Browse publications by year: 2015

  1. McCabe MP, Busija L, Fuller-Tyszkiewicz M, Ricciardelli L, Mellor D, Mussap A
    Body Image, 2015 Jan;12:108-14.
    PMID: 25497878 DOI: 10.1016/j.bodyim.2014.10.008
    This study determined how sociocultural messages to change one's body are perceived by adolescents from different cultural groups. In total, 4904 adolescents, including Australian, Chilean, Chinese, Indo-Fijian, Indigenous Fijian, Greek, Malaysian, Chinese Malaysian, Tongans in New Zealand, and Tongans in Tonga, were surveyed about messages from family, peers, and the media to lose weight, gain weight, and increase muscles. Groups were best differentiated by family pressure to gain weight. Girls were more likely to receive the messages from multiple sociocultural sources whereas boys were more likely to receive the messages from the family. Some participants in a cultural group indicated higher, and others lower, levels of these sociocultural messages. These findings highlight the differences in sociocultural messages across cultural groups, but also that adolescents receive contrasting messages within a cultural group. These results demonstrate the difficulty in representing a particular message as being characteristic of each cultural group.
    MeSH terms: Adolescent; Adolescent Behavior/psychology*; Australia; Body Image/psychology*; Chile; China; Cross-Cultural Comparison*; Culture; Family/ethnology; Family/psychology; Female; Fiji; Greece; Humans; Malaysia; Male; Mass Media; New Zealand; Peer Group; Tonga; Weight Gain/ethnology*; Weight Loss/ethnology*; Muscle, Skeletal; Muscle Strength*
  2. Bauer M, Glenn T, Alda M, Andreassen OA, Angelopoulos E, Ardau R, et al.
    Eur. Psychiatry, 2015 Jan;30(1):99-105.
    PMID: 25498240 DOI: 10.1016/j.eurpsy.2014.10.005
    PURPOSE: Two common approaches to identify subgroups of patients with bipolar disorder are clustering methodology (mixture analysis) based on the age of onset, and a birth cohort analysis. This study investigates if a birth cohort effect will influence the results of clustering on the age of onset, using a large, international database.

    METHODS: The database includes 4037 patients with a diagnosis of bipolar I disorder, previously collected at 36 collection sites in 23 countries. Generalized estimating equations (GEE) were used to adjust the data for country median age, and in some models, birth cohort. Model-based clustering (mixture analysis) was then performed on the age of onset data using the residuals. Clinical variables in subgroups were compared.

    RESULTS: There was a strong birth cohort effect. Without adjusting for the birth cohort, three subgroups were found by clustering. After adjusting for the birth cohort or when considering only those born after 1959, two subgroups were found. With results of either two or three subgroups, the youngest subgroup was more likely to have a family history of mood disorders and a first episode with depressed polarity. However, without adjusting for birth cohort (three subgroups), family history and polarity of the first episode could not be distinguished between the middle and oldest subgroups.

    CONCLUSION: These results using international data confirm prior findings using single country data, that there are subgroups of bipolar I disorder based on the age of onset, and that there is a birth cohort effect. Including the birth cohort adjustment altered the number and characteristics of subgroups detected when clustering by age of onset. Further investigation is needed to determine if combining both approaches will identify subgroups that are more useful for research.

    MeSH terms: Adult; Aged; Bipolar Disorder/diagnosis*; Female; Humans; International Cooperation; Male; Middle Aged; Global Health; Cohort Studies; Cluster Analysis; Databases, Factual; Age of Onset*; Mood Disorders/epidemiology
  3. Jayaprakash PT
    Forensic Sci Int, 2015 Jan;246:110-21.
    PMID: 25498986 DOI: 10.1016/j.forsciint.2014.10.043
    Establishing identification during skull-photo superimposition relies on correlating the salient morphological features of an unidentified skull with those of a face-image of a suspected dead individual using image overlay processes. Technical progression in the process of overlay has included the incorporation of video cameras, image-mixing devices and software that enables real-time vision-mixing. Conceptual transitions occur in the superimposition methods that involve 'life-size' images, that achieve orientation of the skull to the posture of the face in the photograph and that assess the extent of match. A recent report on the reliability of identification using the superimposition method adopted the currently prevalent methods and suggested an increased rate of failures when skulls were compared with related and unrelated face images. The reported reduction in the reliability of the superimposition method prompted a review of the transition in the concepts that are involved in skull-photo superimposition. The prevalent popular methods for visualizing the superimposed images at less than 'life-size', overlaying skull-face images by relying on the cranial and facial landmarks in the frontal plane when orienting the skull for matching and evaluating the match on a morphological basis by relying on mix-mode alone are the major departures in the methodology that may have reduced the identification reliability. The need to reassess the reliability of the method that incorporates the concepts which have been considered appropriate by the practitioners is stressed.
