MyMedR

Displaying publications 81 - 100 of 490 in total

Abstract:

Sort:

Coalescence-Induced Droplet Jumping

Liu C, Zhao M, Zheng Y, Cheng L, Zhang J, Tee CATH

Langmuir, 2021 Jan 26;37(3):983-1000.
PMID: 33443436 DOI: 10.1021/acs.langmuir.0c02758

When two or more droplets coalesce on a superhydrophobic surface, the merged droplet can jump spontaneously from the surface without requiring any external energy. This phenomenon is defined as coalescence-induced droplet jumping and has received significant attention due to its potential applications in a variety of self-cleaning, anti-icing, antifrosting, and condensation heat-transfer enhancement uses. This article reviews the research and applications of coalescence-induced droplet jumping behavior in recent years, including the influence of droplet parameters on coalescence-induced droplet jumping, such as the droplet size, number, and initial velocity, to name a few. The main structure types and influence mechanism of the superhydrophobic substrates for coalescence-induced droplet jumping are described, and the potential application areas of coalescence-induced droplet jumping are summarized and forecasted.

Matched MeSH terms: Physical Phenomena
Fulltext Coherently Tunable Triangular Trefoil Phaseonium Metamaterial

Nguyen DM, Soci C, Ooi CH

Sci Rep, 2016;6:21083.
PMID: 26879520 DOI: 10.1038/srep21083

Phaseonium is a three-level Λ quantum system, in which a coherent microwave and an optical control (pump) beams can be used to actively modulate the dielectric response. Here we propose a new metamaterial structure comprising of a periodic array of triangular phaseonium metamolecules arranged as a trefoil. We present a computational study of the spatial distribution of magnetic and electric fields of the probe light and the corresponding transmission and reflection, for various parameters of the optical and microwave beams. For specific values of the probing frequencies and control fields, the phaseonium can display either metallic or dielectric optical response. We find that, in the metallic regime, the phaseonium metamaterial structure supports extremely large transmission, with optical amplification at large enough intensity of the microwave thanks to strong surface plasmon coupling; while, in the dielectric regime without microwave excitation, the transmission bandwidth can be tuned by varying the control beam intensity. Implementation of such phaseonium metamaterial structure in solid-state systems, such as patterned crystals doped with rare-earth elements or dielectric matrices embedded with quantum dots, could enable a new class of actively tunable quantum metamaterials.

Matched MeSH terms: Physical Phenomena
Combined similarity-numerical solutions of MHD boundary layer slip flow of non-Newtonian power-law nanofluids over a radiating moving plate

Nur Husna Md. Yusoff, Md. Jashim Uddin, Ahmad Izani Md. Ismail

Sains Malaysiana, 2014;43:151-159.

A combined similarity-numerical solution of the magnetohydrodynamic boundary layer slip flow of an electrically conducting non-Newtonian power-law nanofluid along a heated radiating moving vertical plate is explored. Our nanofluid model incorporates the influences of the thermophoresis and the Brownian motion. The basic transport equations are made dimensionless first and then suitable similarity transformations are applied to reduce them into a set of nonlinear ordinary differential equations with the associated boundary conditions. The reduced equations are then solved numerically. Graphical results for the non-dimensional flow velocity, the temperature and the nanoparticles volume fraction profiles as well as for the friction factor, the local Nusselt and the Sherwood numbers are exhibited and examined for various values of the controlling parameters to display the interesting aspects of the solutions. It was found that the friction factor increases with the increase of the magnetic field (M), whilst it is decreased with the linear momentum slip parameter (a). The linear momentum slip parameter (a) reduces the heat transfer rates and the nanoparticles volume fraction rates. Our results are compatible with the existing results for a special case.

