Hydrogen and gaseous fuel derived from wastes have opened up promising alternative pathways for the production of renewable and sustainable fuels to substitute classical fossil energy resources that cause global warming and pollution. Existing review articles focus mostly on gasification, reforming and pyrolysis processes, with limited information on particularly gaseous fuel production via pyrolysis of various waste products. This review provides an overview on the recent advanced pyrolysis technology used in hydrogen and gaseous fuel production. The key parameters to maximize the production of specific compounds were discussed. More studies are needed to optimize the process parameters and improve the understanding of reaction mechanisms and co-relationship between these advanced techniques. These advanced techniques provide novel environmentally sustainable and commercially procedures for waste-based production of hydrogen and gaseous fuels.
Excessive accumulation of waste materials has presented a serious environmental problem on a global scale. This has prompted many researchers to utilise agricultural, industrial, and by-product waste materials as the replacement of aggregate in the concrete matrix. In this present study, the prediction and optimisation of coconut shell (CA) content as the replacement of fine aggregate were evaluated based on the mechanical properties of the concrete (M30). Based on the suggested design array from the response surface methodology (RSM) model, experimental tests were carried out to achieve the goal of this study. The collected data was used to develop mathematical predictive equations using both GEP and RSM models. Analysis of variance (ANOVA) was also taken into account to appraise and verify the performance of the proposed models. Based on the results, the optimum content of replacing CA was 50%. In particular, the compressive, tensile, and flexural strength obtained after 28 days of curing were 46.2, 3.74, and 8.06 MPa, respectively, from the RSM model and 46.18, 3.85, and 7.99 MPa, respectively, from the GEP model. The obtained values were superior to those of the control concrete sample (43.12, 3.51 and 7.14 MPa, respectively). Beyond the optimum content, a loss in strength was observed. It was also found that both the GEP and RSM models exhibited high prediction accuracy with strong correlations (R2 = 0.97 and 0.95, respectively). In addition, minimum prediction error (RMSE
Solid waste collection and disposal are among the most vital services provided to about 700 770 residents of the city of Erbil in northern Iraq. As such, proper waste management systems that consider both the quantity and composition of domestic solid waste are strongly required to address the increasing amount of solid waste. Unfortunately, these essential data are not easily available. The present study sought to gather data on the quantity and composition of domestic solid waste collected from different quarters in Erbil, and the feasibility of recycling these wastes. The solid waste generation rate (GR), uncompacted density, and weight percentages of combustible and incombustible materials were determined based on the collected materials (i.e., food, plastic, paper, metal, glass and cloth). The results show that the average GR and uncompacted density were 0.654 kg capita(-1) day(-1) and 175.72 kg m(-3), respectively. The weight percentages of food, plastic, paper, metal, glass, and cloth as components of domestic solid waste were 79.34, 6.28, 5.9, 3.6, 3.42 and 1.45%, respectively.
The integration of communication technologies such as radio frequency identification (RFID), global positioning system (GPS), general packet radio system (GPRS), and geographic information system (GIS) with a camera are constructed for solid waste monitoring system. The aim is to improve the way of responding to customer's inquiry and emergency cases and estimate the solid waste amount without any involvement of the truck driver. The proposed system consists of RFID tag mounted on the bin, RFID reader as in truck, GPRS/GSM as web server, and GIS as map server, database server, and control server. The tracking devices mounted in the trucks collect location information in real time via the GPS. This information is transferred continuously through GPRS to a central database. The users are able to view the current location of each truck in the collection stage via a web-based application and thereby manage the fleet. The trucks positions and trash bin information are displayed on a digital map, which is made available by a map server. Thus, the solid waste of the bin and the truck are being monitored using the developed system.
Matched MeSH terms: Waste Products/analysis*; Waste Products/statistics & numerical data
Oil spill constitutes a major source of fresh and seawater pollution as a result of accidental discharge from tankers, marine engines, and underwater pipes. Therefore, the need for cost-effective and environmental friendly sorbent materials for oil spill cleanup cannot be overemphasized. The present work focuses on the preliminary study of empty palm fruit bunch fibre as a promising sorbent material. The morphology of the unmodified empty palm fruit bunch, EPFB fibre, was examined using an optical microcopy, scanning electron microcopy coupled with EDX and X-ray diffraction. The effects of oil volume, fibre weight, and time on oil absorption of EPFB fibre were evaluated with new engine oil from the model oil. The results show that EPFB fibre consists of numerous micro pores, hydrophobic, and partially crystalline and amorphous with approximately 13.5% carbon. The oil absorbency of the fibre increased with the increase in oil volume, immersion time, and fibre weight. However, sorption capacity decreased beyond 3 g in 100 mL. Additionally unmodified EPFB fibre showed optimum oil sorption efficiency of approximately 2.8 g/g within three days of immersion time.
