Browse publications by year: 2025

  1. Remesh SD, Chelvaraj J, Perumal V, Gopinath SCB, Ovinis M, Karupannan S, et al.
    PMID: 39924981 DOI: 10.1002/bab.2731
    Dengue fever, a mosquito-borne viral infection, poses a significant global health challenge, particularly in tropical and subtropical regions. The absence of non-effective vaccines and specific treatments underscores the need for advanced diagnostic tools for early detection and management. This study presents a novel biosensor for detecting dengue virus type 4 (DENV-4) by combining carbonyldiimidazole nanoflower (CDI-NF) with Mn3O4 on laser-scribed graphene (LSG). Material characterization techniques, including Raman spectroscopy, TEM, XRD, XPS, and FTIR, were employed to confirm the successful integration of Mn3O4 and CDI-NF, resulting in a unique 3D flower-like structure. In order to verify the sensing efficiency, a selective DNA sample captured on LSG/Mn3O4-CDI-NF was investigated for specifc binding with Aedes aegypti target DNA through selective hybridization and mismatch analysis. Electrochemical impedance studies further confirmed sensitive detection of up to 1 fM, where the sensitivity was confirmed by large transfer resistance (Rct) before and after hybridization with a regression coefficient 0.97373. EIS results demonstrated successful surface modifications and the biosensor's specificity in distinguishing between complementary, mismatched, and non-complementary target sequences. The biosensor's ability to differentiate between these sequences highlights its potential for accurate and targeted DENV-4 detection, offering a promising avenue for advancing dengue diagnostics.
  2. Ren X, Li T, Li F, Liu S
    Brain Behav, 2025 Feb;15(2):e70313.
    PMID: 39925008 DOI: 10.1002/brb3.70313
    PURPOSE: This study utilizes bidirectional Mendelian randomization (MR) to examine the causal relationships between white matter hyperintensity (WMH) phenotypes-namely, WMH volume, fractional anisotropy (FA), and mean diffusivity (MD)-and cognitive abilities, including cognitive performance, intelligence, and overall cognitive function.

    METHODS: This study leverages genetic variation data from genome-wide association study (GWAS) datasets and employs a bidirectional two-sample MR analysis. The analysis incorporates MR Egger, weighted median, weighted mode, and inverse variance weighted (IVW) methods to assess the bidirectional causal relationship between cognitive abilities and WMH volume, FA, and MD.

    RESULTS: This study employed MR to explore the causal relationships between WMH volume, FA, MD, and cognitive outcomes. Most MR methods yielded nonsignificant p values (>0.05) and wide confidence intervals. Heterogeneity tests indicated no significant heterogeneity or pleiotropy between WMH volume and cognitive performance or intelligence. However, significant heterogeneity was found between WMH volume and cognitive function, FA with cognitive performance and intelligence, and MD with cognitive performance and intelligence. Reverse analysis also revealed no significant causal relationships.

    CONCLUSIONS: This study suggests that the bidirectional causal effects between cognitive abilities and WMH volume, FA, and MD are minimal or nonsignificant and highlights data heterogeneity as a concern.

