Displaying publications 61 - 80 of 282 in total

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  1. Proton conducting polymer electrolytes based on PVDF-HFP and PVDF-HFP/PEMA blend
    Rudhziah S, Muda N, Ibrahim S, Rahman A, Mohamed N
    Sains Malaysiana, 2011;40:1179-1186.
    In the present work, polymer electrolytes of poly(vinylidene fluoride co-hexafluoroproplyne) (PVDF-HFP) and PVDF-HFP/poly(ethyl methacrylate) (PVDF-HFP/PEMA) blend complexed with different concentrations of ammonium triflate (NH4CF3SO3) were prepared and characterized. The structural and thermal properties of the electrolytes were studied by XRD and DSC while the electrical properties were investigated by impedance spectroscopy. Ionic transference number measurements were done by D.C polarization technique. The results of these study showed that the PVDF-HFP/PEMA based electrolytes exhibit higher ionic conductivity as compared to PVDF-HFP based electrolytes. This could be attributed to the higher degree of amorphicity in the PVDF-HFP/PEMA based electrolytes. The results of ionic transference number measurements showed that the charge transport in these electrolytes was mainly due to ions and only negligible contribution comes from electrons.
    Matched MeSH terms: Electrons
  2. Electronic structure and optical properties of the dialkali metal monotelluride compounds: Ab initio study
    Souadia Z, Bouhemadou A, Bin-Omran S, Khenata R, Al-Douri Y, Al Essa S
    J Mol Graph Model, 2019 07;90:77-86.
    PMID: 31031219 DOI: 10.1016/j.jmgm.2019.04.008
    Structural parameters, electronic structure and optical properties of the dialkali metal monotelluride M2Te (M = Li, Na, K and Rb) compounds in the cubic antifluorite structure were investigated via ab initio calculations using the all electron linearized augmented plane wave approach based on density functional theory with and without including spin-orbit coupling (SOC). The exchange-correlation interactions were described within the PBEsol version of the generalized gradient approximation and Tran-Blaha modified Becke-Johnson potential (TB-mBJ). Optimized equilibrium lattice parameters are in excellent accordance with existing measured ones. Computed energy band dispersions show that the studied compounds are large band gap materials. Inclusion of SOC reduces the band gap value compared to the corresponding one calculated without including SOC. Determination of the energy band character and interatomic bonding nature are performed using the densities of states diagrams and charge density distribution map. Linear optical function spectra are predicted for a wide energy range and the origin of the dielectric function spectrum peaks are determined.
    Matched MeSH terms: Electrons
  3. Growth conditions of graphene grown in chemical vapour deposition (CVD)
    Mohamad Shukri Sirat, Edhuan Ismail, Hadi Purwanto, Mohd Hanafi Ani, Mohd Asyadi Azam Mohd Abid
    Sains Malaysiana, 2017;46:1033-1038.
    The fabrication of high quality graphene has become the main interest in current chemical vapour deposition (CVD) method due to the scalability for mass production of graphene-based electronic devices. The quality of graphene is determined by defect density, number of layers and properties changed such as electron mobility, transparency and conductivity as compared to the pristine graphene. Here, we did a study on the effects of reaction conditions such as methane, CH4 concentration and deposition time towards the quality of graphene produced. We found that by lowering both CH4 concentration down to 20% and deposition time to 5 min, a better quality graphene was produced with higher I2D/IG ratio of 0.82 compared to other reaction condition. Through the analysis, we concluded that there are two important parameters to be controlled to obtain high quality graphene.
    Matched MeSH terms: Electrons
  4. Aryl diazonium modification for improved graphite fiber brush in microbial fuel cell
    Siti Farah Nadiah Rusli, Mimi Hani Abu Bakar, Loh Kee Shyuan, Mohd Shahbudin Mastar, Seratul Jemiah Abdul Rani, Mohd Shahbudin Mastar
    Sains Malaysiana, 2018;47:3017-3023.
