Displaying publications 201 - 220 of 1020 in total

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  1. Muhamad MH, Sheikh Abdullah SR, Mohamad AB, Rahman RA, Kadhum AA
    Environ Technol, 2012 Apr-May;33(7-9):915-26.
    PMID: 22720416
    A pilot scale granular activated carbon-sequencing batch biofilm reactor with a capacity of 2.2 m3 was operated for over three months to evaluate its performance treating real recycled paper industry wastewater under different operational conditions. In this study, dissolved air floatation (DAF) and clarifier effluents were used as influent sources of the pilot plant. During the course of the study, the reactor was able to biodegrade the contaminants in the incoming recycled paper mill wastewater in terms of chemical oxygen demand (COD), adsorbable organic halides (AOX; specifically 2,4-dichlorophenol (2,4-DCP)) and ammoniacal nitrogen (NH3-N) removal efficiencies at varying hydraulic retention times (HRTs) of 1-3 days, aeration rates (ARs) of 2.1-3.4 m3/min and influent feed concentration of 40-950 mg COD/l. Percentages of COD, 2,4-DCP and NH3-N removals increased with increasing HRT, resulting in more than 90% COD, 2,4-DCP and NH3-N removals at HRT values above two days. Degradation of COD, 2,4-DCP and NH3-N were seriously affected by variation of ARs, which resulted in significant decrease of COD, 2,4-DCP and NH3-N removals by decreasing ARs from 3.4 m3/min to 2.1 m3/min, varying in the ranges of 24-80%, 6-96% and 5-42%, respectively. In comparison to the clarifier effluent, the treatment performance of DAF effluent, containing high COD concentration, resulted in a higher COD removal of 82%. The use of diluted DAF effluent did not improve significantly the COD removal. Higher NH3-N removal efficiency of almost 100% was observed during operation after maintenance shutdown compared to normal operation, even at the same HRT of one day due to the higher dissolved oxygen concentrations (1-7 mg/l), while no significant difference in COD removal efficiency was observed.
    Matched MeSH terms: Water Pollutants, Chemical/metabolism*
  2. Mustapha A, Aris AZ, Ramli MF, Juahir H
    PMID: 22702815 DOI: 10.1080/10934529.2012.680415
    The pollution status of the downstream section of the Jakara River was investigated. Dissolved oxygen (DO), 5-day biochemical oxygen demand (BOD(5)), chemical oxygen demand (COD), suspended solids (SS), pH, conductivity, salinity, temperature, nitrogen in the form of ammonia (NH(3)), turbidity, dissolved solids (DS), total solids (TS), nitrates (NO(3)), chloride (Cl) and phosphates (PO(3-)(4)) were evaluated, using both dry and wet season samples, as a measure of variation in surface water quality in the area. The results obtained from the analyses were correlated using Pearson's correlation matrix, principal component analysis (PCA) and paired sample t-tests. Positive correlations were observed for BOD(5), NH(3), COD, and SS, turbidity, conductivity, salinity, DS, TS for dry and wet seasons, respectively. PCA was used to investigate the origin of each water quality parameter, and yielded 5 varimax factors for each of dry and wet seasons, with 70.7 % and 83.1 % total variance, respectively. A paired sample t-test confirmed that the surface water quality varies significantly between dry and wet season samples (P < 0.01). The source of pollution in the area was concluded to be of anthropogenic origin in the dry season and natural origins in the wet season.
    Matched MeSH terms: Water Pollutants, Chemical/analysis*
  3. Prasanna MV, Nagarajan R, Chidambaram S, Elayaraja A
    Bull Environ Contam Toxicol, 2012 Sep;89(3):507-11.
    PMID: 22684361 DOI: 10.1007/s00128-012-0698-4
    A baseline study was carried out to assess the metal concentrations and microbial contamination at selected Lake waters in and around Miri City, East Malaysia. Sixteen surface water samples were collected at specific Lakes in the environs of major settlement areas and recreational centers in Miri City. The Physico-chemical parameters [pH, Electrical Conductivity (EC) and Dissolved Oxygen (DO)], metals (Fe, Mn, Cu, Cd, Ni and Zn) and Escherichia coli (E. coli) were analysed. The concentrations of Fe, Mn and Ni have been found to be above the permissible limits of drinking water quality standards. The metals data have also been used for the calculation of heavy metal pollution index. Higher values of E. coli indicate microbial contamination in the Lake waters.