    MeSH terms: Female; Humans; Male; Phenotype*; Genome-Wide Association Study*; Diffusion Tensor Imaging; Mendelian Randomization Analysis*
  3. Kumbhar PS, Kamble V, Kolekar KA, Vishwas S, Kumbhar P, Patil KS, et al.
    Drug Dev Res, 2025 Feb;86(1):e70057.
    PMID: 39925109 DOI: 10.1002/ddr.70057
    Acne is a skin disease that impacts 9.4% of the world's population. Available treatments for managing acne include retinoid-like drugs, antibiotics, corticosteroids, photo, and radiotherapy. Howevere, the aforementioned treatments have certain limitations such as possibility of developing skin cancer from tetracycline, doxycycline, and corticosteroids, microbial resistance to antibiotics, and deadly side effects, and so forth. Repurposing of existing therapeutics having excellent safety profile can be promising way to treat acne efficiently. The repurposed drugs and phytoceuticals from diverse classes have demonstrated promising effects in treating acne. These repurposed drugs have displayed antiacne effectiveness by targeting single or multiple signaling pathways. Various repurposed therapeutics undergoing clinical trials at different phases demonstrated their safety and efficacy in treating acne. Despite being a very good, safe, and less time-consuming strategy, drug repurposing (DR) faces multiple challenges such as lack of regulatory guidelines, preservation of intellectual property, and clinical validation of claimed therapeutic indication. DR appears to be a viable approach and is likely to offer effective treatment at a reasonable cost in alleviating acne.
    MeSH terms: Animals; Anti-Bacterial Agents/pharmacology; Anti-Bacterial Agents/therapeutic use; Dermatologic Agents/pharmacology; Dermatologic Agents/therapeutic use; Humans; Drug Repositioning*
  4. Li Y, Zhang B, Cao M, Liang X, Tan KB, Zhang S, et al.
    Mater Horiz, 2025 Feb 10.
    PMID: 39925248 DOI: 10.1039/d4mh01615g
    Red phosphorus, with its high theoretical specific capacity and safe lithiation potential, is a promising anode for lithium-ion batteries. However, challenges such as significant volume expansion, dissolution of lithium polyphosphides (LixpPs), and low electronic conductivity hinder its practical application. In this study, we propose a multifunctional hydrogen-bond enhanced cross-linked binder, polyglutamic acid-tragacanth gum (PGA-TG). The PGA-TG binder not only exhibits strong mechanical properties to inhibit the volume expansion of phosphorus particles but also demonstrates a high affinity for phosphorus, thereby facilitating the capture of soluble LixpPs and enhancing the long-cycle performance. Therefore, the PGA-TG-based electrode achieves a lower volume expansion of 19.4% compared with the PVDF-based electrode (233%). Additionally, the PGA-TG-based electrode delivers high reversible capacity of 1575.91 mA h g-1 after 150 cycles at 260 mA g-1 and 1442 mA h g-1 after 280 cycles at 1 A g-1. This work presents a facile and effective binder design strategy to address the multiple challenges associated with phosphorus anodes in lithium-ion batteries.
  5. Cham CY, Choo KSY, Rajahram GS, Chang CY
    Cureus, 2025 Jan;17(1):e77177.
    PMID: 39925531 DOI: 10.7759/cureus.77177
    Melioidosis is a potentially life-threatening infectious disease caused by the Gram-negative bacterium Burkholderia pseudomallei. Its clinical manifestations are highly diverse, including pneumonia, abscesses in internal organs, non-healing ulcers, bone and joint infections, and encephalomyelitis. Mycotic aneurysms, a rare but serious complication of melioidosis, arise as sequelae of bacteremia involving the arterial wall. Despite appropriate antimicrobial therapy and surgical intervention, the mortality rate associated with this complication remains significant. In this report, we present a case of a melioidosis-related mycotic aneurysm of the distal aorta, successfully managed with a combination of targeted antimicrobial therapy and surgical intervention. This case highlights the challenges in diagnosing and treating such a rare manifestation of melioidosis.
