Landfills are a potential threat to human health and the environment, especially from the detrimental and toxic heavy metals. This study focuses on the assessment of heavy metals contamination in leachate and surface soils from different landfills in Malaysia. Maximum quality rating scale (QRS) values of As (787) and Cr (552) denotes progressive deterioration of leachate contamination in landfill. The impacted soils showed high heavy metal concentrations especially at non-sanitary unlined landfills, as compared to background values, and natural soil nearby the landfills. In addition, to examine the environmental impacts of the landfill area (soil) in more detail, specific indexes; geo-accumulation index (Igeo), pollution index (PI) and integrated pollution index (IPI) were determined. Maximum As (3.122) and Cd (2.633) for Igeo and As (34.037) and Cd (20.881) for PI revealed that the soil samples in non-sanitary landfills were moderate to strongly polluted. The difference in range of IPI values for sanitary (0.294-0.322) and non-sanitary landfill soils (1.263-1.956) confirmed advanced decline of the soil quality in non-sanitary landfills. Arsenic concentrations were found to be statistically significant (ANOVA) for leachate and impacted soil in landfills investigated. It is also important to realize that rise in metal contents in landfill environments were not only caused by anthropogenic sources such as from the waste disposed, but also some other factors such as redox conditions, anoxic environments, pH, oxidation state of metals and microbial activities. Those conditions will actively promotes leaching of metals from waste and also natural soils in the landfill.
There is a global need to use plants to restore the ecological environment. There is no systematic review of phytoremediation mechanisms and the parameters for environmental pollution. Here, we review this situation and describe the purification rate of different plants for different pollutants, as well as methods to improve the purification rate of plants. This is needed to promote the use of plants to restore the ecosystems and the environment. We found that plants mainly use their own metabolism including the interaction with microorganisms to repair their ecological environment. In the process of remediation, the purification factors of plants are affected by many conditions such as light intensity, stomatal conductance, temperature and microbial species. In addition the efficiency of phytoremediation is depending on the plants species-specific metabolism including air absorption and photosynthesis, diversity of soil microorganisms and heavy metal uptake. Although the use of nanomaterials and compost promote the restoration of plants to the environment, a high dose may have negative impacts on the plants. In order to improve the practicability of the phytoremediation on environmental restoration, further research is needed to study the effects of different kinds of catalysts on the efficiency of phytoremediation. Thus, the present review provides a recent update for development and applications of phytoremediation in different environments including air, water, and soil.
The main cause of problematic soil failure under a certain load is due to low bearing capacity and excessive settlement. With a growing interest in employing shallow foundation to support heavy structures, it is important to study the soil improvement techniques. The technique of using geosynthetic reinforcement is commonly applied over the last few decades. This paper aims to determine the effect of using geogrid Tensar BX1500 on the bearing capacity and settlement of strip footing for different types of soils, namely Al-Hamedat, Ba'shiqah, and Al-Rashidia in Mosul, Iraq. The analysis of reinforced and unreinforced soil foundations was conducted numerically and analytically. A series of conditions were tested by varying the number (N) and the width (b) of the geogrid layers. The results showed that the geogrid could improve the footing's bearing capacity and reduce settlement. The soil of the Al-Rashidia site was sandy and indicated better improvement than the other two sites' soils (clayey soils). The optimum geogrid width (b) was five times the footing width (B), while no optimum geogrid number (N) was obtained. Finally, the numerical results of the ultimate bearing capacity were compared with the analytical results, and the comparison showed good agreement between both the analyses and the optimum range published in the literature. The significant findings reveal that the geogrid reinforcement may induce improvement to the soil foundation, however, not directly subject to the width and number of the geogrid alone. The varying soil properties and footing size also contribute to both BCR and SRR values supported by the improvement factor calculations. Hence, the output complemented the benefit of applying reinforced soil foundations effectively.
