Mining activities in the Chini Lake catchment area have been extensive for several years, contributing to acid mine drainage (AMD) events with high concentrations of iron (Fe) and other heavy metals impacting the surface water. However, during the restriction period due to the COVID-19 outbreak, anthropogenic activities have been suspended, which clearly shows a good opportunity for a better environment. Therefore, we aimed to analyze the variation of AMD-associated water pollution in three main zones of the Chini Lake catchment area using Sentinel-2 data for the periods pre-movement control order (MCO), during MCO, and post-MCO from 2019 to 2021. These three zones were chosen due to their proximity to mining areas: zone 1 in the northeastern part, zone 2 in the southeastern part, and zone 3 in the southern part of the Chini Lake area. The acid mine water index (AMWI) was a specific index used to estimate acid mine water. The AMWI values from Sentinel-2 images exhibited that the mean AMWI values in all zones during the MCO period decreased by 14% compared with the pre-MCO period. The spatiotemporal analysis found that the highest polluted zones were recorded in zone 1, followed by zone 3 and zone 2. As compared with during the MCO period, the maximum percentage of increment during post-MCO in all zones was up to 25%. The loosened restriction policy has resulted in more AMD flowing into surface water and increased pollution in Chini Lake. As a whole, our outputs revealed that Sentinel-2 data had a major potential for assessing the AMD-associated pollution of water.
Matched MeSH terms: Water/analysis; Water Pollution/analysis
The subject of water contamination and how it gets defiled to the society and humans is confabulating from the past decades. Phenolic compounds widely exist in the water sources and it is emergent to determine the toxicity in natural and drinking water, because it is hazardous to the humans. Among these compounds, catechol has sought a strong concern because of its rapid occurrence in nature and its potential toxicity to humans. The present work aims to develop an effective electrochemical sensing of catechol using mesoporous structure of Fe3O4-TiO2 decorated on glassy carbon (GC) electrode. The creation of pure TiO2 using the sol-gel technique was the first step in the synthesis protocol for binary nanocomposite, which was then followed by the loading of Fe3O4 nanoparticles on the surface of TiO2 using the thermal decomposition method. The resultant Fe3O4-TiO2 based nanocomposite exhibited mesoporous structure and the cavities were occupied with highly active magnetite nanoparticles (Fe3O4) with high specific surface area (90.63 m2/g). When compared to pure TiO2, catechol showed a more prominent electrochemical response for Fe3O4-TiO2, with a significant increase in anodic peak current at a lower oxidation potential (0.387 V) with a detection limit of 45 μM. Therefore, the prepared magnetite binary nanocomposite can serve as an efficient electroactive material for sensing of catechol, which could also act as a promising electrocatalyst for various electrocatalytic applications.
The utilization of natural zeolite (NZ) as an adsorbent for NH4+ removal was investigated. Three types of NZ (i.e., NZ01, NZ02, and NZ03) were characterized, and their NH4+ adsorption process in aqueous solution was evaluated. The effect of pH towards NH4+ adsorption showed that the NZ01 has the highest NH4+ adsorption capacity compared with other natural zeolites used. The application of NZ01 for a simultaneous removal of NH4+ and turbidity in synthetic NH4+-kaolin suspension by adsorptive coagulation process for treating drinking water was studied. The addition of NZ01 into the system increased the NH4+ removal efficiency (ηNH4+) from 11.64% without NZ01 to 41.86% with the addition of 0.2 g L-1 of NZ01. The turbidity removal (ηT), however, was insignificantly affected since the ηT was already higher than 98.0% over all studied parameter's ranges. The thermodynamic and kinetic data analyses suggested that the removal of NH4+ obeyed the Temkin isotherm model and pseudo-second-order kinetic model, respectively. Generally, the turbidity removal was due to the flocculation of destabilized solid particles by alum in the suspension system. The ηNH4+ in surface water was 29.31%, which is lower compared with the removal in the synthetic NH4+-kaolin suspension, but a high ηT (98.65%) was observed. It was found that the addition of the NZ01 could enhance the removal of NH4+ as well as other pollutants in the surface water.