  6. M Madawana A, Awang Nawi MA, Tang L, Hassan A, Khamis MF
    Cureus, 2025 Jan;17(1):e77123.
    PMID: 39925579 DOI: 10.7759/cureus.77123
    Studies indicate a strong correlation between the length and degree of alcohol and tobacco use and the risk of oral cancer (OC). However, there has been debate concerning the usage of mouthwashes and associated higher risk of OC for many years. The purpose of this study was to gain insight into how using mouthwash influenced the risk of OC. The Preferred Reporting Items for Systematic Reviews and Meta-Analyses (PRISMA) protocol was used when searching the PubMed/MEDLINE, Scopus, and Web of Science databases. Observational studies that addressed the relationship between mouthwash use and OC and involved adult or older adult populations were included. The Newcastle-Ottawa Scale was employed to check the methodological quality, and random effects meta-analysis, along with other subgroup analyses and meta-regression, were utilized to synthesize quantitative data. Out of 5,132 papers identified, 15 case-control studies comprising 6,515 cases and 17,037 controls were included in the review. Seventeen effect measures from these 15 studies were included in the meta-analysis. For individuals who used mouthwash three or more times a day, the pooled OR for OC was 1.00 (95% CI: 0.79-1.26; n = 17 studies). Among those who had used mouthwash for more than 40 years, the OR was 1.30 (95% CI: 1.58-4.82; p = 0.05; n = 2 studies). Some studies suggest that frequent mouthwash use may increase the risk of OC. Given the biological plausibility of this link, we exercise caution in interpreting these findings. It is important to note the limited research on the frequency and duration of mouthwash use. Thus, for the strengthening of the evidence for a possible dose-response effect of mouthwashes on OC risk, we suggest that future research should be focused on the frequency, duration, and substance of mouthwashes in depth.
  7. Kasmara DP, Abdullah E, Harun Z, Sari FN, Abd Rashid N, Teoh SL
    Front Pharmacol, 2025;16:1522814.
    PMID: 39925850 DOI: 10.3389/fphar.2025.1522814
    Monosodium glutamate (MSG) is an odorless white solid crystalline derived from the amino acid glutamic acid. It is widely used as a flavor enhancer, but its excessive consumption has been associated with toxicity to various organs. In MSG-induced liver injury, few mechanisms have been identified, which started with the generation of reactive oxygen species that leads to oxidative stress which further causes liver injury. In response to this health concern, there is growing interest in various plant products such as plant extracts, flavonoids and phenolic compounds that were able to minimize oxidative stress, serum transaminases and scavenge free radicals in the liver after MSG administration. This review explores the potential of various plant products as dietary supplements to MSG-induced liver injury, focusing on their antioxidant activities, modulatory effects on liver function markers, and histological outcomes. By compiling this evidence, this review provides insights into their potential as preventive strategies against MSG-related liver toxicity, supporting their inclusion in dietary regimens for the maintenance of liver function.
  8. Wang X, Abu Bakar MH, Kassim MA, Shariff KA, Mohamad Rosdi MN
    Biochem Biophys Rep, 2025 Mar;41:101928.
    PMID: 39926209 DOI: 10.1016/j.bbrep.2025.101928