Enterobacter tabaci 4M9 (CCB-MBL 5004) was reported to have plant growth-promoting and heavy metal tolerance traits. It was able to tolerate more than 300 mg/L Cd, 600 mg/L As, and 500 mg/L Pb and still maintained the ability to produce plant growth-promoting substances under metal stress conditions. To explore the genetic basis of these beneficial traits, the complete genome sequencing of 4M9 was carried out using Pacific Bioscience (PacBio) sequencing technology. The complete genome consisted of one chromosome of 4,654,430 bp with a GC content of 54.6% and one plasmid of 51,135 bp with a GC content of 49.4%. Genome annotation revealed several genes involved in plant growth-promoting traits, including the production of siderophore, indole acetic acid, and 1-aminocyclopropane-1-carboxylate deaminase; solubilization of phosphate and potassium; and nitrogen metabolism. Similarly, genes involved in heavy metals (As, Co, Zn, Cu, Mn, Se, Cd, and Fe) tolerance were detected. These support its potential as a heavy metal-tolerant plant growth-promoting bacterium and a good genetic resource that can be employed to improve phytoremediation efficiency of heavy metal-contaminated soil via biotechnological techniques. This, to the best of our knowledge, is the first report on the complete genome sequence of heavy metal-tolerant plant growth-promoting E. tabaci.
In this study, Centella asiatica and surface soils were collected from 12 sampling sites in Peninsular Malaysia, and the barium (Ba) concentrations were determined. The Ba concentration [µg/g dry weight (dw)] was 63.72 to 382.01 µg/g in soils while in C. asiatica, Ba concentrations ranged from 5.05 to 21.88 µg/g for roots, 3.31 to 11.22 µg/g for leaves and 2.37 to 6.14 µg/g for stems. In C. asiatica, Ba accumulation was found to be the highest in roots followed by leaves and stems. The correlation coefficients (r) of Ba between plants and soils were found to be significantly positively correlated, with the highest correlation being between roots-soils (r=0.922, p
In the literature, several methods of ground improvement have been presented including compacted stone columns. The bearing capacity of the granular column is governed mainly by the lateral confining pressure mobilized in the soft soil to restrain or prevent bulging of the granular column. Therefore, the technique becomes unfeasible in peat that does not provide sufficient lateral confinement. This condition can be overcome by encasing the stone column with geogrid. This paper investigates the performance of the geogrid encased vibrocompacted stone column in peat. This study was carried out using PLAXIS software equipped with unit cell concept. The peat was modelled using soft soil model and the stone column using Mohr-Coulomb soil model, respectively. The geogrid was modelled using the geogrid option and could take only tensile force. The results indicate that the geogrid encased stone column can take much higher load in comparison to ordinary stone columns as the stiffness of the column increases. Meanwhile, the length of encasement also varied and it was observed that it was very effective up to about two times the diameter of the column. It also increased the column stiffness, and therefore led to a significant strain reduction. It was also observed that the columns at a spacing of three times the diameter are very effective. The results presented here can be used by the geotechnical engineers to design the geogrid reinforced stone column based on the strength of the soil, diameter of the column, spacing of the columns and stiffness of the geogrid.
Residual soils occur in most countries of the world but the greater areas and depths are normally found in tropical humid areas. In these places, the soil forming processes are still very active and the weathering is much faster than the erosive factor. Most residual exhibit high soil suctions for most of the year. The absence of positive pore water pressure except immediately after rain, renders conventional soil mechanics for saturated soil irrelevant. In particular, the effective stress theories of saturated soil are not applicable at the practical leve l. Ignorance or lack of understanding of the geotechnical behavior of soil in the partially or unsaturated state has caused a lot of damages to infrastructures, buildings and other structures. For instances, the collapsibility and volume change of partially saturated soils in connection with the drying or wetting causes a lot of damage to foundation, roads and other structures. As such, the development of extended soil mechanics, which embraces the soil in the unsaturated state or subjected to soil suction, is essential. This paper examines the collapsibility and volume change behavior specifically of an unsaturated residual soil under various levels of applied matric suction (u -u ), and net mean stress (a-u) in a predetermined stress path. The volume change of ;he"' soil is found to be sensitive to both the applied matric suction and net mean stress. The soil is found to exhibit a collapsibility behavior upon a reduction in applied matric suction to 25 kPa at constant net mean stress.