    Aryl diazonium salts are coupling agents that assist in molecules attachment to interfaces for sensing purposes. Despite
    not being fully explored and not yet widely applicable for cell-based sensors, the high stability of aryl diazonium salt
    formed sensing system is highly favorable in biological applications. Carbon-based electrodes are the most commonly
    used in aryl diazonium modification due to its post grafting stable C-C bond formation. Here, salt bridge based microbial
    fuel cells (MFCs) were used to study on the effect of aryl diazonium modification on the anode graphite fibre brush. Aryl
    diazonium salts were in situ generated by the diazonation of p-phenylenediamine with NaNO2 in HCl solution. The
    electrochemical performance of the aryl diazonium modified graphite brush MFC was measured and compared with the
    unmodified graphite brush MFC. The power output of the modified graphite brush bioanode was higher (8.33 W/m3
    )
    than the unmodified graphite brush (7.60 W/m3
    ) after 20 days of operation with ferricyanide as the catholyte. After 70
    days of operation using phosphate buffer solution as the catholyte, the Pmax of modified brush was three times higher
    (0.06 W/m3
    ) than of the unmodified brush (0.02 W/m3
    ), which indicates an enhanced binding towards the substrate that
    facilitates a better electron transfer between the microbial and electrode surface.
    Matched MeSH terms: Electrons
  5. Optical Properties of Azo-Benzothiazole Side Chain Liquid Crystalline Polymers: Effect of Solvents, Substituents and Temperatures
    Dzulkharnien NSF, Karim MR, Zahid NI, Rahman NMMA, Abdullah I, Salleh NM
    J Fluoresc, 2019 Jul;29(4):1049-1056.
    PMID: 31338718 DOI: 10.1007/s10895-019-02418-9
    The optical properties of a series of side chain liquid crystalline polymers (P1-P3) containing azo-benzothiazole mesogen with different terminal substituents (-H, -CH3 and -OCH2CH3) in four organic solvents of varying polarity have been investigated by absorption and fluorescence spectral analysis. Solvatochromic studies of P1-P3 did not show any regular variation on the absorption and emission intensities with changing the polarity of solvent. Theoretical studies were performed based on different solvent correlation methods such as Dimroth-Reichardt and Kamlet-Taft methods to investigate the solute-solvent interactions. Both absorption and emission maxima of investigated polymers were bathochromically shifted with the replacement of sixth position hydrogen atom by electron donating groups in benzothiazole moiety. The emission intensities of the studied polymers showed decreasing trend with increasing temperature.
    Matched MeSH terms: Electrons
  6. Observation of the Production of Three Massive Gauge Bosons at sqrt[s]=13  TeV
    Sirunyan AM, Tumasyan A, Adam W, Ambrogi F, Bergauer T, Dragicevic M, et al.
    Phys Rev Lett, 2020 Oct 09;125(15):151802.
    PMID: 33095594 DOI: 10.1103/PhysRevLett.125.151802
    The first observation is reported of the combined production of three massive gauge bosons (VVV with V=W, Z) in proton-proton collisions at a center-of-mass energy of 13 TeV. The analysis is based on a data sample recorded by the CMS experiment at the CERN LHC corresponding to an integrated luminosity of 137  fb^{-1}. The searches for individual WWW, WWZ, WZZ, and ZZZ production are performed in final states with three, four, five, and six leptons (electrons or muons), or with two same-sign leptons plus one or two jets. The observed (expected) significance of the combined VVV production signal is 5.7 (5.9) standard deviations and the corresponding measured cross section relative to the standard model prediction is 1.02_{-0.23}^{+0.26}. The significances of the individual WWW and WWZ production are 3.3 and 3.4 standard deviations, respectively. Measured production cross sections for the individual triboson processes are also reported.
    Matched MeSH terms: Electrons
  7. Measurement of the Jet Mass Distribution and Top Quark Mass in Hadronic Decays of Boosted Top Quarks in pp Collisions at sqrt[s]=13  TeV
    Sirunyan AM, Tumasyan A, Adam W, Ambrogi F, Bergauer T, Brandstetter J, et al.
