Displaying publications 501 - 520 of 2919 in total

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  1. Ismail IS, Rashidi NA, Yusup S
    Environ Sci Pollut Res Int, 2022 Feb;29(9):12434-12440.
    PMID: 34189693 DOI: 10.1007/s11356-021-15030-x
    Bamboo is the fastest-growing plant and is abundant in Malaysia. It is employed as a starting material for activated carbon production and evaluated for its potential in CO2 capture. A single-stage phosphoric acid (H3PO4) activation is adopted by varying the concentrations of H3PO4 between 50 and 70 wt.% at a constant temperature and holding time of 500°C and 120 min, respectively. The bamboo-based activated carbons are characterized in terms of product yield, surface area, and porosity, as well as surface chemistry properties. Referring to the experimental findings, the prepared activated carbons have BET surface area of >1000 m2 g-1, which implies the effectiveness of the single-stage H3PO4 activation. Furthermore, the prepared activated carbon via 50 wt.% H3PO4 activation shows the highest BET surface area and carbon dioxide (CO2) adsorption capacity of 1.45 mmol g-1 at 25°C/1 bar and 9.0 mmol g-1 at 25°C/30 bar. With respect to both the characterization analysis and CO2 adsorption performance, it is concluded that bamboo waste conversion to activated carbon through H3PO4 activation method is indeed promising.
    Matched MeSH terms: Temperature
  2. Rashidi NA, Bokhari A, Yusup S
    Environ Sci Pollut Res Int, 2021 Jul;28(26):33967-33979.
    PMID: 32333352 DOI: 10.1007/s11356-020-08823-z
    The volumetric adsorption kinetics of carbon dioxide (CO2) onto the synthesized palm kernel shell activated carbon via single-stage CO2 activation and commercial Norit® activated carbon were carried out at an initial pressure of approximately 1 bar at three different temperatures of 25, 50, and 100 °C. The experimental kinetics data were modelled by using the Lagergren's pseudo-first-order model and pseudo-second-order model. Comparing these two, the non-linear pseudo-second-order kinetics model presented a better fit towards CO2 adsorption for both adsorbents, owing to its closer coefficient of determination (R2) to unity, irrespective of the adsorption temperature. In addition, kinetics analysis showed that the corresponding kinetics coefficient (rate of adsorption) of both activated carbons increased with respect to adsorption temperature, and thereby, it indicated higher mobility of CO2 adsorbates at an elevated temperature. Nevertheless, CO2 adsorption capacity of both activated carbons reduced at elevated temperatures, which signified exothermic and physical adsorption (physisorption) behaviour. Besides, process exothermicity of both carbonaceous adsorbents can be corroborated through activation energy (Ea) value, which was deduced from the Arrhenius plot. Ea values that were in range of 32-38 kJ/mol validated exothermic adsorption at low pressure and temperature range of 25-100 °C. To gain an insight into the CO2 adsorption process, experimental data were fitted to intra-particle diffusion model and Boyd's diffusion model, and findings revealed an involvement of both film diffusion and intra-particle diffusion during CO2 adsorption process onto the synthesized activated carbon and commercial activated carbon.
    Matched MeSH terms: Temperature
  3. Banadkooki FB, Ehteram M, Ahmed AN, Teo FY, Ebrahimi M, Fai CM, et al.
    Environ Sci Pollut Res Int, 2020 Oct;27(30):38094-38116.