Matched MeSH terms: Physical Phenomena
Comment on "removal of hexavalent chromium by biochar supported nZVI composite: Batch and fixed-bed column evaluations, mechanisms, and secondary contamination prevention"

Tran HN, Pham VV, Vo DN, Nguyen-Tri P

Chemosphere, 2019 Oct;233:988-990.
PMID: 30853115 DOI: 10.1016/j.chemosphere.2019.02.084

This article aims to discuss (1) the incorrect identification of Cr(III) and Cr(VI) binding energies in the Cr 2p XPS (X-ray photoelectron spectroscopy) spectra of the laden adsorbent (the nZVI-BC sample after Cr(VI) adsorption), (2) misconception regarding the Weber-Morris intraparticle diffusion model, and (3) inconsistency between the experiential data and the Thomas adsorption rate constants. The authors hope that our comments are beneficial for other researchers to avoid the undesirable mistakes.

Matched MeSH terms: Physical Phenomena; Biophysical Phenomena
Fulltext Comparative Study of Different Drills for Bone Drilling: A Systematic Approach

Pazarci O, Torun Y, Ozturk A, Oztemur Z

Malays Orthop J, 2020 Jul;14(2):83-89.
PMID: 32983381 DOI: 10.5704/MOJ.2007.016

Introduction: The performance of the drilling process depends on the characteristics of the drilling equipment and surgeon's skill. To our knowledge, no research has focused on multi-parameter analysis of the dynamic behaviour of drills during the drilling process. This study aimed to characterise the physical changes and effects of different drills attached to a robotic arm during drilling of artificial bones in a standardised experimental setup.
Material and Methods: Drilling processes using three brands of drills attached to a robotic arm were compared in terms of thrust force, vibration, noise level, speed deviation, and temperature. A standardised experimental setup was constructed, and measurement data were analysed statistically. Identical artificial bones were drilled 10 times with each drill.
Results: Thrust force measurements, which varied through the cortex and medulla, showed expressive differences for each drill for maximum and mean values (p<0.001). Meaningful differences were obtained for mean vibration values and noise level (p<0.001). Speed variation measurements in drilling showed conspicuous differences with confident statistics (p<0.001). Induced temperature values were measured statistically for Drill 1, Drill 2, and Drill 3 as 78.38±11.49°C, 78.11±7.79°C, and 89.77±7.79°C, respectively.
Conclusion: Thrust force and drill bit temperature were strongly correlated for each drill. Vibration values and noise level, which also had an influential relationship, were in the acceptable range for all experiments. Both thrust force and speed deviation information could be used to detect the drill bit status in the bone while drilling.

Matched MeSH terms: Physical Phenomena
Comparative analysis of load responses and deformation for crust composite foundation and pile-supported embankment

Ying Wang, Yonghui Chen, Zhenhua Hu, Qiang Feng, Desen Kong

Sains Malaysiana, 2017;46:2231-2239.

Ground improvement using artificial crust composite foundation, consisting of stabilization of soft clay and composite foundation, is an effective technique for the treatment of deep soft soil layers under infrastructure embankments. In this study, the load responses and settlement performance of this improvement technique were investigated using two centrifuge model tests to compare the variations of the vertical deformation, pore water pressure, axial force of the piles and tensile stress at the bottom of the artificial crust in the crust composite foundation with those in pile-supported embankment. The results of centrifuge model tests showed that the load responses and settlement performance of artificial crust composite foundation was different from the pile-supported embankment, which displayed mainly that the final middle settlement of crust composite foundation can be reduced by about 15% compared with those of pile-supported embankment with the same length of pile and construction cost. The deformation of the crust with the characteristics of the plate was found based on the change of the tensile stress. Additionally, the excess pore water pressure in the crust composite foundation was lower owing to the stress diffusion effect of the crust during the loading period and the dissipation rate of excess pore water pressure was slower due to lower permeability of the crust at the same loading period. Eventually, the axial force of the middle piles was reduced. At the same time, the boundary stress was functioned with the crust, the axial force of the side piles was improved. The comparison of measured and calculated results was carried out using the stress reduction ratio, the result shows that the bearing capacity of the subsoil in the crust composite was improved.

Matched MeSH terms: Physical Phenomena
Comparison analysis on scaling the vertical and lateral NMOSFET in nanometer regime

Ismail Saad, Razali Ismail, Ima Sulaiman

Sains Malaysiana, 2008;37:233-237.