    MeSH terms: Face/anatomy & histology*; Humans; Image Processing, Computer-Assisted; Photography; Skull/anatomy & histology*; Reproducibility of Results; Forensic Anthropology/methods; Imaging, Three-Dimensional
  4. Shinn AP, Mühlhölzl AP, Coates CJ, Metochis C, Freeman MA
    J Invertebr Pathol, 2015 Feb;125:81-6.
    PMID: 25499897 DOI: 10.1016/j.jip.2014.12.002
    An outbreak of the sessile peritrich Zoothamnium duplicatum in a pilot, commercial-scale Limulus polyphemus hatchery resulted in the loss of ∼96% (40,000) second/third instar larvae over a 61day period. peritrich growth was heavy, leading to mechanical obstruction of the gills and physical damage. The peritrichs were controlled without resultant loss of juvenile crabs by administering 10ppm chlorine in freshwater for 1h and the addition of aquarium grade sand; a medium into which the crabs could burrow and facilitate cleaning of the carapace. Peritrich identity was confirmed from a partial SSU rDNA contiguous sequence of 1343bp (99.7% similarity to Z. duplicatum).
    MeSH terms: Animals; Chlorine/pharmacology; Horseshoe Crabs/growth & development; Horseshoe Crabs/parasitology*; Horseshoe Crabs/ultrastructure; Host-Parasite Interactions*; Larva/drug effects; Larva/growth & development; Larva/parasitology; Microscopy, Electron, Scanning; Oligohymenophorea/drug effects; Oligohymenophorea/isolation & purification; Oligohymenophorea/physiology*; Aquaculture
  5. Low HC, Silver MI, Brown BJ, Leng CY, Blas MM, Gravitt PE, et al.
    J Clin Microbiol, 2015 Feb;53(2):550-6.
    PMID: 25502520 DOI: 10.1128/JCM.02274-14
    Human papillomavirus (HPV) is causally associated with anal cancer, as HPV DNA is detected in up to 90% of anal intraepithelial neoplasias and anal cancers. With the gradual increase of anal cancer rates, there is a growing need to establish reliable and clinically relevant methods to detect anal cancer precursors. In resource-limited settings, HPV DNA detection is a potentially relevant tool for anal cancer screening. Here, we evaluated the performance of the Hybribio GenoArray (GA) for genotyping HPV in anal samples, against the reference standard Roche Linear Array (LA). Anal swab samples were obtained from sexually active men who have sex with men. Following DNA extraction, each sample was genotyped using GA and LA. The overall interassay agreement, type-specific, and single and multiple genotype agreements were evaluated by kappa statistics and McNemar's χ(2) tests. Using GA and LA, 68% and 76% of samples were HPV DNA positive, respectively. There was substantial interassay agreements for the detection of all HPV genotypes (κ = 0.70, 86% agreement). Although LA was able to detect more genotypes per sample, the interassay agreement was acceptable (κ = 0.53, 63% agreement). GA had poorer specific detection of HPV genotypes 35, 42, and 51 (κ < 0.60). In conclusion, GA and LA showed good interassay agreement for the detection of most HPV genotypes in anal samples. However, the detection of HPV DNA in up to 76% of anal samples warrants further evaluation of its clinical significance.
    MeSH terms: Anal Canal/virology*; Anus Neoplasms/diagnosis*; Anus Neoplasms/virology; Humans; Male; Homosexuality, Male; Papillomaviridae/classification*; Papillomaviridae/genetics; Papillomaviridae/isolation & purification*; Papillomavirus Infections/complications; Papillomavirus Infections/virology*; Early Detection of Cancer/methods*; Genotyping Techniques/methods*
  6. Zailani S, Iranmanesh M, Nikbin D, Beng JK
    J Med Syst, 2015 Jan;39(1):172.