    PMID: 32621196 DOI: 10.1007/s11356-020-09876-w
    Suspended sediment load (SSL) estimation is a required exercise in water resource management. This article proposes the use of hybrid artificial neural network (ANN) models, for the prediction of SSL, based on previous SSL values. Different input scenarios of daily SSL were used to evaluate the capacity of the ANN-ant lion optimization (ALO), ANN-bat algorithm (BA) and ANN-particle swarm optimization (PSO). The Goorganrood basin in Iran was selected for this study. First, the lagged SSL data were used as the inputs to the models. Next, the rainfall and temperature data were used. Optimization algorithms were used to fine-tune the parameters of the ANN model. Three statistical indexes were used to evaluate the accuracy of the models: the root-mean-square error (RMSE), mean absolute error (MAE) and Nash-Sutcliffe efficiency (NSE). An uncertainty analysis of the predicting models was performed to evaluate the capability of the hybrid ANN models. A comparison of models indicated that the ANN-ALO improved the RMSE accuracy of the ANN-BA and ANN-PSO models by 18% and 26%, respectively. Based on the uncertainty analysis, it can be surmised that the ANN-ALO has an acceptable degree of uncertainty in predicting daily SSL. Generally, the results indicate that the ANN-ALO is applicable for a variety of water resource management operations.
    Matched MeSH terms: Temperature
  4. Rashidi NA, Yusup S
    Environ Sci Pollut Res Int, 2020 Aug;27(22):27480-27490.
    PMID: 31907816 DOI: 10.1007/s11356-019-07448-1
    Accelerating greenhouse gas emission particularly carbon dioxide (CO2) in the atmosphere has become a major concern. Adsorption process has been proposed as a promising technology for CO2 adsorption from flue gas, and the carbonaceous adsorbent is a potential candidate for CO2 adsorption at atmospheric pressure and ambient temperature. Biochar derived from palm kernel shell waste was applied as a potential precursor for activated carbon production. This research study employed the response surface methodology coupled with Box-Behnken design to optimize the parameters involved in producing exceptional activated carbon with high yield (Y1) and CO2 adsorptive characteristics (Y2). Specifically, parameters studied include the activation temperature (750-950 °C), holding time (60-120 min), and CO2 flow rate (150-450 mL/min). The activated carbon at the optimum conditions was characterized using various analytical instruments, including elemental analyzer, nitrogen (N2) physisorption analyzer, and field emission scanning electron microscopy. Overall, utilization of biochar as the activated carbon precursor is practical compared with the traditional non-renewable materials, due to its cost efficiencies and it being more environment-friendly ensuring process sustainability. Besides, this research study that incorporates physical activation with CO2 as the activating agent is attractive, because it directly promotes CO2 utilization and capture, in addition to the absence of any chemicals that may result in the secondary pollution problems.
    Matched MeSH terms: Temperature
  5. Lim HS, Rajab J, Al-Salihi A, Salih Z, MatJafri MZ
    Environ Sci Pollut Res Int, 2022 Feb;29(7):9755-9765.
    PMID: 34505243 DOI: 10.1007/s11356-021-16321-z
    Air surface temperature (AST) is a crucial importance element for many applications such as hydrology, agriculture, and climate change studies. The aim of this study is to develop regression equation for calculating AST and to analyze and investigate the effects of atmospheric parameters (O3, CH4, CO, H2Ovapor, and outgoing longwave radiation (OLR)) on the AST value in Iraq. Dataset retrieved from the Atmospheric Infrared Sounder (AIRS) at EOS Aqua Satellite, spanning the years of 2003 to 2016, and multiple linear regression were used to achieve the objectives of the study. For the study period, the five atmospheric parameters were highly correlated (R, 0.855-0.958) with predicted AST. Statistical analyses in terms of β showed that OLR (0.310 to 1.053) contributes significantly in enhancing AST values. Comparisons among selected five stations (Mosul, Kanaqin, Rutba, Baghdad, and Basra) for the year 2010 showed a close agreement between the predicted and observed AST from AIRS, with values ranging from 0.9 to 1.5 K and for ground stations data, within 0.9 to 2.6 K. To make more complete analysis, also, comparison between predicted and observed AST from AIRS for four selected month in 2016 (January, April, July, and October) has been carried out. The result showed a high correlation coefficient (R, 0.87 and 0.95) with less variability (RMSE ≤ 1.9) for all months studied, indicating model's capability and accuracy. In general, the results indicate the advantage of using the AIRS data and the regression analysis to investigate the impact of the atmospheric parameters on AST over the study area.