Effect of washing solutions’ pH on removal of radium-226 from radium-contaminated soil using distilled water and humic acid extracted from Malaysian peat soil was studied by a single batch washing method. The study encompassed the extraction of humic acid and the washing of radium-contaminated soil using distilled water and humic acid solutions of varying pH in the range between 3 to 11. Activity of radium-226 was determined by gamma spectrometer. In the pH range studied, the removal of radium-226 was greater when humic acid solutions were used compared to distilled water. Greater removal of radium-226 was obtained using highly basic pH washing solutions compared to neutral and acidic solutions.
The soil plant transfer coefficient or f factor of 14 C-carbofuran pesticide was studied in outdoor lysimeter experiment consisting of Brassica sp. vegetable crop, riverine alluvial clayey soil and Bungor series sandy loam soil. Soil transfer coefficients at 0-10 cm soil depth were 4.38 + 0.30, 5.76 + 1.04, 0.99 + 0.25 and 2.66 + 0.71; from 1X recommended application rate in alluvial soil, 2X recommended application rate in alluvial soil, 1X recommended application rate in Bungor soil and 2X recommended application rate in Bungor soil, respectively. At 0-25 cm soil depth, soil plant transfer coefficients were 8.96 + 0.91, 10.40 + 2.63, 2.34 + 0.68 and 6.19 + 1.40; from 1X recommended application rate in alluvial soil, 2X recommended application rate in alluvial soil, 1X recommended application rate in Bungor soil and 2X recommended application rate in Bungor soil, respectively. At 77 days after treatment (DAT), the soil plant transfer coefficient was significantly higher in riverine alluvial soil than Bungor soil whereas shoot and root growth was significantly higher in Bungor soil than in riverine alluvial soil. At both 0-10 cm Brassica sp. rooting depth and 0-25 cm soil depth, the soil plant transfer coefficient was significantly higher in 2X recommended application rate of 14 C-carbofuran as compared to 1X recommended application rate, in both Bungor and riverine alluvial soils.
Concentrations of Natural Occurring Radioactive Material (NORM) and terrestrial gamma radiation have been shown to be associated with certain lithology and soil types. An attempt was made to statistically predict and validate environmental gamma radiation dose rates based on limited number of actual field measurements using sodium iodide (NaI(Tl)) detector. Statistical analysis including the correlations between the actual and predicted dose were made based on 32 different lithology and soil type combinations. Results of field measurements, have shown that more than 50% of the predicted data were not significantly different from the actual measured data. The interpolation method in GIS was used to produce an isodose map based on the prediction equation. A correlation of multiple regression on the predicted versus lithology and soils dose rates gave relationships of DP = 0.35 DL + 0.82 DS – 0.02, r2 = 0.736. A predicted isodose map was subsequently plotted base on 4 dose rates classes, ranging from 0.1 – 0.3 μSvhr-1.
The effect of sample density in the determination of radionuclides by gamma spectrometry was studied using two multinuclide standard sources of different densities. The self absorption corrections due to differences in sample matrix densities were estimated. The corrections were used in the analysis food and soil samples having packing densities between 0.2 – 1.6g/ml.
The importance of numerical analysis in investigation of piled embankment over soft soil has been developed since 1990. Several investigators have extended the numerical analysis to model ground improvement using soil-column to support embankment or structures. This paper presents a numerical analysis of the Pulverized Fuel Ash (PFA) column-treated peat and compared with field static-loading test results. Back analysis was performed to determine the material parameters and soil stiffness surrounding soil & soil-column. Two geometrical models were used in this analysis: (a) block (Model A), and (b) column group (Model B). This situation was analyzed using commercially available finite element package PLAXIS 2D ver. 8.2. It is found that both models are reliable to simulate the field static-loading test for column-treated peat. Model B shows a higher stability to failure if compared to Model A.