    Phys Rev Lett, 2020 May 22;124(20):202001.
    PMID: 32501048 DOI: 10.1103/PhysRevLett.124.202001
    A measurement is reported of the jet mass distribution in hadronic decays of boosted top quarks produced in pp collisions at sqrt[s]=13  TeV. The data were collected with the CMS detector at the LHC and correspond to an integrated luminosity of 35.9  fb^{-1}. The measurement is performed in the lepton+jets channel of tt[over ¯] events, where the lepton is an electron or muon. The products of the hadronic top quark decay t→bW→bqq[over ¯]^{'} are reconstructed as a single jet with transverse momentum larger than 400 GeV. The tt[over ¯] cross section as a function of the jet mass is unfolded at the particle level and used to extract a value of the top quark mass of 172.6±2.5  GeV. A novel jet reconstruction technique is used for the first time at the LHC, which improves the precision by a factor of 3 relative to an earlier measurement. This highlights the potential of measurements using boosted top quarks, where the new technique will enable future precision measurements.
    Matched MeSH terms: Electrons
  8. Photoluminescence Investigation of Carrier Localization in Colloidal PbS and PbS/MnS Quantum Dots
    Zaini MS, Liew JYC, Alang Ahmad SA, Mohmad AR, Ahmad Kamarudin M
    ACS Omega, 2020 Dec 08;5(48):30956-30962.
    PMID: 33324803 DOI: 10.1021/acsomega.0c03768
    The existence of surface organic capping ligands on quantum dots (QDs) has limited the potential in QDs emission properties and energy band gap structure alteration as well as the carrier localization. This drawback can be addressed via depositing a thin layer of a semiconductor material on the surface of QDs. Herein, we report on the comparative study for photoluminescent (PL) properties of PbS and PbS/MnS QDs. The carrier localization effect due to the alteration of energy band gap structure and carrier recombination mechanism in the QDs were investigated via PL measurements in a temperature range of 10-300 K with the variation of the excitation power from 10 to 200 mW. For PbS QDs, the gradient of integrated PL intensity (IPL) as a function of excitation power density graph was less than unity. When the MnS shell layer was deposited onto the PbS core, the PL emission exhibited a blue shift, showing dominant carrier recombination. It was also found that the full width half-maximum showed a gradual broadening with the increasing temperature, affirming the electron-phonon interaction.
    Matched MeSH terms: Electrons
  9. Fulltext Effects of 3.0 MeV electron irradiation on 4H-SiC wafer properties
    Yusof Abdullah, Mohd Reusmaazran Yusof, Megat Harun Al Rashid Megat Ahmad, Hafizal Yazid, Abdul Aziz Mohamed, Norazila Mat Sali, et al.
    Jurnal Sains Nuklear Malaysia, 2013;25(1):9-15.
    MyJurnal
    Effects of 3 MeV electron (10 mA) irradiation at room temperature on the phase, microstructure,
    electrical and life time properties of 4H-SiC wafer were investigated by scanning electron
    microscopy (SEM), X-ray diffraction (XRD), four point probe current-voltage measurements and
    positron annihilation spectroscopy. It was found that irradiation damage in SiC wafer is
    significantly increased with the increase of radiation dose as observed in SEM. Irradiation also
    resulted in modification of crystallite size as identified by XRD. The resistance of a sample before
    irradiation was found to be 0.8 MΩ, whereas for a sample irradiated at 200 kGy, the resistance as
    measured by four point probe was 5.2 MΩ. It seems that the increase of resistance hence, reduction
    in conductivities could be due to defects induced by the radiation dose received then created
    leakage currents at both reverse and low-forward biases and creation of traps in the SiC.
    Meanwhile positron annihilation spectroscopy (PAS) was used to analyse the life time of irradiated
    samples which nonetheless shows that all irradiated sample have similar life time of 151 ps. It was
    observed that that no degradation process of materials experienced by SiC wafer irradiated at 500
    kGy.
