NiCo2O4-loaded sunflower husk-derived biochar as efficient peroxymonosulfate activator for tetracycline removal in water

Nguyen TB 1 , Nguyen TK 1 , Chen CW 2 , Chen WH 3 , Bui XT 4 , Lam SS 5 Show all authors , Dong CD 6

Affiliations 

  • 1 Institute of Aquatic Science and Technology, National Kaohsiung University of Science and Technology, Kaohsiung City 81157, Taiwan
  • 2 Institute of Aquatic Science and Technology, National Kaohsiung University of Science and Technology, Kaohsiung City 81157, Taiwan; Department of Marine Environmental Engineering, National Kaohsiung University of Science and Technology, Kaohsiung City 81157, Taiwan
  • 3 Department of Aeronautics and Astronautics, National Cheng Kung University, Tainan 701, Taiwan; Research Center for Smart Sustainable Circular Economy, Tunghai University, Taichung 407, Taiwan; Department of Mechanical Engineering, National Chin-Yi University of Technology, Taichung 411, Taiwan
  • 4 Key Laboratory of Advanced Waste Treatment Technology, Ho Chi Minh City University of Technology (HCMUT), Vietnam National University Ho Chi Minh (VNU-HCM), Thu Duc city, Ho Chi Minh City 700000, Viet Nam; Faculty of Environment and Natural Resources, Ho Chi Minh City University of Technology (HCMUT), 268 Ly Thuong Kiet Street, District 10, Ho Chi Minh City 700000, Viet Nam
  • 5 Higher Institution Centre of Excellence (HICoE), Institute of Tropical Aquaculture and Fisheries (AKUATROP), Universiti Malaysia Terengganu, 21030 Kuala Nerus, Terengganu, Malaysia; Center for Transdisciplinary Research, Saveetha Institute of Medical and Technical Sciences, Saveetha University, Chennai, India
  • 6 Institute of Aquatic Science and Technology, National Kaohsiung University of Science and Technology, Kaohsiung City 81157, Taiwan; Department of Marine Environmental Engineering, National Kaohsiung University of Science and Technology, Kaohsiung City 81157, Taiwan. Electronic address: cddong@nkust.edu.tw
Bioresour Technol, 2023 Aug;382:129182.
PMID: 37210031 DOI: 10.1016/j.biortech.2023.129182

Abstract

In this study, biochar produced from sunflower seeds husk was activated through ZnCl2 to support the NiCo2O4 nanoparticles (NiCo2O4@ZSF) in catalytic activation of peroxymonosulfate (PMS) toward tetracycline (TC) removal from aqueous solution. The good dispersion of NiCo2O4 NPs on the ZSF surface provided sufficient active sites and abundant functional groups for the adsorption and catalytic reaction. The NiCo2O4@ZSF activating PMS showed high removal efficiency up to 99% after 30 min under optimal condition ([NiCo2O4@ZSF] = 25 mg L-1, [PMS] = 0.04 mM, [TC] = 0.02 mM and pH = 7). The catalyst also exhibited good adsorption performance with a maximum adsorption capacity of 322.58 mg g-1. Sulfate radicals (SO4•-), superoxide radical (O2•-), and singlet oxygen (1O2) played a decisive role in the NiCo2O4@ZSF/PMS system. In conclusion, our research elucidated the production of highly efficient carbon-based catalysts for environmental remediation, and also emphasized the potential application of NiCo2O4 doped biochar.

* Title and MeSH Headings from MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine.

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