
    This study compares the mean glandular dose (MGD) across 2D, 3D projection and Contrast-Enhanced Digital Mammography (CEDM) mammographic techniques. The important metadata were extracted from the digital mammography console. 650 subjects were clustered based on projections, age and CBT. The MGD of 2D, 3D, and CEDM was positively correlated with CBT but inversely correlated with the age factor. This study indicate MGD of CEDM was 16% and 22% lower compared to 2D and 3D techniques, respectively.
    Matched MeSH terms: Radiation Dosage
  15. Sulieman A, Salah H, Rabbaa M, Abuljoud M, Alkhorayef M, Tahir D, et al.
    Appl Radiat Isot, 2023 Mar;193:110626.
    PMID: 36640699 DOI: 10.1016/j.apradiso.2022.110626
    Breast cancer is a common malignancy for females (25% of female cancers) and also has low incidence in males. It was estimated that 1% of all breast malignancies occur in males with mortality rate about 20%, with annual increase in incidence. Risk factors include age, family history, exposure to ionizing radiation and high estrogen and low of androgens hormones level. Diagnosis and screening are challenging due to limiting effectiveness of breast cancer screening. Therefore, patients may expose to ionizing radiation that may contribute in breast cancer incidence in males. In literature, limited studies were published regarding radiation exposure for males during mammography. The objective of this research is to quantify patient doses during male mammogram and to estimate the projected radiogenic risk during the procedure. In total, 42 male patients were undergone mammogram for breast cancer diagnosis during two consecutive years. The mean and range of patient age (years) is 45 (23-80). The mean and standard deviation (SD) of the peak tube potential and tube current time product are 28.64 ± 2. and 149 ± 35.1, respectively. The mean, and range of patients' entrance surface air kerma (ESAK, mGy) per single breast procedure was 5.3 (0.47-27.5). Male patient's received comparable radiation dose per mammogram compared to female procedures. With increasing incidence of male breast cancer, proper guidelines are necessary for the mammographic procedure are necessary to reduce unnecessary radiation doses and radiogenic risk.
    Matched MeSH terms: Radiation Dosage
  16. Shamekhi F, Shuhaimi M, Ariff A, Manap YA
    Folia Microbiol (Praha), 2013 Mar;58(2):91-101.
    PMID: 22843029 DOI: 10.1007/s12223-012-0183-9
    The purpose of this study was to improve the survival of Bifidobacterium animalis subsp. lactis 10140 during freeze-drying process by microencapsulation, using a special pediatric prebiotics mixture (galactooligosaccharides and fructooligosaccharides). Probiotic microorganisms were encapsulated with a coat combination of prebiotics-calcium-alginate prior to freeze-drying. Both encapsulated and free cells were then freeze-dried in their optimized combinations of skim milk and prebiotics. Response surface methodology (RSM) was used to produce a coating combination as well as drying medium with the highest cell viability during freeze-drying. The optimum encapsulation composition was found to be 2.1 % Na-alginate, 2.9 % prebiotic, and 21.7 % glycerol. Maximum survival predicted by the model was 81.2 %. No significant (p > 0.05) difference between the predicted and experimental values verified the adequacy of final reduced models. The protection ability of encapsulation was then examined over 120 days of storage at 4 and 25 °C and exposure to a sequential model of infantile GIT conditions including both gastric conditions (pH 3.0 and 4.0, 90 min, 37 °C) and intestinal conditions (pH 7.5, 5 h, 37 °C). Significantly improved cell viability showed that microencapsulation of B. lactis 10140 with the prebiotics was successful in producing a stable symbiotic powdery nutraceutical.
    Matched MeSH terms: Bifidobacterium/radiation effects; Probiotics/radiation effects*; Microbial Viability/radiation effects*
  17. Narayanan SN, Kumar RS, Potu BK, Nayak S, Mailankot M
    Clinics (Sao Paulo), 2009;64(3):231-4.
    PMID: 19330250
    INTRODUCTION: With the tremendous increase in number of mobile phone users world wide, the possible risks of this technology have become a serious concern.

    OBJECTIVE: We tested the effects of mobile phone exposure on spatial memory performance.

    MATERIALS AND METHODS: Male Wistar rats (10-12 weeks old) were exposed to 50 missed calls/day for 4 weeks from a GSM (900/1800 MHz) mobile phone in vibratory mode (no ring tone). After the experimental period, the animals were tested for spatial memory performance using the Morris water maze test.

    RESULTS: Both phone exposed and control animals showed a significant decrease in escape time with training. Phone exposed animals had significantly (approximately 3 times) higher mean latency to reach the target quadrant and spent significantly (approximately 2 times) less time in the target quadrant than age- and sex-matched controls.