    Matched MeSH terms: Temperature
  6. Terry LM, Wee MXJ, Chew JJ, Khaerudini DS, Darsono N, Aqsha A, et al.
    Environ Res, 2023 May 01;224:115550.
    PMID: 36841526 DOI: 10.1016/j.envres.2023.115550
    Pyrolysis oil from oil palm biomass can be a sustainable alternative to fossil fuels and the precursor for synthesizing petrochemical products due to its carbon-neutral properties and low sulfur and nitrogen content. This work investigated the effect of applying mesoporous acidic catalysts, Ni-Mo/TiO2 and Ni/Al2O3, in a catalytic co-pyrolysis of oil palm trunk (OPT) and polypropylene (PP) from 500 to 700 °C. The obtained oil yields varied between 12.67 and 19.50 wt.% and 12.33-17.17 wt.% for Ni-Mo/TiO2 and Ni/Al2O3, respectively. The hydrocarbon content in oil significantly increased up to 54.07-58.18% and 37.28-68.77% after adding Ni-Mo/TiO2 and Ni/Al2O3, respectively. The phenolic compounds content was substantially reduced to 8.46-20.16% for Ni-Mo/TiO2 and 2.93-14.56% for Ni/Al2O3. Minor reduction in oxygenated compounds was noticed from catalytic co-pyrolysis, though the parametric effects of temperature and catalyst type remain unclear. The enhanced deoxygenation and cracking of phenolic and oxygenated compounds and the PP decomposition resulted in increased hydrocarbon production in oil during catalytic co-pyrolysis. Catalyst addition also promoted the isomerization and oligomerization reactions, enhancing the formation of cyclic relative to aliphatic hydrocarbon.
    Matched MeSH terms: Hot Temperature
  7. Setyawan D, Amrillah T, Abdullah CAC, Ilhami FB, Dewi DMM, Mumtazah Z, et al.
    J Drug Target, 2023 Apr;31(4):369-389.
    PMID: 36721905 DOI: 10.1080/1061186X.2023.2175833
    The development of two-dimensional (2D) materials for biomedical applications has accelerated exponentially. Contrary to their bulk counterparts, the exceptional properties of 2D materials make them highly prospective for contrast agents for bioimage, drug, and heat delivery in biomedical treatment. Nevertheless, empty space in the integration and utilisation of 2D materials in living biological systems, potential toxicity, as well as required complicated synthesis and high-cost production limit the real application of 2D materials in those advance medical treatments. On the other hand, green technology appears to be one of strategy to shed a light on the blurred employment of 2D in medical applications, thus, with the increasing reports of green technology that promote advanced technologies, here, we compile, summarise, and synthesise information on the biomedical technology of 2D materials through green technology point of view. Beginning with a fundamental understanding, of crystal structures, the working mechanism, and novel properties, this article examines the recent development of 2D materials. As well as 2D materials made from natural and biogenic resources, a recent development in green-related synthesis was also discussed. The biotechnology and biomedical-related application constraints are also discussed. The challenges, solutions, and prospects of the so-called green 2D materials are outlined.
    Matched MeSH terms: Hot Temperature
  8. Zhang Y, Liu S, De Meyer M, Liao Z, Zhao Y, Virgilio M, et al.
    J Adv Res, 2023 Nov;53:61-74.
    PMID: 36574947 DOI: 10.1016/j.jare.2022.12.012
    INTRODUCTION: The oriental fruit fly Bactrocera dorsalis is one of the most destructive agricultural pests worldwide, with highly debated species delimitation, origin, and global spread routes.

    OBJECTIVES: Our study intended to (i) resolve the taxonomic uncertainties between B. dorsalis and B. carambolae, (ii) reveal the population structure and global invasion routes of B. dorsalis across Asia, Africa, and Oceania, and (iii) identify genomic regions that are responsible for the thermal adaptation of B. dorsalis.

    METHODS: Based on a high-quality chromosome-level reference genome assembly, we explored the population relationship using a genome-scale single nucleotide polymorphism dataset generated from the resequencing data of 487 B. dorsalis genomes and 25 B. carambolae genomes. Genome-wide association studies and silencing using RNA interference were used to identify and verify the candidate genes associated with extreme thermal stress.