    PMID: 25503418 DOI: 10.1007/s10916-014-0172-4
    With today's highly competitive market in the healthcare industry, Radio Frequency Identification (RFID) is a technology that can be applied by hospitals to improve operational efficiency and to gain a competitive advantage over their competitors. The purpose of this study is to investigate the factors that may effect RFID adoption in Malaysia's healthcare industry. In addition, the moderating role of occupational level was tested. Data was collected from 223 managers as well as healthcare and supporting staffs. This data was analyzed using the partial least squares technique. The results show that perceived ease of use and usefulness, government policy, top management support, and security and privacy concerns have an effect on the intent to adopt RFID in hospitals. There is a wide gap between managers and healthcare staff in terms of the factors that influence RFID adoption. The results of this study will help decision makers as well as managers in the healthcare industry to better understand the determinants of RFID adoption. Additionally, it will assist in the process of RFID adoption, and therefore, spread the usage of RFID technology in more hospitals.
    MeSH terms: Attitude of Health Personnel*; Confidentiality; Hospital Administration*; Humans; Leadership; Malaysia; Perception*; Computer Security; Radio Frequency Identification Device*; Policy
  7. Sani MH, Taher M, Susanti D, Kek TL, Salleh MZ, Zakaria ZA
    Biol Res Nurs, 2015 Jan;17(1):68-77.
    PMID: 25504952 DOI: 10.1177/1099800414529648
    Elucidate the antinociceptive mechanisms of α-mangostin isolated from Garcinia malaccensis Linn.
    MeSH terms: Analgesics/pharmacology*; Animals; Arginine/administration & dosage; Capsaicin/administration & dosage; Disease Models, Animal; Male; Mice, Inbred ICR; Glutamic Acid/administration & dosage; NG-Nitroarginine Methyl Ester/administration & dosage; Xanthones/pharmacology*; Mice; Rats
  8. Tumian NR, Wong M, Wong CL
    J Obstet Gynaecol Res, 2015 Jun;41(6):967-70.
    PMID: 25510540 DOI: 10.1111/jog.12648
    α°-thalassemia is a well-known cause of hydrops fetalis in South-East Asia and can be detected in utero. We report a very rare case of thyrotoxic cardiomyopathy associated with hyperplacentosis secondary to α°-thalassemia-associated hydrops fetalis. A 22-year-old primigravida with microcytic anemia presented at 27 weeks' gestation with pre-eclampsia, hyperthyroidism and cardiac failure. Serum β-human chorionic gonadotrophin was markedly elevated and abdominal ultrasound revealed severe hydropic features and enlarged placenta. Serum β-human chorionic gonadotrophin, cardiac function and thyroid function tests normalized after she delivered a macerated stillbirth. Histopathology of the placenta showed hyperplacentosis. Blood DNA analysis revealed that both patient and husband have the α°-thalassemia trait. This case illustrates a very atypical presentation of α°-thalassemia-associated hydrops fetalis and the importance of early prenatal diagnosis of α-thalassemia in women of relevant ethnic origin with microcytic anemia so that appropriate genetic counseling can be provided to reduce maternal morbidity and the incidence of hydrops fetalis.
    MeSH terms: Asia; Asia, Southeastern; DNA; Female; Genetic Counseling; Heart Failure; Humans; Hyperthyroidism; Cardiomyopathies; Placenta; Pre-Eclampsia; Pregnancy; Prenatal Diagnosis; Thyroid Function Tests; Hydrops Fetalis; Incidence; alpha-Thalassemia; Spouses; Anemia, Iron-Deficiency; Stillbirth
  9. Lulu T, Park SY, Ibrahim R, Paek KY
    J Biosci Bioeng, 2015 Jun;119(6):712-7.