Matched MeSH terms: Water Pollutants, Chemical*; Water Purification*
Several parts of the world have been facing the problem of nitrite and nitrate contamination in ground and surface water. The acute toxicity of nitrite has been shown to be 10-fold higher than that of nitrate. In the present study, aminated silica carbon nanotube (ASCNT) was synthesised and tested for nitrite removal. The synergistic effects rendered by both amine and silica in ASCNT have significantly improved the nitrite removal efficiency. The IEP increased from 2.91 for pristine carbon nanotube (CNT) to 8.15 for ASCNT, and the surface area also increased from 178.86 to 548.21 m2 g-1. These properties have promoted ASCNT a novel adsorbent to remove nitrite. At optimum conditions of 700 ppm of nitrite concentration at pH 7 and 5 h of contact with 15 mg of adsorbent, the ASCNT achieved the maximal loading capacity of 396 mg/g (85% nitrite removal). The removal data of nitrite onto ASCNT fitted the Langmuir isotherm model better than the Freundlich isotherm model with the highest regression value of 0.98415, and also, the nonlinear analysis of kinetics data showed that the removal of nitrite followed pseudo-second-order kinetic. The positive values of both ΔS° and ΔH° suggested an endothermic reaction and an increase in randomness at the solid-liquid interface. The negative ΔG° values indicated a spontaneous adsorption process. The ASCNT was characterised using FESEM-EDX and FTIR, and the results obtained confirmed the removal of nitrite. Based on the findings, ASCNT can be considered as a novel and promising candidate for the removal of nitrite ions from wastewater.
Matched MeSH terms: Water/chemistry; Water Pollutants, Chemical/analysis; Water Pollutants, Chemical/chemistry*; Water Purification/methods; Waste Water/analysis
The utilization of phthalates and bisphenol A (BPA) as the major component in plastic and its derivative industry has raised concerns among the public due to the harmful effects caused by these organic pollutants. These pollutants are found to exhibit unique physicochemical properties that allow the pollutants to have prolonged existence in the environment, thus causing damage to the environment. Since phthalates and bisphenol A are used in a variety of industrial applications, the industry must recover these compounds from its water before releasing the pollutants into the environment. As a result, these materials have a promising future in industrial applications. Therefore, the discovery of new quick and reliable abatement technologies is important to ensure that these organic pollutants can be detected and removed from the water sources. This review highlights the use of the adsorption method to remove phthalates and BPA from water sources by employing novel modified adsorbent magnetite functionalized covalent organic frameworks (MCOFs). MCOFs is a new class of porous materials that have demonstrated promising features in a variety of applications due to their adaptable structures, significant surface areas, configurable porosity, and customizable chemistry. The structural attributes, functional design strategies, and specialized for environmental applications before offering some closing thoughts and suggestions for further research were discussed in this paper in addition to developing an innovative solution for the industry to the accessibility for clean water.
Simulation of fluidized bed reactor (FBR) was accomplished for treating wastewater using Fenton reaction, which is an advanced oxidation process (AOP). The simulation was performed to determine characteristics of FBR performance, concentration profile of the contaminants, and various prominent hydrodynamic properties (e.g., Reynolds number, velocity, and pressure) in the reactor. Simulation was implemented for 2.8 L working volume using hydrodynamic correlations, continuous equation, and simplified kinetic information for phenols degradation as a model. The simulation shows that, by using Fe(3+) and Fe(2+) mixtures as catalyst, TOC degradation up to 45% was achieved for contaminant range of 40-90 mg/L within 60 min. The concentration profiles and hydrodynamic characteristics were also generated. A subsequent scale-up study was also conducted using similitude method. The analysis shows that up to 10 L working volume, the models developed are applicable. The study proves that, using appropriate modeling and simulation, data can be predicted for designing and operating FBR for wastewater treatment.
Matched MeSH terms: Water Pollutants, Chemical/isolation & purification; Water Pollutants, Chemical/chemistry*; Water Purification/instrumentation; Water Purification/methods*; Waste Water/chemistry*
Water level forecasting is an essential topic in water management affecting reservoir operations and decision making. Recently, modern methods utilizing artificial intelligence, fuzzy logic, and combinations of these techniques have been used in hydrological applications because of their considerable ability to map an input-output pattern without requiring prior knowledge of the criteria influencing the forecasting procedure. The artificial neurofuzzy interface system (ANFIS) is one of the most accurate models used in water resource management. Because the membership functions (MFs) possess the characteristics of smoothness and mathematical components, each set of input data is able to yield the best result using a certain type of MF in the ANFIS models. The objective of this study is to define the different ANFIS model by applying different types of MFs for each type of input to forecast the water level in two case studies, the Klang Gates Dam and Rantau Panjang station on the Johor river in Malaysia, to compare the traditional ANFIS model with the new introduced one in two different situations, reservoir and stream, showing the new approach outweigh rather than the traditional one in both case studies. This objective is accomplished by evaluating the model fitness and performance in daily forecasting.