    RESULTS: We showed that B. dorsalis originates from the Southern India region with three independent invasion and spread routes worldwide: (i) from Northern India to Northern Southeast Asia, then to Southern Southeast Asia; (ii) from Northern India to Northern Southeast Asian, then to China and Hawaii; and (iii) from Southern India toward the African mainland, then to Madagascar, which is mainly facilitated by human activities including trade and immigration. Twenty-seven genes were identified by a genome-wide association study to be associated with 11 temperature bioclimatic variables. The Cyp6a9 gene may enhance the thermal adaptation of B. dorsalis and thus boost its invasion, which tended to be upregulated at a hardening temperature of 38 °C. Functional verification using RNA interference silencing against Cyp6a9, led to the specific decrease in Cyp6a9 expression, reducing the survival rate of dsRNA-feeding larvae exposed to extreme thermal stress of 45 °C after heat hardening treatments in B. dorsalis.

    CONCLUSION: This study provides insights into the evolutionary history and genetic basis of temperature adaptation in B. dorsalis.

    Matched MeSH terms: Temperature
  9. Virdis SGP, Kongwarakom S, Juneng L, Padedda BM, Shrestha S
    Environ Res, 2024 Apr 15;247:118412.
    PMID: 38316380 DOI: 10.1016/j.envres.2024.118412
    The temperature of surface and epilimnetic waters, closely related to regional air temperatures, responds quickly and directly to climatic changes. As a result, lake surface temperature (LSWT) can be considered an effective indicator of climate change. In this study, we reconstructed and investigated historical and future LSWT across different scenarios for over 80 major lakes in mainland Southeast Asia (SEA), an ecologically diverse region vulnerable to climate impacts. Five different predicting models, incorporating statistical, machine and deep learning approaches, were trained and validated using ERA5 and CHIRPS climatic feature datasets as predictors and 8-day MODIS-derived LSWT from 2000 to 2020 as reference dataset. Best performing model was then applied to predict both historical (1986-2020) and future (2020-2100) LSWT for SEA lakes, utilizing downscaled climatic CORDEX-SEA feature data and multiple Representative Concentration Pathway (RCP). The analysis uncovered historical and future thermal dynamics and long-term trends for both daytime and nighttime LSWT. Among 5 models, XGboost results the most performant (NSE 0.85, RMSE 1.14 °C, MAE 0.69 °C, MBE -0.08 °C) and it has been used for historical reconstruction and future LSWT prediction. The historical analysis revealed a warming trend in SEA lakes, with daytime LSWT increasing at a rate of +0.18 °C/decade and nighttime LSWT at +0.13 °C/decade over the past three decades. These trends appeared of smaller magnitude compared to global estimates of LSWT change rates and less pronounced than concurrent air temperature and LSWT increases in neighbouring regions. Projections under various RCP scenarios indicated continued LSWT warming. Daytime LSWT is projected to increase at varying rates per decade: +0.03 °C under RCP2.6, +0.14 °C under RCP4.5, and +0.29 °C under RCP8.5. Similarly, nighttime LSWT projections under these scenarios are: +0.03 °C, +0.10 °C, and +0.16 °C per decade, respectively. The most optimistic scenario predicted marginal increases of +0.38 °C on average, while the most pessimistic scenario indicated an average LSWT increase of +2.29 °C by end of the century. This study highlights the relevance of LSWT as a climate change indicator in major SEA's freshwater ecosystems. The integration of satellite-derived LSWT, historical and projected climate data into data-driven modelling has enabled new and a more nuanced understanding of LSWT dynamics in relation to climate throughout the entire SEA region.
    Matched MeSH terms: Temperature
  10. Mohammed MA, Mohd Yunus NZ, Hezmi MA, Abang Hasbollah DZ, A Rashid AS
    Environ Sci Pollut Res Int, 2021 Feb;28(8):8968-8988.
