The Akaki River in the Upper Awash Basin, which flows through Addis Ababa, the capital city of Ethiopia, has been highly polluted by sewage from factories and residential areas. A population-based cross-sectional study was used to assess the association between trace elements and kidney injury from residents living in polluted areas downstream (Akaki-Kality) versus upstream (Gullele) in Sub-Cities of Addis Ababa. A total of 95 individuals (53 from Akaki-Kality and 42 from Gullele) were included in the study. Kidney injury molecule 1 (KIM-1), lead, arsenic, cadmium, cobalt, lead, manganese, zinc, iron, copper, chromium and nickel were evaluated in residents' urine and nail samples. A large proportion (74%) of the sample population contained KIM-1, including 81% residents in Akaki-Kality and 64% residents in Gullele. KIM-1 was, however, not significantly different (p = 0.05) between the two Sub-Cities, with median of 0.224 ng/mL in Akaki-Kality and 0.152 ng/mL in Gullele. Most of the analyzed elements, except Pb, As, Cd and Co, were found in all of the nail samples, with median (µg/g) in the range of 442‒714 Fe, 97.0‒246 Zn, 11.6‒24.1 Mn, 4.49‒5.85 Cu, 1.46‒1.66 Cr and 1.22‒1.41 Ni. The high incidence of KIM-1 indicates a potential for long term renal tubular damage among residents of the Sub-Cities. The concentrations of the elements in nails were, however, not significantly associated (p = 0.05) with the corresponding levels of KIM-1 in urine. Hence, the observed KIM-1 might be related to exposure to toxic substances or factors other than those included in this study.
This paper presents an assessment of the start-up performance of aerobic granular sludge (AGS) for the treatment of low-strength (chemical oxygen demand, COD
Wastewater monitoring for SARS-CoV-2 has attracted considerable attention worldwide to complement the existing clinical-based surveillance system. In this study, we report our first successful attempt to prove the circulation of SARS-CoV-2 genes in Malaysian urban wastewater. A total of 18 wastewater samples were obtained from a regional sewage treatment plant that received municipal sewage between February 2021 and May 2021. Using the quantitative PCR assay targeting the E and RdRp genes of SARS-CoV-2, we confirmed that both genes were detected in the raw sewage, while no viral RNA was found in the treated sewage. We were also able to show that the trend of COVID-19 cases in Kuala Lumpur and Selangor was related to the changes in SARS-CoV-2 RNA levels in the wastewater samples. Overall, our study highlights that monitoring wastewater for SARS-CoV-2 should help local health professionals to obtain additional information on the rapid and silent circulation of infectious agents in communities at the regional level.
The present study applied the use of sequential extraction technique and simple bioaccessibility extraction test to investigate the bioavailable fractions and the human bioaccessible concentration of metals collected from nine stations in surface sediment of the Bernam River. The concentrations of total and bioaccessible metals from different stations were in the range of 0.30-1.43 μg g(-1) and 0.04-0.14 μg g(-1) for total cadmium and bioaccessibility of cadmium, respectively, 6.20-288 μg kg(-1) and 2.06-8.53 μg kg(-1) for total mercury and bioaccessibility of mercury, respectively, and 9.2-106.59 μg g(-1) and 0.4-2.75 μg kg(-1) for total tin and bioaccessibility of tin, respectively. The chemical speciation of Cd in most sampling stations was in the order of oxidisable-organic > acid-reducible > residual > exchangeable, while the chemical speciation of Hg was in the order of exchangeable > residual > oxidisable-organic > acid-reducible and the chemical speciation of Hg was in the order of residual > oxidisable-organic > acid-reducible > exchangeable. The principal component analysis showed that the main factors influencing the bioaccessibility of mercury in surface sediments were the sediment total organic matter, cation exchange capacity, and easily, freely, or leachable and exchangeable fraction, and the factors influencing the bioaccessibility of tin were the total tin and cation exchange capacity, while the bioaccessibility of Cd in surface sediments was influenced by the only factor which is the easily, freely, or leachable and exchangeable fraction.