    Matched MeSH terms: Water Pollutants, Chemical/analysis*
  4. Shuhaimi-Othman M, Nur-Amalina R, Nadzifah Y
    ScientificWorldJournal, 2012;2012:125785.
    PMID: 22666089 DOI: 10.1100/2012/125785
    Adult freshwater snails Melanoides tuberculata (Gastropod, Thiaridae) were exposed for a four-day period in laboratory conditions to a range of copper (Cu), cadmium (Cd), zinc (Zn), lead (Pb), nickel (Ni), iron (Fe), aluminium (Al), and manganese (Mn) concentrations. Mortality was assessed and median lethal times (LT₅₀) and concentrations (LC₅₀) were calculated. LT₅₀ and LC₅₀ increased with the decrease in mean exposure concentrations and times, respectively, for all metals. The LC(50) values for the 96-hour exposures to Cu, Cd, Zn, Pb, Ni, Fe, Al, and Mn were 0.14, 1.49, 3.90, 6.82, 8.46, 8.49, 68.23, and 45.59 mg L⁻¹, respectively. Cu was the most toxic metal to M. tuberculata, followed by Cd, Zn, Pb, Ni, Fe, Mn, and Al (Cu > Cd > Zn > Pb > Ni > Fe > Mn > Al). Metals bioconcentration in M. tuberculata increases with exposure to increasing concentrations and Cu has the highest accumulation (concentration factor) in the soft tissues. A comparison of LC₅₀ values for metals for this species with those for other freshwater gastropods reveals that M. tuberculata is equally sensitive to metals.
    Matched MeSH terms: Water Pollutants, Chemical/toxicity*
  5. Gazzaz NM, Yusoff MK, Ramli MF, Aris AZ, Juahir H
    Mar Pollut Bull, 2012 Apr;64(4):688-98.
    PMID: 22330076 DOI: 10.1016/j.marpolbul.2012.01.032
    This study employed three chemometric data mining techniques (factor analysis (FA), cluster analysis (CA), and discriminant analysis (DA)) to identify the latent structure of a water quality (WQ) dataset pertaining to Kinta River (Malaysia) and to classify eight WQ monitoring stations along the river into groups of similar WQ characteristics. FA identified the WQ parameters responsible for variations in Kinta River's WQ and accentuated the roles of weathering and surface runoff in determining the river's WQ. CA grouped the monitoring locations into a cluster of low levels of water pollution (the two uppermost monitoring stations) and another of relatively high levels of river pollution (the mid-, and down-stream stations). DA confirmed these clusters and produced a discriminant function which can predict the cluster membership of new and/or unknown samples. These chemometric techniques highlight the potential for reasonably reducing the number of WQVs and monitoring stations for long-term monitoring purposes.
    Matched MeSH terms: Water Pollutants, Chemical/analysis*
  6. Azrina A, Khoo HE, Idris MA, Amin I, Razman MR
    Malays J Nutr, 2011 Aug;17(2):271-6.
    PMID: 22303580 MyJurnal
    Quality drinking water should be free from harmful levels of impurities such as heavy metals and other inorganic elements.
    Matched MeSH terms: Water Pollutants, Chemical/analysis*
  7. Almayahi BA, Tajuddin AA, Jaafar MS
    Appl Radiat Isot, 2012 Nov;70(11):2652-60.
    PMID: 22982603 DOI: 10.1016/j.apradiso.2012.07.021
    The radioactivity quantity and quality were determined in soil and water samples in Northern Malaysian Peninsula (NMP) using HPGe spectroscopy and GR-135 spectrometer. The (226)Ra, (232)Th and (40)K concentrations in soil samples are 57±2, 68±4 and 427±17 Bq kg(-1), respectively, whereas in water samples were found to be 2.86±0.79, 3.78±1.73 and 152±12 Bq l(-1), respectively. These concentrations are within those reported from literature in other countries in the world. The radiological hazard indices of the samples were also calculated. The mean values obtained from soil samples are 186 Bq kg(-1), 88 nGy h(-1), 108 μSv y(-1), 0.50 and 0.65 for Radium Equivalent Activity (Ra(eq)), Absorbed Dose Rates (D(R)), Annual Effective Dose Rates (ED), External Hazard Index (H(ex)) and Internal Hazard Index (H(in)) respectively, whereas, for water samples were found to be 20, 10, 13, 0.05 and 0.06, respectively. All the health hazard indices are well below their recommended limits, except in two soil sampling sites which were found to be (*)025 (1.1 H(ex)) and (*)026 (1.1 H(ex), 1.6 H(in)). The calculated and the measured gamma dose rates had a good correlation coefficient, R=0.88. Moreover, the average value radon is 20 (in the range of 7-64) Bq m(-3), a positive correlation (R=0.81) was observed between the (222)Rn and (226)Ra concentrations in samples measured by the SNC continuous radon monitor (model 1029, Sun Nuclear Corporation) and HPGe detector, respectively. Some soils in this study with H(in) and H(ex)<1 are suitable for use in agriculture and as building materials. Also, in this study H(in) and H(ex)<1 for water samples, therefore, water after processing and filtration is safe and suitable for use in household and industrial purposes.