Conventional lateral and vertical n-channel MOS transistors with channel length in the range of 100nm to 50nm have been systematically investigated by means of device simulation. The comparison analysis includes critical parameters that govern device performance. Threshold voltage VT roll-off, leakage current Ioff, drain saturation current IDsat and sub-threshold swing S were analyze and compared between the device. Due to double gate (DG) structure over the side of silicon pillar a better electrostatics potential control of channel is obtained in vertical device shown by an analysis on VT roll-off. A two decade higher of Ioff in planar device is observed with Lg=50nm. A factor of three times larger IDsat is observed for vertical MOSFETs compared to planar device. The sub-threshold swing S remains almost the same when the Lg larger than 80 nm. It increased rapidly when the Lg is scaled down to 50 nm due to the short channel effect SCE. However, the vertical device has a steady increase whereas the planar device has suffered immediate enhance of SCE. The analysis results confirmed that vertical MOSFET with double-gate structure is a potential solution to overcome SCE when scaled the channel length to 50nm and beyond.

Matched MeSH terms: Physical Phenomena
Comparison between Nucleate Pool Boiling Heat Transfer of Graphene Nanoplatelet- and Carbon Nanotube- Based Aqueous Nanofluids

Akbari A, Mohammadian E, Alavi Fazel SA, Shanbedi M, Bahreini M, Heidari M, et al.

ACS Omega, 2019 Nov 19;4(21):19183-19192.
PMID: 31763542 DOI: 10.1021/acsomega.9b02474

An increase of nucleate pool boiling with the use of different fluid properties has received much attention. In particular, the presence of nanostructures in fluids to enhance boiling was given special consideration. This study compares the effects of graphene nanoplatelet (GNP), functionalized GNP with polyethylene glycol (PEG), and multiwalled carbon nanotube (CNT) nanofluids on the pool boiling heat transfer coefficient and the critical heat flux (CHF). Our findings showed that at the same concentration, CHF for functionalized GNP with PEG (GNP-PEG)/deionized water (DW) nanofluids was higher in comparison with GNP- and CNT-based nanofluids. The CHF of the GNP/DW nanofluids was also higher than that of CNT/DW nanofluids. The CHF of GNP-PEG was 72% greater than that of DW at the concentration of 0.1 wt %. There is good agreement between measured critical heat fluxes and the Kandlikar correlation. In addition, the current results proved that the GNP-PEG/DW nanofluids are highly stable over 3 months at a concentration of 0.1 wt %.

Matched MeSH terms: Physical Phenomena
Fulltext Comparison of Hook and Straight Steel Fibers Addition on Malaysian Fly Ash-Based Geopolymer Concrete on the Slump, Density, Water Absorption and Mechanical Properties

Faris MA, Abdullah MMAB, Muniandy R, Abu Hashim MF, Błoch K, Jeż B, et al.

Materials (Basel), 2021 Mar 09;14(5).
PMID: 33803313 DOI: 10.3390/ma14051310

Geopolymer concrete has the potential to replace ordinary Portland cement which can reduce carbon dioxide emission to the environment. The addition of different amounts of steel fibers, as well as different types of end-shape fibers, could alter the performance of geopolymer concrete. The source of aluminosilicate (fly ash) used in the production of geopolymer concrete may lead to a different result. This study focuses on the comparison between Malaysian fly ash geopolymer concrete with the addition of hooked steel fibers and geopolymer concrete with the addition of straight-end steel fibers to the physical and mechanical properties. Malaysian fly ash was first characterized by X-ray fluorescence (XRF) to identify the chemical composition. The sample of steel fiber reinforced geopolymer concrete was produced by mixing fly ash, alkali activators, aggregates, and specific amounts of hook or straight steel fibers. The steel fibers addition for both types of fibers are 0%, 0.5%, 1.0%, 1.5%, and 2.0% by volume percentage. The samples were cured at room temperature. The physical properties (slump, density, and water absorption) of reinforced geopolymer concrete were studied. Meanwhile, a mechanical performance which is compressive, as well as the flexural strength was studied. The results show that the pattern in physical properties of geopolymer concrete for both types of fibers addition is almost similar where the slump is decreased with density and water absorption is increased with the increasing amount of fibers addition. However, the addition of hook steel fiber to the geopolymer concrete produced a lower slump than the addition of straight steel fibers. Meanwhile, the addition of hook steel fiber to the geopolymer concrete shows a higher density and water absorption compared to the sample with the addition of straight steel fibers. However, the difference is not significant. Besides, samples with the addition of hook steel fibers give better performance for compressive and flexural strength compared to the samples with the addition of straight steel fibers where the highest is at 1.0% of fibers addition.