    PMID: 25511788 DOI: 10.1016/j.jbiosc.2014.11.010
    The present study aimed to optimize the conditions for the production of adventitious roots from Eurycoma longifolia Jack, an important medicinal woody plant, in bioreactor culture. The effects of the type and concentration of auxin on root growth were studied, as well as the effects of the NH4(+):NO3(-) ratio on adventitious root growth and the production of phenolics and flavonoids. Approximately 5 g L(-1) fresh weight of adventitious roots was inoculated into a 3 L balloon-type bubble bioreactor, which contained 2 L 3/4 MS medium supplemented with 30 g L(-1) sucrose and cultures were maintained in the dark for 7 weeks at 24 ± 1°C. Higher concentrations of IBA (7.0 and 9.0 mg L(-1)) and NAA (5.0 mg L(-1)) enhanced the biomass and accumulation of total phenolics and flavonoids. The adventitious roots were thin, numerous, and elongated in 3/4 MS medium supplemented with 5.0 and 7.0 mg L(-1) IBA, whereas the lateral roots were shorter and thicker with 5.0 mg L(-1) NAA compared with IBA treatment. The optimum biomasses of 50.22 g L(-1) fresh weight and 4.60 g L(-1) dry weight were obtained with an NH4(+):NO3(-) ratio of 15:30. High phenolic and flavonoid productions (38.59 and 11.27 mg L(-1) medium, respectively) were also obtained with a ratio of 15:30. Analysis of the 2,2-diphenyl-1-picrylhydrazyl (DPPH)-scavenging activity indicated higher antioxidant activity with an NH4(+):NO3(-) ratio of 30:15. These results suggest that balloon-type bubble bioreactor cultures are suitable for the large-scale commercial production of E. longifolia adventitious roots which contain high yield of bioactive compounds.
    MeSH terms: Antioxidants/metabolism; Biphenyl Compounds/metabolism; Culture Media/pharmacology; Culture Media/chemistry; Flavonoids/biosynthesis*; Indoleacetic Acids/pharmacology; Nitrates/pharmacology; Phenols/metabolism*; Picrates/metabolism; Plant Roots/drug effects; Plant Roots/growth & development*; Plant Roots/metabolism*; Biomass*; Bioreactors*; Eurycoma/drug effects; Eurycoma/growth & development*; Eurycoma/metabolism; Ammonium Compounds/pharmacology
  10. Ng SF, Anuwi NA, Tengku-Ahmad TN
    AAPS PharmSciTech, 2015 Jun;16(3):656-63.
    PMID: 25511806 DOI: 10.1208/s12249-014-0248-y
    Hydrocortisone cream intended for atopic eczema often produces unwanted side effects after long-term use. These side effects are essentially due to repeated percutaneous administration of the medication for skin dermatitis, as atopic eczema is a relapsing disorder. Hence, there is a need to develop a new hydrocortisone formulation that will deliver the drug more effectively and require a reduced dosing frequency; therefore, the side effects could be minimized. In this study, a hydroxypropyl methylcellulose (HPMC) lyogel system based on 80% organic and 20% aqueous solvents containing 1% hydrocortisone was formulated. The hydrocortisone lyogel physicochemical characteristics, rheological properties, stability profile, and in vitro Franz cell drug release properties, as well as the in vivo therapeutic efficacies and dermal irritancy in Balb/c mice were investigated. The HPMC lyogel appeared clear and soft and was easy to rub on the skin. The lyogel also showed a higher drug release profile compared with commercial hydrocortisone cream. Similar to the cream, HPMC lyogels exhibited pseudoplastic behavior. From the mouse model, the hydrocortisone lyogel showed higher inflammatory suppressive effects than the cream. However, it did not reduce the transepidermal water loss as effectively as the control did. The dermal irritancy testing revealed that the hydrocortisone lyogel caused minimal irritation. In conclusion, HPMC lyogel is a promising vehicle to deliver hydrocortisone topically, as it showed a higher drug release in vitro as well as enhanced therapeutic efficacy in resolving eczematous inflammatory reaction compared with commercial cream.
    MeSH terms: Administration, Cutaneous; Adrenal Cortex Hormones/administration & dosage*; Adrenal Cortex Hormones/immunology; Animals; Anti-Inflammatory Agents/administration & dosage; Anti-Inflammatory Agents/immunology; Chemistry, Pharmaceutical/methods; Dermatitis, Atopic/drug therapy*; Dermatitis, Atopic/immunology; Dermatologic Agents/administration & dosage; Dermatologic Agents/immunology; Hydrocortisone/administration & dosage; Hydrocortisone/immunology; Immunoglobulin E/immunology*; Mice, Inbred BALB C; Skin/drug effects*; Skin/immunology*; Mice
  11. Karupaiah T, Wong K, Chinna K, Arasu K, Chee WS
    Health Educ Behav, 2015 Jun;42(3):339-51.