    CONCLUSION: Mobile phone exposure affected the acquisition of learned responses in Wistar rats. This in turn points to the poor spatial navigation and the object place configurations of the phone-exposed animals.

    Matched MeSH terms: Memory/radiation effects*; Spatial Behavior/radiation effects*; Maze Learning/radiation effects*
  18. Shameli K, Ahmad MB, Yunus WM, Ibrahim NA, Gharayebi Y, Sedaghat S
    Int J Nanomedicine, 2010 Dec 01;5:1067-77.
    PMID: 21170354 DOI: 10.2147/IJN.S15033
    Silver nanoparticles (Ag-NPs) were synthesized into the interlamellar space of montmorillonite (MMT) by using the γ-irradiation technique in the absence of any reducing agent or heat treatment. Silver nitrate and γ-irradiation were used as the silver precursor and physical reducing agent in MMT as a solid support. The MMT was suspended in the aqueous AgNO(3) solution, and after the absorption of silver ions, Ag(+) was reduced using the γ-irradiation technique. The properties of Ag/MMT nanocomposites and the diameters of Ag-NPs were studied as a function of γ-irradiation doses. The interlamellar space limited particle growth (d-spacing [d(s)] = 1.24-1.42 nm); powder X-ray diffraction and transmission electron microscopy (TEM) measurements showed the production of face-centered cubic Ag-NPs with a mean diameter of about 21.57-30.63 nm. Scanning electron microscopy images indicated that there were structure changes between the initial MMT and Ag/MMT nanocomposites under the increased doses of γ-irradiation. Furthermore, energy dispersive X-ray fluorescence spectra for the MMT and Ag/ MMT nanocomposites confirmed the presence of elemental compounds in MMT and Ag-NPs. The results from ultraviolet-visible spectroscopy and TEM demonstrated that increasing the γ-irradiation dose enhanced the concentration of Ag-NPs. In addition, the particle size of the Ag-NPs gradually increased from 1 to 20 kGy. When the γ-irradiation dose increased from 20 to 40 kGy, the particle diameters decreased suddenly as a result of the induced fragmentation of Ag-NPs. Thus, Fourier transform infrared spectroscopy suggested that the interactions between Ag-NPs with the surface of MMT were weak due to the presence of van der Waals interactions. The synthesized Ag/MMT suspension was found to be stable over a long period of time (ie, more than 3 months) without any sign of precipitation.
    Matched MeSH terms: Bentonite/radiation effects; Nanocomposites/radiation effects; Metal Nanoparticles/radiation effects
  19. Yeang HY
    Ann Bot, 2015 Jul;116(1):15-22.
    PMID: 26070640 DOI: 10.1093/aob/mcv070
    BACKGROUND AND AIMS: An endogenous rhythm synchronized to dawn cannot time photosynthesis-linked genes to peak consistently at noon since the interval between sunrise and noon changes seasonally. In this study, a solar clock model that circumvents this limitation is proposed using two daily timing references synchronized to noon and midnight. Other rhythmic genes that are not directly linked to photosynthesis, and which peak at other times, also find an adaptive advantage in entrainment to the solar rhythm.

    METHODS: Fourteen datasets extracted from three published papers were used in a meta-analysis to examine the cyclic behaviour of the Arabidopsis thaliana photosynthesis-related gene CAB2 and the clock oscillator genes TOC1 and LHY in T cycles and N-H cycles.

    KEY RESULTS: Changes in the rhythms of CAB2, TOC1 and LHY in plants subjected to non-24-h light:dark cycles matched the hypothesized changes in their behaviour as predicted by the solar clock model, thus validating it. The analysis further showed that TOC1 expression peaked ∼5·5 h after mid-day, CAB2 peaked close to noon, while LHY peaked ∼7·5 h after midnight, regardless of the cycle period, the photoperiod or the light:dark period ratio. The solar clock model correctly predicted the zeitgeber timing of these genes under 11 different lighting regimes comprising combinations of seven light periods, nine dark periods, four cycle periods and four light:dark period ratios. In short cycles that terminated before LHY could be expressed, the solar clock correctly predicted zeitgeber timing of its expression in the following cycle.

    CONCLUSIONS: Regulation of gene phases by the solar clock enables the plant to tell the time, by which means a large number of genes are regulated. This facilitates the initiation of gene expression even before the arrival of sunrise, sunset or noon, thus allowing the plant to 'anticipate' dawn, dusk or mid-day respectively, independently of the photoperiod.

