This research aimed to investigate the effect of nanorice husk ash (NRHA) prepared using different thermal treatment methods on ultra-high-performance concrete (UHPC) behaviour. NRHA was prepared by two methods: (1) burning for 3 h at 300, 500, 700 and 900 °C and (2) burning for different durations (9, 7, 5 and 3 h) at 300, 500, 700 and 900 °C. NRHA was added to UHPC to make 25 mixtures with three dosages (1%, 3% and 5%). Density, compressive strength, tensile strength, flexure strength and ultrasonic pulse velocity tests were performed at the experimental level. Moreover, full microstructure analysis, including X-ray diffractometry, Brunauer-Emmett-Teller surface area analysis, thermogravimetric analysis, scanning electron microscopy and energy-dispersive X-ray spectroscopy, was performed. The best performances in in the first method (constant duration, different temperatures) were obtained by 1% NRHA burned at 900 °C with 12.5% compressive strength and 1% NRHA burned at 700 °C with increased ratio (10%). Moreover, the best performance in the second method (different burning durations and temperatures) was obtained by 3% NRHA with a ratio of 22.5% at 700 °C for 5 h. Burning rice husk ash improved the compressive strength. It also remarkably improved the splitting tensile strength and flexure strength by 32% and 47%, respectively, at 3% NRHA treated at 700 °C for 3 h. The microstructural analysis showed the efficient role of NRHA in the compactness of concrete sections. It improved the formation of new calcium silicate hydrate gel; decreased the cracks, voids, CaCO3 and Ca(OH)2; and increased the Ca/Si composition. The obtained experimental results were used to build an artificial neural network (ANN) to predict UHPC properties. The ANN model was used as a validation tool to determine the correlation between results. Results showed a remarkable improvement in the mechanical properties of UHPC incorporating NRHA for all mixtures. The ANN model indicated a reliable correlation between input and output variables. The R2 values for the training, validation and testing steps were all 0.99.
Replacing conventional fine aggregates with spent mushroom substrate (SMS) is aimed at developing a sustainable lightweight masonry mortar. It is also an alternative solution for the current improper mushroom waste disposals. Density, workability, compressive strength, specific strength, flexural strength, ultrasonic pulse velocity, water absorption, sorptivity, and equivalent CO2 emission in relation to sand reduction in mortars containing 2.5-15.0% (by volume) SMS passing through a 4.75-mm sieve were investigated. As the percentages of replacement increased from 2.5 to 15.0%, the density of the SMS mortar reduced up to 34.8%, with corresponding compressive strengths of 24.96 to 3.37 MPa. Mixes with up to 12.5% SMS met the minimum compressive and flexural strengths as stated in the ASTM C129 standard. In addition, the equivalent CO2 emission of the mixes reduced 15.09% as the SMS content increased while cost-effectiveness increases up to 98.15% until 7.5% SMS replacement. In conclusion, the use of SMS as fine aggregates up to 12.5% is a viable mix design strategy for producing sustainable lightweight mortar with a lower carbon emission.
The aim of the work reported in this article was to investigate the effects of medium temperature and industrial by-products on the key hardened properties of high performance concrete. Four concrete mixes were prepared based on a water-to-binder ratio of 0.35. Two industrial by-products, silica fume and Class F fly ash, were used separately and together with normal portland cement to produce three concrete mixes in addition to the control mix. The properties of both fresh and hardened concretes were examined in the laboratory. The freshly mixed concrete mixes were tested for slump, slump flow, and V-funnel flow. The hardened concretes were tested for compressive strength and dynamic modulus of elasticity after exposing to 20, 35 and 50 °C. In addition, the initial surface absorption and the rate of moisture movement into the concretes were determined at 20 °C. The performance of the concretes in the fresh state was excellent due to their superior deformability and good segregation resistance. In their hardened state, the highest levels of compressive strength and dynamic modulus of elasticity were produced by silica fume concrete. In addition, silica fume concrete showed the lowest level of initial surface absorption and the lowest rate of moisture movement into the interior of concrete. In comparison, the compressive strength, dynamic modulus of elasticity, initial surface absorption, and moisture movement rate of silica fume-fly ash concrete were close to those of silica fume concrete. Moreover, all concretes provided relatively low compressive strength and dynamic modulus of elasticity when they were exposed to 50 °C. However, the effect of increased temperature was less detrimental for silica fume and silica fume-fly ash concretes in comparison with the control concrete.
Ordinary Portland Cement (OPC) is widely used by the construction industry. Research to find the precise proportion of cement replacement material which can be used to produce a product called Ternary Blended Cement (TBC) is not new. The objective of this study is to determine the effect of POFA and SF as TBC on the heat of hydration and compressive strength of mortar. Before producing TBC, specimens using BBC is required. Mix design proportion for POFA and SF are 5%, 10%, 15%, and 20%. Mix design proportion TBC are chose from the highest compressive strength value achieved at 7 days of curing. This research found the heat of hydration of TBC containing 20% POFA and 5% SF is high in the beginning to drop at the end of hydration process in addition to producing lower compressive strength.