    Matched MeSH terms: Electrons
  10. Signet-ring Cell Lymphoma-a Case Report
    Masir N, Cheong SK, Noordin K
    Hematology, 2001;6(3):187-92.
    PMID: 27420125 DOI: 10.1080/10245332.2001.11746571
    A case of signet-ring cell lymphoma diagnosed initially by fine needle aspiration cytology is reported. This rare tumor is a variant of follicular lymphoma, which closely resembles metastatic adenocarcinoma and other tumors which exhibit signet-ring cell appearance. Correct diagnosis can be achieved by careful morphologic analysis together with positive reactivity with lymphoid markers. The cytohistologic, immunohistochemical and electron microscopic features are described, and the differ ential diagnostic considerations are discussed in the report.
    Matched MeSH terms: Electrons
  11. Fulltext Determination optimal aperture parameters for neutron collimator design using MCNP code
    Wagiran, Husin, Supramaniam, Thiagu, Azali Mohamad, Abdul Aziz Mohamed, Faridah M. Idris
    Journal of Nuclear and Related Technologies, 2009;2009(2):49-62.
    MyJurnal
    Neutron aperture is one of the collimator components in a neutron radiography facility. The optimum design of neutron aperture is very importance in order to obtain largest L/D ratio with highest thermal neutron flux and low gamma-rays at the image plane. In this study, the optimization of neutron aperture parameters were done using Monte Carlo N-Particle Transport Code, version five (MCNP5). This code has a capability to simulate the neutron, photon, and electron or coupled of neutron/photon/electron transport, including the capability to calculate eigen values for critical system. The aperture parameters concerned in this study are the selection of best aperture material, aperture thickness, aperture position and aperture center hole diameter. In these simulations, vacuum beam port medium was applied.
    Matched MeSH terms: Electrons
  12. Fulltext Laboratory scale electron beam system for treatment of flue gases from diesel combustion
    Siti A'iasah Hashim, Khairul Zaman Mohd Dahlan, Khomsaton Abu Bakar, Ayub Muhamad
    Journal of Nuclear and Related Technologies, 2004;2004(2):29-37.
    MyJurnal
    A laboratory scale test rig to treat simulated flue gas using electron beam technology was installed at the Alurtron EB-Irradiation Center, MINT. The experiment test rig was proposed as a result of feasibility studies conducted jointly by IAEA, MINT and TNB Research in 1997. The test rig system consists of several components, among others, diesel generator sets, pipe ducts, spray cooler, ammonia dosage system, irradiation vessel, bag filter and gas analyzers. The installation was completed and commissioned in October 2001. Results from the commissioning test runs and subsequent experimental work showed that the efficiency of flue gas treatment is high. It was proven that electron beam technology might be applied in the treatment of air pollutants. This paper describes the design and work function of the individual major components as well as the full system function. Results from the initial experimental works are also presented.
    Matched MeSH terms: Electrons
  13. Fulltext Lenra as compatibilizer in NR/HDPE blends
    Dahlan Mohd, Mahathir Mohamed
    Journal of Nuclear and Related Technologies, 2006;2006(1):9-17.
    MyJurnal
    Polymer blends of 60/40 NR/HDPE were prepared using Brabender PL2000 Plasticorder with 60g capacity. The blends were added with radiation-sensitive natural rubber (NR)-based compatibilizer, known as LENRA. They were irradiated with electron-beam radiation at various doses. The efficacy of the compatibilizer was monitored by measuring various properties of the blends such as physical and dynamic mechanical properties including morphological studies by electron microscopic technique. Early results show that the addition of LENRA improves the properties of the TPNR blends.
    Matched MeSH terms: Electrons
  14. Fulltext Radiation crosslinked natural rubber/ethylene vinyl acetate/clay nanocomposites - effect of organoclay concentration
    Jamaliah Sharif, Khairul Zaman Mohd Dahlan, Wan Md Zin Wan Yunus
    Journal of Nuclear and Related Technologies, 2008;2008(1):65-80.