Uncontrolled stormwater runoff not only creates drainage problems and flash floods but also presents a considerable threat to water quality and the environment. These problems can, to a large extent, be reduced by a type of stormwater management approach employing permeable pavement systems (PPS) in urban, industrial and commercial areas, where frequent problems are caused by intense undrained stormwater. PPS could be an efficient solution for sustainable drainage systems, and control water security as well as renewable energy in certain cases. Considerable research has been conducted on the function of PPS and their improvement to ensure sustainable drainage systems and water quality. This paper presents a review of the use of permeable pavement for different purposes. The paper focuses on drainage systems and stormwater runoff quality from roads, driveways, rooftops and parking lots. PPS are very effective for stormwater management and water reuse. Moreover, geotextiles provide additional facilities to reduce the pollutants from infiltrate runoff into the ground, creating a suitable environment for the biodegradation process. Furthermore, recently, ground source heat pumps and PPS have been found to be an excellent combination for sustainable renewable energy. In addition, this study has identified several gaps in the present state of knowledge on PPS and indicates some research needs for future consideration.
Matched MeSH terms: Water Movements; Water Quality
The influence of reaction temperature (160-200°C), residence time (45-90min), and liquid-solid ratio (8-16v/w) on oil palm frond (OPF) pre-treated with hot compressed water (HCW) was evaluated using severity factors. Effect of the process parameters studied on pulps composition and digestibility were found to be complex. The results revealed that digestibility could not be predicted merely according to composition. Severity factor was correlated with compositional changes and digestibility with good R-squared values at varied liquid-solid ratios (8-16v/w), but not with overall glucose yield. HCW pretreatment significantly improved the overall glucose yield up to 83.72% with severity of 3.31 and liquid-solid ratio of 8.0 compared to untreated raw OPF which only recorded an overall glucose yield of 30.97%. HCW is therefore an effective method for pretreatment of OPF for glucose recovery.
Gadilam river basin has gained its importance due to the presence of Neyveli Lignite open cast mines and other industrial complexes. It is also due to extensive depressurization of Cuddalore aquifer, and bore wells for New Veeranam Scheme are constructed downstream of the basin. Geochemical indicators of groundwater were used to identify the chemical processes that control hydrogeochemistry. Chemical parameters of groundwater such as pH, electrical conductivity, total dissolved solids, sodium (Na(+)), potassium (K(+)), calcium (Ca(+)), magnesium (Mg(+)), bicarbonate (HCO(-)(3)), sulfate (SO(-)(4)), phosphate (PO(-)(4)), and silica (H(4)SiO(4)) were determined. Interpretation of hydrogeochemical data suggests that leaching of ions followed by weathering and anthropogenic impact controls the chemistry of the groundwater. Isotopic study reveals that recharge from meteoric source in sedimentary terrain and rock-water interaction with significant evaporation prevails in hard rock region.
Matched MeSH terms: Fresh Water/chemistry*; Water Movements; Water Pollutants, Chemical/analysis*; Water Pollutants, Chemical/chemistry; Water Pollution, Chemical/statistics & numerical data
The growths of oil and gas exploration and production activities have increased environmental problems, such as oil spillage and the resulting pollution. The study of the methods for cleaning up oil spills is a critical issue to protect the environment. Various techniques are available to contain oil spills, but they are typically time consuming, energy inefficient and create secondary pollution. The use of a sorbent, such as a nanofibre sorbent, is a technique for controlling oil spills because of its good physical and oil sorption properties. This review discusses about the application of nanofibre sorbent for oil removal from water and its current developments. With their unique physical and mechanical properties coupled with their very high surface area and small pore sizes, nanofibre sorbents are alternative materials for cleaning up oil spills.
Matched MeSH terms: Water; Water Pollutants, Chemical
The main aim of this study is to investigate the performance of organic oxidation and denitrification of the system under long-term operation. The MFC reactor was operated in continuous mode for 180 days. Nitrate was successfully demonstrated as terminal electron acceptor, where nitrate was reduced at the cathode using electron provided by acetate oxidation at the anode. The removal efficiencies of chemical oxygen demand (COD) and nitrate were higher in the closed circuit system than in open circuit system. Both COD and nitrate reduction improved with the increase of organic loading and subsequently contributed to higher power output. The maximum nitrate removal efficiency was 88 ± 4 % (influent of 141 ± 14 mg/L). The internal resistant was 50 Ω, which was found to be low for a double chambered MFC. The maximum power density was 669 mW/m(3) with current density of 3487 mA/m(3).
