Displaying publications 141 - 160 of 383 in total

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  1. Abdul Wahab MF, Mohamad Ghani NI, Kuppuswamy R
    Forensic Sci Int, 2012 Nov 30;223(1-3):53-63.
    PMID: 22955030 DOI: 10.1016/j.forsciint.2012.07.020
    Most of the automotive companies use cast iron for their engine blocks. Restoration of obliterated number on these iron surfaces by chemical etching is known to be quite difficult. Heating of the obliterated surface using oxyacetylene flame is an alternative recovery treatment suggested in literature and used in practice. However chemical etching has been established to be the most sensitive technique for detection of metal deformation present under stamped serial numbers. Hence, the current work investigated the suitability of some common etchants on cast iron surfaces with a view to determining the most suitable one for revealing the obliterated marks. The reagents tested were mostly copper containing Fry's reagent and its modifications. Two cast iron engine blocks (3.29%C and 3.1%C) of two cars--a Proton Saga and a Toyota--were utilized for the experiments. The engine blocks were cut into several small plates and each plate was stamped with some numerical characters at 8 kN load using Instron Table Mounted Universal Testing Machine. The depth of stamping impression varied between 0.2 mm and 0.3 mm. The stamped number was completely ground off manually using a metal file. The grounded surface was then polished smooth using emery papers and etched with a few selected reagents mostly by swabbing. Experimental results showed that a modified Fry's composition consisting of 4 5g CuCl(2), 100 mL HCl, and 180 mL H(2)O restored the number with better contrast at a reasonably shorter time. The above reagent is a slightly modified form of one of the Fry's original compositions--45 g CuCl(2), 180 mL HCl, and 100 mL H(2)O. Quite importantly the proposed reagent restored the original stamped numbers of both Proton and Toyota cars and also a Mitsubishi car that had been obliterated. The most widely used Fry's composition (90 g CuCl(2), 120 mL HCl and 100 mL H(2)O), although recovered the obliterated number, did not cause the desired contrast.
    Matched MeSH terms: Copper
  2. Wan Ngah WS, Hanafiah MA
    J Environ Sci (China), 2008;20(10):1168-76.
    PMID: 19143339
    The efficiency of sodium hydroxide treated rubber (Hevea brasiliensis) leaves powder (NHBL) for removing copper ions from aqueous solutions has been investigated. The effects of physicochemical parameters on biosorption capacities such as stirring speed, pH, biosorbent dose, initial concentrations of copper, and ionic strength were studied. The biosorption capacities of NHBL increased with increase in pH, stirring speed and copper concentration but decreased with increase in biosorbent dose and ionic strength. The isotherm study indicated that NHBL fitted well with Langmuir model compared to Freundlich and Dubinin-Radushkevich models. The maximum biosorption capacity determined from Langmuir isotherm was 14.97 mg/g at 27 degrees C. The kinetic study revealed that pseudosecond order model fitted well the kinetic data, while Boyd kinetic model indicated that film diffusion was the main rate determining step in biosorption process. Based on surface area analysis, NHBL has low surface area and categorized as macroporous. Fourier transform infrared (FT-IR) analyses revealed that hydroxyl, carboxyl, and amino are the main functional groups involved in the binding of copper ions. Complexation was one of the main mechanisms for the removal of copper ions as indicated by FT-IR spectra. Ion exchange was another possible mechanism since the ratio of adsorbed cations (Cu2+ and H+) to the released cations (Na+, Ca2+, and Mg2+) from NHBL was almost unity. Copper ions bound on NHBL were able to be desorbed at > 99% using 0.05 mol/L HCl, 0.01 mol/L HNO3, and 0.01 mol/L EDTA solutions.
    Matched MeSH terms: Copper/isolation & purification*; Copper/metabolism*; Copper/pharmacology
  3. Vikneswaran R, Syafiq MS, Eltayeb NE, Kamaruddin MN, Ramesh S, Yahya R
    PMID: 26046495 DOI: 10.1016/j.saa.2015.05.087
    Copper ion recognition and DNA interaction of a newly synthesized fluorescent Schiff base (HPyETSC) were investigated using UV-vis and fluorescent spectroscopy. Examination using these two techniques revealed that the detection of copper by HPyETSC is highly sensitive and selective, with a detection limit of 0.39 μm and the mode of interaction between HPyETSC and DNA is electrostatic, with a binding constant of 8.97×10(4) M(-1). Furthermore, gel electrophoresis studies showed that HPyETSC exhibited nuclease activity through oxidative pathway.