    Hyperglycemia-induced inflammation and fibrosis in renal tubular epithelial cells are critical factors driving the progression of diabetic nephropathy (DN). Celastrol, a bioactive compound derived from Tripterygium wilfordii Hook.F, is recognized for its anti-inflammatory and anti-fibrotic properties. This study aimed to investigate the renoprotective effects of celastrol against high glucose (HG)-induced damage in human kidney 2 (HK-2) cells. Briefly, HK-2 cells were exposed to high glucose and treated with celastrol. Cell viability and apoptosis were evaluated using CCK-8 assay kit and flow cytometry, respectively. The pro-inflammatory cytokines, oxidative stress markers, and fibrotic-related proteins were measured using ELISA and immunoblotting. To further confirm the mechanistic actions of celastrol, the PI3K/Akt/NF-κB pathway was examined, and HG-treated cells were co-incubated with the NF-κB inhibitor bortezomib. Our result revealed that celastrol at the moderate concentration of 50 nM mitigated HG-induced toxicity, suggesting an optimal therapeutic window. Celastrol improved cell viability and reduced apoptosis in HG-treated HK-2 cells. It significantly decreased levels of inflammatory cytokines such as IL-6, TNF-α, IL-1β, and MCP-1, while enhancing antioxidant activities of GSH-Px and SOD, and lowering MDA levels, indicating diminished oxidative stress. Mechanistically, these renoprotective effects of celastrol partly attributed via inhibition of the PI3K/Akt/NF-κB signalling pathway, as blocking NF-κB signalling by bortezomib resulted in similar inhibitory effects against inflammation and fibrosis. Collectively, celastrol acts as a renoprotective agent against renal inflammation, oxidative stress, and fibrosis, partly through the inhibition of the PI3K/Akt/NF-κB pathway, offering potential therapeutic benefits against hyperglycemia-induced renal injury in DN.
  9. Manik YGO, Goh BT, Siburian R, Alias Y
    ACS Omega, 2025 Feb 04;10(4):3338-3350.
    PMID: 39926523 DOI: 10.1021/acsomega.4c05745
    Graphene nanosheets (GNS) have garnered significant attention due to their exceptional properties and wide-ranging applications. This research aims to synthesize GNS from coconut shells and candlenut shells and to compare their performance in Fe ion adsorption and electrochemical properties. Both coconut and candlenut shells were used as raw materials, and the pyrolysis method was chosen to produce large-scale GNS. The GNS were characterized using Raman spectroscopy, X-ray diffraction, FTIR, FESEM-EDX, AAS, and electrochemical measurements, including CV and EIS on modified electrodes. New findings from this study reveal that GNS derived from candlenut shells exhibit thinner layers and fewer defects compared with those derived from coconut shells. This structural advantage contributes to superior Fe ion adsorption efficiency and better electrochemical performance, making the GNS from candlenut shells more suitable for applications in flexible electronics and electrochemical devices. Furthermore, the synthesis method effectively reduces the amount of oxides associated with defects in the GNS, enhancing the material's potential for high-performance applications. The GNS produced from candlenut shells showed an Fe adsorption effectiveness of 0.33 ± 0.012 mg/g, a charge transfer resistance of 0.78 kΩ, and a capacitance of 108.8 F/g, indicating their promising role in future technological applications.
  10. Kamarulzaman N, Wan Abdullah WNA, Othman MK, Isa WYHW, Yusof Z, Mohamad Jamali AA, et al.
    Eur J Case Rep Intern Med, 2025;12(2):005144.
    PMID: 39926563 DOI: 10.12890/2025_005144
    Post-cardiac injury syndrome (PCIS) is one of the complications of cardiac interventional procedures. This condition has been postulated to be due to an immune reaction, especially with pacemaker lead implantation. Patients with PCIS can have uncomplicated pericardial effusion until they develop cardiac tamponade. The management of PCIS, which can be conservative management or require pericardiocentesis or surgery depends on the patient's clinical symptoms. As the left bundle branch area pacing (LBBAP) implantation technique and technology are still new, it is associated with longer procedural time than conventional pacemaker implantation. Herein, we report a case of PCIS in a patient who had a prolonged LBBAP procedure due to difficult anatomy and presented with recurrent cardiac tamponade.