This paper presents an evaluation of the alternative use of natural cellulose coir fibres for
soil reinforcement. Soil reinforcement is defined as a technique to improve the engineering properties
of soil. Inserting natural fibres into the soil has been proposed as a reinforcement method. Randomly
distributed coir fibre reinforced soils have recently attracted increasing attention in geotechnical
engineering due to their strength. Furthermore, there is a need to develop an innovative and
sustainable pre-treatment method to improve the effectiveness and performance of coir fibre as soil
reinforcement. The primary purpose of this paper is, therefore, to review the characteristics, benefits,
applications and weaknesses of coir fibre as soil reinforcement.
Although a promising technique, phytoextraction has yet to see significant commercialization. Major limitations include metal uptake rates and subsequent processing costs. However, it has been shown that liquid-culture-grown Arabidopsis can take up and store palladium as nanoparticles. The processed plant biomass has catalytic activity comparable to that of commercially available catalysts, creating a product of higher value than extracted bulk metal. We demonstrate that the minimum level of palladium in Arabidopsis dried tissues for catalytic activity comparable to commercially available 3% palladium-on-carbon catalysts was achieved from dried plant biomass containing between 12 and 18 g·kg-1 Pd. To advance this technology, species suitable for in-the-field application: mustard, miscanthus, and 16 willow species and cultivars, were tested. These species were able to grow, and take up, palladium from both synthetic and mine-sourced tailings. Although levels of palladium accumulation in field-suitable species are below that required for commercially available 3% palladium-on-carbon catalysts, this study both sets the target, and is a step toward, the development of field-suitable species that concentrate catalytically active levels of palladium. Life cycle assessment on the phytomining approaches described here indicates that the use of plants to accumulate palladium for industrial applications has the potential to decrease the overall environmental impacts associated with extracting palladium using present-day mining processes.
Home composting can be an effective way to reduce the volume of municipal solid waste. The aim of this study is to evaluate the effect of Effective Microorganism™ (EM) for the home scale co-composting of food waste, rice bran and dried leaves. A general consensus is lacking regarding the efficiency of inoculation composting. Home scale composting was carried out with and without EM (control) to identify the roles of EM. The composting parameters for both trials showed a similar trend of changes during the decomposition. As assayed by Fourier Transform Infrared Spectroscopy (FTIR), the functional group of humic acid was initially dominated by aliphatic structure but was dominated by the aromatic in the final compost. The EM compost has a sharper peak of aromatic CC bond presenting a better degree of humification. Compost with EM achieved a slightly higher temperature at the early stage, with foul odour suppressed, enhanced humification process and a greater fat reduction (73%). No significant difference was found for the final composts inoculated with and without EM. The properties included pH (∼7), electric conductivity (∼2), carbon-to-nitrogen ratio (C: N 100%), humic acid content (4.5-4.8%) and pathogen content (no Salmonella, <1000 Most Probable Number/g E. coli). All samples were well matured within 2 months. The potassium and phosphate contents in both cases were similar however the EM compost has a higher nitrogen content (+1.5%). The overall results suggested the positive effect provided by EM notably in odour control and humification.
The association of arbuscular mycorrhiza fungi (AMF) and roots undoubtedly
gives positive advantages to the host plant. However, heavily fertilised soil such as in oil
palm plantation, inhibit the growth of mycorrhiza. Thus, the aim of this research is to
distinguish and quantify the availability of AMF population and propagules at different sites
of an oil palm plantation by Most Probable Number (MPN) assay. In addition, root infection
method was employed to observe host compatibility through the propagation of AMF using
two different types of hosts, monocotyledon (Echinochloa cruss-galli) and dicotyledon
(Vigna radiata). Three different locations at an oil palm plantation were chosen for
sampling. Each location was represented by a distinctive soil series, and were further
divided into two sites, that is canopy and midway area. Midway site had a greater
population of AMF compared to canopy. The result showed that different environments
affect the availability of AMF in the soil. Higher number of AMF infection observed in
monocotyledon host suggests that the fibrous root system provide a better association
with mycorrhiza.