    Matched MeSH terms: Water Pollutants, Radioactive/analysis*
  8. Shuhaimi-Othman M, Nadzifah Y, Nur-Amalina R, Umirah NS
    ScientificWorldJournal, 2012;2012:861576.
    PMID: 22919358 DOI: 10.1100/2012/861576
    Freshwater quality criteria for iron (Fe), lead (Pb), nickel (Ni), and zinc (Zn) were developed with particular reference to aquatic biota in Malaysia, and based on USEPA's guidelines. Acute toxicity tests were performed on eight different freshwater domestic species in Malaysia which were Macrobrachium lanchesteri (prawn), two fish: Poecilia reticulata and Rasbora sumatrana, Melanoides tuberculata (snail), Stenocypris major (ostracod), Chironomus javanus (midge larvae), Nais elinguis (annelid), and Duttaphrynus melanostictus (tadpole) to determine 96 h LC(50) values for Fe, Pb, Ni, and Zn. The final acute value (FAV) for Fe, Pb, Ni, and Zn were 74.5, 17.0, 165, and 304.9 μg L(-1), respectively. Using an estimated acute-to-chronic ratio (ACR) of 8.3, the value for final chronic value (FCV) was derived. Based on FAV and FCV, a criterion maximum concentration (CMC) and a criterion continuous concentration (CCC) for Fe, Pb, Ni, and Zn that are 37.2, 8.5, 82.5, and 152.4 μg L(-1) and 9.0, 2.0, 19.9, and 36.7 μg L(-1), respectively, were derived. The results of this study provide useful data for deriving national or local water quality criteria for Fe, Pb, Ni, and Zn based on aquatic biota in Malaysia. Based on LC(50) values, this study indicated that N. elinguis, M. lanchesteri, N. elinguis, and R. sumatrana were the most sensitive to Fe, Pb, Ni, and Zn, respectively.
    Matched MeSH terms: Water Pollutants, Chemical/analysis*
  9. Lim WY, Aris AZ, Zakaria MP
    ScientificWorldJournal, 2012;2012:652150.
    PMID: 22919346 DOI: 10.1100/2012/652150
    This paper determines the controlling factors that influence the metals' behavior water-sediment interaction facies and distribution of elemental content ((75)As, (111)Cd, (59)Co, (52)Cr, (60)Ni, and (208)Pb) in water and sediment samples in order to assess the metal pollution status in the Langat River. A total of 90 water and sediment samples were collected simultaneously in triplicate at 30 sampling stations. Selected metals were analyzed using ICP-MS, and the metals' concentration varied among stations. Metal concentrations of water ranged between 0.08-24.71 μg/L for As, <0.01-0.53 μg/L for Cd, 0.06-6.22 μg/L for Co, 0.32-4.67 μg/L for Cr, 0.80-24.72 μg/L for Ni, and <0.005-6.99 μg/L for Pb. Meanwhile, for sediment, it ranged between 4.47-30.04 mg/kg for As, 0.02-0.18 mg/kg for Cd, 0.87-4.66 mg/kg for Co, 4.31-29.04 mg/kg for Cr, 2.33-8.25 mg/kg for Ni and 5.57-55.71 mg/kg for Pb. The average concentration of studied metals in the water was lower than the Malaysian National Standard for Drinking Water Quality proposed by the Ministry of Health. The average concentration for As in sediment was exceeding ISQG standards as proposed by the Canadian Sediment Quality Guidelines. Statistical analyses revealed that certain metals (As, Co, Ni, and Pb) were generally influenced by pH and conductivity. These results are important when making crucial decisions in determining potential hazardous levels of these metals toward humans.