    PMID: 33443736 DOI: 10.1007/s11356-021-12392-0
    Environmental global issues affecting global warming, such as carbon dioxide (CO2), have attracted the attention of researchers around the world. This paper reviews and discusses the ground improvement and its contribution to reducing CO2 in the atmosphere. The approach is divided into three parts: the Streamlined Energy and Emissions Assessment Model (SEEAM), the replacement of soil stabilisation materials that lead to the emission of a large amount of CO2 with alternatives and mineral carbonation. A brief discussion about the first two is reviewed in this paper and a detailed discussion about mineral carbonation and its role in enhancing soil strength while absorbing a large amount of CO2. It is emphasised that natural mineral carbonation requires a very long time for a material to reach its full capacity to form CO2; as a result, different acceleration processes can be done from increasing pressure, temperature, the concentration of CO2 and the addition of various additives. In conclusion, it was found that magnesium is more attractive than calcium, and calcium is complicated in terms of strength behaviour. Magnesium has a larger capacity for CO2 sequestration and it has a greater potential to increase soil strength than calcium.
    Matched MeSH terms: Temperature
  11. Su G, Jiang P
    Bioresour Technol, 2024 May;399:130519.
    PMID: 38437964 DOI: 10.1016/j.biortech.2024.130519
    This study developed six machine learning models to predict the biochar properties from the dry torrefaction of lignocellulosic biomass by using biomass characteristics and torrefaction conditions as input variables. After optimization, gradient boosting machines were the optimal model, with the highest coefficient of determination ranging from 0.89 to 0.94. Torrefaction conditions exhibited a higher relative contribution to the yield and higher heating value (HHV) of biochar than biomass characteristics. Temperature was the dominant contributor to the elemental and proximate composition and the yield and HHV of biochar. Feature importance and SHapley Additive exPlanations revealed the effect of each influential factor on the target variables and the interactions between these factors in torrefaction. Software that can accurately predict the element, yield, and HHV of biochar was developed. These findings provide a comprehensive understanding of the key factors and their interactions influencing the torrefaction process and biochar properties.
    Matched MeSH terms: Temperature
  12. Song J, Farhadi A, Tan K, Lim L, Tan K
    Sci Total Environ, 2024 May 20;926:172056.
    PMID: 38552980 DOI: 10.1016/j.scitotenv.2024.172056
    Dissolved oxygen (DO) is an important parameter that affects the biology, physiology, and immunology of aquatic animals. In recent decades, DO levels in the global oceans have sharply decreased, partly due to an increase in atmospheric carbon dioxide, temperature, and anthropogenic nutrient loads. Although there have been many reports on the effects of hypoxia on the survival, growth, behavior, and immunity of bivalves, this information has not been well organized. Therefore, this article provides a comprehensive review of the effects of hypoxia on bivalves. In general, hypoxia negatively impacts the food consumption rate and assimilation efficiency, as well as increasing respiration rates in many bivalves. As a result, it reduces the energy allocation for bivalve growth, shell formation, and reproduction. In severe cases, prolonged exposure to hypoxia can result in mass mortality in bivalves. Moreover, hypoxia also has adverse effects on the immunity and response of bivalves to predators, including decreased burial depths, sensitivity to predators, impairment of byssus production, and negatively impacts on the integrity, strength, and composition of bivalve shells. The tolerance of bivalves to hypoxia largely depends on size and species, with larger bivalves being more susceptible to hypoxia and intertidal species being relatively more tolerant to hypoxia. The information in this article is very useful for elucidating the current research status of hypoxia on bivalves and determining future research directions.
    Matched MeSH terms: Temperature
  13. Chew ZL, Koh QQ, Chu EE, Kua YL, Gan S, Tan KW, et al.
    Int J Biol Macromol, 2024 May;267(Pt 1):131201.
