The Zn-Al mixed metal oxide (ZnAl-MMO) with a plate-like structure was derived from Zn-Al layered double hydroxide. The ZnAl-MMO with a Zn/Al molar ratio of 3:1 exhibits superior absorption ability for H2S in a simulated coal gas at 600 ℃ due to the special structure of the ZnAl-MMO. Besides ZnS, elemental sulfur is also produced during the desulfurization process. The deactivation model could well simulate the absorption behavior of H2S. The sulfidation reaction over the sorbent shows large initial reaction rate constants (1110-5390 m3 min-1 kg-1) and low activation energy (29.5 kJ mol-1). The regeneration rate of the used sorbent can reach 99.8% under the optimum conditions. The regenerated sorbents still show high sulfur capacity (ca. 30%), implying its great application potential for industrial-scale desulfurization of the hot coal gas.
The engineering of surface oxygen vacancies (OVs) in WO3 was primitively done using a facile solvothermal method. The photocatalytic activities of the as-prepared samples were studied by evaluating their performances in the photocatalytic OER. The best sample (W-3) yielded 57.6 μmol of O2 in 6 h under the illumination of simulated sunlight.
The formation of nano pores on aluminum at 30oC- 38oC, employing a one step anodization technique which does not require removing the oxide layer formed is presented. A 20% phosphoric acid electrolyte (concentration higher than the normal anodization concentration of 5 to 10%) at a cell potential of 60 volts was used. A platinum electrode was used as the cathode electrode while the aluminum substrate as the anode electrode. A dc powered electrochemical cell to provide the required amount of current density (without the use of temperature controlled water bath) suitable or necessary for pore formation at room temperature was employed. The results obtained show that pore formation at room temperature is achievable and the pore diameter ranged between 80-120 nm.
Multicomposition of Er3+ -Y11-3+ codoped tellurite oxide, Te02-ZnO-PbO-Ti02-Na20 glass has been investigated. A detailed spectroscopic study of the Judd-Ofelt analysis has been performed from the measured absorption spectrum in order to obtain the intensity parameters S2, (t=2, 4, 6). The calculated S2, values were then utilized in the determination of transition probabilities, radiative lifetimes and branching ratios of the Er3+ transitions between the J(upper)-J'(lower) manifolds. Both visible upconversion and near-infrared spectra were characterized under the 980 nm laser diode excitation at room temperature.
In this study, graphene oxide (Go) filled epoxy nanocomposites were prepared using hot pressed method. The GO was produced using modified Hummers' method. The produced GO at different compositions (0.1, 0.3 and 0.5 wt%) were mixed with epoxy before the addition of hardener using ultra-sonication. The produced epoxy nanocomposites were characterized in terms of mechanical and thermal properties. The mechanical properties of the nanocomposites were significantly enhanced by the addition of GO. About 50% of increment in the flexural strength of the composite sample filled with 03 wt% of GO as compared to the neat epoxy sample. However, only slight improvement in the impact strength of the composite were obtained by adding 0.1 wt% of GO.
Nanocomposite thin films of chitosanlgraphene oxide (cs/Go) and chitosanl EDTA-GO (CSIEDTA-GO) were prepared by environmental friendly method and the properties were compared. The experimental results showed fine dispersion of GO and EDTA-GO in CS matrix and some interaction occur between the filler and the CS matrix that leads to better distribution of stress transfer. At 0.5 wt. %, both CSIGO and CSIEDTA-GO experienced maximum tensile stress by 51 and 71% compared with CS. Moreover, the elongation at break for both nanocomposites increases and the amount of filler increases.
Elektrod komposit dwilogam yang disediakan hasil campuran serbuk argentums (Ag) dan 'carbon (C) (dinamakan AgC-Pvc) memberikan hasil elektrolisis larutan pewarna C. I. Reactive Orange 4 (R04) yang tidak berwarna dan tanpa penghasilan enapan lumpur berbanding elektrod komposit dwilogam lain. Perbezaan nisbah komposisi serbuk Ag:C (30:70, 50:50 and 70:30) dalam penyediaan elektrod seterusnya diuji untuk melihat kesan perbezaan komposisi ini terhadap penyahwarnaan R04. Melalui persamaan Tafel yang diperoleh, elektrod Ag285C 665-PVC 5 yang menggunakan komposisi 30% Ag dan 70% C memberikan nilai perubahan ketumpatan arus, io yang lebih tinggi iaitu 3.555 mAl cm2 berbanding elektrod lain. Elektrod ini mempunyai aktiviti pemangkinan elektrokimia yang lebih baik berbanding elektrod lain. Hasil proses elektrolisis elektrod Ag285C66.5-PVC 5 terhadap larutan RO4 telah dianalisis menggunakan spektrofotometer uv-Nampak dan didapati proses degredasi kumpulan azo dalam pewarna tersebut telah berlaku selepas proses elektrolisis yang menghasilkan larutan tidak berwarna.
