Foot arch determines the shape of the foot, whether it is normal, flat or high. Excessive body weight is known to be the
main factor in altering the foot arches. The foot arches of adult women were determined based on five different footprint
parameters (Clarke index, Chippaux-Smirak index, Staheli index, Arch index and the Harris-imprint index) and the
relationship between Body Mass Index (BMI) and foot arches were studied. A total of 309 adult women from the age of
20 to 60 years were recruited in this study. The shape of participants’ feet were obtained and their left and right foot
arches were determined using five different footprint parameters. Body weight and height were measured and BMI was
calculated. Paired t-test and one-way ANOVA were applied to perform the statistical analysis. Our analysis showed that
two third of the participants have different foot arches between the left and right feet. The Harris-imprint index exhibited
the most significant (p=0.004) differences between the left (mean=0.168) and right (mean=1.011) foot arches. Most of
the overweight (53%) and obese (15%) participants have normal arches; however the prevalence of flat and high arches
is still higher in overweight (flat arch= 51%; high arch= 52% ) and obese (flat arch= 18%; high arch= 12%) compared
to other BMI categories. Harris-imprint index was successfully studied as a suitable parameter in determining the left
and right foot arches.
Penunjuk pH sebagai suatu pendekatan untuk memantau kualiti atau kesegaran makanan semasa telah mendapat perhatian
industri pembungkusan makanan. Penggunaan sumber semula jadi pigmen tumbuhan terutamanya daripada buah-buahan
dan sayur-sayuran menjadi pilihan para pengguna untuk menggantikan pewarna sintetik dalam memastikan keselamatan
makanan yang diambil setiap hari. Dalam kajian ini, ekstrak daripada bilberi telah digunakan sebagai pewarna sensitif
pH. Perubahan warna sampel dikaji secara terperinci melalui kaedah kromametri dan juga kaedah spektrofotometri
ultra-lembayung nampak. Warna merah terang terhasil dalam pH berasid, merah pudar pada neutral dan magenta ke
kuning dalam pH beralkali. Keputusan kajian kromametri menunjukkan bahawa ekstrak bilberi berupaya mempamerkan
perubahan warna yang jelas terhadap perubahan pH, iaitu terdapat perubahan nilai warna a* yang menyumbang kepada
perubahan yang bererti dalam perbezaan warna keseluruhan (ΔE*). Nilai ΔE* juga ditentukan wujud hubungan linear
dan kuantitatif terhadap julat pH tertentu. Oleh yang demikian, ekstrak bilberi didapati berpotensi sebagai bahan sensor
untuk pH dalam membangunkan satu sensor pH bagi memantau kesegaran makanan terutamanya hasilan laut berbungkus
memandangkan tahap kerosakan produk tersebut berkait rapat dengan perubahan pH ke arah alkali.
The Re(I) complex, [Re(PyPzH)(CO)3
Cl] where PyPzH = 2-(1H-pyrazol-3-yl)pyridine, was successfully synthesised
and characterised with an infrared (IR), ultraviolet-visible (UV-Vis), 1
H and 13C nuclear magnetic resonance (NMR)
spectroscopies and X-ray crystallography. The IR spectrum featured three n(C≡O), n(N-H), n(C=N) and n(C=C) signals
at (1860-2020), 3137, 1614 and 1513 cm-1, respectively. The UV-Vis spectrum of the complex exhibited ligand-centred
(π®>*) electronic excitations [λmax = 227 nm, ε = 1.942 x 104 M-1cm-1; lmax = 292 nm, ε = 0.853 x 104 M-1cm-1] and
a metal-to-ligand charge transfer (MLCT) band [lmax = 331 nm, ε = 0.467 x 104 M-1cm-1]. The 13C and 1
H-NMR spectra
exhibited the characteristic signals of the three C≡O (189.0 – 199.0 ppm) and NH (14.84 ppm), respectively. The X-ray
structure of [Re(PyPzH)(CO)3
Cl] showed the crystal adopted a monoclinic system with a C2/c space group [unit cell
dimensions: a = 27.7422(14) Å, b = 11.1456(5) Å, c = 9.2461(4) Å with α = γ = 90º and β = 92.552(2)º]. Density
functional theory (DFT) and time-dependent (TD) DFT calculations were performed to investigate the optimised structural
geometry and electronic properties of the title complex. The results showed that the highest-occupied molecular orbital
(HOMO) was predominantly found on the dπ-orbitals of Re(I), Cl and CO. While the lowest-unoccupied molecular orbital
(LUMO) was located on the PyPzH moiety. The structural and photophysical properties of the [Re(PyPzH)(CO)3
Cl] were
established and the reaction enthalpies for the dissociation of Cl atom in the formation of [Re(PyPzH)(CO)3
]•
were
discussed in view of its potential application for photocatalytic CO2
reduction.