    Matched MeSH terms: Copper
  4. Lim YY, Lim KH
    J Colloid Interface Sci, 1997 Dec 01;196(1):116-9.
    PMID: 9441659
    Micellar properties of binary mixed surfactants of a surface active mixed copper(II) chelate, [Cu(C12-tmed)(acac)Cl] (where C12-tmed is N,N,N'-trimethyl-N'-dodecylethylenediamine) with three common surfactants, viz. sodium dodecyl sulfate (SDS), cetyltrimethylammonium bromide (CTAB), and octaethylene glycol monododecyl ether (C12E8), were investigated by surface tensiometry, ESR, and UV-visible absorption techniques. The surface tension data were treated with Rubingh's method for mixed micelle formation and Rosen's method for mixed monolayer formation at the aqueous solution/air interface. It was found that in the mixed micelle there is strong attractive interaction between cationic copper surfactant and anonic dodecyl sulfate while there is almost ideal mixing between copper surfactant and CTAB and C12E8. From the ESR and UV-visible studies, a mixed block-type arrangement of head groups is proposed. Copyright 1997 Academic Press. Copyright 1997Academic Press
    Matched MeSH terms: Copper
  5. Wong MK, Koh LL
    Biol Trace Elem Res, 1986 Aug;10(2):91-7.
    PMID: 24254355 DOI: 10.1007/BF02795561
    Ninety-nine samples of common Chinese medicines were purchased from Chinese medical shops in Singapore and Malaysia and analyzed for mercury, lead, copper, cadmium, cobalt, iron, and nickel. The majority of these medicines were manufactured in China, Hong Kong, and Malaysia. A few of them were of Singapore and Taiwan origin. Atomic absorption method (both flame and flameless) was used for the analyses. Mercury was found to be present in high concentrations in several of the medicines that were for oral consumption.
    Matched MeSH terms: Copper
  6. Khan MZU, Uddin E, Akbar B, Akram N, Naqvi AA, Sajid M, et al.
    Nanomaterials (Basel), 2020 Sep 09;10(9).
    PMID: 32916991 DOI: 10.3390/nano10091796
    A new micro heat exchanger was analyzed using numerical formulation of conjugate heat transfer for single-phase fluid flow across copper microchannels. The flow across bent channels harnesses asymmetric laminar flow and dean vortices phenomena for heat transfer enhancement. The single-channel analysis was performed to select the bent channel aspect ratio by varying width and height between 35-300 μm for Reynolds number and base temperature magnitude range of 100-1000 and 320-370 K, respectively. The bent channel results demonstrate dean vortices phenomenon at the bend for Reynolds number of 500 and above. Thermal performance factor analysis shows an increase of 18% in comparison to straight channels of 200 μm width and height. Alumina nanoparticles at 1% and 3% concentration enhance the Nusselt number by an average of 10.4% and 23.7%, respectively, whereas zirconia enhances Nusselt number by 16% and 33.9% for same concentrations. On the other hand, thermal performance factor analysis shows a significant increase in pressure drop at high Reynolds number with 3% particle concentration. Using zirconia for nanofluid, Nusselt number of the bent multi-channel model is improved by an average of 18% for a 3% particle concentration as compared to bent channel with deionized water.
    Matched MeSH terms: Copper
  7. Rahman ML, Fui CJ, Ting TX, Sarjadi MS, Arshad SE, Musta B
    Polymers (Basel), 2020 Oct 29;12(11).