Addition of chemical binders such as lime and cement improves the strength and stiffness
of fine grained soils. However, the treated soils exhibit brittle stress-strain behaviour.
Inclusion of randomly oriented discrete fibers in the soil-binder mixture changes its brittle
behaviour into ductile behaviour. Most synthetic fibers, however, tend to get entangled
and cannot be easily separated from one another. Therefore, it is difficult to realize soilbinder-
fiber mixtures in which the fibers are distributed uniformly throughout the mass.
This issue has been an impediment in the utilization of the positive modification in the
behaviours of soils and soil-binder mixtures by the fibers. The present study aims to address
the limitations in using fibers as soil reinforcement. Further, it also aims to investigate
the use of synthetic mesh or net elements as an alternative type of soil reinforcement.
The paper presents the experimental study on a fine grained soil. Lime has been chosen
as the binder due to its low cost and the scarcity of fiber reinforced soil studies in which
lime has been used as a binder. The main experimental program is a series of unconfined
compression tests on samples prepared using untreated soil, soil-reinforcement mixture,
soil-lime mixture, and soil-lime-reinforcement mixture. The lime treated samples were
cured up to 120 days at laboratory temperature. The results demonstrate the combinational
effects of lime and discrete reinforcement
elements on the behaviour and mechanical
properties of the soil. The performances of
the fiber and mesh element reinforcements
have also been compared.
Fast pyrolysis is a potential technology for converting lignocellulosic biomass into bio-oil. Nevertheless, the high amounts of acid, oxygenated compounds, and water content diminish the energy density of the bio-oil and cause it to be unsuitable for direct usage. Catalytic fast pyrolysis (CFP) is able to improve bio-oil properties so that downstream upgrading processes can be economically feasible. Here, calcium oxide (CaO), magnesium oxide (MgO), and zinc oxide (ZnO) were employed due to their potential in enhancing bio-oil properties. The results showed that overall, all three catalysts positively impacted the empty fruit bunch fibre-derived bio-oil properties. Among the catalysts, CaO showed the most favorable effects in terms of reducing the acidity of the bio-oil and anhydrosugar. Thermal stability of bio-oils produced in the presence of CaO was studied as well.
Since 5-sulfosalicylic acid (SFA) has been increasingly released to the environment, SO4--based oxidation processes using Oxone have been considered as useful methods to eliminate SFA. As Co3O4 has been a promising material for OX activation, the four 3D Co3O4 catalysts with distinct morphologies, including Co3O4-C (with cubes), Co3O4-P (with plates), Co3O4-N (with needles) and Co3O4-F (with floral structures), are fabricated for activating OX to degrade SFA. In particular, Co3O4-F not only exhibits the highest surface area but also possesses the abundant Co2+ and more reactive surface, making Co3O4-F the most advantageous 3D Co3O4 catalyst for OX activation to degrade SFA. The mechanism of SFA by this 3D Co3O4/OX is also investigated and the corresponding SFA degradation pathway has been elucidated. The catalytic activities of Co3O4 catalysts can be correlated to physical and chemical properties which were associated with particular morphologies to provide insights into design of 3D Co3O4-based catalysts for OX-based technology to degrade emerging contaminants, such as SFA.
The durability of natural and treated clay soil stabilized with lime and alkaline activation (AA) affected by environmental factors (hot and humid) was determined in this study. Investigation and evaluation on the strength of the soil, moisture content, and volume change of the specimen were determined at each curing period (7, 28, and 90 days) based on the weather conditions. An unconfined compressive strength (UCS) of the specimen at three different wetting/drying cycles (one, three, and five cycles) was determined. The findings show that the strength of the treated specimens fluctuated with increment and decrement strength (one and three cycles) in the range of 1.41 to 1.88 MPa (lime) and 2.64 to 8.29 MPa (AA), while for five cycles with a curing period of 90 days the decrement was in the range of 1.62 to 1.25 MPa and 6.06 to 5.89 MPa for lime and AA, respectively. The decrement percentage for treated samples that were subjected to five cycles of wetting and drying in 90 days was found to be 20.38% (lime) and 38.64% (AA), respectively. Therefore, it can be summarized that wetting/drying cycles have a significant influence on the durability, strength, and the volume changes of the specimens.