The persistence of metsulfuron-methyl (methyl 2-[[(4-methoxy-6-methyl-1,3,5-triazin-2-yl)aminocarbonyl]aminosul fonyl]benzoate) in nonautoclaved and autoclaved Selangor, Lating, and Serdang series soils incubated at different temperatures and with different moisture contents was investigated under laboratory conditions using cucumber (Cucumis sativus L.) as the bioassay species. Significant degradation of metsulfuron-methyl was observed in nonautoclaved soil compared with the autoclaved soil sample, indicating the importance of microorganisms in the breakdown process. At higher temperatures the degradation rate in nonautoclaved soil improved with increasing soil moisture content. In nonautoclaved Selangor, Lating and Serdang series soils, the half-life was reduced from 4.79 to 2.78 days, 4.9 to 3.5, and from 3.3 to 1.9 days, respectively, when the temperature was increased from 20 degrees to 30 degrees C at 80% field capacity. Similarly, in nonautoclaved soil, the half-life decreased with an increasing soil moisture from 20% to 80% at 30 degrees C in the three soils studied. In the autoclaved soil, the half-life values were slightly higher than those obtained in the nonautoclaved soils, perhaps indicating that the compound may be broken down by nonbiological processes. The fresh weight of the bioassay species was reduced significantly in Serdang series soil treated with metsulfuron-methyl at 0.1 ppm. However, the reduction in fresh weight of the seedlings was least in Lating series soil, followed by Selangor series soil.
Deep eutectic solvents (DESs) are a class of green solvents analogous to ionic liquids, but less costly and easier to prepare. The objective of this study is to remove lead (Pb) from a contaminated soil by using polyol based DESs mixed with a natural surfactant saponin for the first time. The DESs used in this study were prepared by mixing a quaternary ammonium salt choline chloride with polyols e.g. glycerol and ethylene glycol. A natural surfactant saponin obtained from soapnut fruit pericarp, was mixed with DESs to boost their efficiency. The DESs on their own did not perform satisfactory due to higher pH; however, they improved the performance of soapnut by up to 100%. Pb removal from contaminated soil using mixture of 40% DES-Gly and 1% saponin and mixture of 10% DES-Gly and 2% saponin were above 72% XRD and SEM studies did not detect any major corrosion in the soil texture. The environmental friendliness of both DESs and saponin and their affordable costs merit thorough investigation of their potential as soil washing agents.
Compost leachate (CL) is often treated as sewage. Limited studies have characterised the use of CL for agriculture application due to the variation of nutrient range, potential pollutants and need for pretreatment before use. This paper reviewed the characteristics of CL in terms of its nutrients and physical characteristics from three types of biowastes, i.e. the organic portion of municipal solid waste (OP-MSW), animal manure and green waste. The nutrient range characterised are used to develop the dilution rate of the CL as fertigation water for three types of vegetables. The dilution rate of CL developed is based on the fertigation standards set by the Food and Agriculture Organization of the United Nations and Malaysia Standards. The results show that all CL contain high organic content and micronutrients, which exceeded the upper limits. For the fertigation of vegetables using the CL, based on the requirement of COD and micronutrients (Fe, Mn, Zn, Cu, Pb, Ni, Cd, Cr) of the vegetables, the CL from green waste required the lowest dilution rate (8-45 fold), followed by animal waste (33-65 fold) and the OP-MSW (193-1770 fold). The novel dilution range developed is vital to balance the essential nutrients in the CL while avoiding phototoxicity on plant and soil pollution. The dilution strategy developed is essential to support the conversion of CL as an organic liquid fertiliser for agricultural application.