    PMID: 33137923 DOI: 10.3390/polym12112521
    Industrial operations, domestic and agricultural activities worldwide have had major problems with various contaminants caused by environmental pollution. Heavy metal pollution in wastewater also a prominent issue; therefore, a well built and economical treatment technology is demanded for pollution-free wastewater. The present work emphasized pure cellulose extracted from jute fiber and further modification was performed by a free radical grafting reaction, which resulted in poly(methyl acrylate) (PMA)-grafted cellulose and poly(acrylonitrile)-grafted cellulose. Subsequently, poly(hydroxamic acid) and poly(amidoxime) ligands were prepared from the PMA-grafted cellulose and PAN-grafted cellulose, respectively. An adsorption study was performed using the desired ligands with heavy metals such as copper, cobalt, chromium and nickel ions. The binding capacity (qe) with copper ions for poly(hydroxamic acid) is 352 mg g-1 whereas qe for poly(amidoxime) ligand it was exhibited as 310 mg g-1. Other metal ions (chromium, cobalt and nickel) show significance binding properties at pH 6. The Langmuir and Freundlich isotherm study was also performed. The Freundlich isotherm model showed good correlation coefficients for all metal ions, indicating that multiple-layers adsorption was occurred by the polymer ligands. The reusability was evaluated and the adsorbents can be reused for 7 cycles without significant loss of removal performance. Both ligands showed outstanding metals removal capacity from the industrial wastewater as such 98% of copper can be removed from electroplating wastewater and other metals (cobalt, chromium, nickel and lead) can also be removed up to 90%.
    Matched MeSH terms: Copper
  8. Nicodemus Ujih, M.B., Mohammad Isa Mohamadin, Millaa Armila Asli, Bebe Norlita Mohamed
    Scientific Research Journal, 2017;14(1):15-27.
    MyJurnal
    Heavy metal ions contamination has become more serious which is caused
    by the releasing of toxic waterfrom industrial area and landfill that are very
    harmful to all living organism especially human and can even cause death
    if contaminated in small amount of heavy metal concentration. Currently,
    peoples are using classic method namely electrochemical treatment,
    chemical oxidation/reduction, chemical precipitation and reverse osmosis
    to eliminate the metal ions from toxic water. Unfortunately, these methods
    are costly and not environmentally friendly as compared to bioadsorption
    method, where agricultural waste is used as biosorbent to remove heavy
    metals. Two types of agricultural waste used in this research namely oil
    palm mesocarp fiber (Elaesis guineensis sp.) (OPMF) and mangrove bark
    (Rhizophora apiculate sp.) (MB) biomass. Through chemical treatment,
    the removal efficiency was found to improve. The removal efficiency is
    examined based on four specification namely dosage, of biosorbent to
    adsorb fourtypes of metalsion explicitly nickel, lead, copper, and chromium.
    The research has found that the removal efficiency of MB was lower than
    OPMF; whereas, the multiple metals ions removal efficiency decreased in
    the order of Pb2+ > Cu2+ > Ni2+ > Cr2+.
    Matched MeSH terms: Copper
  9. Palihakkara CR, Dassanayake S, Jayawardena C, Senanayake IP
    J Health Pollut, 2018 Mar;8(17):14-19.
    PMID: 30524845 DOI: 10.5696/2156-9614-8.17.14
    Background: Acid mine drainage (AMD) is a major environmental impact associated with the mining industry. Elevated acidic conditions resulting from the discharge of AMD into the surrounding environment can cause heavy metals to dissolve and transport through water streams and accumulate in the aquatic environment, posing a risk to the health of living organisms. There have been several novel approaches in the remediation of AMD involving passive treatment techniques. The constructed treatment wetland approach is a passive remediation option that has proven to be a cost effective and long-lasting solution in abating toxic pollutant concentrations.

    Objectives: The present study investigates the applicability of water hyacinth (Eichhornia crassipes), a tropical aquatic plant with reported heavy metal hyper-accumulation in microcosm floating wetland treatment systems designed to remediate AMD with copper (Cu) and cadmium (Cd) concentrations exceeding threshold limits.

    Methods: Twelve water hyacinth samples were prepared with varying concentrations of Cu (1 mg/L, 2 mg/L, 4 mg/L) and Cd (0.005 mg/L, 0.01 mg/L, 0.02 mg/L). Water samples of 5 ml each were collected from each sample at 24-hour intervals for analysis with an atomic absorption spectrometer.