    Matched MeSH terms: Biological Clocks/radiation effects; Circadian Rhythm/radiation effects*; Arabidopsis/radiation effects
  20. Yang Harmony TC, Yusof N, Ramalingam S, Baharin R, Syahrom A, Mansor A
    Clin Orthop Relat Res, 2022 Feb 01;480(2):407-418.
    PMID: 34491235 DOI: 10.1097/CORR.0000000000001968
    BACKGROUND: Gamma irradiation, which minimizes the risk of infectious disease transmission when human bone allograft is used, has been found to negatively affect its biomechanical properties. However, in those studies, the deep-freezing temperature during irradiation was not necessarily maintained during transportation and sterilization, which may have affected the findings. Prior reports have also suggested that controlled deep freezing may mitigate the detrimental effects of irradiation on the mechanical properties of bone allograft.

    QUESTION/PURPOSE: Does a controlled deep-freezing temperature during irradiation help preserve the compressive mechanical properties of human femoral cortical bone allografts?

    METHODS: Cortical bone cube samples, each measuring 64 mm3, were cut from the mid-diaphyseal midshaft of five fresh-frozen cadaver femurs (four male donors, mean [range] age at procurement 42 years [42 to 43]) and were allocated via block randomization into one of three experimental groups (with equal numbers of samples from each donor allocated into each group). Each experimental group consisted of 20 bone cube samples. Samples irradiated in dry ice were subjected to irradiation doses ranging from 26.7 kGy to 27.1 kGy (mean 26.9 kGy) at a deep-freezing temperature below -40°C (the recommended long-term storage temperature for allografts). Samples irradiated in gel ice underwent irradiation doses ranging from 26.2 kGy and 26.4 kGy (mean 26.3 kGy) in a freezing temperature range between -40°C and 0°C. Acting as controls, samples in a third group were not subjected to gamma irradiation. The mechanical properties (0.2% offset yield stress, ultimate compression stress, toughness, and the Young modulus) of samples from each group were subsequently evaluated via axial compression loading to failure along the long axis of the bone. The investigators were blinded to sample group during compression testing.

    RESULTS: The mean ultimate compression stress (84 ± 27 MPa versus 119 ± 31 MPa, mean difference 35 [95% CI 9 to 60]; p = 0.005) and toughness (3622 ± 1720 kJ/m3 versus 5854 ± 2900 kJ/m3, mean difference 2232 [95% CI 70 to 4394]; p = 0.009) of samples irradiated at a higher temperature range (-40°C to 0°C) were lower than in those irradiated at deep-freezing temperatures (below -40°C). The mean 0.2% offset yield stress (73 ± 28 MPa versus 109 ± 38 MPa, mean difference 36 [95% CI 11 to 60]; p = 0.002) and ultimate compression stress (84 ± 27 MPa versus 128 ± 40 MPa, mean difference 44 [95% CI 17 to 69]; p < 0.001) of samples irradiated at a higher temperature range (-40°C to 0°C) were lower than the nonirradiated control group samples. The mean 0.2% offset yield stress (73 ± 28 MPa versus 101 ± 28 MPa, mean difference 28 [95% CI 3 to 52]; p = 0.02; effect size = 1.0 [95% CI 0.8 to 1.2]) of samples irradiated at higher temperature range (-40°C to 0°C) were no different with the numbers available to those irradiated at deep-freezing temperature. The mean toughness (3622 ± 1720 kJ/m3 versus 6231 ± 3410 kJ/m3, mean difference 2609 [95% CI 447 to 4771]; p = 0.02; effect size = 1.0 [95% CI 0.8 to 1.2]) of samples irradiated at higher temperature range (-40°C to 0°C) were no different with the numbers available to the non-irradiated control group samples. The mean 0.2% offset yield stress, ultimate compression stress, and toughness of samples irradiated in deep-freezing temperatures (below -40°C) were not different with the numbers available to the non-irradiated control group samples. The Young modulus was not different with the numbers available among the three groups.

    CONCLUSION: In this study, maintenance of a deep-freezing temperature below -40°C, using dry ice as a cooling agent, consistently mitigated the adverse effects of irradiation on the monotonic-compression mechanical properties of human cortical bone tissue. Preserving the mechanical properties of a cortical allograft, when irradiated in a deep-freezing temperature, may have resulted from attenuation of the deleterious, indirect effects of gamma radiation on its collagen architecture in a frozen state. Immobilization of water molecules in this state prevents radiolysis and the subsequent generation of free radicals. This hypothesis was supported by an apparent loss of the protective effect when a range of higher freezing temperatures was used during irradiation.

    CLINICAL RELEVANCE: Deep-freezing temperatures below -40°C during gamma irradiation may be a promising approach to better retain the native mechanical properties of cortical bone allografts. A further study of the effect of deep-freezing during gamma radiation sterilization on sterility and other important biomechanical properties of cortical bone (such as, tensile strength, fracture toughness, and fatigue) is needed to confirm these findings.

    Matched MeSH terms: Femur/radiation effects*; Compressive Strength/radiation effects*; Cortical Bone/radiation effects*
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