    Matched MeSH terms: Water Pollutants, Chemical/analysis*
  10. Hajeb P, Jinap S, Ismail A, Mahyudin NA
    PMID: 22610296 DOI: 10.1007/978-1-4614-3414-6_2
    Although several studies have been published on levels of mercury contamination of the environment, and of food and human tissues in Peninsular Malaysia, there is a serious dearth of research that has been performed in East Malaysia (Sabah and Sarawak). Industry is rapidly developing in East Malaysia, and, hence, there is a need for establishing baseline levels of mercury contamination in environmental media in that part of the country by performing monitoring studies. Residues of total mercury and inorganic in food samples have been determined in nearly all previous studies that have been conducted; however, few researchers have analyzed samples for the presence of methlymercury residues. Because methylmercury is the most toxic form of mercury, and because there is a growing public awareness of the risk posed by methylmercury exposure that is associated with fish and seafood consumption, further monitoring studies on methylmercury in food are also essential. From the results of previous studies, it is obvious that the economic development in Malaysia, in recent years, has affected the aquatic environment of the country. Primary areas of environmental concern are centered on the rivers of the west Peninsular Malaysian coast, and the coastal waters of the Straits of Malacca, wherein industrial activities are rapidly expanding. The sources of existing mercury input to both of these areas of Malaysia should be studied and identified. Considering the high levels of mercury that now exists in human tissues, efforts should be continued, and accelerated in the future, if possible, to monitor mercury contamination levels in the coastal states, and particularly along the west Peninsular Malaysian coast. Most studies that have been carried out on mercury residues in environmental samples are dated, having been conducted 20-30 years ago; therefore, the need to collect much more and more current data is urgent. Furthermore, establishing baseline levels of mercury exposure to humans in Malaysia will be useful in establishing the levels at which detrimental effects in both humans and marine life may occur, and therefore the levels at which warning should be raised or limits established. In particular, we believe that two or three monitoring centers should be established in Peninsular Malaysia, and one in East Malaysia for the specific purpose of monitoring for the presence of hazardous environmental chemicals, and particularly monitoring for heavy metals such as mercury that reach food that is subject to consistent human consumption.
    Matched MeSH terms: Water Pollutants, Chemical/toxicity*
  11. Chun TS, Malek MA, Ismail AR
    Environ Sci Process Impacts, 2014 Sep 20;16(9):2208-14.
    PMID: 25005632 DOI: 10.1039/c4em00282b
    Effluent discharge from septic tanks is affecting the environment in developing countries. The most challenging issue facing these countries is the cost of inadequate sanitation, which includes significant economic, social, and environmental burdens. Although most sanitation facilities are evaluated based on their immediate costs and benefits, their long-term performance should also be investigated. In this study, effluent quality-namely, the biological oxygen demand (BOD), chemical oxygen demand (COD), and total suspended solid (TSS)-was assessed using a biomimetics engineering approach. A novel immune network algorithm (INA) approach was applied to a septic sludge treatment plant (SSTP) for effluent-removal predictive modelling. The Matang SSTP in the city of Kuching, Sarawak, on the island of Borneo, was selected as a case study. Monthly effluent discharges from 2007 to 2011 were used for training, validating, and testing purposes using MATLAB 7.10. The results showed that the BOD effluent-discharge prediction was less than 50% of the specified standard after the 97(th) month of operation. The COD and TSS effluent removals were simulated at the 85(th) and the 121(st) months, respectively. The study proved that the proposed INA-based SSTP model could be used to achieve an effective SSTP assessment and management technique.
    Matched MeSH terms: Water Pollutants/analysis
  12. Watanabe A, Tsutsuki K, Inoue Y, Maie N, Melling L, Jaffé R
    Sci Total Environ, 2014 Sep 15;493:220-8.