The massive growth of construction industry especially in the developing countries results in extensive quarrying activities which ultimately would lead to the depletion of natural resources. Apart from extensive extraction of the natural granite from the earth for concrete production, marble production industry is also majorly contributing to the quarrying activities. In addition, high volume of waste is generated by the marble production industry as 70% of marble is wasted during the production such as quarrying, cutting, processing and others which is environmental unfriendly. In a way to achieve sustainable construction, the present study is to utilise the waste marble in replacing the coarse aggregate in concrete production. The engineering performance including workability, compressive strength, ultrasonic pulse velocity (UPV) and chloride penetration were analysed. The raw waste marble obtained from the industry were crushed and sieved into maximum size 20 mm and used to replace the coarse aggregate at the level of 20%, 40%, 60%, 80% and 100% respectively. Results show that 60% of the replacement level has yield to optimum result by achieving the highest compressive strength and UPV at approximate 5% higher than the control. Meanwhile, the effect on chloride penetration resistance is more significant, i.e. approximate 19% better than the control. However, increasing the replacement level of waste marble has no significant effect on workability, although an increasing trend was observed.
Intact glenoid labrum is one of passive stabilizer for glenohumeral joint, which have various stiffness at different region. The aim of this study is to develop new artificial glenoid labrum from Polyvinyl Alcohol (PVA) hydrogel, which known as good biomaterial due to its biocompatibility and ability to tailor its modulus. PVA hydrogel was formed using freeze-thaw (FT) method and the stiffness of PVA was controlled by manipulating the concentration of PVA and number of FT cycles. Then, the gradual stiffness was formed using simple diffusion method by introducing the pre-freeze-and-thaw steps. The results showed 20% PVA with three FT cycles suit to highest stiffness of glenoid labrum while 10% PVA with three FT cycles suit to lowest stiffness of glenoid labrum. The functionally graded PVA hydrogel was then developed using the same method by diffusing two mixture (20% PVA and 10% PVA). Mechanical compression test showed, the highest modulus (0.41 MPa) found at the 20% PVA region and lowest modulus (0.1 MPa) found at 10% PVA region. While, at intermediate region, the compressive modulus was in between 20% and 10%, 0.2 MPa. The existence of gradual stiffness was further prove by checking crystallinity of material at each region using Differential Scanning Calorimetry (DSC) and Wide Angle X-ray Diffraction (WAXD). Microstructure of material was obtained from Scanning Electron Microscopy (SEM). This functionally graded PVA hydrogel also able to reduce about 51% of stress at glenoid implant and up to 17% for micromotion at the interfaces. Existence of artificial glenoid labrum could minimize the occurrence of glenoid component loosening.
Introduction: The purpose of this in vitro study was to evaluate the effect of thermocycling on the compressive strength of selected luting cements. Material and methods: 5 types of luting cements were tested. A total of thirty cylindrical specimens measuring 6mm in height and 4mm in diameter were prepared for each type of cement which were then divided into two groups ie Group 1: Exposure, and Group 2: Control. Both groups were stored in distilled water at 37°C for 24 hours. Group 1 was subjected to 500 cycles in a thermocycling baths of 5ºC and 55ºC with 20 seconds in each bath. Group 2 was not exposed to thermocycling procedure. The compressive strength for each cement type was determined by using a universal testing machine. Results: Resin adhesive cement had the highest compressive strength; followed by conventional glass ionomer cement (GIC) whilst resin modified GIC was the least. Thermocycling had no significant effect on the compressive strength of RelyXTM ARC and Fuji I (p>0.05), but a significant effect on Fuji I CAPSULE, Fuji CEM, Fuji Plus CAPSLUE (p
The influence of water-to-cement ratio (w/c) on the compressive strength of cement-biochar-spent resins matrix was
investigated. Spent resins waste from nuclear reactor operation was solidified using cement with w/c ranging from 0.35
to 0.90 by weight. In this study, biochar was used as a cement admixture. Some properties of spent resins and biochar
were determined prior to the formulation study. Compressive strength of harden cement-biochar-spent resins matrix
was determined at 28 days. The compressive strength of cement-biochar-spent resins matrix was found to depend on the
w/c and the amount of spent resins added to the formulation. The immersion test of cement-biochar-spent resins matrix
showed no significant effects of cracking and swelling. The compressive strength of the cement-biochar-spent resins
matrix increased after two weeks in water immersion test.