    PMID: 38554921 DOI: 10.1016/j.ijbiomac.2024.131201
    As a promising green and sustainable coating material, gum was extracted from durian seed to produce eutectogel, which the properties were tunable using natural deep eutectic solvent (NADES). Ten different eutectogels were successfully synthesized using durian seed gum (DSG) and xanthan gum (XG) gelators at different composition (5, 10, 15 %) to gel choline chloride-glucose (1:1), choline chloride-fructose (1:2) and betaine-glucose-water (1:1:1) NADESs. Results revealed that eutectogel was non-Newtonian and weak gel material with excellent thermostability up to 200 °C. When the gum content increased, the resulted eutectogel showed higher viscosity, yield stress, hardness, gumminess, adhesiveness, and weight holding capacity. In overall, choline chloride-fructose (1:2) NADES and 10 % of DSG formed an excellent eutectogel which remained stable and compatible upon 12 weeks of storage. It displayed superior viscoelastic, texture, gases and moisture barrier properties which were beneficial for food coating application. This eutectogel was able to extend the shelf life of fresh-cut apples during storage with lower weight loss and higher total phenolic content (TPC). The potential future of this well-characterized tunable DSG-derived eutectogel includes, but not limited to, food and pharmaceutical industries, smart sensing, flexible wearable electronics, water purification, supercapacitors and batteries.
    Matched MeSH terms: Temperature
  14. Yang Y, Fedorov G, Shafranjuk SE, Klapwijk TM, Cooper BK, Lewis RM, et al.
    Nano Lett, 2015 Dec 09;15(12):7859-66.
    PMID: 26506109 DOI: 10.1021/acs.nanolett.5b02564
    Van Hove singularities (VHSs) are a hallmark of reduced dimensionality, leading to a divergent density of states in one and two dimensions and predictions of new electronic properties when the Fermi energy is close to these divergences. In carbon nanotubes, VHSs mark the onset of new subbands. They are elusive in standard electronic transport characterization measurements because they do not typically appear as notable features and therefore their effect on the nanotube conductance is largely unexplored. Here we report conductance measurements of carbon nanotubes where VHSs are clearly revealed by interference patterns of the electronic wave functions, showing both a sharp increase of quantum capacitance, and a sharp reduction of energy level spacing, consistent with an upsurge of density of states. At VHSs, we also measure an anomalous increase of conductance below a temperature of about 30 K. We argue that this transport feature is consistent with the formation of Cooper pairs in the nanotube.
    Matched MeSH terms: Temperature
  15. Jeroish ZE, Bhuvaneshwari KS, Samsuri F, Narayanamurthy V
    Biomed Microdevices, 2021 Dec 03;24(1):3.
    PMID: 34860299 DOI: 10.1007/s10544-021-00595-8
    Heating plays a vital role in science, engineering, mining, and space, where heating can be achieved via electrical, induction, infrared, or microwave radiation. For fast switching and continuous applications, hotplate or Peltier elements can be employed. However, due to bulkiness, they are ineffective for portable applications or operation at remote locations. Miniaturization of heaters reduces power consumption and bulkiness, enhances the thermal response, and integrates with several sensors or microfluidic chips. The microheater has a thickness of ~ 100 nm to ~ 100 μm and offers a temperature range up to 1900℃ with precise control. In recent years, due to the escalating demand for flexible electronics, thin-film microheaters have emerged as an imperative research area. This review provides an overview of recent advancements in microheater as well as analyses different microheater designs, materials, fabrication, and temperature control. In addition, the applications of microheaters in gas sensing, biological, and electrical and mechanical sectors are emphasized. Moreover, the maximum temperature, voltage, power consumption, response time, and heating rate of each microheater are tabulated. Finally, we addressed the specific key considerations for designing and fabricating a microheater as well as the importance of microheater integration in COVID-19 diagnostic kits. This review thereby provides general guidelines to researchers to integrate microheater in micro-electromechanical systems (MEMS), which may pave the way for developing rapid and large-scale SARS-CoV-2 diagnostic kits in resource-constrained clinical or home-based environments.
    Matched MeSH terms: Temperature
  16. Noramira SM, Dom NC, Samsuri A
    Med J Malaysia, 2024 Mar;79(Suppl 1):122-127.