    PMID: 24946034 DOI: 10.1016/j.scitotenv.2014.05.095
    As basic information for assessing reactivity and functionality of wetland-associated dissolved organic matter (DOM) based on their composition and structural properties, chemical characteristics of N in ultrafiltered DOM (UDON; >1 kD) isolated from wetland-associated rivers in three climates (cool-temperate, Hokkaido, Japan; sub-tropical, Florida, USA; tropical, Sarawak, Malaysia) were investigated. The UDON was isolated during dry and wet seasons, or during spring, summer, and autumn. The proportion of UDON present as humic substances, which was estimated as the DAX-8 adsorbed fraction, ranged from 47 to 91%, with larger values in the Sarawak than at the other sites. The yield of hydrolyzable amino acid N ranged 1.24 to 7.01 mg g(-1), which correlated positively to the total N content of UDOM and tended to be larger in the order of Florida>Hokkaido>Sarawak samples. X-ray photoelectron N1s spectra of UDON showed a strong negative correlation between the relative abundances of amide/peptide N and primary amine N. The relative abundances of amide/peptide N and primary amine N in the Sarawak samples were smaller (70-76%) and larger (20-23%) respectively compared to those (80-88% and 4-9%) in the Florida and Hokkaido samples. Assuming terminal amino groups and amide N of peptides as major constituents of primary amine N and amide/peptide N, respectively, the average molecular weight of peptides was smaller in the Sarawak samples than that in the Florida and Hokkaido samples. Seasonal variations in UDON composition were scarce in the Sarawak and Florida samples, whereas the distribution of humic substance-N and nonhumic substance-N and compositions of amino acids and N functional groups showed a clear seasonality in the Hokkaido samples. While aromatic N increased from spring to autumn, contributions from fresh proteinaceous materials were also enhanced during autumn, resulting in the highest N content of UDOM for this season.
    Matched MeSH terms: Water Pollutants, Chemical/analysis*
  13. Al-Baldawi IA, Sheikh Abdullah SR, Abu Hasan H, Suja F, Anuar N, Mushrifah I
    J Environ Manage, 2014 Jul 1;140:152-9.
    PMID: 24762527 DOI: 10.1016/j.jenvman.2014.03.007
    This study investigated the optimum conditions for total petroleum hydrocarbon (TPH) removal from diesel-contaminated water using phytoremediation treatment with Scirpus grossus. In addition, TPH removal from sand was adopted as a second response. The optimum conditions for maximum TPH removal were determined through a Box-Behnken Design. Three operational variables, i.e. diesel concentration (0.1, 0.175, 0.25% Vdiesel/Vwater), aeration rate (0, 1 and 2 L/min) and retention time (14, 43 and 72 days), were investigated by setting TPH removal and diesel concentration as the maximum, retention time within the given range, and aeration rate as the minimum. The optimum conditions were found to be a diesel concentration of 0.25% (Vdiesel/Vwater), a retention time of 63 days and no aeration with an estimated maximum TPH removal from water and sand of 76.3 and 56.5%, respectively. From a validation test of the optimum conditions, it was found that the maximum TPH removal from contaminated water and sand was 72.5 and 59%, respectively, which was a 5 and 4.4% deviation from the values given by the Box-Behnken Design, providing evidence that S. grossus is a Malaysian native plant that can be used to remediate wastewater containing hydrocarbons.
    Matched MeSH terms: Water Pollutants, Chemical/metabolism*
  14. Zahrim AY, Hilal N, Tizaoui C
    Water Sci Technol, 2013;67(4):901-6.
    PMID: 23306271 DOI: 10.2166/wst.2012.638
    Tubular nanofiltration membrane performance to treat water for reuse was carried out by choosing C.I. Acid Black 210 dye as a model dye. It has been shown that increasing pH causes reduction in irreversible fouling factor (IFF) and the dye removal is also affected by solution pH. The total organic carbon removal for pH 4, pH 7, pH 8 and pH 10 is 97.9, 92.3, 94.5 and 94.6%, respectively. The conductivity removal for pH 4, pH 7, pH 8 and pH 10 is 85.1, 88.3, 87.8 and 90.7% respectively. The increase in the initial dye concentration causes rapid increase in fouling until 100 mg/l. Then the fouling increases gradually as it reaches a maximum IFF around 13%. This study also shows that the colour of permeate changes from colourless to light greenish/yellowish (initial concentration of 2,000 and 4,000 mg/l) as the initial dye concentration increases. The conductivity removal was also reduced as the initial dye concentration increased due to screening of the Donnan effect with the presence of salt.
    Matched MeSH terms: Water Pollutants, Chemical/chemistry*
  15. Osman WH, Abdullah SR, Mohamad AB, Kadhum AA, Rahman RA
    J Environ Manage, 2013 May 30;121:80-6.