This paper presents a forecasting study of municipal solid waste generation (MSWG) rate and potential of its recyclable components in Kuala Lumpur (KL), the capital city of Malaysia. The generation rates and composition of solid wastes of various classes such as street cleansing, landscape and garden, industrial and constructional, institutional, residential and commercial are analyzed. The past and present trends are studied and extrapolated for the coming years using Microsoft office 2003 Excel spreadsheet assuming a linear behavior. The study shows that increased solid waste generation of KL is alarming. For instance, the amount of daily residential SWG is found to be about 1.62 kg/capita; with the national average at 0.8-0.9 kg/capita and is expected to be increasing linearly, reaching to 2.23 kg/capita by 2024. This figure seems reasonable for an urban developing area like KL city. It is also found that, food (organic) waste is the major recyclable component followed by mix paper and mix plastics. Along with estimated population growth and their business activities, it has been observed that the city is still lacking in terms of efficient waste treatment technology, sufficient fund, public awareness, maintaining the established norms of industrial waste treatment etc. Hence it is recommended that the concerned authority (DBKL) shall view this issue seriously.
Floating plastic debris was investigated in the transition region in the North Pacific between 141°E and 165°W to understand its transportation process from Asian coast to central subtropical Pacific. Distribution was influenced primarily by the current system and the generation process of the high concentration area differed between the western and eastern areas. West of 180°, debris largely accumulated around nearshore convergent area and was transported by eddies and quasi-stationary jet from south to the subarctic region. The average was 15% higher than that previously reported in 1989, suggesting an increase in plastic debris in 30 years. East of 180°, debris concentrated in the calm water downstream of the Kuroshio Extension Bifurcation with considerably high concentration (505,032 ± 991,989 pieces km-2), due to the accumulation of small transparent film caused by calm weather conditions, suggesting a further investigation on small plastic (<1 mm) in the subsurface depth in the subtropical North Pacific.
Southeast (SE) Asia is a highly biodiverse region, yet it is also estimated to cumulatively contribute a third of the total global marine plastic pollution. This threat is known to have adverse impacts on marine megafauna, however, understanding of its impacts has recently been highlighted as a priority for research in the region. To address this knowledge gap, a structured literature review was conducted for species of cartilaginous fishes, marine mammals, marine reptiles, and seabirds present in SE Asia, collating cases on a global scale to allow for comparison, coupled with a regional expert elicitation to gather additional published and grey literature cases which would have been omitted during the structured literature review. Of the 380 marine megafauna species present in SE Asia, but also studied elsewhere, we found that 9.1 % and 4.5 % of all publications documenting plastic entanglement (n = 55) and ingestion (n = 291) were conducted in SE Asian countries. At the species level, published cases of entanglement from SE Asian countries were available for 10 % or less of species within each taxonomic group. Additionally, published ingestion cases were available primarily for marine mammals and were lacking entirely for seabirds in the region. The regional expert elicitation led to entanglement and ingestion cases from SE Asian countries being documented in 10 and 15 additional species respectively, highlighting the utility of a broader approach to data synthesis. While the scale of the plastic pollution in SE Asia is of particular concern for marine ecosystems, knowledge of its interactions and impacts on marine megafauna lags behind other areas of the world, even after the inclusion of a regional expert elicitation. Additional funding to help collate baseline data are critically needed to inform policy and solutions towards limiting the interactions of marine megafauna and plastic pollution in SE Asia.
Many studies have been done using recycled waste materials to minimise environmental problems. It is a great opportunity to explore mechanical recycling and the use of recycled and virgin blend as a material to produce new products with minimum defects. In this study, appropriate processing parameters were considered to mould the front panel housing part using R0% (virgin), R30% (30% virgin: 70% recycled), R40% (40% virgin: 60% recycled) and R50% (50% virgin: 50% recycled) of Polycarbonate (PC). The manufacturing ability and quality during preliminary stage can be predicted through simulation analysis using Autodesk Moldflow Insight 2012 software. The recommended processing parameters and values of warpage in x and y directions can also be obtained using this software. No value of warpage was obtained from simulation studies for x direction on the front panel housing. Therefore, this study only focused on reducing the warpage in the y direction. Response Surface Methodology (RSM) and Genetic Algorithm (GA) optimisation methods were used to find the optimal processing parameters. As the results, the optimal ratio of recycled PC material was found to be R30%, followed by R40% and R50% materials using RSM and GA methods as compared to the average value of warpage on the moulded part using R0%. The most influential processing parameter that contributed to warpage defect was packing pressure for all materials used in this study.