    LEARNING POINTS: Prolonged fluoroscopy in cardiac procedures can potentially lead to post-cardiac injury syndrome.Active pacemaker lead fixation is one of the risk factors for post-cardiac injury syndrome due to immune reaction.Left bundle branch area pacing in adults with congenital heart disease is challenging because of anatomical differences.

  11. Jouhar R, Halim MS, Ahmed MA, Shah F, Quadri SA
    Pak J Med Sci, 2025 Feb;41(2):519-524.
    PMID: 39926673 DOI: 10.12669/pjms.41.2.11001
    BACKGROUND & OBJECTIVE: Root canal infections are challenging to eradicate with conventional methods due to their complexity. Traditional chemical irrigants often fail to reach all bacterial colonies. Methylene blue (MB), used in photoactivated disinfection (PAD), generates reactive oxygen species (ROS) upon light activation, effectively killing bacteria. This study aimed to synthesize, characterize, and explore MB-functionalized reduced graphene oxide (MB/rGO) for enhanced photoactivated disinfection in root canal treatment.

    METHODS: This in-vitro study was conducted from April 2024 to September 2024 at Universiti Sains Malaysia and King Faisal University. Graphene oxide (GO) was reduced by dispersing GO in deionized water with sonication, followed by adding sodium hydroxide (NaOH) under vigorous stirring. The suspension obtained was centrifuged, washed, and dried to yield reduced graphene oxide (rGO). For functionalization, rGO was dispersed in ethanol and mixed with methylene blue (MB) solution, followed by stirring and drying to obtain MB-functionalized rGO. The antibacterial and antifungal activities of MB alone and in combination with rGO, with or without laser exposure, were tested using the agar well diffusion method. The paired sample t-test was used to compare the inhibition zones for different treatment groups of E. faecalis and C. albicans.

    RESULTS: FTIR analysis confirmed successful functionalization by identifying specific functional groups of rGO and MB. Similarly, Raman spectroscopy indicated that GO-MB had an intermediate level of defects, and SEM analysis confirmed slight morphological changes with MB molecules attached to the rGO surface. Moreover, the antimicrobial test revealed that MB/rGO with laser performed significantly better (p=0.042) than MB/rGO without laser and MB with laser group (p=0.034) against E. faecalis.

    CONCLUSIONS: The functionalization of MB with rGO and its application with laser treatment significantly enhanced antimicrobial and antifungal activity, suggesting potential benefits for endodontic treatments and other dental applications.

  12. Tan MH, Jayne D
    Clin Kidney J, 2025 Feb;18(2):sfae389.
    PMID: 39927255 DOI: 10.1093/ckj/sfae389
    Diagnosing and managing antineutrophil cytoplasmic antibody (ANCA)-associated vasculitis (AAV) remain a challenge for many clinicians, due to the complexity of the disease manifestations and its treatment. There has been a paradigm shift in ANCA vasculitis management, where treatment incorporates both emergency life- and organ-saving procedures and longer-term care to manage relapse and co-morbidity risk and the complications of organ damage. Here, we highlight 10 key tips for the management of ANCA-associated vasculitis based on current evidence and clinical experience. First, we advise making the diagnosis as early as possible, emphasizing the importance of using high-quality ANCA assays. Second, we recommend the use of glucocorticoids in combination with rituximab and/or cyclophosphamide as induction therapy. Third, plasma exchange should be considered in patients with severe renal impairment and diffuse alveolar haemorrhage. We advise the use of rapidly reducing glucocorticoid regimens and advocate consideration of avacopan early in the disease course. We recommend the use of rituximab as maintenance therapy and routine monitoring of kidney function, proteinuria, ANCA and immunoglobulin levels at baseline and during follow-up. The use of prophylactic antibiotics in susceptible patients and timely vaccination schedules is discussed. Rituximab is the preferred immune suppressive for treatment of relapse. Finally, we recommend switching treatment modalities in patients whose vasculitis is refractory to induction therapy and to consider plasma exchange in selected patients. These key tips aim to provide the necessary guidance to improve patient outcomes and reduce adverse events.
  13. Vythilingam G, Larsson HM, Yeoh WS, Zainuddin SAM, Engelhardt EM, Sanmugam A, et al.
    Urology, 2025 Feb;196:294-299.
    PMID: 39710073 DOI: 10.1016/j.urology.2024.12.016
    OBJECTIVE: To engineer an acellular mesh to reconstruct the urethra to replace the current surgical practice of using autologous tissue grafts. Cell based approaches have shown progress. However, these have been associated with high costs and logistical challenges.

    MATERIALS AND METHODS: Acellular meshes were engineered using liquid collagen. They underwent in vitro, mechanical and bench testing by surgeons. Sixty-nine male New Zealand rabbits were used to refine the design. The final prototype based on the TissueSpan patented technology was then implanted again in a 2 cm long urethral defect in 9 rabbits and in a 4 cm long defect in 6 dogs.

    RESULTS: The TissueSpan technology platform allows for the manufacturing of tubular and rectangular meshes in different diameters and thicknesses. The tubular mesh acted as physical conduit to gap the urethral defect with a patent urethra demonstrated after 1month in both animal models. The mesh was absorbed within 1-3months. Spontaneous urothelial coverage of the mesh and smooth muscle cell migration into the surgical area was demonstrated even in a 4 cm long urethral defect. A first in man clinical trial was subsequently initiated.