Matched MeSH terms: Physical Phenomena
Fulltext Complex Permittivity and Electromagnetic Interference Shielding Effectiveness of OPEFB Fiber-Polylactic Acid Filled with Reduced Graphene Oxide

Ibrahim Lakin I, Abbas Z, Azis RS, Abubakar Alhaji I

Materials (Basel), 2020 Oct 16;13(20).
PMID: 33081082 DOI: 10.3390/ma13204602

This study was aimed at fabricating composites of polylactic acid (PLA) matrix-reinforced oil palm empty fruit bunch (OPEFB) fiber filled with chemically reduced graphene oxide (rGO). A total of 2-8 wt.% rGO/OPEFB/PLA composites were characterized for their complex permittivity using an open-ended coaxial probe (OEC) technique. The shielding efficiency properties were calculated using the measured transmission (S21) and the reflection (S11) coefficient results. All the measurements and calculations were performed in the 8-12 GHz frequency range. The morphological and microstructural study included X-ray diffraction (XRD), field emission scanning electron microscopy (FE-SEM), and Fourier transform infrared spectroscopy (FTIR). The results indicated that the incorporation of rGO as filler into the composites enhanced their complex permittivity properties. The composites showed a total shielding efficiency (SET) of about 31.2 dB at a frequency range of 8-12 GHz, which suggests their usefulness for microwave absorption.

Matched MeSH terms: Physical Phenomena
Fulltext Complex Permittivity and Microwave Absorption Properties of OPEFB Fiber-Polycaprolactone Composites Filled with Recycled Hematite (α-Fe2O3) Nanoparticles

Mensah EE, Abbas Z, Azis RS, Ibrahim NA, Khamis AM

Polymers (Basel), 2019 May 24;11(5).
PMID: 31137695 DOI: 10.3390/polym11050918

Recycled hematite (α-Fe2O3) nanoparticles with enhanced complex permittivity properties have been incorporated as a filler in a polycaprolactone (PCL) matrix reinforced with oil palm empty fruit bunch (OPEFB) fiber for microwave absorption applications. The complex permittivity values were improved by reducing the particle sizes to the nano scale via high-energy ball milling for 12 h. A total of 5-20 wt.% recycled α-Fe2O3/OPEFB/PCL nanocomposites were examined for their complex permittivity and microwave absorption properties via the open ended coaxial (OEC) technique and the transmission/reflection line measurement using a microstrip connected to a two-port vector network analyzer. The microstructural analysis of the samples included X-ray diffraction (XRD), high-resolution transmission electron microscopy (HRTEM) and Fourier transform infrared spectroscopy (FTIR). At 1 GHz, the real (ε') and imaginary (ε″) parts of complex permittivity of recycled α-Fe2O3 particles, respectively, increased from 7.88 to 12.75 and 0.14 to 0.40 when the particle size was reduced from 1.73 μm to 16.2 nm. A minimum reflection loss of -24.2 dB was achieved by the 20 wt.% nanocomposite at 2.4 GHz. Recycled α-Fe2O3 nanoparticles are effective fillers for microwave absorbing polymer-based composites in 1-4 GHz range applications.