Matched MeSH terms: Water Purification; Waste Water
Three building complexes in Kuala Lumpur were surveyed for the presence of legionellae in cooling towers. The organisms were grown from 12 out of 46 samples of water collected from 30 towers. L. pneumophila serogroups 1 and 7 were the commonest serogroups isolated. None belonged to the Pontiac subgroup of L. pneumophila serogroup 1.
Biochar/layered double hydroxide (LDH) composites have gained considerable attention in recent times as low-cost sustainable materials for applications in water treatment. This paper critically evaluates the latest development in applications of biochar/LDH composites in water treatment with an emphasis on adsorption and catalytic degradation of various pollutants. The adsorption of various noxious contaminants, i.e., heavy metals, dyes, anions, and pharmaceuticals onto biochar/LDH composites are described in detail by elaborating the adsorption mechanism and regeneration ability. The synergistic effect of LDH with biochar exhibited significant improvement in specific surface area, surface functional groups, structure heterogeneity, stability, and adsorption characteristics of the resulting biochar/LDH composites. The major hurdles and challenges associated with the synthesis and applications of biochar/LDH composites in water remediation are emphasized. Finally, a roadmap is suggested for future research to assure the effective applications of biochar/LDH composites in water purification.
This paper elucidates the capability of isolated indigenous bacteria to remove aluminium from wastewater and soil. Two indigenous species of Brochothrix thermosphacta and Vibrio alginolyticus were isolated from an aluminium-contaminated site. These two species were used to treat aluminium-containing wastewater and contaminated soil using the bioaugmentation method. B. thermosphacta showed the highest aluminium removal of 57.87 ± 0.45% while V. alginolyticus can remove aluminium up to 59.72 ± 0.33% from wastewater. For aluminium-contaminated soil, B. thermosphacta and V. alginolyticus, showed a highest removal of only 4.58 ± 0.44% and 5.48 ± 0.58%, respectively. The bioaugmentation method is more suitable to be used to treat aluminium in wastewater compared to contaminated soil. The produced biomass separation after wastewater treatment was so much easier and applicable, compared to the produced biomass handling from contaminated soil treatment. A 48.55 ± 2.45% and 40.12 ± 4.55% of aluminium can be recovered from B. thermosphacta and V. alginolyticus biomass, respectively, with 100 mg/L initial aluminium concentration in wastewater.
Wide spread documentation of antibiotic pollution is becoming a threat to aquatic environment. Erythromycin (ERY), a macrolide belonging antibiotic is at the top of this list with its concentrations ranging between ng/L to a few μg/L in various global waterbodies giving rise to ERY-resistance genes (ERY-RGs) and ERY- resistance bacteria (ERY-RBs) posing serious threat to the aquatic organisms. ERY seems resistant to various conventional water treatments, remained intact and even increased in terms of mass loads after treatment. Enhanced oxidation potential, wide pH range, elevated selectivity, adaptability and greater efficiency makes advance oxidation processes (AOPs) top priority for degrading pollutants with aromatic rings and unsaturated bonds like ERY. In this manuscript, recent developments in AOPs for ERY degradation are reported along with the factors that affect the degradation mechanism. ERY, marked as a risk prioritized macrolide antibiotic by 2015 released European Union watch list, most probably due to its protein inhibition capability considered third most widely used antibiotic. The current review provides a complete ERY overview including the environmental entry sources, concentration in global waters, ERY status in STPs, as well as factors affecting their functionality. Along with that this study presents complete outlook regarding ERY-RGs and provides an in depth detail regarding ERY's potential threats to aquatic biota. This study helps in figuring out the best possible strategy to tackle antibiotic pollution keeping ERY as a model antibiotic because of extreme toxicity records.