    PMID: 23524399 DOI: 10.1016/j.jenvman.2013.02.005
    A lab-scale granular activated carbon sequencing batch biofilm reactor (GAC-SBBR), a combined adsorption and biological process, was developed to treat real wastewater from a recycled paper mill. In this study, one-consortia of mixed culture (4000-5000 mg/L) originating from recycled paper mill activated sludge from Kajang, Malaysia was acclimatized. The GAC-SBBR was fed with real wastewater taken from the same recycled paper mill, which had a high concentration of chemical oxygen demand (COD) and adsorbable organic halides (AOX). The operational duration of the GAC-SBBR was adjusted from 48 h to 24, 12 and finally 8 h to evaluate the effect of the hydraulic retention time (HRT) on the simultaneous removal of COD and AOX. The COD and AOX removals were in the range of 53-92% and 26-99%, respectively. From this study, it was observed that the longest HRT (48 h) yielded a high removal of COD and AOX, at 92% and 99%, respectively.
    Matched MeSH terms: Water Pollutants, Chemical/isolation & purification*
  16. Isa NM, Aris AZ, Sulaiman WN
    Sci Total Environ, 2012 Nov 1;438:414-25.
    PMID: 23022725 DOI: 10.1016/j.scitotenv.2012.08.069
    Small islands are susceptible to anthropogenic and natural activities, especially in respect of their freshwater supply. The freshwater supply in small islands may be threatened by the encroachment of seawater into freshwater aquifers, usually caused by over pumping. This study focused on the hydrochemistry of the Kapas Island aquifer, which controls the groundwater composition. Groundwater samples were taken from six constructed boreholes for the analysis and measurement of its in-situ and major ions. The experimental results show a positive and significant correlation between Na-Cl (r=0.907; p<0.01), which can be defined as the effect of salinization. The mechanisms involved in groundwater chemistry changes were ion exchange and mineralization. These processes can be demonstrated using Piper's diagram in which the water type has shifted into a Na-HCO(3) water type from a Ca-HCO(3) water type. Saturation indices have been calculated in order to determine the saturation condition related to dissolution or the precipitation state of the aquifer bedrock. About 76% of collected data (n=108) were found to be in the dissolution process of carbonate minerals. Moreover, the correlation between total CEC and Ca shows a positive and strong relationship (r=0.995; p<0.01). This indicates that the major mineral component in Kapas Island is Ca ion, which contributes to the groundwater chemical composition. The output of this research explains the chemical mechanism attributed to the groundwater condition of the Kapas Island aquifer.
    Matched MeSH terms: Water Pollutants, Chemical/analysis*
  17. Suratman S, Hang HC, Shazili NA, Mohd Tahir N
    Bull Environ Contam Toxicol, 2009 Jan;82(1):16-9.
    PMID: 18665317 DOI: 10.1007/s00128-008-9507-5
    This paper presents a preliminary result carried out in the Besut River basin, Terengganu, Malaysia to determine the selected trace metal concentrations. Concentrations of dissolved Pb, Cu, and Fe during the present study were in the range of 3.3-8.3 microg/L Pb, 0.1-0.3 microg/L Cu, and 1.1-12.3 microg/L Fe. For the particulate fraction concentrations of Pb, Cu, and Fe ranged from 1.0 to 3.6 microg/L, 0.3 to 2.8 microg/L, and 114 to 1,537 microg/L, respectively. The concentrations of metals in this study area, in general, were lower than those reported for other study areas. Higher metal concentrations measured in the wet monsoon season suggest that the input was mainly due to terrestrial runoff.
    Matched MeSH terms: Water Pollutants, Chemical/analysis*
  18. Harino H, Arai T, Ohji M, Ismail AB, Miyazaki N
    Arch Environ Contam Toxicol, 2009 Apr;56(3):468-78.