Matched MeSH terms: Physical Phenomena
Fulltext Computational analysis of fluid flow past a bluff body at low Reynolds number in different apex angle

Jusoh, M.Z.M., Nur Ain, A.R, Muhammad Wafi Md Nor

ESTEEM Academic Journal, 2020;16(2):65-74.
MyJurnal

A computational fluid dynamic analysis (CFD) is presented in the study of low Reynolds number fluid flow moving past bluff bodies. The study is focusing on the understanding of the effects of the apex-angles orientation on the flow structure and related occurring force. The apex-angle both facing upstream and downstream were computationally investigated. The simulation results of the cylinder solid are compared with available experimental data to justify the results and the model used. Results obtained in the present work were Strouhal number, drag coefficient, and Fast Fourier Transform (FFT). The study had found that the value of the drag force is increasing directly proportional to the apex angle. In contrast, the value of Strouhal number inversely proportional to the increasing of the apex angle. This was due to the flow over a cylinder creating a vortex shedding in the wake region which influenced the flow separation of fluid. Through the changing on orientation of the apex angle, it was also found that the characteristic linear dimension of the geometry will also be changed, thus affecting the flow pattern.

Matched MeSH terms: Physical Phenomena
Fulltext Computational and Experimental Approaches for Determining Scattering Parameters of OPEFB/PLA Composites to Calculate the Absorption and Attenuation Values at Microwave Frequencies

Fahad Ahmad A, Aziz SHA, Abbas Z, Mohammad Abdalhadi D, Khamis AM, Aliyu US

Polymers (Basel), 2020 Aug 26;12(9).
PMID: 32858790 DOI: 10.3390/polym12091919

This article describes attenuation and absorption measurements using the microstrip transmission line technique connected with a microwave vector network analyzer (Agilent 8750B). The magnitudes of the reflection (S11) and transmission (S21) coefficients obtained from the microstrip transmission line were used to determine the attenuation and absorption of oil palm empty fruit bunch/polylactic acid (OPEFB/PLA) composites in a frequency range between 0.20 GHz and 12 GHz at room temperature. The main structure of semi-flexible substrates (OPEFF/PLA) was fabricated using different fiber loading content extracted from oil palm empty fruit bunch (OPEFB) trees hosted in polylactic acid (PLA) using the Brabender blending machine, which ensured mixture homogeneity. The commercial software package, Computer Simulation Technology Microwave Studio (CSTMWS), was used to investigate the microstrip line technique performance by simulating and determine the S11 and S21 for microwave substrate materials. Results showed that the materials' transmission, reflection, attenuation, and absorption properties could be controlled by changing the percentage of OPEFB filler in the composites. The highest absorption loss was calculated for the highest percentage of filler (70%) OPEFB at 12 GHz to be 0.763 dB, while the lowest absorption loss was calculated for the lowest percentage of filler 30% OPEFB at 12 GHz to be 0.407 dB. Finally, the simulated and measured results were in excellent agreement, but the environmental conditions slightly altered the results. From the results it is observed that the value of the dielectric constant (εr') and loss factor (εr″) is higher for the OPEFB/PLA composites with a higher content of OPEFB filler. The dielectric constant increased from 2.746 dB to 3.486 dB, while the loss factor increased from 0.090 dB to 0.5941 dB at the highest percentage of 70% OPEFB filler. The dielectric properties obtained from the open-ended coaxial probe were required as input to FEM to calculate the S11 and S21 of the samples.

Matched MeSH terms: Physical Phenomena
Fulltext Concentrated Solar thermal thermoelectric power generation under natural and forced convection cooling

Dee, S., Singh, B., Remeli, M.F., Tan, L., Oberoi, A.

Pertanika Journal of Science & Technology, 2017;25(107):123-132.
MyJurnal

This paper looks at electrical power generation from solar concentrator using thermoelectric generator. An experiment was conducted on a concentrator thermoelectric generator (CTEG) utilising solar thermal energy. The CTEG used a parabolic dish as concentrator with thermoelectric device installed at the focal point to convert thermal energy to generate electricity. The investigation covered the cooling effect of the cold side of the thermoelectric generator using natural and forced convection cooling for optimum output. Forced convection cooling with a fan provided 69% more power output from the CTEG system as the temperature difference across the TEG was greater than the system cooled by natural convection. The outcome of this project showed maximum power output was obtained for the CTEG system cooled by forced convection cooling.