    Results: Plant growth varied according to Cu and Cd concentrations and no plants survived for more than 14 days. There was a significant discrepancy in the rate at which the Cd concentrations abated. The rate of reduction was rapid for higher concentrations and after 24 hours a substantial reduction was achieved. There was a reduction in Cu concentration after the first 24-hour period, and after the next 24-hour period the concentrations were again elevated in the samples at initial concentrations of 2 mg/L and A4 mg/L. 4 mg/L Cu concentration was shown to be toxic to the plants, as they had low accumulations and rapid dying was evident.

    Conclusions: Water hyacinth has the capability to reduce both Cu and Cd concentrations, except at an initial concentration of 4 mg/L of Cu, which was toxic to the plants.

    Competing Interests: The authors declare no competing financial interests.

    Matched MeSH terms: Copper
  10. Al'Abri AM, Abdul Halim SN, Abu Bakar NK, Saharin SM, Sherino B, Rashidi Nodeh H, et al.
    J Environ Sci Health B, 2019;54(12):930-941.
    PMID: 31407615 DOI: 10.1080/03601234.2019.1652072
    This article demonstrates the first application of a copper-based porous coordination polymer (BTCA-P-Cu-CP) as a carbon paste electrode (CPE) modifier for the detection of malathion. The electrochemical behavior of BTCA-P-Cu-CP/CPE was explored using cyclic voltammetry (CV) while chrono-amperometry methods were applied for the analytical evaluation of the sensor performance. Under optimized conditions, the developed sensor exhibited high reproducibility, stability, and wide dynamic range (0.6-24 nM) with the limits of detection and sensitivity equal to 0.17 nM and 5.7 µAnMcm-1, respectively, based on inhibition signal measurement. Furthermore, the presence of common coexisting interfering species showed a minor change in signals (<4.4%). The developed sensor has been applied in the determination of malathion in spiked vegetable extracts. It exhibited promising results in term of fast and sensitive determination of malathion in real samples at trace level with recoveries of 91.0 to 104.4%. (RSDs < 5%, n = 3). A comparison of the two studied techniques showed that the HPLC technique is unable to detect malathion when the concentration is lower than 1.8 µM while 0.006 µM is detected with appropriate RSDs 0.2-5.2% (n = 3) by amperometric method. Due to the high sensitivity and selectivity, this new electrochemical sensor will be useful for monitoring trace malathion in real samples.
    Matched MeSH terms: Copper
  11. Aslina A. Bakar, Amirul A. Mustafa, Ahmad R. Razali, Norhayati Mutalib, Amirudin Ibrahim
    ESTEEM Academic Journal, 2020;16(2):75-87.
    MyJurnal
    This study aims to investigate the bending effects on the flexible wearable antenna by using copper nanowires and polydimethylsiloxane (PDMS). This project focuses on the bending effect on the proposed wearable antenna in the presence of skin tissue and at free space. The radiation characteristics were simulated and analyzed when the antenna was under flat and bent conditions. The performance result of return loss and radiation pattern (Efield and H-field) of proposed wearable antenna was analyzed. The material for the proposed antenna is designed to be flexible and wearable for the application of body-centric wireless communication (BCWCs) at the frequency of 2.45 GHz with the approval specifications of industrial, scientific and medical (ISM) band. Radiator for the proposed wearable antenna is fabricated using copper nanowire, and the antenna substrate is by using polydimethylsiloxane (PDMS). The performance result of the proposed wearable antenna was simulated by using CST microwave studio. From the simulated result for different bending angles, a conclusion was drawn that bending of structure can improve the impedance matching and return loss during the bent condition. However, the resonant frequency tends to shift as the antenna is bent up to 50°. At the critical angle of 70°, the frequency is shifted to a lower frequency.
    Matched MeSH terms: Copper
  12. Raju G, Mas Haris MRH, Azura AR, Ahmed Mohamed Eid AM
    ACS Omega, 2020 Nov 10;5(44):28760-28766.