    PMID: 18979060 DOI: 10.1007/s00244-008-9252-0
    The concentrations of butyltins (BTs) in sediment from Peninsular Malaysia along the Strait of Malacca and their spatial distribution are discussed. The concentrations of BTs were high in the southern part of Peninsular Malaysia where there is a lot of ship traffic, because trade is prosperous. The concentrations of monobutyltin (MBT), dibutyltin (DBT), and tributyltin (TBT) in sediment from the coastal waters of Peninsular Malaysia were in the range 4.1-242 microg/kg dry weight (dw), 1.1-186 microg/kg dw, and 0.7-228 microg/kg dw, respectively. A higher percentage of TBT was observed in the area where TBT concentrations were high. The concentrations of monophenyltin (MPT), diphenyltin (DPT), and triphenyltin (TPT) were in the range <0.1-121 microg/kg dw, 0.4-27 microg/kg dw, and 0.1-34 microg/kg dw in sediment from Peninsular Malaysia, respectively. MPT was the dominant phenyltin species. MBT, DBT, and TBT in green mussel (Perna viridis) samples were detected in the range 41-102 microg/kg, 3-5 microg/kg, and 8-32 microg/kg, respectively. A tolerable average residue level (TARL) was estimated at 20.4 microg/kg from a tolerable daily intake (TDI) of 0.25 microg TBTO/kg body weight/day. The maximum value of TBT detected in green mussel samples was the value near the TARL. TPTs were not detected in green mussel samples. The concentrations of Diuron and Irgarol 1051 in sediment from Peninsular Malaysia were in the range <0.1-5 microg/kg dw and <0.1-14 microg/kg dw, respectively. High concentrations of these compounds were observed in locations where the concentrations of TBT were high. Sea Nine 211, Dichlofluanid, and Pyrithiones were not detected in sediment. The concentrations of antifouling biocides in Melaka and the Strait of Johor were investigated in detail. BTs were found in similar concentrations among all sampling sites from Melaka, indicating that BT contamination spread off the coast. However, Sea Nine 211, Diuron, and Irgarol 1051 in the sediment from Melaka were high at the mouth of the river. BT concentrations at the Strait of Johor were higher than those in Peninsular Malaysia and Melaka and were high at the narrowest locations with poor flushing of water. The concentrations of antifouling biocides were compared among Malaysia, Thailand, and Vietnam. A higher concentration and wide variations of TBT and TPT in sediment from Malaysia were observed among these countries. The Irgarol 1051 concentrations in sediment from Malaysia were higher than those in Thailand and Vietnam.
    Matched MeSH terms: Water Pollutants, Chemical/analysis*
  19. Lin C, Lee CJ, Mao WM, Nadim F
    J Hazard Mater, 2009 Jan 15;161(1):270-5.
    PMID: 18456397 DOI: 10.1016/j.jhazmat.2008.03.082
    Sediment samples were analyzed for di-(2-ethylhexyl) phthalate (DEHP), an organic endocrine disruptor, in Houjing River in southern Taiwan. The average DEHP concentration at 10 sampling locations, spanning from upper, middle, and lower segments of the stream, was calculated at 3.81+/-6.36mgkg(-1)drywt. Highest concentration was recorded at the Jhongsing Bridge (20.22mgkg(-1)drywt.) near the Dashe Industrial Park, followed by the Renwu Bridge (8.93mgkg(-1)drywt.) near the Renwu Industrial Park. The surface sediment concentration of DEHP was found to be higher in the dry season (October and December), and lower in the wet (flood) season (August), indicating that sources of DEHP remained active and continued to recharge the Houjing River. Vertical sediment core analysis revealed that highest concentration occurred at the depth of 40-60cm, indicating that historical discharges of DEPH may have been higher than recent years. Domestic comparison of DEHP concentrations in sediment from highest to lowest could be categorized as northern, southern, central, and eastern Taiwan, respectively, and seemed to be positively correlated with population density and/or industrial activity. Compared to other countries, DEHP concentration of the Houjing River was relatively higher than rivers studied in Japan, Germany, Italy, and Malaysia, and was relatively lower than the Aire and Trent Rivers in the United Kingdom.
    Matched MeSH terms: Water Pollutants, Chemical/analysis*
  20. Akpan UG, Hameed BH
    J Hazard Mater, 2009 Oct 30;170(2-3):520-9.
    PMID: 19505759 DOI: 10.1016/j.jhazmat.2009.05.039
    This paper presents the review of the effects of operating parameters on the photocatalytic degradation of textile dyes using TiO2-based photocatalysts. It further examines various methods used in the preparations of the considered photocatalysts. The findings revealed that various parameters, such as the initial pH of the solution to be degraded, oxidizing agents, temperature at which the catalysts must be calcined, dopant(s) content and catalyst loading exert their individual influence on the photocatalytic degradation of any dye in wastewaters. It was also found out that sol-gel method is widely used in the production of TiO2-based photocatalysts because of the advantage derived from its ability to synthesize nanosized crystallized powder of the photocatalysts of high purity at relatively low temperature.
    Matched MeSH terms: Water Pollutants, Chemical/analysis*
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