Matched MeSH terms: Physical Phenomena
Constraining Gluon Distributions in Nuclei Using Dijets in Proton-Proton and Proton-Lead Collisions at sqrt[s_{NN}]=5.02 TeV

Sirunyan AM, Tumasyan A, Adam W, Ambrogi F, Asilar E, Bergauer T, et al.

Phys Rev Lett, 2018 Aug 10;121(6):062002.
PMID: 30141647 DOI: 10.1103/PhysRevLett.121.062002

The pseudorapidity distributions of dijets as functions of their average transverse momentum (p_{T}^{ave}) are measured in proton-lead (pPb) and proton-proton (pp) collisions. The data samples were collected by the CMS experiment at the CERN LHC, at a nucleon-nucleon center-of-mass energy of 5.02 TeV. A significant modification of the pPb spectra with respect to the pp spectra is observed in all p_{T}^{ave} intervals investigated. The ratios of the pPb and pp distributions are compared to next-to-leading order perturbative quantum chromodynamics calculations with unbound nucleon and nuclear parton distribution functions (PDFs). These results give the first evidence that the gluon PDF at large Bjorken x in lead ions is strongly suppressed with respect to the PDF in unbound nucleons.

Matched MeSH terms: Physical Phenomena
Fulltext Copper Nanowires as Highly Efficient and Recyclable Catalyst for Rapid Hydrogen Generation from Hydrolysis of Sodium Borohydride

Hashimi AS, Nohan MANM, Chin SX, Khiew PS, Zakaria S, Chia CH

Nanomaterials (Basel), 2020 Jun 12;10(6).
PMID: 32545513 DOI: 10.3390/nano10061153

: Hydrogen (H2) is a clean energy carrier which can help to solve environmental issues with the depletion of fossil fuels. Sodium borohydride (NaBH4) is a promising candidate material for solid state hydrogen storage due to its huge hydrogen storage capacity and nontoxicity. However, the hydrolysis of NaBH4 usually requires expensive noble metal catalysts for a high H2 generation rate (HGR). Here, we synthesized high-aspect ratio copper nanowires (CuNWs) using a hydrothermal method and used them as the catalyst for the hydrolysis of NaBH4 to produce H2. The catalytic H2 generation demonstrated that 0.1 ng of CuNWs could achieve the highest volume of H2 gas in 240 min. The as-prepared CuNWs exhibited remarkable catalytic performance: the HGR of this study (2.7 × 1010 mL min-1 g-1) is ~3.27 × 107 times higher than a previous study on a Cu-based catalyst. Furthermore, a low activation energy (Ea) of 42.48 kJ mol-1 was calculated. Next, the retreated CuNWs showed an outstanding and stable performance for five consecutive cycles. Moreover, consistent catalytic activity was observed when the same CuNWs strip was used for four consecutive weeks. Based on the results obtained, we have shown that CuNWs can be a plausible candidate for the replacement of a costly catalyst for H2 generation.

Matched MeSH terms: Physical Phenomena
Fulltext Corn Starch (Zea mays) Biopolymer Plastic Reaction in Combination with Sorbitol and Glycerol

Hazrol MD, Sapuan SM, Zainudin ES, Zuhri MYM, Abdul Wahab NI

Polymers (Basel), 2021 Jan 12;13(2).
PMID: 33445740 DOI: 10.3390/polym13020242

The research included corn starch (CS) films using sorbitol (S), glycerol (G), and their combination (SG) as plasticizers at 30, 45, and 60 wt %, with a traditional solution casting technique. The introduction of plasticizer to CS film-forming solutions led to solving the fragility and brittleness of CS films. The increased concentration of plasticizers contributed to an improvement in film thickness, weight, and humidity. Conversely, plasticized films reduced their density and water absorption, with increasing plasticizer concentrations. The increase in the amount of the plasticizer from 30 to 60% showed a lower impact on the moisture content and water absorption of S-plasticized films. The S30-plasticized films also showed outstanding mechanical properties with 13.62 MPa and 495.97 MPa, for tensile stress and tensile modulus, respectively. Glycerol and-sorbitol/glycerol plasticizer (G and SG) films showed higher moisture content and water absorption relative to S-plasticized films. This study has shown that the amount and type of plasticizers significantly affect the appearances, physical, morphological, and mechanical properties of the corn starch biopolymer plastic.