Open biomass burning in Peninsula Malaysia, Sumatra, and parts of the Indochinese region is a major source of transboundary haze pollution in the Southeast Asia. To study the influence of haze on rainwater chemistry, a short-term investigation was carried out during the occurrence of a severe haze episode from March to April 2014. Rainwater samples were collected after a prolonged drought and analyzed for heavy metals and major ion concentrations using inductively coupled plasma mass spectroscopy (ICP-MS) and ion chromatography (IC), respectively. The chemical composition and morphology of the solid particulates suspended in rainwater were examined using a scanning electron microscope coupled with energy-dispersive X-ray spectroscopy (SEM-EDS). The dataset was further interpreted using enrichment factors (EF), statistical analysis, and a back trajectory (BT) model to find the possible sources of the particulates and pollutants. The results show a drop in rainwater pH from near neutral (pH 6.54) to acidic (
Several research efforts have been conducted to monitor and analyze the impact of environmental factors on the heavy metal concentrations and physicochemical properties of water bodies (lakes and rivers) in different countries worldwide. This article provides a general overview of the previous works that have been completed in monitoring and analyzing heavy metals. The intention of this review is to introduce the historical studies to distinguish and understand the previous challenges faced by researchers in analyzing heavy metal accumulation. In addition, this review introduces a survey on the importance of time increment sampling (monthly and/or seasonally) to comprehend and determine the rate of change of different parameters on a monthly and seasonal basis. Furthermore, suggestions are made for future research to achieve more understandable figures on heavy metal accumulation by considering climate conditions. Thus, the intent of the current study is the provision of reliable models for predicting future heavy metal accumulation in water bodies in different climates and pollution conditions so that water management can be achieved using intelligent proactive strategies and artificial neural network (ANN) techniques.
Studies that associate environmental parameters with aquatic organisms in man-made lakes remain limited by accessibility and interest particularly in many Asian countries. With missed opportunities to monitor environmental transitions at Lake Kenyir, our knowledge of lake transition is restricted to the non-mixing shallow waters only. Triplicate monthly benthic invertebrate samples were collected concurrently with various environmental parameters at three locations (zones A-C) of Kenyir Lake, Malaysia. Our results affirmed that the northeast part of Lake Kenyir is oligotrophic. Abundance of phytoplankton, total suspended solids, phosphate, nitrite and nitrate drive the abundance of various groups of benthic invertebrates. All of these extrinsic variables (except phosphate) negatively influenced the density of Trichoptera and positively influenced (P<0.05) the densities of Polychaeta, Oligochaeta, Bivalvia, Gastropod, Isopoda and Copepod in all zones. Phosphate negatively influenced the density of Trichoptera and positively influenced (P<0.05) the densities of Oligochaeta, Bivalvia and Copepod. Its influences on the Polychaeta, Gastropod and Isopoda densities were zone-specific. Overall, seasons equally influenced the relationships between extrinsic and response variables in all zones. The results of this study are useful to evaluate the lake's environmental quality, in conservation and in similar projects involving environmental handling, monitoring and recovery.
At the end of 2019, a novel coronavirus COVID-19 emerged in Wuhan, China, and later spread throughout the world, including Iraq. To control the rapid dispersion of the virus, Iraq, like other countries, has imposed national lockdown measures, such as social distancing, restriction of automobile traffic, and industrial enterprises. This has led to reduced human activities and air pollutant emissions, which caused improvement in air quality. This study focused on the analysis of the impact of the six partial, total, and post-lockdown periods (1st partial lockdown from March 1 to16, 2020, 1st total lockdown from March 17 to April 21, 2nd partial lockdown from April 22 to May 23, 2nd total lockdown from May 24 to June 13, 3rd partial lockdown from June 14 to August 19, and end partial lockdown from August 20 to 31) on the average of daily NO2, O3, PM2.5, and PM10 concentrations, as well as air quality index (AQI) in 18 Iraqi provinces during these periods (from March 1st to August 31st, 2020). The analysis showed a decline in the average of daily PM2.5, PM10, and NO2 concentrations by 24%, 15%, and 8%, respectively from March 17 to April 21, 2020 (first phase of total lockdown) in comparison to the 1st phase of partial lockdown (March 1 to March 16, 2020). Furthermore, the O3 increased by 10% over the same period. The 2nd phase of total lockdown, the 3rd partial lockdown, and the post-lockdown periods witnessed declines in PM2.5 by 8%, 11%, and 21%, respectively, while the PM10 increases over the same period. Iraqi also witnessed improvement in the AQI by 8% during the 1st phase of total lockdown compared to the 1st phase of partial lockdown. The level of air pollutants in Iraq declined significantly during the six lockdown periods as a result of reduced human activities. This study gives confidence that when strict measures are implemented, air quality can improve.