Concrete mix design and the determination of concrete performance are not merely engineering studies, but also mathematical and statistical endeavors. The study of concrete mechanical properties involves a myriad of factors, including, but not limited to, the amount of each constituent material and its proportion, the type and dosage of chemical additives, and the inclusion of different waste materials. The number of factors and combinations make it difficult, or outright impossible, to formulate an expression of concrete performance through sheer experimentation. Hence, design of experiment has become a part of studies, involving concrete with material addition or replacement. This paper reviewed common design of experimental methods, implemented by past studies, which looked into the analysis of concrete performance. Several analysis methods were employed to optimize data collection and data analysis, such as analysis of variance (ANOVA), regression, Taguchi method, Response Surface Methodology, and Artificial Neural Network. It can be concluded that the use of statistical analysis is helpful for concrete material research, and all the reviewed designs of experimental methods are helpful in simplifying the work and saving time, while providing accurate prediction of concrete mechanical performance.
Pectin and modified pectin differ in the structure of the chains in which the modified version of pectin is shorter in length, non-branched, and galactose-rich. These differences in structure may be exploited for the removal of heavy metals. Durian (Durio zibethinus) rind, that is regarded as agri-food waste was processed into durian rind pectin (DRP) and modified durian rind pectin (mDRP). DRP and mDRP were evaluated as biosorbent for removal of toxic heavy metals (Pb(II), Cd(II), Cu(II), Zn(II) and Ni(II)) and were compared with two commercial products; citrus pectin (CP) and modified citrus pectin (MCP). In general, the order of removal of heavy metals by all biosorbents was Cu(II) > Pb(II) > Ni(II) > Zn > Cd(II). Except for the removal of Pb(II), the order of effectiveness of heavy metal removal of the biosorbents was MCP > mDRP > CP > DRP. MCP, a commercial biosorbent showed the best biosorbent ability, and mDRP a waste product from durian was also a favorable sorber that should be considered for sorption and removal of heavy metals.
This study was conducted using crab shells as a biosorbent to remove Cu and Cd with different initial concentrations of 1, 5, 10, 15, and 20 mg/L in a biosorption treatment process. Crab shells were selected as biosorbents due to their abundance in the environment and ready availability as waste products from the market place. This study aimed to determine the ability of Scylla Serrata shells to remove Cu and Cd in an aqueous solution, as well as to provide a comparison of the removal rate between the two metals. The data were incorporated into hydrochemical software, PHREEQC, to investigate the chemical speciation distribution of each heavy metal. The shells of S. serrata were found to have a significant (p< 0.05) ability to remove Cu and Cd following the treatment. After six hours of treatment, the crab shells had removed 60 to 80% of both metals. However, the highest removal percentage was achieved for Cu with up to 94.7% removal rate in 5 mg/L initial Cu concentration, while 85.1% of Cd was removed in 1 mg/L initial solution, respectively. It can be concluded that the shells of S. serrata could remove Cu and Cd better with significant results (p
Malaysia has over 5 million hectares of land planted with palm oil, divided almost equally between peninsula Malaysia and East Malaysia. This paper presents a laboratory evaluation of the performance of the waste product palm kernel shell (PKS) in creating plant-based asphalt concrete (bio-asphalt concrete). PKS aggregate partially replaced granite aggregate in preparing the mixes (10%, 30%, and 100%) in the range of 5mm-14mm in ACW 14 mixed with 5% to 7% of bitumen content. 35 blows and 50 blows compaction of mixes was used to evaluate the potential of palm kernel shells in the preparation of bitumen to deal with light to medium traffic. Results showed that PKS aggregate can be used up to 30% PKS replacement for the light traffic design and only 10% PKS replacement was potential to be used in medium traffic design.
Sawdust is considered a waste material and a number of innovative ways are being taken to mitigate its effects on the environment. The use of sawdust as additional admixture in cement-sand brick production is an alternative option to mitigate the problem. In this study, three different types of cement-sand brick mixture in proportion of 1%, 2% and 3% of sawdust added to the normal mixture are prepared. Compression test was conducted on the brick mixture and results indicated 1% sawdust satisfy the Class 1 loadbearing brick whilst the 2% sawdust is slightly above the minimum required strength of 5.2 MN/ m2 for an ordinary quality brick set by the Standards MS 76:1972. Thus, the use of sawdust as admixture in cement-sand brick should not exceed 3%.
In light of concerns relating to improper waste disposal and resources preservation, reclamation of the discarded glass in construction materials had been extensively carried out since 1963. In the past decade, although more than 100 papers associated with the use of glass powder (GP) in the micron level scale were published, comprehensive review of all practical applications in cement-based materials and construction products is not available. This paper therefore provides a summary of the body of knowledge on the interaction and effects of using GP in cement-based and extended construction materials. This review concludes that GP is an innovative and promising eco-supplementary cementitious material. Beyond that, use of GP is demonstrated to be potentially beneficial as a precursor in geopolymer and suitable for manufacturing eco-cement, artificial lightweight aggregate and composite phase change material. The multiple applications of GP are seen as an important step towards waste glass recycling as a sustainable construction material and for the overall betterment of the industry.