    PMID: 25512075 DOI: 10.1177/1090198114558588
    The CORFIS (Community-Based Cardiovascular Risk Factors Intervention Strategies) program was piloted in community clinics in Malaysia to address the lack of health education in chronic disease management. The stages of change model was applied in a multicenter quasi-experimental design to evaluate adherence to advocated behaviors in CORFIS patients with hypertension. Based on submitted diet and exercise records (n = 209), adherence to sodium reduction, regular exercise, and increasing fruit and vegetable intake behaviors were quantified against weight, waist circumference (WC), systolic blood pressure (SBP), and diastolic blood pressure (DBP) changes. Patients were categorized at 6 months into nonadherent/N-A (Precontemplation, Contemplation, and Preparation), newly adherent/NA (Action) and totally adherent/TA (Maintenance) groups. Self-reported adherence records did not meet recommended targets for healthful behaviors, but clinical benefits were achieved by adherent groups as indicated by effect size (Cohen's d) comparisons. SBP reduction was associated with adherence to sodium reduction in NA (d = 0.60, p < .001) and TA (d = 0.45, p < .001) compared to N-A (d = 0.13, p > .05). Marginally increasing fruit and vegetable consumption (Δ = 0.41 servings) resulted in sizeable reductions in weight for NA (d = 0.81, p < .001) > TA (d = 0.54, p < .001) > N-A (d = 0.21, p > .05) and in WC for NA (d = 0.68, p < .00) > TA (d = 0.53, p < .001) > N-A (d = 0.52, p > .05). Exercise behavior was least successful as pedometer counting was below 10,000 steps but sizeable weight and WC reductions were largest for NA (d = 0.71 and 0.79, respectively) > TA (d = 0.60 and 0.53, respectively) > N-A (d = 0.33 and 0.35, respectively). Patients reporting a shift to positive stages of change behaviors enjoyed clinically beneficial reductions in SBP, DBP, weight, and WC.
    MeSH terms: Adult; Ambulatory Care Facilities; Blood Pressure; Diet; Female; Health Education*; Humans; Hypertension/therapy*; Malaysia/epidemiology; Male; Middle Aged; Models, Psychological; Patient Compliance/psychology*; Risk Factors; Sodium, Dietary; Cohort Studies; Weight Loss; Health Behavior*; Exercise; Body Mass Index; Self Report
  12. Goh KL, Razlan H, Hartono JL, Qua CS, Yoong BK, Koh PS, et al.
    J Dig Dis, 2015 Mar;16(3):152-8.
    PMID: 25512092 DOI: 10.1111/1751-2980.12223
    Hepatocellular carcinoma (HCC) is an important cancer in Malaysia. This study aimed to determine the epidemiological characteristics and clinical presentations of patients in a multiracial population consisting of three major Asian races: Malays, Chinese and Indians.
    MeSH terms: Aged; alpha-Fetoproteins/metabolism; China/ethnology; Female; Health Surveys; Carcinoma, Hepatocellular/diagnosis; Carcinoma, Hepatocellular/ethnology*; Carcinoma, Hepatocellular/etiology; Carcinoma, Hepatocellular/secondary; Carcinoma, Hepatocellular/therapy; Humans; India/ethnology; Liver Cirrhosis/ethnology; Liver Neoplasms/diagnosis; Liver Neoplasms/ethnology*; Liver Neoplasms/etiology; Liver Neoplasms/therapy; Lung Neoplasms/epidemiology; Lung Neoplasms/secondary; Magnetic Resonance Imaging; Malaysia/epidemiology; Male; Middle Aged; Neoplasm Staging; Population Surveillance; Tomography, X-Ray Computed; Biomarkers, Tumor/blood
  13. Harruddin N, Othman N, Ee Sin AL, Raja Sulaiman RN
    Environ Technol, 2015 Jan-Feb;36(1-4):271-80.
    PMID: 25514128 DOI: 10.1080/09593330.2014.943301
    Effluent containing colour/dyes, especially reactive dyes, becomes a great concern of wastewater treatment because it is toxic to human life and aquatic life. In this study, reactive dye of Black B was separated using the supported liquid membrane process. Commercial polypropylene membrane was used as a support of the kerosene-tridodecylamine liquid membrane. Several parameters were tested and the result showed that almost 100% of 70 ppm Black B was removed and 99% of 70 ppm Black B was recovered at pH 2 of the feed phase containing 0.00001 M Na2SiO3, flow rate of 150 ml/min and 0.2 M NaOH. The membrane support also remained stable for up to 36 hours under an optimum condition.