    MyJurnal
    Effects of organoclay concentration on the properties of radiation crosslinked natural rubber (NR)/ ethylene vinyl acetate (EVA)/clay nanocomposites were investigated. The NR/EVA blend with a ratio of 40/60 was melt blended with different concentration of either dodecyl ammonium montmorillonite (DDA-MMT) or dimethyl dihydrogenated tallow quarternary ammonium montmorillonite (C20A). Composite of NR/EVA blend with unmodified clay (Na-MMT) was also prepared for comparison purposes. The composites were irradiated with electron beam (EB) at an optimum irradiation dose. The formation of radiation-induced crosslinking depends on the type and concentration of the organoclay used in the preparation of nanocomposites as measured by gel content. Changes in the interlayer distance of the silicate layers with the increase of organoclay concentration were shown by the XRD results. Variation in the tensile properties of the nanocomposites with the increase of organoclay concentration depends on the formation of crosslinking as well as reinforcement effect of the organoclay. Improvement in thermal stability of the NR/EVA blend was also observed with the presence of organoclay.
    Matched MeSH terms: Electrons
  15. Fulltext First-Principles Studies for Electronic Structure and Optical Properties of Strontium Doped β-Ga2O3
    Kean Ping L, Mohamed MA, Kumar Mondal A, Mohamad Taib MF, Samat MH, Berhanuddin DD, et al.
    Micromachines (Basel), 2021 Mar 24;12(4).
    PMID: 33804978 DOI: 10.3390/mi12040348
    The crystal structure, electron charge density, band structure, density of states, and optical properties of pure and strontium (Sr)-doped β-Ga2O3 were studied using the first-principles calculation based on the density functional theory (DFT) within the generalized-gradient approximation (GGA) with the Perdew-Burke-Ernzerhof (PBE). The reason for choosing strontium as a dopant is due to its p-type doping behavior, which is expected to boost the material's electrical and optical properties and maximize the devices' efficiency. The structural parameter for pure β-Ga2O3 crystal structure is in the monoclinic space group (C2/m), which shows good agreement with the previous studies from experimental work. Bandgap energy from both pure and Sr-doped β-Ga2O3 is lower than the experimental bandgap value due to the limitation of DFT, which will ignore the calculation of exchange-correlation potential. To counterbalance the current incompatibilities, the better way to complete the theoretical calculations is to refine the theoretical predictions using the scissor operator's working principle, according to literature published in the past and present. Therefore, the scissor operator was used to overcome the limitation of DFT. The density of states (DOS) shows the hybridization state of Ga 3d, O 2p, and Sr 5s orbital. The bonding population analysis exhibits the bonding characteristics for both pure and Sr-doped β-Ga2O3. The calculated optical properties for the absorption coefficient in Sr doping causes red-shift of the absorption spectrum, thus, strengthening visible light absorption. The reflectivity, refractive index, dielectric function, and loss function were obtained to understand further this novel work on Sr-doped β-Ga2O3 from the first-principles calculation.
    Matched MeSH terms: Electrons
  16. Differential cross sections for intermediate-energy electron scattering from α-tetrahydrofurfuryl alcohol: excitation of electronic-states
    Chiari L, Duque HV, Jones DB, Thorn PA, Pettifer Z, da Silva GB, et al.
    J Chem Phys, 2014 Jul 14;141(2):024301.