    PMID: 33195929 DOI: 10.1021/acsomega.0c04081
    The slow-release mechanism of copper into soil followed by soil biodegradation was studied using the chitosan (CTS)/epoxidized natural rubber (ENR) biocomposite. The biocomposite was prepared by homogenizing CTS in ENR50 (ENR with about 50% epoxy content) latex in the presence of curing agents and acetic acid. It was found that the adsorption property of the biocomposite was very much influenced by chitosan loading, where 20phrCTS-t-ENR biocomposite can absorb 76.31% of Cu(II) ions. The desorption study indicates that the copper (II) ion can be released at a very slow and control phase as proven by the kinetic study using zero-order, first-order, Higuchi, and Korsmeyer Peppas equations. The slow-release studies comply with the Higuchi square-root equation, indicating that the release process is diffusion-controlled. Results of desorption and biodegradation process suggest that this biocomposite has the potential use of being a slow-release matrix in the field of agriculture.
    Matched MeSH terms: Copper
  13. Rajendran SD, Wahab SN, Yeap SP
    Saf Health Work, 2020 Dec;11(4):537-542.
    PMID: 33329921 DOI: 10.1016/j.shaw.2020.06.007
    Background: Personal protective equipment (PPE) has been designed in such a way to reduce accident rates. Unfortunately, existing PPE is rather ineffective as it is not able to provide warning signals when hazard is around. The integration of intelligent systems is envisaged to increase the efficiency of existing PPE.

    Methods: This project designed a safety vest incorporated with metal detectors which can provide immediate warning to the field workers when there is metal hazard around. This product has greater freedom of design via smart manufacturing as it involves the assembly of few commercially available parts into a single entity. Briefly, the metal detector is a do it yourself (DIY) kit, and the safety vest is purchasable from any local market. The DIY kit was connected to a copper coil and being sewed into the safety vest.

    Results: The metal detector induces beeping sound when there is metal hazard around. A total of 121 engineering students were introduced to the prototype before being requested to answer a survey associated with the design. Respondents have rated >3.00/5.00 for the design simplicity, ease of usage, and light weight. Meanwhile, respondents suggested that the design should be further improved by increasing the metal detection range.

    Conclusion: It is envisaged that the introduction of this smart safety vest will allow the workers to carry out their duties securely by reducing the accident rates. Particularly, such design is expected to reduce workplace accident especially during night time at construction sites where the visibility is low.

    Matched MeSH terms: Copper
  14. Almessiere MA, Trukhanov AV, Slimani Y, You KY, Trukhanov SV, Trukhanova EL, et al.
    Nanomaterials (Basel), 2019 Feb 04;9(2).
    PMID: 30720737 DOI: 10.3390/nano9020202
    In this work, Sr0.3Ba0.4Pb0.3Fe12O19/(CuFe₂O₄)x (x = 2, 3, 4, and 5) as strongly exchange-coupled nanosized ferrites were fabricated using a one-pot sol⁻gel combustion method (citrate sol-gel method). The X-ray diffraction (XRD) powder patterns of the products confirmed the occurrence of pure, exchange-coupled ferrites. Frequency dependencies of the microwave characteristics (MW) were investigated using a co-axial method. The non-linear behavior of the MW with the composition transformation may be due to different degrees of Fe ion oxidation on the spinel/hexaferrite grain boundaries and strong exchange coupling during the hard and soft phases.
    Matched MeSH terms: Copper
  15. Ali SKI, Khandaker MU, Al-Mugren KS, Latif SA, Bradley DA, Okhunov AA, et al.
    Appl Radiat Isot, 2021 Jul;173:109735.