    CONCLUSION: The acellular mesh may have the potential to be an off-the-shelf product for substitution urethroplasty. Its mechanical properties allow surgeons to easily create a physical conduit while its material properties favor tissue remodeling. A large-scale clinical trial is still required to further confirm the safety, performance, and patient benefit of this new medical device.

    MeSH terms: Animals; Dogs; Humans; Male; Rabbits; Surgical Mesh*; Time Factors; Tissue Engineering/methods
  14. Jiang-Peng S, Jia-Qin F, Chuang L, Shou-Ping L, Chin-Ping T, Ping-Ping W, et al.
    Int J Biol Macromol, 2025 Apr;304(Pt 1):140705.
    PMID: 39920928 DOI: 10.1016/j.ijbiomac.2025.140705
    Dendrobium officinale polysaccharide (DOP), a natural hydrocolloid derived from polysaccharides, holds significant promise for enhancing the quality of frozen dough-based products. This research systematically examined the effects of DOP on the quality attributes of both frozen dough and the resulting bread throughout the period of frozen storage. Findings demonstrated that DOP enhanced thermal stability and slowed starch retrogradation. Dough containing 1.2 % DOP showed increased water absorption (68.63 ± 0.21 %), extended development time (8.63 ± 0.25 min), and decreased stability time (9.33 ± 0.06 min), along with diminished gluten strength and gelatinization viscosity. Moreover, higher concentrations of DOP markedly inhibited water migration, curtailed the rise in freezable water content, and reduced moisture loss during frozen storage (p 
    MeSH terms: Flour/analysis; Freezing*; Glutens/chemistry; Rheology; Viscosity; Water/chemistry; Triticum/chemistry
  15. Jafri NF, Salleh KM, Ghazali NA, Hua CC, Wang C, Zakaria S
    Int J Biol Macromol, 2025 Apr;303:140707.
    PMID: 39920938 DOI: 10.1016/j.ijbiomac.2025.140707
    To maintain the versatility of a hydrogel, extensive modifications are necessary, particularly to overcome the daunting mechanical trait of this material. In agriculture especially, achieving the desired balance between strength and high water absorption ability with this polymer is a significant challenge. Therefore, this study used and evaluated both carboxymethyl cellulose (CMC) mesofiber (CMCF) and CMC-chitosan mesofiber (CMC/CHF) as a reinforcing agent at varying concentrations in the widely known regenerated cellulose hydrogel. These fibers were fined and revamped as mesofiber before being integrated into the cellulose solution for crosslinking and formation stages. The hydrogel filled with 2 wt% mesofiber, especially CMC/CHF exhibited the highest storage modulus value (3300 Pa), compression strength (0.315 MPa), and thermal stability, showing the resistivity of this composite towards external pressure. Morphologically, the distribution of smaller pores within the mesofiber-reinforced hydrogel improved along with the water absorption ability. The composite hydrogels, however, demonstrated lower transparency compared to the plain hydrogel due to the high loading of CMCF and complex CMC/CHF. The utilization of CMC/CHF is especially successful and effective in enhancing the resulting composite's mechanical strength and hydrophilicity. Thus, it is expected to be beneficial as a planting medium that provides both functionality and vitality.
    MeSH terms: Cellulose/analogs & derivatives; Cellulose/chemistry; Water/chemistry; Compressive Strength; Hydrophobic and Hydrophilic Interactions
  16. Rosca EC, Garg D, Perez-Lloret S, Mohamed Ibrahim N, Phokaewvarangkul O, Sringean J, et al.
    Mov Disord, 2025 Feb 08.
    PMID: 39921518 DOI: 10.1002/mds.30142