The study was conducted to determine the best model suitable for the determination of ferrum uptake in Brassica chinensis (flowering white cabbage). A nonlinear regression model was selected to determine the amount of ferrum absorbed by each part of the Brassica chinensis plant namely the leaves, stems and roots. The Levenberg-Marquardt method was used to perform the nonlinear least square fit. This method employs information on the gradients and hence requires specification of the partial derivatives. A suitable model was obtained from the exponential regression model. The polynomial model was found to be appropriate for leaves, the mono-exponential model was suitable for stems and the simple exponential model for roots. The residual plots and the normal probability plots from each of the models indicated no substantial diagnostic problems, so it can be concluded that the polynomial and exponential regression models provide adequate fit to determine data on heavy metal uptake by the flowering white cabbage.
An optical fiber chemical sensor for the determination of free glutamate in food samples was fabricated based on the
immobilization of 0.1 M copper(II) nitrate trihydrate onto sol-gel glass powder which was then mixed with methyl cellulose
to form a pellet. A distinctive colour change from light blue to dark blue was observed in the presence of glutamate in
less than 1 min. The colour change was measured by reflectance spectrophotometer at 691 nm. A linear relationship
between the reflectance intensity and glutamate concentration was observed in the range of 12.5 to 500 mM with a limit
of detection of 10.6 mM. This method is also reproducible with a relative standard deviation of less than 5%, no effect on
pH of the glutamate solution and a good recovery of above 80%. The sensor was used for the determination of glutamate
in common food items such as soups and flavor enhancers. The results obtained from the fabricated sensor were found
to be comparable with HPLC method.
Selenocompounds have been widely synthesized for their potential in pharmacology. Ebselen, a selenazole oxide, is a
glutathione peroxidase mimic which is known to possess high antioxidant activity. Four derivatives of 3-(2-amino-1,3-
selenazol-4-yl)-2H-chromen-2-ones were synthesized by reacting 3-(2-bromoacetyl)-chromen-2-one derivatives with
selenourea through Hantzsch reaction using NaF as a catalyst in methanol-water (1:1) at room temperature. These
reactions were completed in 30 min and purified using column chromatography eluted with n-hexane-ethyl acetate (7:3)
to give 50-83% yields. All the compounds were successfully characterized using IR, 1H and 13C NMR as well as mass
spectrometry. The synthesized compounds were tested with DPPH assay to determine the free radical scavenging activity
and were compared to gallic and ascorbic acids as standard. Nonetheless, all compounds exhibited weak free radical
scavenging activity with IC50 value ranging from 672.13 to 984.03 µM signifying that the derivatives may possess weak
antioxidant activities.
Diverting waste material from landfill sites has a big implication for the creation of new markets and has environmental benefits through offsetting the need for the extraction of raw materials. Besides, the major attention especially in construction industry is the problem to make natural resources sustainable for three to four decades in future. However, in this study finely glass powder with pozzolanic properties is found to be a partial replacement for cement and can acts as filler in the microstructure of a mortar block. Thus, a study was conducted to see the effects of various proportions of windscreen glass waste powder (WGWP) in determining the degree of water absorption on mortar incorporated with WGWP and to determine the optimum replacement to the ordinary Portland cement (OPC) with WGWP. Several compositions of WGWP (0%, 5%, 10%, 15% and 20% by cement weight) of mortar cube sample were prepared and cured at 7, 28 and 60 days to undergo a water absorption test. From this research, it shows that the use of WGWP was found to be the best features pozzolanic enough to use as a partial replacement for cement and it can reduced the pores of mortar by blocking the large voids in the hydrated cement paste through pozzolanic reaction. In the term of water absorption, the lowest reading was achieved in 15% and it can be said that 15% replacement is the optimum replacement of OPC.