Sole nanomaterials or nanomaterials bound to specific biomolecules have been proposed to regulate the immune system. These materials have now emerged as new tools for eliciting immune-based therapies to treat various cancers. Graphene, graphene oxide (GO) and reduced GO (rGO) are the latest nanomaterials among other carbon nanotubes that have attracted wide interest among medical industry players due to their extraordinary properties, inert-state, non-toxic and stable dispersion in a various solvent. Currently, GO and rGO are utilized in various biomedical application including cancer immunotherapy. This review will highlight studies that have been carried out in elucidating the stimulation of GO and rGO on selected innate and adaptive immune cells and their effect on cancer progression to shed some insights for researchers in the development of various GO- and rGO-based immune therapies against various cancers.
Metal nanoparticles prepared by exsolution at the surface of perovskite oxides have been recently shown to enable new dimensions in catalysis and energy conversion and storage technologies owing to their socketed, well-anchored structure. Here we show that contrary to general belief, exsolved particles do not necessarily re-dissolve back into the underlying perovskite upon oxidation. Instead, they may remain pinned to their initial locations, allowing one to subject them to further chemical transformations to alter their composition, structure and functionality dramatically, while preserving their initial spatial arrangement. We refer to this concept as chemistry at a point and illustrate it by tracking individual nanoparticles throughout various chemical transformations. We demonstrate its remarkable practical utility by preparing a nanostructured earth abundant metal catalyst which rivals platinum on a weight basis over hundreds of hours of operation. Our concept enables the design of compositionally diverse confined oxide particles with superior stability and catalytic reactivity.
Despite the many attractive potential uses of ceramic materials as humidity sensors, some unavoidable drawbacks, including toxicity, poor biocompatibility, long response and recovery times, low sensitivity and high hysteresis have stymied the use of these materials in advanced applications. Therefore, in present investigation, we developed a capacitive humidity sensor using lead-free Ca,Mg,Fe,Ti-Oxide (CMFTO)-based electro-ceramics with perovskite structures synthesized by solid-state step-sintering. This technique helps maintain the submicron size porous morphology of the developed lead-free CMFTO electro-ceramics while providing enhanced water physisorption behaviour. In comparison with conventional capacitive humidity sensors, the presented CMFTO-based humidity sensor shows a high sensitivity of up to 3000% compared to other materials, even at lower signal frequency. The best also shows a rapid response (14.5 s) and recovery (34.27 s), and very low hysteresis (3.2%) in a 33%-95% relative humidity range which are much lower values than those of existing conventional sensors. Therefore, CMFTO nano-electro-ceramics appear to be very promising materials for fabricating high-performance capacitive humidity sensors.
Perovskite solar cells based on series of inorganic cesium lead bromide and iodide mixture, CsPbBr3-xI x , where x varies between 0, 0.1, 0.2, and 0.3 molar ratio were synthesized by two step-sequential deposition at ambient condition to design the variations of wide band gap light absorbers. A device with high overall photoconversion efficiency of 3.98 % was obtained when small amount of iodide (CsPbBr2.9I0.1) was used as the perovskite and spiro-OMeTAD as the hole transport material (HTM). We investigated the origin of variation in open circuit voltage, Voc which was shown to be mainly dependent on two factors, which are the band gap of the perovskite and the work function of the HTM. An increment in Voc was observed for the device with larger perovskite band gap, while keeping the electron and hole extraction contacts the same. Besides, the usage of bilayer P3HT/MoO3 with deeper HOMO level as HTM instead of spiro-OMeTAD, thus increased the Voc from 1.16 V to 1.3 V for CsPbBr3 solar cell, although the photocurrent is lowered due to charge extraction issues. The stability studies confirmed that the addition of small amount of iodide into the CsPbBr3 is necessarily to stabilize the cell performance over time.
2D perovskites is one of the proposed strategies to enhance the moisture resistance, since the larger organic cations can act as a natural barrier. Nevertheless, 2D perovskites hinder the charge transport in certain directions, reducing the solar cell power conversion efficiency. A nanostructured mixed-dimensionality approach is presented to overcome the charge transport limitation, obtaining power conversion efficiencies over 9%.