    MeSH terms: Industrial Waste/prevention & control; Naphthalenesulfonates/isolation & purification*; Naphthalenesulfonates/chemistry; Solutions; Textile Industry; Textiles/analysis*; Ultrafiltration/methods; Water Pollutants, Chemical/isolation & purification*; Water Pollutants, Chemical/chemistry; Water Purification/methods*; Recycling/methods*; Waste Water/chemistry*
  14. Waran V, Narayanan V, Karuppiah R, Thambynayagam HC, Muthusamy KA, Rahman ZA, et al.
    Simul Healthc, 2015 Feb;10(1):43-8.
    PMID: 25514588 DOI: 10.1097/SIH.0000000000000060
    Training in intraventricular endoscopy is particularly challenging because the volume of cases is relatively small and the techniques involved are unlike those usually used in conventional neurosurgery. Present training models are inadequate for various reasons. Using 3-dimensional (3D) printing techniques, models with pathology can be created using actual patient's imaging data. This technical article introduces a new training model based on a patient with hydrocephalus secondary to a pineal tumour, enabling the models to be used to simulate third ventriculostomies and pineal biopsies.
    MeSH terms: Humans; Hydrocephalus/surgery*; Manikins*; Models, Biological*; Ventriculostomy/education*; Neuroendoscopy/education*
  15. Nathan AM, de Bruyne JA
    Indian J Pediatr, 2015 Jul;82(7):660-1.
    PMID: 25514886 DOI: 10.1007/s12098-014-1640-z
    MeSH terms: Anti-Bacterial Agents/therapeutic use; Child; Hospitalization; Humans; Pneumonia*; Community-Acquired Infections/drug therapy*; Pneumonia, Bacterial/drug therapy
  16. Azad MC, Fraser K, Rumana N, Abdullah AF, Shahana N, Hanly PJ, et al.
    J Clin Sleep Med, 2015 Jan 15;11(1):69-74.
    PMID: 25515274 DOI: 10.5664/jcsm.4370
    Medical students carry a large academic load which could potentially contribute to poor sleep quality above and beyond that already experienced by modern society. In this global literature review of the medical students' sleep experience, we find that poor sleep is not only common among medical students, but its prevalence is also higher than in non-medical students and the general population. Several factors including medical students' attitudes, knowledge of sleep, and academic demands have been identified as causative factors, but other potential mechanisms are incompletely understood. A better understanding about the etiology of sleep problems in medical trainees is essential if we hope to improve the overall quality of medical students' lives, including their academic performance. Sleep self-awareness and general knowledge appear insufficient in many studied cohorts, so increasing education for students might be one beneficial intervention. We conclude that there is ample evidence for a high prevalence of the problem, and research in this area should now expand towards initiatives to improve general sleep education for medical students, identify students at risk, and target them with programs to improve sleep.
    MeSH terms: Humans; Surveys and Questionnaires; Sleep Wake Disorders/epidemiology*; Students, Medical/statistics & numerical data*; Prevalence; Internationality*
  17. Abubakar IB, Lim KH, Loh HS
    Nat Prod Res, 2015;29(22):2137-40.
    PMID: 25515603 DOI: 10.1080/14786419.2014.991927
    Tocotrienols have been reported to possess anticancer effects other than anti-inflammatory and antioxidant activities. This study explored the potential synergism of antiproliferative effects induced by individual alkaloid extracts of Ficus fistulosa, Ficus hispida and Ficus schwarzii combined with δ- and γ-tocotrienols against human brain glioblastoma (U87MG), lung adenocarcinoma (A549) and colorectal adenocarcinoma (HT-29) cells. Cell viability and morphological results demonstrated that extracts containing a mixture of alkaloids from the leaves and bark of F. schwarzii inhibited the proliferation of HT-29 cells, whereas the alkaloid extracts of F. fistulosa inhibited the proliferation of both U87MG and HT-29 cells and showed synergism in combined treatments with either δ- or γ-tocotrienol resulting in 2.2-34.7 fold of reduction in IC50 values of tocotrienols. The observed apoptotic cell characteristics in conjunction with the synergistic antiproliferative effects of Ficus species-derived alkaloids and tocotrienols assuredly warrant future investigations towards the development of a value-added chemotherapeutic regimen against cancers.