The Three Gorges Dam's construction and industrial transfer have resulted in a new air pollution pattern with the potential to threaten the reservoir eco-environment. To assess the impact of socioeconomic factors on the pattern of air quality vairation and economical risks, concentrations of SO2, NO2, and PM10, industry genres, and meteorological conditions were selected in the Three Gorges Reservoir of Chongqing (TGRC) during 2006-2015. Results showed that air quality had improved to some extent, but atmospheric NO2 showed an increased trend during 2011-2015. Spatially, higher atmospheric NO2 extended to the surrounding area. The primary industry, especially for agriculture, had shown to be responsible for the remarkable increase of atmospheric NO2 (p
Dhaka and its neighboring areas suffer from severe air pollution, especially during dry season (November-April). We investigated temporal and directional variations in particulate matter (PM) concentrations in Dhaka, Gazipur, and Narayanganj from October 2012 to March 2015 to understand different aspects of PM concentrations and possible sources of high pollution in this region. Ninety-six-hour backward trajectories for the whole dry season were also computed to investigate incursion of long-range pollution into this area. We found yearly PM10 concentrations in this area about three times and yearly PM2.5 concentrations about six times greater than the national standards of Bangladesh. Dhaka and its vicinity experienced several air pollution episodes in dry season when PM2.5 concentrations were 8-13 times greater than the World Health Organization (WHO) guideline value. Higher pollution and great contribution of PM2.5 most of the time were associated with the north-westerly wind. Winter (November to January) was found as the most polluted season in this area, when average PM10 concentrations in Dhaka, Gazipur, and Narayanganj were 257.1, 240.3, and 327.4 μg m(-3), respectively. Pollution levels during wet season (May-October) were, although found legitimate as per the national standards of Bangladesh, exceeded WHO guideline value in 50 % of the days of that season. Trans-boundary source identifications using concentration-weighted trajectory method revealed that the sources in the eastern Indian region bordering Bangladesh, in the north-eastern Indian region bordering Nepal and in Nepal and its neighboring areas had high probability of contributing to the PM pollutions at Gazipur station.
Urban road dust contains anthropogenic components at toxic concentrations which can be hazardous to human health. A total of 36 road dust samples from five different urban areas, a commercial (CM), a high traffic (HT), a park (GR), a rail station (LRT), and a residential area (RD), were collected in Kuala Lumpur City followed by investigation into compositions, sources, and human health risks. The concentrations of trace metals in road dust and the bioaccessible fraction were determined using inductively couple plasma-mass spectrometry (ICP-MS) while ion concentrations were determined using ion chromatography (IC). The trace metal concentrations were dominated by Fe and Al with contributions of 53% and 21% to the total trace metal and ion concentrations in road dust. Another dominant metal was Zn while the dominant ion was Ca2+ with average concentrations of 314 ± 190 μg g-1 and 3470 ± 1693 μg g-1, respectively. The most bioaccessible fraction was Zn followed by the sequence Sr > Cd > Cr > Cu > Ni > Co > Mn > As > V > Pb > Fe > Al > U. The results revealed that the highest trace metal and ion concentrations in road dust and in the bioaccessible fraction were found at the LRT area. Based on the source apportionment analysis, the major source of road dust was vehicle emissions/traffic activity (47%), and for the bioaccessible fraction, the major source was soil dust (50%). For the health risk assessments, hazard quotient (HQ) and cancer risk (CR) values for each element were
In this study, a systematic procedure for establishing the relationship between particulate matter (PM) and microbial counts in four operating rooms (ORs) was developed. The ORs are located in a private hospital on the western coast of Peninsular Malaysia. The objective of developing the systematic procedure is to ensure that the correlation between the PMs and microbial counts are valid. Each of the procedures is conducted based on the ISO, IEST, and NEBB standards. The procedures involved verifying the operating parameters are air change rate, room differential pressure, relative humidity, and air temperature. Upon verifying that the OR parameters are in the recommended operating range, the measurements of the PMs and sampling of the microbes were conducted. The TSI 9510-02 particle counter was used to measure three different sizes of PMs: PM 0.5, PM 5, and PM 10. The MAS-100ECO air sampler was used to quantify the microbial counts. The present study confirms that PM 0.5 does not have an apparent positive correlation with the microbial count. However, the evident correlation of 7% and 15% were identified for both PM 5 and PM 10, respectively. Therefore, it is suggested that frequent monitoring of both PM 5 and PM 10 should be practised in an OR before each surgical procedure. This correlation approach could provide an instantaneous estimation of the microbial counts present in the OR.