The aim of this article was to validate an instrument of quality management practices (QMPs) and performance
measurement for the manufacturing industry in Malaysia. QMPs and performance were measured using the following
six value indicators: Management commitment, training, process management, quality tools, continuous improvement
and organisational performance. A total of 480 questionnaires were distributed and 210 questionnaires were valid for
analysis. A confirmatory factor analysis (CFA) approach was employed using analysis of moment structures (AMOS)
software. The results for the hypothesised CFA model showed the following fit statistics: Comparative fit index (CFI) =
0.924, Tucker Lewis index (TLI) = 0.913 and root mean square error of approximation (RMSEA) = 0.061. The values of
CFI and TLI ≥ 0.9 and at the same time the value of RMSEA ≤ 0.08 showed that CFA model fits the data very well. Hence,
the results of the study can be used by managers in manufacturing companies to consider and adapt their QMPs and
performance assessments toward increasing competitiveness
Jerebu merupakan fenomena pencemaran udara yang memberi impak negatif kepada kesihatan dan kegiatan sosial masyarakat serta negara. Isu jerebu dibincangkan dalam al-Quran iaitu sura al-Dukhan secara menyeluruh. Kertas ini bertujuan menganalisis perbahasan berkaitan masalah jerebu yang disebutkan oleh al-Quran dan tafsiran para sarjana Islam dalam konteks dan sudut pandang Islam. Kertas ini turut membincangkan punca dan kesan berlakunya masalah jerebu daripada perspektif sains. Kajian ini menggunakan kaedah kualitatif iaitu dengan merujuk kepada kaedah transdisiplin daripada perspektif Quran dan sains. Keputusan kajian mendapati terdapat tafsiran para sarjana Islam yang mentafsirkan surah al-Dukhan dan fenomena jerebu yang berlaku pada zaman Rasullullah SAW. Ia merupakan azab dan seksaan kepada kaum Musyrikin disebabkan oleh perbuatan mereka yang enggan menerima ajaran Islam. Fenomena jerebu merupakan peringatan Allah dan pengajaran kepada umat manusia supaya sentiasa taat kepada perintah dan meninggalkan segala larangan-Nya di samping bersama-sama menjaga keharmonian dan kesejahteraan alam semesta ini. Manakala para saintis pula mendapati fenomena jerebu yang berlaku adalah berpunca daripada asap dan habuk kesan daripada aktiviti antropogen dan semula jadi serta kesannya terhadap kesihatan tubuh badan manusia yang mengakibatkan hidung berair, masalah kulit, mata terasa pedih dan berair, batuk, sakit kerongkong, kesukaran untuk bernafas dan kesakitan di bahagian dada.
Oil palm empty fruit bunch (EFB) fibres were pretreated by gamma irradiation followed by sodium carbonate (Na2
CO3
)
before the acid hydrolysis process to produce reducing sugars using diluted sulphuric acid (H2
SO4
). In this study, EFB
fibres were irradiated at different doses, i.e. 0, 100 and 200 kGy. Meanwhile, the gamma irradiated sample were then
subjected to Na2
CO3 pretreatment with 0 and 5% total titratable alkali (TTA). The effect of the pretreatment using gamma
irradiation and Na2
CO3
on the physical and chemical properties of the EFB fibres and the yield of the reducing sugar
obtained from the acid hydrolysis process was investigated. The obtained results showed that the content of holocellulose
was increased significantly with the increase of irradiation doses combined with Na2
CO3 pretreatment, whereas lignin
content of the EFB was decreased. The gamma irradiation and Na2
CO3 pretreatment resulted in structure breakage
and removal of silica of EFB fibres which can be due to the swelling of the fibres. A synergistic effect between gamma
irradiation and Na2
CO3 was observed, in which the yield of reducing sugars was increased by combining the gamma
irradiation and Na2
CO3 pretreatment.