    PMID: 25028013 DOI: 10.1063/1.4885856
    We report on measurements of differential cross sections (DCSs) for electron impact excitation of a series of Rydberg electronic-states in α-tetrahydrofurfuryl alcohol (THFA). The energy range of these experiments was 20-50 eV, while the scattered electron was detected in the 10°-90° angular range. There are currently no other experimental data or theoretical computations against which we can directly compare the present measured results. Nonetheless, we are able to compare our THFA DCSs with earlier cross section measurements for Rydberg-state electronic excitation for tetrahydrofuran, a similar cyclic ether, from Do et al. [J. Chem. Phys. 134, 144302 (2011)]. In addition, "rotationally averaged" elastic DCSs, calculated using our independent atom model with screened additivity rule correction approach are also reported. Those latter results give integral cross sections consistent with the optical theorem, and supercede those from the only previous study of Milosavljević et al. [Eur. Phys. J. D 40, 107 (2006)].
    Matched MeSH terms: Electrons
  17. Enhancing the radiation dose detection sensitivity of optical fibres
    Bradley DA, Mahdiraji GA, Ghomeishi M, Dermosesian E, Adikan FR, Rashid HA, et al.
    Appl Radiat Isot, 2015 Jun;100:43-9.
    PMID: 25533626 DOI: 10.1016/j.apradiso.2014.12.005
    A method for improving the thermoluminescence (TL) yield of silica-based optical fibres is demonstrated. Using silica obtained from a single manufacturer, three forms of pure (undoped) fibre (capillary-, flat-, and photonic crystal fibre (PCF)) and two forms of Ge-doped fibre (capillary- and flat-fibre) were fabricated. The pure fibre samples were exposed to 6 and 21MeV electrons, the doped fibres to 6MV photons. The consistent observation of large TL yield enhancement is strongly suggestive of surface-strain defects generation. For 6MeV irradiations of flat-fibre and PCF, respective TL yields per unit mass of about 12.0 and 17.5 times that of the undoped capillary-fibre have been observed. Similarly, by making a Ge-doped capillary-fibre into flat-fibre, the TL response is found to increase by some 6.0 times. Thus, in addition to TL from the presence of a dopant, the increase in fused surface areas of flat-fibres and PCF is seen to be a further important source of TL. The glow-curves of the undoped fibres have been analysed by computational deconvolution. Trap centre energies have been estimated and compared for the various fibre samples. Two trap centre types observed in capillary-fibre are also observed in flat-fibre and PCF. An additional trap centre in flat-fibre and one further trap centre in PCF are observed when compared to capillary fibre. These elevated-energy trap centres are linked with strain-generated defects in the collapsed regions of the flat fibre and PCF.
    Matched MeSH terms: Electrons
  18. Nanostructured SnO2-Ge Multi-layer thin Films with Quantum Confinement Effects for Solar Cell
    Khan AF, Sajjad W, Rahim NA
    Recent Pat Nanotechnol, 2016;10(1):77-82.
    PMID: 27018275
    BACKGROUND: It is well-known that multi-layer films with nanostructure can give novel properties by interfacial phenomenon and quantum confinement effects. Nanostructured multi-layer thin films are presently being analyzed for their vast applications in the area of optoelectronics technology particularly photovoltaics. Hereof, two dimensional thin films with nanostructure are of prime importance due to their structure dependent optical, electrical, and opto-electronic properties. It has been revealed that these films exhibit quantum confinement effects with band gap engineering. The main focus of the research is to evaluate the effect on structural and optical properties with number of layers.

    METHODS: Nanostructured SnO2-Ge multi-layer thin films were fabricated using electron beam evaporation and resistive heating techniques. Alternate layers of SnO2 and Ge were deposited on glass substrate at a substrate temperature of 300 °C in order to obtain uniform and homogeneous deposition. The substrate temperature of 300 °C has been determined to be effective for the deposition of these multi-layer films from our previous studies. The films were characterized by investigating their structural and optical properties. The structural properties of the as-deposited films were characterized by Rutherford Backscattering Spectroscopy (RBS) and Raman spectroscopy and optical properties by Ultra-Violet-Near infrared (UV-VIS-NIR) spectroscopy.