    PMID: 33915407 DOI: 10.1016/j.apradiso.2021.109735
    Copper-67 (T1/2 = 61.83 h, Eβ-mean=141 keV, Iβ-total=100%; Eγ = 184.577 keV, Iγ = 48.7%) is a promising radionuclide for theranostic applications especially in radio immunotherapy. However, one of the main drawbacks for its application is related to its limited availability. Various nuclear reaction routes investigated in the last years can result in 67Cu production, although the use of proton beams is the method of choice taken into account in this work. The goal of this work is a revision of the cross-sections aimed at 67Cu yield, which were evaluated for the 68Zn(p,2p)67Cu reaction route up to 80 MeV proton energy. A well-defined statistical procedure, i.e., the Simultaneous Evaluation on KALMAN (SOK), combined with the least-squares concept, was used to obtain the evaluated data together with the covariance matrix. The obtained evaluated data were also compared to predictions provided by the nuclear reaction model codes TALYS and EMPIRE, and a partial agreement among them has been found. These data may be useful for both existing and potential applications in nuclear medicine, to achieve an improvement and validation of the various nuclear reaction models, and may also find applications in other fields (e.g., activation analysis and thin layer activation).
    Matched MeSH terms: Copper Radioisotopes
  16. Arina Nasruddin, Azura Amid, Muhd Ezza Faiez Othman
    MyJurnal
    Green chemical method was applied to synthesize nanoparticles using recombinant
    bromelain. Among the numerous applications of recombinant bromelain, there is still no research
    on nanoparticles synthesis which encourages its utilization in this study. Four chemicals which are
    copper (II) chloride dihydrate (CuCl2.2H2O), cerium nitrate hexahydrate (Ce(NO3)3.6H2O), sodium
    selenite (Na2SeO3), and iron (III) chloride hexahydrate (FeCl3.6H2O) were selected to be screened
    for the suitability in nanoparticles biosynthesis by recombinant bromelain. The nanoparticles
    formed were characterized by using UV-visible absorption spectra. The biosynthesis process then
    was optimized by varying the centrifugation speed, temperature, and time to get the maximum
    absorption and weight of nanoparticles through central composite design (CCD) tool. Only
    CuCl2.2H2O showed a positive result for the screening process which was represented by the
    formation of colloidal solution and a maximum absorption at 580 nm. Thus, optimization was
    carried out for this chemical. Based on the optimization model, maximum absorption and weight
    were predicted at 67.5°C, 2 hrs, and 9,600 rpm. These optimal conditions were validated by
    repeating the biosynthesis process. The absorption and weight of the nanoparticles depended on the
    reaction of the chemical with recombinant bromelain. 3D plots showed that the optimal condition
    for high responses mostly depends on temperature and time.
    Matched MeSH terms: Copper
  17. Hussin R, Sharif S, Nabiałek M, Zamree Abd Rahim S, Khushairi MTM, Suhaimi MA, et al.
    Materials (Basel), 2021 Feb 01;14(3).
    PMID: 33535504 DOI: 10.3390/ma14030665
    The mold-making industry is currently facing several challenges, including new competitors in the market as well as the increasing demand for a low volume of precision moldings. The purpose of this research is to appraise a new formulation of Metal Epoxy Composite (MEC) materials as a mold insert. The fabrication of mold inserts using MEC provided commercial opportunities and an alternative rapid tooling method for injection molding application. It is hypothesized that the addition of filler particles such as brass and copper powders would be able to further increase mold performance such as compression strength and thermal properties, which are essential in the production of plastic parts for the new product development. This study involved four phases, which are epoxy matrix design, material properties characterization, mold design, and finally the fabrication of the mold insert. Epoxy resins filled with brass (EB) and copper (EC) powders were mixed separately into 10 wt% until 30 wt% of the mass composition ratio. Control factors such as degassing time, curing temperature, and mixing time to increase physical and mechanical properties were optimized using the Response Surface Method (RSM). The study provided optimum parameters for mixing epoxy resin with fillers, where the degassing time was found to be the critical factor with 35.91%, followed by curing temperature with 3.53% and mixing time with 2.08%. The mold inserts were fabricated for EB and EC at 30 wt% based on the optimization outcome from RSM and statistical ANOVA results. It was also revealed that the EC mold insert offers better cycle time compared to EB mold insert material.
    Matched MeSH terms: Copper
  18. Ahmed S, Shahid MM, Bakar SA, Arshed N, Basirun WJ, Fouad H
    J Nanosci Nanotechnol, 2020 12 01;20(12):7705-7709.