The emergence of microplastics (MPs) pollution as a global environmental concern has attracted significant attention in the last decade. The majority of the human population spends most of their time indoors, leading to increased exposure to MPs contamination through various sources such as settled dust, air, drinking water and food. Although research on indoor MPs has intensified significantly in recent years, comprehensive reviews on this topic remain limited. Therefore, this review comprehensively analyses the occurrence, distribution, human exposure, potential health impact and mitigation strategies of MPs in the indoor air environment. Specifically, we focus on the risks associated with finer MPs that can translocate into the circulatory system and other organs, emphasizing the need for continued research to develop effective strategies to mitigate the risks associated with MPs exposure. Our findings suggest that indoor MPs impose potential risk to human health, and strategies for mitigating exposure should be further explored.
Southeast (SE) Asia is a highly biodiverse region, yet it is also estimated to cumulatively contribute a third of the total global marine plastic pollution. This threat is known to have adverse impacts on marine megafauna, however, understanding of its impacts has recently been highlighted as a priority for research in the region. To address this knowledge gap, a structured literature review was conducted for species of cartilaginous fishes, marine mammals, marine reptiles, and seabirds present in SE Asia, collating cases on a global scale to allow for comparison, coupled with a regional expert elicitation to gather additional published and grey literature cases which would have been omitted during the structured literature review. Of the 380 marine megafauna species present in SE Asia, but also studied elsewhere, we found that 9.1 % and 4.5 % of all publications documenting plastic entanglement (n = 55) and ingestion (n = 291) were conducted in SE Asian countries. At the species level, published cases of entanglement from SE Asian countries were available for 10 % or less of species within each taxonomic group. Additionally, published ingestion cases were available primarily for marine mammals and were lacking entirely for seabirds in the region. The regional expert elicitation led to entanglement and ingestion cases from SE Asian countries being documented in 10 and 15 additional species respectively, highlighting the utility of a broader approach to data synthesis. While the scale of the plastic pollution in SE Asia is of particular concern for marine ecosystems, knowledge of its interactions and impacts on marine megafauna lags behind other areas of the world, even after the inclusion of a regional expert elicitation. Additional funding to help collate baseline data are critically needed to inform policy and solutions towards limiting the interactions of marine megafauna and plastic pollution in SE Asia.
Dartford, a town in England, heavily relied on industrial production, particularly mining, which caused significant environmental pollution and geological damage. However, in recent years, several companies have collaborated under the guidance of the local authorities to reclaim the abandoned mine land in Dartford and develop it into homes, known as the Ebbsfleet Garden City project. This project is highly innovative as it not only focuses on environmental management but also provides potential economic benefits, employment opportunities, builds a sustainable and interconnected community, fosters urban development and brings people closer together. This paper presents a fascinating case that employs satellite imagery, statistical data, and Fractional Vegetation Cover (FVC) calculations to analyse the re-vegetation progress of Dartford and the development of the Ebbsfleet Garden City project. The findings indicate that Dartford has successfully reclaimed and re-vegetated the mine land, maintaining a high vegetation cover level while the Ebbsfleet Garden City project has advanced. This suggests that Dartford is committed to environmental management and sustainable development while pursuing construction projects.
In recent years, the environmental pollution of microplastics (MPs) has increasingly drawn our attention. MPs are small fragments of plastics that are commonly dispersed in the environment. The accumulation of environmental MPs is due to population growth and urbanization, while natural disasters such as hurricanes, flooding and human activity may influence their distribution. The leaching of chemicals from MPs raises a significant safety problem and environmental approaches aimed at reducing the use and recycling of plastics, with the replacement by bioplastics and wastewater treatment developments are called for. This summary also helps in demonstrating the connection between terrestrial and freshwater MPs and wastewater treatment plants as the major contributors to environmental MPs by discharges of sludge and effluent. More research on the classification, detection, characterization and toxicity of MPs are essential to enable greater options and solutions. Control initiatives need to intensify the comprehensive study of MP waste control and management information programmes in the fields of institutional engagement, technological research and development, legislation and regulation. A comprehensive quantitative analysis approach for MPs should be created in the future, and more reliable traceability analysis methods should be built to examine further its environmental activity and existence, where this should be done to improve scientific research on MP pollution in terrestrial, freshwater and marine environments and hence, develop more scientific and rational control policies.