This research aims to analyse and understand recycling phenomena and competition between large-scale and small-scale enterprises under different public attention. It mainly emphasizes service-providing behaviours to the consumers in the recycling industry, where recyclers are struggling to enhance their profits. The government strives to protect the environment by promoting an efficient recycling industry. As fast-growing waste products, the recyclers should achieve the advantage of number and be equipped with service capability for the consumers. Thus, this study employs an evolutionary game model to analyse the competition for waste products acquisitions between large and small recyclers. Due to a significant association between the service and acquisition waste product price for the consumers and recycling quantity, there is a strong mutual influence between the acquisition price of waste products and the price strategy-taken rate of large and small recyclers. Results also reveal that the market acquisition price and processing cost play a crucial role in recyclers' decision-making on setting prices for acquiring waste products from consumers. Furthermore, it is also found that waste products acquisition price and recyclers' processing cost are the key factors that affect large and small recyclers' recycling quantity.
Every day, more and more binding materials are being used in the construction industry all over the world. However, Portland cement (PC) is used as a binding material, and its production discharges a high amount of undesirable greenhouse gases into the environment. This research work is done to reduce the amount of greenhouse gases discharged during PC manufacturing and to reduce the cost and energy incurred in the cement manufacturing process by making effective consumption of industrial/agricultural wastes in the construction sector. Therefore, wheat straw ash (WSA) as an agricultural waste is utilized as cement replacement material, while used engine oil as an industrial waste is utilized as an air-entraining admixture in concrete. This study's main goal was to examine the cumulative impact of both waste materials on fresh (slump test) and hardened concrete (compressive strength, split tensile strength, water absorption, and dry density). The cement was replaced by up to 15% and used engine oil incorporated up to 0.75% by weight of cement. Moreover, the cubical samples were cast for determining the compressive strength, dry density, and water absorption, while the cylindrical specimen was cast for evaluating the splitting tensile strength of concrete. The results confirmed that compressive and tensile strengths augmented by 19.40% and 16.67%, at 10% cement replacement by wheat straw ash at 90 days, respectively. Besides, the workability, water absorption, dry density, and embodied carbon were decreased as the quantity of WSA increased with the mass of PC, and all of these properties are increased with the incorporation of used engine oil in concrete after 28 days, respectively.
The ageing of the bitumen during storage, mixing, transport and laying on the road, as well as in service life, are the most important problems presented by the use of bitumen in pavements. This paper investigates the possibility of using waste cooking oil (WCO), which is a waste material that pollutes landfills and rivers, as an alternative natural rejuvenating agent for aged bitumen to a condition that resembles the original bitumen. With this target, the physical and chemical properties of the original bitumen, aged bitumen and rejuvenated bitumen were measured and compared by the bitumen binder tests - softening point, penetration, Brookfield viscosity, dynamic shear rheometer and Fourier transform infrared spectroscopy. In addition, the behaviour of the WCO rejuvenated bitumen is investigated and compared with virgin bitumen after using the rolling thin film oven ageing process. In general, the results showed that using 3-4% of WCO the aged bitumen group 40/50 was rejuvenated to a condition that closely resembled the physical, rheological properties of the original bitumen (80/100), however, there was a difference in the tendency to ageing between the WCO rejuvenated bitumen and the virgin bitumen during mixing, transport and laying on the road.
We report on a recycling project in which α-Al(2)O(3) was produced from aluminum cans because no such work has been reported in literature. Heated aluminum cans were mixed with 8.0 M of H(2)SO(4) solution to form an Al(2)(SO(4))(3) solution. The Al(2)(SO(4))(3) salt was contained in a white semi-liquid solution with excess H(2)SO(4); some unreacted aluminum pieces were also present. The solution was filtered and mixed with ethanol in a ratio of 2:3, to form a white solid of Al(2)(SO(4))(3)·18H(2)O. The Al(2)(SO(4))(3)·18H(2)O was calcined in an electrical furnace for 3 h at temperatures of 400-1400 °C. The heating and cooling rates were 10 °C /min. XRD was used to investigate the phase changes at different temperatures and XRF was used to determine the elemental composition in the alumina produced. A series of different alumina compositions, made by repeated dehydration and desulfonation of the Al(2)(SO(4))(3)·18H(2)O, is reported. All transitional alumina phases produced at low temperatures were converted to α-Al(2)O(3) at high temperatures. The X-ray diffraction results indicated that the α-Al(2)O(3) phase was realized when the calcination temperature was at 1200 °C or higher.