    RESULTS: RBS studies confirmed that the layer structure has been effectively formed. Raman spectroscopy results show that the peaks of both Ge and SnO2 shifts towards lower wavenumbers (in comparison with bulk Ge and SnO2, suggesting that the films consist of nanostructures and demonstrate quantum confinement effects. UV-VIS-NIR spectroscopy showed an increase in the band gap energy of Ge and SnO2 and shifting of transmittance curves toward higher wavelength by increasing the number of layers. The band gap lies in the range of 0.9 to 1.2 eV for Ge, while for SnO2, it lies between 1.7 to 2.1 eV.

    CONCLUSION: Analysis of results suggests that the nanostructured SnO2-Ge multi-layer thin film can work as heterojunction materials with quantum confinement effects. Accordingly, the present SnO2-Ge multi-layer films may be employed for photovoltaic applications. Few relevant patents to the topic have been reviewed and cited.

    Matched MeSH terms: Electrons
  19. Fulltext Monte Carlo dose calculation in dental amalgam phantom
    Aziz MZ, Yusoff AL, Osman ND, Abdullah R, Rabaie NA, Salikin MS
    J Med Phys, 2015 Jul-Sep;40(3):150-5.
    PMID: 26500401 DOI: 10.4103/0971-6203.165080
    It has become a great challenge in the modern radiation treatment to ensure the accuracy of treatment delivery in electron beam therapy. Tissue inhomogeneity has become one of the factors for accurate dose calculation, and this requires complex algorithm calculation like Monte Carlo (MC). On the other hand, computed tomography (CT) images used in treatment planning system need to be trustful as they are the input in radiotherapy treatment. However, with the presence of metal amalgam in treatment volume, the CT images input showed prominent streak artefact, thus, contributed sources of error. Hence, metal amalgam phantom often creates streak artifacts, which cause an error in the dose calculation. Thus, a streak artifact reduction technique was applied to correct the images, and as a result, better images were observed in terms of structure delineation and density assigning. Furthermore, the amalgam density data were corrected to provide amalgam voxel with accurate density value. As for the errors of dose uncertainties due to metal amalgam, they were reduced from 46% to as low as 2% at d80 (depth of the 80% dose beyond Zmax) using the presented strategies. Considering the number of vital and radiosensitive organs in the head and the neck regions, this correction strategy is suggested in reducing calculation uncertainties through MC calculation.
    Matched MeSH terms: Electrons
  20. Accelerated sunlight photocatalysis through improved electron mobility between g-C3N4 and BiPO4 nanomaterial
    Ng JJ, Sim LC, Oh WD, Saravanan P, Tan B, Leong KH
    Environ Sci Pollut Res Int, 2022 Dec;29(57):86068-86076.
    PMID: 34523092 DOI: 10.1007/s11356-021-16449-y
    Herein, we report a detailed study on creating heterojunction between graphitic carbon nitride (g-C3N4) and bismuth phosphate (BiPO4), enhancing the unpaired free electron mobility. This leads to an accelerated photocatalysis of 2,4-dichlorophenols (2,4-DCPs) under sunlight irradiation. The heterojunction formation was efficaciously conducted via a modest thermal deposition technique. The function of g-C3N4 plays a significant role in generating free electrons under sunlight irradiation. Together, the generated electrons at the g-C3N4 conduction band (CB) are transferred and trapped by the BiPO4 to form active superoxide anion radicals (•O2-). These active radicals will be accountable for the photodegradation of 2,4-DCPs. The synthesized composite characteristics were methodically examined through several chemical and physical studies. Due to the inimitable features of both g-C3N4 and BiPO4, its heterojunction formation, 2.5wt% BiPO4/g-C3N4 achieved complete 2,4-DCP removal (100%) in 90 min under sunlight irradiation. This is due to the presence of g-C3N4 that enhanced electron mobility through the formation of heterojunctions that lengthens the electron-hole pairs' lifetime and maximizes the entire solar spectrum absorption to generate active electrons at the g-C3N4 conduction band. Thus, this formation significantly draws the attention for future environmental remediation, especially in enhancing the entire solar spectrum's harvesting.
    Matched MeSH terms: Electrons
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