Food waste has been considered a global problem due to its adverse impacts on food security, the environment, and the economy; hence needs urgent attention and action. Its generation is expected to increase as the world population grows rapidly, leading to more global waste. This study sought the impacts of the COVID-19 outbreak on the 1-week operation of selected casual dining restaurants in urban (Ampang, Kuala Lumpur) and suburban areas (Kota Bharu, Kelantan and Jasin, Melaka) of Peninsular Malaysia, as the local community adjusted to life with COVID-19. The food waste in this study was classified into three categories: preparation loss, serving loss, and customer's plate waste. Our material flow analysis revealed that the highest food loss at these locations came from preparation loss (51.37%), followed by serving loss (30.95%), and preparation loss (17.8%). Meanwhile, the total average electricity consumption and its carbon footprint for Ampang were 127 kWh and 13.87 kgCO2e, Kota Bharu 269.8 kWh and 29.47 kgCO2e, and Jasin 142.2 kWh and 15.54 kgCO2e, respectively. As for water, Ampang exhibited 22.93 m3 total average consumption and 7.91 kgCO2e greenhouse emissions from this source, Jasin consuming 17.11 m3 of water and releasing 5.88 kgCO2e of carbon footprint, while Kota Bharu emitted 20.21 kgCO2e of greenhouse gases from its 58.71 m3 water consumption. Our findings indicate a major 'food leak' at the preparation stage, from which the waste could be utilised as livestock feed, and that electricity consumption is a greater carbon emitter than water consumption, suggesting a need for improvement to the kitchen practices and equipment.
Calix[4]arene/polyurethane (C4PU) has been synthesized and characterized as an alternative adsorbent for the adsorption of methylene blue (MB) and malachite green (MG) dyes from the aqueous solution. C4PU was synthesized by reacting p-tert-butyl calix[4]arene with hexamethylene diisocyanate (HMDI) as the cross-linking agent. Different polymer ratios were synthesized, and C4PU-4 shows better adsorption than other ratios. The polymer was characterized by Fourier transform infrared spectroscopy (FTIR), thermogravimetric analysis (TGA), Brunauer-Emmett-Teller (BET) analysis, and point of zero charges (pHPZC). The isotherms and kinetics of the adsorption of MB and MG were studied under a range of experimental conditions, including pH, adsorbent dosage, initial dye concentration, and contact time. The adsorption was determined by the adsorption percentage of MB and MG dyes from the solution. The Langmuir isotherm model best describes the adsorption process for both dyes, and it follows a pseudo-second-order kinetic model, with the maximum adsorption capacity (qmax) of MB and MG, respectively, was found to be 1.991 mg·g-1 and 2.240 mg·g-1.
Plankton seasonality in tropical coastal waters is becoming more apparent as a result of monsoon-driven changes in environmental conditions, but research on the monsoonal variation of microplastics (MP) is still limited. We examined the monsoonal variation of MP in the water column and their ingestion by zooplankton in Sepanggar Bay, Sabah, Malaysia. MP concentrations were significantly higher during the Southwest monsoon whereas MP ingestions showed no monsoonal difference across major zooplankton taxa. Canonical Correspondence Analysis (CCA) and Generalized Additive Models (GAM) indicate that MP concentrations were driven by changes in rainfall and salinity while MP bioavailability to zooplankton was consistent regardless of monsoon. MP ingestion increased progressively up the planktonic food chain, and bioavailability of fibers and small-sized MP of high-density polymers to zooplankton was proportionately higher. Distinct changes in the MP concentration relative to the monsoons provide new insights into the seasonal variation of MP in tropical coastal ecosystems.
Understanding the main driving factors of oasis river nutrients in arid areas is important to identify the sources of water pollution and protect water resources. Twenty-seven sub-watersheds were selected in the lower oasis irrigated agricultural reaches of the Kaidu River watershed in arid Northwest China, divided into the site, riparian, and catchment buffer zones. Data on four sets of explanatory variables (topographic, soil, meteorological elements, and land use types) were collected. The relationships between explanatory variables and response variables (total phosphorus, TP and total nitrogen, TN) were analyzed by redundancy analysis (RDA). Partial least squares structural equation modeling (PLS-SEM) was used to quantify the relationship between explanatory as well as response variables and fit the path relationship among factors. The results showed that there were significant differences in the TP and TN concentrations at each sampling point. The catchment buffer exhibited the best explanatory power of the relationship between explanatory and response variables based on PLS-SEM. The effects of various land use types, meteorological elements (ME), soil, and topography in the catchment buffer were responsible for 54.3% of TP changes and for 68.5% of TN changes. Land use types, ME and soil were the main factors driving TP and TN changes, accounting for 95.56% and 94.84% of the total effects, respectively. The study provides a reference for river nutrients management in arid oases with irrigated agriculture and a scientific and targeted basis to mitigate water pollution and eutrophication of rivers in arid lands.