    PMID: 38555896
    INTRODUCTION: The SARS-CoV-2 virus, responsible for the global COVID-19 pandemic and its associated high morbidity and mortality, continues to be a significant public health concern. This study investigates the influence of temperature variables on COVID-19 transmission in Terengganu, Malaysia, which, despite having experienced a comparatively lower number of cases, presents a unique environment for understanding how temperature factors may play a critical role in virus transmission dynamics.

    MATERIALS AND METHODS: We conducted a descriptive analysis to assess the spatial distribution of COVID-19 cases in our study area. To explore the relationship between temperature variables and COVID-19 transmission, we employed Pearson correlation analysis, examining the correlations between daily average, minimum, and maximum temperature data and the temporal distribution of COVID-19 cases as reported by the Ministry of Health, Malaysia. This approach allowed us to comprehensively investigate the impact of weather on the transmission dynamics of COVID-19.

    RESULTS: Our findings reveal a noteworthy correlation (p<0.05) between average and maximum temperatures and COVID-19 transmission, highlighting the influence of weather on disease dynamics. Notably, exceptions were observed in the Hulu Terengganu district, where fewer than 10 cases occurred in each sub-district throughout the study period, warranting special consideration.

    CONCLUSION: In summary, our study highlights the significance of temperature in shaping COVID-19 transmission. This stresses the importance of including weather variables in pandemic strategies. We also suggest comparing various cities to broaden our understanding of how weather affects disease spread, aiding future public health efforts.

    Matched MeSH terms: Temperature
  17. Md Saad WM, Mohd Noor NA, Mohamad Salin NS, Mohd Z, Eshak Z, Abdul Razak HR
    Med J Malaysia, 2024 Mar;79(Suppl 1):8-13.
    PMID: 38555879
    INTRODUCTION: Bismuth oxide (Bi2O3) particles gained attention in preclinical research especially in medical imaging. Bismuth oxide with its long circulation time is an alternative to the current iodine contrast media which directly possesses high X-ray attenuation coefficient. Exploration of bismuth compound is hampered owing to challenges in synthesizing control for in vivo stability.

    MATERIALS AND METHODS: This study aimed are to characterize Bi2O3 particles synthesized at 60, 90 and 120 °C via hydrothermal method and investigated cytotoxicity of cell viability assay, cell morphology analysis, intracellular reactive oxygen species (ROS) assay and expression of ER stress genes by real-time PCR.

    RESULTS: Results indicated that the size of rod-shaped Bi2O3 particles increased with rising synthesizing temperatures. The cytotoxicity of Bi2O3 particles in Chang liver cells was size-dependent. Bigger-sized Bi2O3 particles resulted in lesser toxicity effects. mRNA expressions of GRP78 and C/EBP homologous protein (CHOP) were down-regulated in all treated Chang liver cells due to the increasing size of Bi2O3 particles. Bi2O3 particles synthesized at 120 °C was found to be less toxic than iodine.

    CONCLUSION: Data suggested that the response of Chang liver cells to Bi2O3 particle cytotoxicity has a significant relationship with its reaction temperatures. This outcome is important in hazard assessment of Bi2O3 particles as a new contrast media and provides better understanding in synthesizing control to enhance its biocompatibility.

    Matched MeSH terms: Temperature
  18. Abioye KJ, Harun NY, Sufian S, Yusuf M, Jagaba AH, Waqas S, et al.
    Environ Res, 2024 Apr 01;246:118027.
    PMID: 38159670 DOI: 10.1016/j.envres.2023.118027
    The study explores co-gasification of palm oil decanter cake and alum sludge, investigating the correlation between input variables and syngas production. Operating variables, including temperature (700-900 °C), air flow rate (10-30 mL/min), and particle size (0.25-2 mm), were optimized to maximize syngas production using air as the gasification agent in a fixed bed horizontal tube furnace reactor. Response Surface Methodology with the Box-Behnken design was used employed for optimization. Fourier Transformed Infra-Red (FTIR) and Field Emission Scanning Electron Microscopic (FESEM) analyses were used to analyze the char residue. The results showed that temperature and particle size have positive effects, while air flow rate has a negative effect on the syngas yield. The optimal CO + H2 composition of 39.48 vol% was achieved at 900 °C, 10 mL/min air flow rate, and 2 mm particle size. FTIR analysis confirmed the absence of C─Cl bonds and the emergence of Si─O bonds in the optimized char residue, distinguishing it from the raw sample. FESEM analysis revealed a rich porous structure in the optimized char residue, with the presence of calcium carbonate (CaCO3) and aluminosilicates. These findings provide valuable insights for sustainable energy production from biomass wastes.