    PMID: 32711646 DOI: 10.1166/jnn.2020.18570
    Herein, we report the synthesis of SnO, Cu₂O and SnO-Cu₂O mixed oxide thin films on fluorinedoped tin oxide (FTO) substrate by Aerosol-Assisted Chemical Vapour Deposition (AACVD) process using [Cu (dmae)₂(H₂O)] and [Sn (dmae) (OAc)]₂ as molecular precursors for SnO and Cu₂O, respectively at 400 °C. The X-ray diffraction (XRD) pattern can be ascribed to the tetragonal phase of SnO crystals with space group P4 and cubic phase of Cu₂O crystals with space group Pn- 3m/nmm, respectively. The surface morphology characteristics of SnO, Cu₂O and SnO-Cu₂Omixed oxide have been investigated using Field Emission Scanning Electron Microscope (FESEM) which revealed that the SnO was grown homogeneously in cubical shape while Cu₂O possess nano balls shaped morphologies. The UV band gap values of SnO-Cu₂O mixed oxide thin film was found to be 2.6 eV appropriate for photoelectrochemical (PEC) applications. The synthesized material was proposed for PEC applications and has shown enhanced catalytic performance in the presence of light.
    Matched MeSH terms: Copper
  19. Mansur R, Gusmanizar N, Roslan MA, Ahmad SA, Shukor MY
    Trop Life Sci Res, 2017 Jan;28(1):69-90.
    PMID: 28228917 MyJurnal DOI: 10.21315/tlsr2017.28.1.5
    A molybdenum reducing bacterium with the novel ability to decolorise the azo dye Metanil Yellow is reported. Optimal conditions for molybdenum reduction were pH 6.3 and at 34°C. Glucose was the best electron donor. Another requirement includes a narrow phosphate concentration between 2.5 and 7.5 mM. A time profile of Mo-blue production shows a lag period of approximately 12 hours, a maximum amount of Mo-blue produced at a molybdate concentration of 20 mM, and a peak production at 52 h of incubation. The heavy metals mercury, silver, copper and chromium inhibited reduction by 91.9, 82.7, 45.5 and 17.4%, respectively. A complete decolourisation of the dye Metanil Yellow at 100 and 150 mg/L occurred at day three and day six of incubations, respectively. Higher concentrations show partial degradation, with an approximately 20% decolourisation observed at 400 mg/L. The bacterium is partially identified based on biochemical analysis as Bacillus sp. strain Neni-10. The absorption spectrum of the Mo-blue suggested the compound is a reduced phosphomolybdate. The isolation of this bacterium, which shows heavy metal reduction and dye-decolorising ability, is sought after, particularly for bioremediation.
    Matched MeSH terms: Copper
  20. Zuhailawati Hussain, Yong, Tuck Leong
    MyJurnal
    In this paper, densification of in-situ copper-niobium carbide composite using cold pressing technique was addressed. Mixtures of Cu-20vol%NbC powder were prepared by two methods.
    In first method, a mixture of Cu-15.79wt%Nb-2.04wt%C powder was milled at 400 rpm for 35 hours in a planetary mill. In second method, Cu and commercial NbC powder was mixed at 100 rpm for 2 hours in a jar mill. Then, both powders were pressed at different pressure (i.e. 350 MPa, 450 MPa, 550 MPa and 650 MPa) and sintered at 900 o C for 1 hour. Sample of in-situ and ex-situ Cu-20vol%NbC composite were characterized for density, hardness, phase formation by x-ray diffraction analysis and microstructure by scanning electron microscope. Xray diffraction analysis showed that NbC phase was formed in the in-situ processed sample. Hardness of in-situ processed copper composite was higher than that of the ex-situ processed copper composite due to good interface between coper matrix and niobium carbide reinforcement particle as well as distribution of finer niobium carbide particles in copper matrix. Sintered density of in-situ composite is lower than density of ex-situ composite beacuse of work hardening of the Cu-Nb-C mixture powder during powder to ball collision. Density and hardness of the in-situ and ex-situ Cu-20vol%NbC composites increase with the increase in compaction pressure as porosity is eliminated at higher compaction pressure.
    Matched MeSH terms: Copper
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