    Movement disorders after dengue virus (DENV) infection have been increasingly recognized. We aimed to synthesize the clinical and paraclinical characteristics, treatment responses, and outcomes of these neurologic complications. We systematically reviewed PubMed, Embase, Scopus, and LILACS databases up to September 2023 following a published protocol. We identified 73 cases of DENV-induced movement disorders. Cerebellar ataxia was the most common, followed by parkinsonism, opsoclonus-myoclonus-ataxia syndrome, and dystonia. Movement disorders typically developed within 14 days of DENV infection and were associated with a range of neurological symptoms, including cognitive impairment and psychiatric disturbances. Neuroimaging studies frequently showed abnormalities in the basal ganglia and brainstem. Treatment varied depending on the specific movement disorder and included corticosteroids, intravenous immunoglobulin, and symptomatic medications. Whereas a handful of cases met the criteria for acute encephalitis, many lacked sufficient data to establish a definitive diagnosis. Para-infectious and postinfectious immune-mediated movement disorders were also reported. A rare case of chronic progressive panencephalitis due to DENV infection highlights the potential for long-term neurological consequences. Other DENV-related complications, such as stroke, pituitary apoplexy, subacute thyroiditis, and metabolic disturbances, can also cause movement disorders. We emphasize the importance of recognizing the diverse neurological manifestations of DENV infection and the need for further research to improve our understanding of the underlying mechanisms and optimize treatment strategies. We propose a more rigorous approach to determining the causality between infection and movement disorder, demanding stronger evidence beyond mere association and advocating for targeted research to fill the existing knowledge gaps. © 2025 International Parkinson and Movement Disorder Society.
  17. Abubakar M, Ahmad Hidayat AF, Abd Halim AA, Khanna K, Zaroog MS, Rajagopal MS, et al.
    PMID: 39921569 DOI: 10.1515/znc-2024-0223
    The research examined the molecular interaction between nirmatrelvir (NIR), a drug used to treat COVID-19, and human serum albumin (HSA) using various techniques, viz., isothermal titration calorimetry (ITC), absorption, fluorescence, CD spectroscopy, and atomic force microscopy (AFM). ITC analysis showed that the NIR-HSA system possessed a moderate binding affinity, with a K a value of 6.53 ± 0.23 × 104 M-1 at a temperature of 300 K. The thermodynamic values demonstrated that the NIR-HSA complex was stabilized by hydrophobic contacts, hydrogen bonds, and van der Waals forces. The research also discovered modifications in the UV-Vis absorption spectrum of the protein as well as swelling of the HSA molecule when exposed to NIR, based on AFM results. The three-dimensional fluorescence spectral data indicated changes in the microenvironment around HSA's Trp and Tyr residues. Alterations in the protein structure (both secondary and tertiary structures) of HSA after NIR binding were verified using CD spectral studies in the far-UV and near-UV regions. The identification of the NIR binding site in subdomain IB (Site III) of HSA was predicted through competitive displacement experiments.
  18. Lim SW, Kansedo J, Tan IS, Nandong J, Tan YH, Lam MK, et al.
    J Environ Manage, 2025 Mar;376:124394.
    PMID: 39921954 DOI: 10.1016/j.jenvman.2025.124394
    With growing environmental concerns over plastic pollution, polyhydroxyalkanoates (PHAs) have recently gained significant attention as promising biodegradable polymers to substitute petroleum-based plastics. In this work, non-edible Cerbera odollam oil was employed as a renewable carbon source for PHA production to improve the economic competitiveness and environmental sustainability of the process. The optimization and mechanism of PHA production from C. odollam oil using Pseudomonas resinovorans DSM 21078 were presented. Through response surface methodology, the optimal condition for PHA production was 0.3 g/L urea concentration, 17.52 g/L oil concentration, and 10.46% (v/v) inoculum size. Results showed that a maximum PHA concentration of 0.50 g/L (with a polymer content of 26.0%) was attained at this optimal condition. The