    MeSH terms: Alkaloids/isolation & purification; Alkaloids/pharmacology*; Antineoplastic Agents, Phytogenic/isolation & purification; Antineoplastic Agents, Phytogenic/pharmacology; Drug Synergism; Humans; Plant Extracts/pharmacology*; Plant Oils/chemistry*; Plant Leaves/chemistry; Plant Bark/chemistry; Tocotrienols/isolation & purification; Tocotrienols/pharmacology*; Ficus/chemistry*; Cell Line, Tumor
  18. Feroz SR, Sumi RA, Malek SN, Tayyab S
    Exp Anim, 2015;64(2):101-8.
    PMID: 25519455 DOI: 10.1538/expanim.14-0053
    The interaction of pinostrobin (PS), a multitherapeutic agent with serum albumins of various mammalian species namely, goat, bovine, human, porcine, rabbit, sheep and dog was investigated using fluorescence quench titration and competitive drug displacement experiments. Analysis of the intrinsic fluorescence quenching data revealed values of the association constant, K(a) in the range of 1.49 - 6.12 × 10(4) M(-1), with 1:1 binding stoichiometry. Based on the PS-albumin binding characteristics, these albumins were grouped into two classes. Ligand displacement studies using warfarin as the site I marker ligand correlated well with the binding data. Albumins from goat and bovine were found to be closely similar to human albumin on the basis of PS binding characteristics.
    MeSH terms: Animals; Binding Sites; Cattle; Dogs; Ethyl Chloride; Humans; Protein Binding; Rabbits; Serum Albumin/metabolism*; Sheep; Species Specificity; Spectrometry, Fluorescence/methods; Swine; Molecular Structure; Models, Animal; Flavanones/metabolism*; Flavanones/chemistry
  19. Han WB, Dou H, Yuan WH, Gong W, Hou YY, Ng SW, et al.
    Planta Med, 2015 Jan;81(2):145-51.
    PMID: 25519918 DOI: 10.1055/s-0034-1383392
    The endophytic fungus Guignardia mangiferae isolated from Ilex cornuta leaves was shown to produce a family of meroterpenes with toll-like receptor 3 regulating activity (1-9), of which 1-3 possessed new structures. The absolute stereochemistry of 1-3 was assigned through a combination of nuclear magnetic resonance experiments, chemical derivation, CD spectra, and single-crystal X-ray diffraction analyses (CuK α ). The precursor labeled cultivation suggests that these meroterpenes are most likely assembled through terpenoid-shikimate pathways. Moreover, meroterpenes 1-3, 5-7, and 9 selectively upregulate, but 4 and 8 downregulate the toll-like receptor 3 expression in mouse dendritic cells at 10.0 µM.
    MeSH terms: Ascomycota/chemistry*; Gene Expression Regulation; Terpenes/isolation & purification; Terpenes/pharmacology*; Terpenes/chemistry; Molecular Structure; Plant Leaves/microbiology; Ilex/microbiology*; Toll-Like Receptor 3/metabolism*; Toll-Like Receptor 3/chemistry; Endophytes
  20. Wan Ibrahim WA, Arsad SR, Maarof H, Sanagi MM, Aboul-Enein HY
    Chirality, 2015 Mar;27(3):223-7.
    PMID: 25523071 DOI: 10.1002/chir.22416
    This work aimed to develop a chiral separation method of ketoconazole enantiomers using electrokinetic chromatography. The separation was achieved using heptakis (2, 3, 6-tri-O-methyl)-β-cyclodextrin (TMβCD), a commonly used chiral selector (CS), as it is relatively inexpensive and has a low UV absorbance in addition to an anionic surfactant, sodium dodecyl sulfate (SDS). The influence of TMβCD concentration, phosphate buffer concentration, SDS concentration, buffer pH, and applied voltage were investigated. The optimum conditions for chiral separation of ketoconazole was achieved using 10 mM phosphate buffer at pH 2.5 containing 20 mM TMβCD, 5 mM SDS, and 1.0% (v/v) methanol with an applied voltage of 25 kV at 25 °C with a 5-s injection time (hydrodynamic injection). The four ketoconazole stereoisomers were successfully resolved for the first time within 17 min (total analysis time was 28 min including capillary conditioning). The migration time precision of this method was examined to give repeatability and reproducibility with RSDs ≤5.80% (n =3) and RSDs ≤8.88% (n =9), respectively.
    MeSH terms: Methanol/pharmacology; Hydrogen-Ion Concentration; Ketoconazole/chemistry*; Sodium Dodecyl Sulfate/chemistry; Stereoisomerism; Temperature; Electrophoresis, Capillary/methods*; beta-Cyclodextrins/chemistry
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