Aktiviti guna tanah di kawasan lembangan adalah salah satu faktor yang mendorong kepada kemerosotan kualiti air
sungai akibat daripada hakisan tanih. Potensi hakisan tanih di kawasan lembangan Sungai Bilut, Raub, Pahang yang
menjadi sumber bekalan air minuman utama di daerah Raub boleh ditentukan dengan menggunakan integrasi model
Semakan Semula Persamaan Kehilangan Tanih Universal (RUSLE) dan Sistem Maklumat Geografi (GIS). Kajian ini
bertujuan untuk menentukan potensi hakisan tanih dan faktor utama yang mempengaruhi kadar hakisan tanih. Kajian ini
melibatkan penggunaan data sekunder yang terdiri daripada data hujan, data siri tanih dan topografi bagi menghasilkan
faktor kehakisan hujan (R), kebolehhakisan tanih (K), serta panjang dan kecuraman cerun (LS). Faktor litupan tumbuhan
(C) dan amalan pemuliharaan (P) pula dijana daripada imej satelit Landsat 8 (2014). Keputusan kajian menunjukkan
nilai faktor R di kawasan kajian ialah 8927.68-9775.18 MJ mm ha-1 jam-1 tahun-1, nilai K ialah 0.036-0.500 tan jam-1
MJ-1 mm-1, nilai LS ialah 0-514, nilai C ialah 0.03-0.80 dan nilai P ialah 0.1-0.7. Kawasan yang mempunyai potensi
hakisan sangat rendah hingga rendah meliputi 81%, manakala potensi hakisan tanih sederhana hingga sangat tinggi
meliputi 19% daripada keseluruhan kawasan kajian. Model yang dihasilkan mempunyai ketepatan sebanyak 81%. Faktor
utama yang mempengaruhi berlakunya hakisan tanih di kawasan kajian adalah faktor topografi, litupan tumbuhan dan
kebolehhakisan tanih. Keputusan menunjukkan analisis integrasi RUSLE dan GIS berpotensi dalam penentuan potensi
hakisan tanih untuk kawasan luas yang mempunyai pelbagai jenis guna tanah, topografi dan jenis tanih.
Tiga spesies ikan air tawar iaitu Rasbora sumatrana (Cyprinidae), Poecilia reticulata (guppy; Poeciliidae) dan Carrasius
auratus telah didedahkan kepada kromium (Cr) dan selenium (Se) yang mempunyai julat kepekatan yang berbeza selama
4 hari (96 jam) di dalam makmal. Kadar kematian dicatatkan dan kepekatan kematian ambang (LC50) dan masa kematian
ambang (LT50) dihitung. Nilai LC50 kepekatan kematian median (LC50) dan masa kematian median (LT50) didapati
berkurang dengan peningkatan kepekatan logam dan masa pendedahan bagi kesemua spesies ikan. Nilai LC50 bagi
pendedahan selama 96 jam bagi R. sumatrana, P. reticulata dan C. auratus kajian ini masing-masing bagi Cr adalah
20.91, 19.85, 28.31 mg/L dan bagi Se pula 0.21, 3.03, 0.24 mg/L. Se mempamerkan ketoksikan paling tinggi terhadap
tiga spesies ikan air tawar ini apabila mempunyai nilai LC50 96 jam paling rendah jika dibandingkan dengan Cr.
Forest structure, diversity and above-ground biomass assessment are important to understand the structural and floristic
dynamics of a mangrove forest ecosystem. Our study provides valuable comparative analysis between two areas of
disturbed mangroves at Kisap Forest Reserve, Langkawi Island. The two study sites were swamp forest at C5 which was
disrupted by harvesting activities for charcoal production and C7 was disturbed by lightning strikes. A total of 1,217
and 390 trees measuring 1 cm diameter and above were enumerated in 0.25 ha plots at both sites. Seven mangrove plant
species in C5 and eight in C7 were recorded. Ceriops tagal and Rhizophora apiculata were the most prominent species
in the C5 and C7, respectively, whereby the Rhizophoraceae was the densest family at both sites. The major contributor
of total basal area at C5 and C7 were C. tagal (5.02 m2
/ha) and R. apiculata (11.14 m2
/ha). Similarly, C. tagal (22.41 t/
ha) and R. apiculata (111.75 t/ha) also contributed the highest biomass in C5 and C7, respectively. Diversity and species
richness were higher at C7 H’=1.22; R’=1.17 compared to C5 H’= 0.76; R’=0.85 and low evenness at both sites. High
similarity was indicated between the two sites by 93%. The distribution of individuals in C7 was homogenous than that
of C5, which had more saplings. In conclusion, anthropogenic activities resulted in lower productivity of forest compared
to natural disturbances.