Matched MeSH terms: Physical Phenomena
Fulltext Cornstarch-based biopolymer electrolyte doped with Na3PO4

Syakirah Shahrudin, Azizah Hanom Ahmad

Science Letter, 2016;10(2):26-30.
MyJurnal

In this work, polymer electrolytes have been prepared by doping starch with Sodium Phosphate (Na3PO4). The incorporation of 25% Na3PO4 optimizes the room temperature conductivity of the electrolyte at 7.27 x 10-6 Scm-1. The temperature dependence of conductivity for the electrolyte is Arrhenius and the activation energy, Ea, of 75% corn starch-25% Na3PO4 electrolyte is 0.26eV. The dielectric studies reveal the non-Debye nature of the electrolyte. The complexation of Na3PO4 with the polymer host was studied using Fourier transform infrared (FTIR) spectroscopy.

Matched MeSH terms: Physical Phenomena
Fulltext Correlated transitions in TKE and mass distributions of fission fragments described by 4-D Langevin equation

Usang MD, Ivanyuk FA, Ishizuka C, Chiba S

Sci Rep, 2019 Feb 06;9(1):1525.
PMID: 30728435 DOI: 10.1038/s41598-018-37993-7

We have decomposed to symmetric and asymmetric modes the mass-TKE fission fragment distributions calculated by 4-dimensional Langevin approach and observed how the dominant fission mode and symmetric mode change as functions of [Formula: see text] of the fissioning system in the actinides and trans-actinide region. As a result, we found that the symmetric mode makes a sudden transition from super-long to super short fission mode around 254Es. The dominant fission modes on the other hand, are persistently asymmetric except for 258Fm, 259Fm and 260Md when the dominant fission mode suddenly becomes symmetric although it returns to the asymmetric mode around 256No. These correlated "twin transitions" have been known empirically by Darleane Hoffman and her group back in 1989, but for the first time we have given a clear explanation in terms of a dynamical model of nuclear fission. More specifically, since we kept the shape model parameters unchanged over the entire mass region, we conclude that the correlated twin transition emerge naturally from the dynamics in 4-D potential energy surface.

Matched MeSH terms: Physical Phenomena
Fulltext Crystal structure of 2'-hy-droxy-aceto-phenone 4-methyl-thio-semicarbazide

Jamsari J, Abas NF, Ravoof TB, Tiekink ER

Acta Crystallogr E Crystallogr Commun, 2015 Apr 1;71(Pt 4):o244-5.
PMID: 26029436 DOI: 10.1107/S2056989015004958

In the organic mol-ecule of the title hydrate, C11H15N3OS·H2O, {systematic name: 3-ethyl-1-{(E)-[1-(2-hy-droxy-phen-yl)ethyl-idene]amino}-thio-urea monohydrate}, a dihedral angle of 5.39 (2)° is formed between the hy-droxy-benzene ring and the non-H atoms comprising the side chain (r.m.s. deviation = 0.0625 Å), with the major deviation from planarity noted for the terminal ethyl group [the C-N-C-C torsion angle = -172.17 (13)°]. The N-H H atoms are syn and an intra-molecular hy-droxy-imine O-H⋯N hydrogen bond is noted. In the crystal, the N-bonded H atoms form hydrogen bonds to symmetry-related water mol-ecules, and the latter form donor inter-actions with the hy-droxy O atom and with a hy-droxy-benzene ring, forming a O-H⋯π inter-action. The hydrogen bonding leads to supra-molecular tubes aligned along the b axis. The tubes are connected into layers via C-H⋯O inter-actions, and these stack along the c axis with no directional inter-actions between them.

Matched MeSH terms: Physical Phenomena

Filters

Please provide feedback to Administrator (afdal@afpm.org.my)

External Links