product was composed of 1.3% 3-hydroxybutyrate (3HB), 9.2% 3-hydroxyhexanoate (3HHx), 43.3% 3-hydroxyoctanoate (3HO), 32.0% 3-hydroxydecanoate (3HD), 11.9% 3-hydroxydodecanoate (3HDD), and 2.2% 3-hydroxytetradecanoate (3HTD). The PHA polymers exhibited adhesive, soft, and amorphous properties at room temperature, with high thermal stability, making them desirable for polymer processing. From the mechanism proposed, it was inferred that P. resinovorans DSM 21078 produces longer-chain PHA monomers mainly through the direct β-oxidation of long-chain fatty acids and shorter-chain monomers via the de novo fatty acid synthesis pathway when oil-based substrates are utilized. The findings from this work could pave the way for new paradigms that significantly enhance future research in the development of highly efficient oil resource valorization technologies to produce PHAs with intriguing properties, thereby contributing to the commercial success of sustainable bioplastics as an effective environmental management solution.
    MeSH terms: Biodegradation, Environmental; Fermentation; Plant Oils/metabolism; Mangifera/metabolism
  19. Lv Y, Zheng Y, Lee YY, Li Y, Wang Y, Zhang Y, et al.
    Food Chem, 2025 May 01;473:143050.
    PMID: 39922184 DOI: 10.1016/j.foodchem.2025.143050
    This research employed environmentally friendly dry fractionation to systematically modify the physicochemical properties of 80 % diacylglycerol derived from peanut oil (PDAG-80), expanding its potential food applications. The properties of olein and stearin were optimized by adjusting key parameters: crystallization temperatures (11, 13, 15 and 17 °C), cooling rates (2, 5, 8 and 11 °C/h), agitation speeds (10, 20, 30 and 40 rpm)and residence times (3, 6, 9 and 12 h). Lowering the crystallization temperature and extending the residence time increased the iodine value and solid fat content of olein. Additionally, diverse fractionation parameters yieled stearin with varying crystal ratios. The resulting olein fractionated from PDAG-80, a liquid at room temperature and rich in unsaturated fatty acids, exhibited superior cloudy property and oxidative stability. These findings not only deepen the understanding of PDAG-80 physical modification, but also provide a scientific foundation for developing high value-added PDAG products within the food industry.
    MeSH terms: Crystallization*; Chemical Fractionation/methods; Oxidation-Reduction*
  20. Li H, Wang Y, Mustapha WAW, Zhang X, Zeng F, Liu J
    Int J Biol Macromol, 2025 Apr;304(Pt 1):140757.
    PMID: 39922348 DOI: 10.1016/j.ijbiomac.2025.140757
    A fish scale (FS) gelatin-fatty acid conjugate (GFC) with alkyl chain lengths of 8-18 was constructed to increase the aqueous solubility of curcumin. The effect of alkyl chain length on the interaction between GFC and curcumin was characterized by dynamic light scattering (DLS), X-ray photoelectron spectroscopy (XPS), fluorescence spectroscopy (FS), and isothermal titration calorimetry (ITC). The surface hydrophobicity (from 4987 ± 223.79 to 9982 ± 262.78) and curcumin loading capacity (from 8.20 ± 0.54 to 31.18 ± 1.41 μg/mg) of the GFC exhibited significant enhancements through increasing alkyl chain lengths from 8 to 18. This was accompanied by a reduction in particle size (from 661.5 ± 28.9 to 329.7 ± 6.6 nm) and ζ-potential (from -2.7 ± 0.92 to -26.8 ± 0.27). FS and ITC confirmed that GOC shared an optimal binding constant (Ka, 2.40 × 108 L·mol-1 and 3.47 × 105 M-1) and binding site (n, 1.45 and 2.276) with curcumin among GFCs. Increasing GFC's alkyl chain length also boosted the stability of entrapped curcumin against the thermal environment and ultraviolet radiation. These results could be beneficial for gelatin-based nanocarrier development and application.
    MeSH terms: Animals; Carps; Drug Carriers/chemistry; Drug Stability; Particle Size; Solubility; Hydrophobic and Hydrophilic Interactions*
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