Kajian ini bertujuan untuk mereka bentuk dan mengkaji prestasi pengumpul fotovoltan-terma (PV/T) dengan menggunakan
reka bentuk pengumpul terma aliran air secara pilin. Reka bentuk pengumpul terma aliran air secara pilin telah dibina
semula daripada reka bentuk penyelidik sebelum ini. Pengumpul terma ini menggunakan saiz tiub yang lebih besar dan
jarak antara tiub lebih dekat berbanding dengan reka bentuk penyelidik sebelum ini. Pengumpul PV/T ini telah diuji di
bawah tiga keamatan yang berbeza iaitu 300, 500 dan 700 W/m2 serta diuji pada kadar aliran jisim air yang berbeza
iaitu 0.01, 0.02 dan 0.04 kg/s. Pada keadaan yang sama, kecekapan fotovoltan, terma dan tergabung juga menunjukkan
nilai yang paling tinggi, iaitu 4.18%, 76.68% dan 80.86%. Kecekapan terma yang dihasilkan pada kajian ini lebih tinggi
dibandingkan dengan kajian sebelumnya.
The presence of two different chromophores in benzothiazole molecule namely benzothiazole and aromatic rings lead to
interesting chemical and biological properties that attract more researches on the compounds. Three new benzothiazolylbenzoythiourea
compounds namely 1-(1,3-benzothiazol-2-yl)-3-(benzoylthiourea) (BBT), 1-(1,3-benzothiazol-2-yl)-3-
(4-chlorobenzoylthiourea) (BBT-4Cl) and 1-(1,3-benzothiazol-2-yl)-3-(4-methoxybenzoylthiourea) (BBT-4OCH3
) with
different electron withdrawing substituents (R) at the para positions on the benzene ring of benzoylthiourea ring have
been synthesized from the reaction of R-benzoyl isothiocyanate (R= H, Cl, and OCH3
) and 2-aminobenzothiazole. The
compounds were characterized by spectroscopic techniques (infrared, 1
H proton NMR and UV-Vis). The IR spectra showed
the frequency signals of n (C=O), n (C=S), n (N-H) at 1664-1673, 1238-1249 and 3031-3055 cm-1, respectively. The 1
H
proton NMR spectra showed the presence of N-H amine and amide signals in the region of (12.14-12.35) and (14.17-14.43)
ppm, respectively. The proton signals of the two benzothiazole and benzoylthiourea moieties appear at 7.08-8.16 ppm.
A theoretical study based on Density Functional Theory (DFT) and Time-Dependent (TD) DFT was conducted to optimize
the geometrical structure and investigate the electronic properties of title compounds. The highest occupied molecular
orbital (HOMO) was found on the benzothiazole moiety; while, the lowest-unoccupied molecular orbital (LUMO) was
located at the benzoylthiourea fragment. The DFT optimized structures possessed an intramolecular hydrogen bonding
and the types of para substituents used influenced the properties of hydrogen bonding.
The present study was aimed at determining the compounds available in Eleusine indica methanol extract and the effects on
herpes simplex virus type 1 (HHV1) replication cycle and progeny infectivity. Twelve compounds mostly from the flavonoid
and phenolic groups were identified by Liquid Chromatography-Tandem Mass Spectrometry (LC-MS/MS) analysis. The
effect on replication phases of HHV1 was determined by time-of-addition, time-removal and virus yield reduction assays
with expression of selected genes analysed by quantitative Real Time-Polymerase Chain Reaction (qRT-PCR). The extract
inhibited plaque formation the most during the first 2 h and at 24 h of infection. Plaque formation inhibition was also
noted at all other time points but at lesser percentage. Treatment with E. indica reduced progeny infectivity when treated
for 10 h and was dose-dependent. E. indica methanol extract inhibited immediate early, early and late phases of HHV1
replication cycle by modifying the expression of UL
54, UL
27 and UL
30 genes during the infection. Immunostaining of
infected cells confirmed that E. indica inhibited mainly Glycoproteins B but not Glycoprotein C and D. Thus, the methanol
extract of E. indica has the ability to alter HHV1 replication cycle at almost all stages and reduce progeny infectivity.