Natural enzymes possess several drawbacks which limits their application in industries, wastewater remediation and biomedical field. Therefore, in recent years researchers have developed enzyme mimicking nanomaterials and enzymatic hybrid nanoflower which are alternatives of enzyme. Nanozymes and organic inorganic hybrid nanoflower have been developed which mimics natural enzymes functionalities such as diverse enzyme mimicking activities, enhanced catalytic activities, low cost, ease of preparation, stability and biocompatibility. Nanozymes include metal and metal oxide nanoparticles mimicking oxidases, peroxidases, superoxide dismutase and catalases while enzymatic and non-enzymatic biomolecules were used for preparing hybrid nanoflower. In this review nanozymes and hybrid nanoflower have been compared in terms of physiochemical properties, common synthetic routes, mechanism of action, modification, green synthesis and application in the field of disease diagnosis, imaging, environmental remediation and disease treatment. We also address the current challenges facing nanozyme and hybrid nanoflower research and the possible way to fulfil their potential in future.
In this study, structural, electronic, optical, thermoelectric, and thermodynamics properties of vacancy-ordered double perovskites Rb2 XCl6 (X = Se, Ti) were explored theoretically. The results revealed that Rb2SeCl6 and Rb2 TiCl6 are indirect band gap (Eg ) semiconductors with Eg values of 2.95 eV, and 2.84 eV respectively. The calculated properties (phonons, elastic constant, Poisson's ratio, and Pugh's ratio) revealed that both materials are dynamically and chemically stable and can exhibit brittle (Rb2 SeCl6 ) and ductile (Rb2 TiCl6 ) nature. From the analysis of optical parameters, it was noticed that the refractive index of the materials has a value of 1.5-2.0 where light absorption was found from the visible to the ultraviolet region. The thermoelectric properties determined by using the BoltzTrap code demonstrated that at room temperature, the Figure of merit (ZT) was found to be 0.74 and 0.76 for Rb2 SeCl6 and Rb2 TiCl6 , respectively. Despite a moderate value of ZT in such materials, further studies might explore effective methods for tuning the electronic band gap and improving the thermoelectric response of the material for practical energy production applications.
The present study examines the synthesis of Co3O4 ultra-nanosheets (Co3O4 UNSs) and Co3O4 ultra-nanosheet-Ni(OH)2 (Co3O4 UNS-Ni(OH)2) via solvothermal process and their application as non-enzymatic electrochemical sensors for glucose detection. X-ray diffraction and transmission electron microscopy results confirmed the Co3O4 UNS deposition on Ni(OH)2 surface. The presence of Co3O4 UNSs on Ni (OH) 2 surface improved the sensitivity of glucose detection, from the increase of glucose oxidation peak current at the Co3O4 UNS-Ni(OH)2/glassy carbon electrode (current density: 2000μA·cm(-2)), compared to the Co3O4 UNSs. These results confirmed that Ni(OH)2 on glassy carbon electrode is a sensitive material for glucose detection, moreover the Co3O4 UNSs can increase the interaction and detection of glucose due to their high surface area. The estimated limit of detection (S/N=3) and limit of quantification (S/N=10) of the linear segment (5-40μM) are 1.08μM and 3.60μM respectively. The reproducibility experiments confirmed the feasibility of Co3O4 UNS-Ni(OH)2 for the quantitative detection of certain concentration ranges of glucose.
During the process and operation of the dyes, the wastes produced were commonly found to contain organic and inorganic impurities leading to risks in the ecosystem and biodiversity with the resultant impact on the environment. Improper effluent disposal in aqueous ecosystems leads to reduction of sunlight penetration which in turn diminishes photosynthetic activity, resulting in acute toxic effects on the aquatic flora/fauna and dissolved oxygen concentration. Recently, photodegradation of various synthetic dyes has been studied in terms of their absorbance and the reduction of oxygen content by changes in the concentration of the dye. The advantages that make photocatalytic techniques superior to traditional methods are the ability to remove contaminates in the range of ppb, no generation of polycyclic compounds, higher speed, and lower cost. Semiconductor metal oxides, typically TiO2, ZnO, SnO, NiO, Cu2O, Fe3O4, and also CdS have been utilized as photocatalyst for their nontoxic nature, high photosensitivity, wide band gap and high stability. Various process parameters like photocatalyst dose, pH and initial dye concentrations have been varied and highlighted. Research focused on surface modification of semiconductors and mixed oxide semiconductors by doping them with noble metals (Pt, Pd, Au, and Ag) and organic matter (C, N, Cl, and F) showed enhanced dye degradation compared to corresponding native semiconductors. This paper reviews recent advances in heterogeneous photocatalytic decolorization for the removal of synthetic dyes from water and wastewater. Thus, the main core highlighted in this paper is the critical selection of semiconductors for photocatalysis based on the chemical, physical, and selective nature of the poisoning dyes.