    Matched MeSH terms: Temperature
  19. Hazir MHM, Gloor E, Docherty E, Galbraith D
    Tree Physiol, 2024 Feb 11;44(3).
    PMID: 38349811 DOI: 10.1093/treephys/tpae022
    Land surface temperature is predicted to increase by 0.2 °C per decade due to climate change, although with considerable regional variability, and heatwaves are predicted to increase markedly in the future. These changes will affect where crops can be grown in the future. Understanding the thermal limits of plant physiological functioning and how flexible such limits are is thus important. Here, we report on the measurements of a core foliar thermotolerance trait, T50, defined as the temperature at which the maximum quantum yield (Fv/Fm) of photosystem II declines by 50%, across nine different Malaysian Hevea brasiliensis clones. We explore the relative importance of interclonal versus intraclonal variation in T50 as well as its association with leaf and hydraulic traits. We find very low variation in T50 within individual clones (mean intraclonal coefficient of variation (CoV) of 1.26%) and little variation across clones (interclonal CoV of 2.1%). The interclonal variation in T50 was lower than for all other functional traits considered. The T50 was negatively related to leaf mass per area and leaf dry matter content, but it was not related to hydraulic traits such as embolism resistance (P50) or hydraulic safety margins (HSM50). The range of T50 observed (42.9-46.2 °C) is well above the current maximum air temperatures Tmax,obs (T50 - Tmax,obs >5.8 °C), suggesting that H. brasiliensis is likely thermally safe in this south-east Asian region of Malaysia.
    Matched MeSH terms: Temperature
  20. Yip YS, Manas NHA, Jaafar NR, Rahman RA, Puspaningsih NNT, Illias RM
    Int J Biol Macromol, 2023 Jul 01;242(Pt 1):124675.
    PMID: 37127056 DOI: 10.1016/j.ijbiomac.2023.124675
    Maltooligosaccharides (MOS) are functional oligosaccharides that can be synthesized through enzymatic cascade reaction between cyclodextrin glucanotransferase (CGTase) and maltogenic amylase (Mag1) from Bacillus lehensis G1. To address the problems of low operational stability and non-reusability of free enzymes, both enzymes were co-immobilized as combined cross-linked enzyme aggregates (Combi-CLEAs-CM) with incorporation of bovine serum albumin (BSA) and Tween 80 (Combi-CLEAs-CM-add). Combi-CLEAs-CM and Combi-CLEAs-CM-add showed activity recoveries of 54.12 % and 69.44 %, respectively after optimization. Combi-CLEAs-CM-add showed higher thermal stability at higher temperatures (40 °C) with longer half-life (46.20 min) as compared to those of free enzymes (36.67 min) and Combi-CLEAs-CM (41.51 min). Both combi-CLEAs also exhibited higher pH stability over pH 5 to pH 9, and displayed excellent reusability with >50 % of initial activity retained after four cycles. The reduction in Km value of about 22.80 % and 1.76-fold increase in starch hydrolysis in comparison to Combi-CLEAs-CM attested the improvement of enzyme-substrate interaction by Tween 80 and pores formation by BSA in Combi-CLEAs-CM-add. The improved product specificity of Combi-CLEAs-CM-add also produced the highest yield of MOS (492 mg/g) after 3 h. Therefore, Combi-CLEAs-CM-add with ease of preparation, excellent reusability and high operational stability is believed to be highly efficacious biocatalyst for MOS production.
    Matched MeSH terms: Temperature
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