Proses penuaan seringkali dikaitkan dengan kemerosotan pada sistem kognitif. Kemerosotan kognitif bermula seawal
usia dua puluhan dan berterusan secara linear. Selain itu, kemerosotan kognitif juga menjadi lebih nyata dengan
kehadiran hingar latar. Walau bagaimanapun, kesan penuaan ke atas mekanisme pemprosesan persepsi pertuturan
menggunakan tugasan mengulang secara terus (FRT) dalam senyap dan hingar belum difahami dengan jelas. Dalam
kajian ini, pengimejan resonans magnet kefungsian (fMRI) digunakan untuk membandingkan kesan penuaan ke atas
kehubungan efektif otak yang terhasil daripada tugasan FRT ke atas subjek normal dengan empat kumpulan umur yang
berlainan iaitu 20 - 29 tahun (n = 15), 30 - 39 tahun (n = 15), 40 - 49 tahun (n = 10) dan 50 - 65 tahun (n = 14). Satu siri
lima perkataan yang diselang-seli dalam keadaan hingar dengan senyap diberikan secara auditori. Pemetaan statistik
berparameter (SPM8) dan pemodelan dinamik penyebab (DCM10) digunakan untuk menentukan kehubungan efektif otak.
Kawasan yang terlibat dalam pembinaan model kehubungan efektif otak adalah STG, HG dan PCG. Model optimum yang
dipilih dalam kajian ini adalah model yang menunjukkan keseimbangan antara ketepatan dan kesukaran. Keputusan
fMRI kehubungan efektif menunjukkan bahawa komunikasi antara intrahemisfera tidak berubah dengan menggunakan
tugasan FRT ini apabila seseorang semakin berusia, tetapi komunikasi antara interhemisfera menjadi semakin kompleks.
This research investigated the behaviour of walls produced from wood wool cement board (WWCB) which were reinforced
with a lesser known commercial timber, Kelempayan, when subjected to compression load. Kelempayan timbers were
shredded into wood wool and used as reinforcement agent in this study. WWCB having dimensions of 600 × 2400 × 50 mm
and 600 × 2400 × 75 mm, respectively, were fabricated. Properties of the WWCB samples, namely swelling, bending and
compression strength were tested. 75 mm WWCB has higher fracture toughness but lower strength compared to 50 mm
WWCB. Four types of wall systems with different type of configuration were produced and the test results were compared
focusing on their value of ultimate load and failure mode. Walls that constructed without application of link and plaster
displayed the poorest performance. Plastered and linked wall had the highest ultimate load and comparable with other
load bearing walls. The results suggested that walls constructed using WWCB reinforced with Kelempayan wood wool
are suitable for load bearing as they exhibited comparable properties when compared to the other load bearing walls
such as masonry and straw bale wall.
Natural fibre is known useful in many applications however, the existing fibre treatment method able to reduce its overall properties. In this study, a new, simple and cost-effective fibre coating treatment method was developed which was able to improve the physical and morphological properties that open a new path for natural based materials to be used in a more robust application. The physical and morphological properties of various coated kenaf fibres were analysed to comprehend the cutting behaviour of coated fibres after subjected to the pulverisation process. The kenaf fibres were individually immersed in 1:4, 1:5 and 1:6 epoxy to acetone coating solutions prior cured, and pulverised consecutively using 5 mm, 1 mm, 0.5 mm and 0.25 mm mesh sizes aperture. The morphological characteristic was analysed using polarised optical and scanning electron microscope. The result showed that 1:6 coating ratio solution able to effectively coat the fibres’ aspect ratio that forming individual coated fibre which in long length pulverised fibres. Moreover, the low viscous 1:6 solution able to penetrate inside fibre structure that supported by density and fibre crosssection analysis compare to the other solutions. In future, this analysis is crucial to give insight on the coated fibres behaviour after subjected to the mechanical means of cutting process that later relates to the reinforcing mechanism in the composite samples.
We describe a case of nephrotic syndrome case who defaulted treatment but presented with acute medical complication due to non-compliance to treatment. He subsequently developed neurological sequalae following definitive hemodialysis. Due to disease severity and its complication, active dialysis has been abandoned. There are many factors leading to this decision, but are palliative care physician right to follow the primary team’s decision, in palliating a patient with chronic kidney disease with potential hyperkalaemia consequences? The article focuses on potential ethical dilemma faced by the palliative care team in the subsequent management of this scenario.