This study investigated the feasibility of integrated ammonium stripping and/or coconut shell waste-based activated carbon (CSWAC) adsorption in treating leachate samples. To valorize unused biomass for water treatment application, the adsorbent originated from coconut shell waste. To enhance its performance for target pollutants, the adsorbent was pretreated with ozone and NaOH. The effects of pH, temperature, and airflow rate on the removal of ammoniacal nitrogen (NH3-N) and refractory pollutants were studied during stripping alone. The removal performances of refractory compounds in this study were compared to those of other treatments previously reported. To contribute new knowledge to the field of study, perspectives on nutrients removal and recovery like phosphorus and nitrogen are presented. It was found that the ammonium stripping and adsorption treatment using the ozonated CSWAC attained an almost complete removal (99%) of NH3-N and 90% of COD with initial NH3-N and COD concentrations of 2500 mg/L and 20,000 mg/L, respectively, at optimized conditions. With the COD of treated effluents higher than 200 mg/L, the combined treatments were not satisfactory enough to remove target refractory compounds. Therefore, further biological processes are required to complete their biodegradation to meet the effluent limit set by environmental legislation. As this work has contributed to resource recovery as the driving force of landfill management, it is important to note the investment and operational expenses, engineering applicability of the technologies, and their environmental concerns and benefits. If properly managed, nutrient recovery from waste streams offers environmental and socio-economic benefits that would improve public health and create jobs for the local community.
The sustainability performance of the desalination processes has received increasing attention in recent years. In this study, the current progress and future perspective of a life cycle assessment (LCA) of desalination technology in 62 previous studies have been reviewed for the period 2004-2019. It was found that the number of LCA studies related to seawater reverse osmosis has gained popularity compared to other types of desalination technologies. The review emphasized the application of LCA to desalination by means of research objective, scope of study, life stages, and impact assessment. Although previous LCA studies were conducted to assess the environmental performance of the desalination technology, little attention was given to evaluating the impact of other sustainability aspects (i.e., economic and social). The latter part of this study discusses the challenges, feasibility, and recommendations for future LCA studies on desalination technology. The integration of the LCA approach with other approaches allows a comprehensive assessment of the sustainability performance of desalination technology. Thus, the combined approaches should be explored in future studies to gain insight into the sensitivity and uncertainty of the data to make an assessment that can be useful in policy-making.
The coexistence of algae and bacteria in nature dates back to the very early stages when life came into existence. The interaction between algae and bacteria plays an important role in the planet ecology, cycling nutrients, and feeding higher trophic levels, and have been evolving ever since. The emerging concept of algal-bacterial consortia is gaining attention, much towards environmental management and protection. Studies have shown that algal-bacterial synergy does not only promote carbon capture in wastewater bioremediation but also consequently produces biofuels from algal-bacterial biomass. This review has evaluated the optimistic prospects of algal-bacterial consortia in environmental remediation, biorefinery, carbon sequestration as well as its contribution to the production of high-value compounds. In addition, algal-bacterial consortia offer great potential in bloom control, dye removal, agricultural biofertilizers, and bioplastics production. This work also emphasizes the advancement of algal-bacterial biotechnology in environmental management through the incorporation of Industry Revolution 4.0 technologies. The challenges include its pathway to greener industry, competition with other food additive sources, societal acceptance, cost feasibility, environmental trade-off, safety and compatibility. Thus, there is a need for further in-depth research to ensure the environmental sustainability and feasibility of algal-bacterial consortia to meet numerous current and future needs of society in the long run.
Methylene blue is a refractory pollutant commonly present in textile wastewater. This study tests the feasibility of TiO2/graphene oxide (GO) composite in enhancing photocatalytic degradation of MB in synthetic wastewater with respect to scientific and engineering aspects. To enhance its removal, we vary the composition of the composite based on the TiO2 weight. Under UV-vis irradiation, the effects of photocatalyst's dose, pH, and reaction time on MB removal by the composites are evaluated under optimum conditions, while any changes in their physico-chemical properties before and after treatment are analyzed by using TEM, SEM, XRD, FTIR and BET. The photodegradation pathways of the target pollutant by the composite and its removal mechanisms are also elaborated. It is found that the same composite with a 1:2 wt ratio of GO/TiO2 has the largest surface area of 104.51 m2/g. Under optimum reactions (0.2 g/L of dose, pH 10, and 5 mg/L of pollutant's concentration), an almost complete MB removal could be attained within 4 h. This result is higher than that of the TiO2 alone (30%) under the same conditions. Since the treated effluents could meet the strict discharge standard limit of ≤0.2 μg/L set by China's regulation, subsequent biological treatments are unnecessary for completing biodegradation of remaining oxidation by-products in the wastewater effluents.