The main objective of this work was to investigate the influence of waterborne epoxy resin emulsion (WER) on the physical properties of oil well cement slurries. Cement slurries containing 5%, 10% and 15% of WER bwoc were compared with WER-free slurries. The rheological behavior was carried out according to API standard. Uniaxial compressive strength and shear bond strength of cement stone were evaluated at the ages of 24, 48 and 72 h. The experimental results illustrate that the addition of WER does not alter the rheological behavior. The addition of WER has increased the shear bond strength almost 52% at 24 h of aging for 10% WER bwoc when compared with unmodified slurry. The enhancement on shear bond strength was attributed to the mechanical anchoring and resin film forming at the interface
Nanosilica particles were utilized as secondary reinforcement to enhance the strength of the epoxy resin matrix. Thin glass fibre reinforced polymer (GFRP) composite laminates of 3 ± 0.25 mm were developed with E-Glass mats of 610 GSM and LY556 epoxy resin. Nanosilica fillers were mixed with epoxy resin in the order of 0.25, 0.5, 0.75 and 1 wt% through mechanical stirring followed by an ultrasonication method. Thereafter, the damage was induced on toughened laminates through low-velocity drop weight impact tests and the induced damage was assessed through an image analysis tool. The residual compression strength of the impacted laminates was assessed through compression after impact (CAI) experiments. Laminates with nanosilica as secondary reinforcement exhibited enhanced compression strength, stiffness, and damage suppression. Results of Fourier-transform infrared spectroscopy revealed that physical toughening mechanisms enhanced the strength of the nanoparticle-reinforced composite. Failure analysis of the damaged area through scanning electron microscopy (SEM) evidenced the presence of key toughening mechanisms like damage containment through micro-cracks, enhanced fiber-matrix bonding, and load transfer.
The study was carried out to determine the physical and mechanical properties of composite lumber made from cassava (Mahinot esculenta Crantz) and bamboo (Bambusa vulgaris) in different ratios which is 100% cassava with 0% bamboo, 75% cassava with 25% bamboo, 50% cassava with 50% bamboo, 25% cassava with 75% bamboo and 0% cassava with 100% bamboo. The tests samples for determining the strength properties were divided into two categories namely mechanical testing and physical testing. Basic density of the samples was carried out for physical testing. The lowest basic density was in samples with 100% cassava which is 0.49 g/cm3 and highest in samples with 100% bamboo which is 0.68 g/cm3. Two tests for the mechanical testing are bending test and compression test. In bending test, modulus of elasticity (MOE) and modulus of rupture (MOR) were both highest for samples with 100% bamboo which the reading of MOE was 16794.03 N/mm2 and 122.52 N/mm2 for MOR. Similar to the bending test, compression test is the highest for the samples with 100% bamboo which are 65.58 N/mm2. From statistical analysis, the basic density, static bending can compression strength give significant value at 95% confidence interval.
This paper discussed the effects of modified metakaolin (MK) with nano-silica (NS) on the mechanical properties and durability of concrete. In the first phase, trial mixes of concrete were prepared for achieving the desired value of the 28 days compressive strength, and the charge passed in rapid chloride permeability test (RCPT). In the second phase, statistical analysis was performed on the experimental results using the response surface method (RSM). The RSM was applied for optimizing the mix proportions for the required performance by exploiting the relationship between the mix characteristics and the corresponding test results. A blend of 10% MK + 1% NS as part of cement replacement exhibited the highest mechanical properties and durability characteristics of concrete; concrete mix showed that the 28-days compressive strength (CS) was 103 MPa, which was 15% greater than the CS of the control mix without MK or NS. The same mix showed more than 40% higher flexural and split-tensile strength than the control mix; also it resulted in a reduction of 73% in the rapid chloride permeability value. ANOVA technique was used for optimizing the nano-silica and metakaolin content for achieving maximum compressive strength and minimum RCPT value. Statistical analysis using ANOVA technique showed that the maximum compressive strength and lowest RCPT value could be achieved with a blend of 10% MK and 1.55% NS.
The recycling of millions of tons of glass bottle waste produced each year is far from optimal. In the present work, ground blast furnace slag (GBFS) was substituted in fly ash-based alkali-activated mortars (AAMs) for the purpose of preparing glass bottle waste nano-powder (BGWNP). The AAMs mixed with BGWNP were subsequently subjected to assessment in terms of their energy consumption, economic viability, and mechanical and chemical qualities. Besides affording AAMs better mechanical qualities and making them more durable, waste recycling was also observed to diminish the emissions of carbon dioxide. A more than 6% decrease in carbon dioxide emissions, an over 16% increase in compressive strength, better durability and lower water absorption were demonstrated by AAM consisting of 5% BGWNP as a GBFS substitute. By contrast, lower strength was exhibited by AAM comprising 10% BGWNP. The conclusion reached was that the AAMs produced with BGWNP attenuated the effects of global warming and thus were environmentally advantageous. This could mean that glass waste, inadequate for reuse in glass manufacturing, could be given a second life rather than being disposed of in landfills, which is significant as concrete remains the most commonplace synthetic material throughout the world.
Precast concrete panel is one of the Industrial Building System (IBS) components currently used in modern construction industry, especially, in a highly populated urban area in Malaysia, owing to its cost and time efficiency in a project completion. However, the constraints lie in Musculoskeletal Disorders (MSDs) when IBS workers manually lift the concrete panel repeatedly. The aim of this study is to analyze the recommended weight limit (RWL), lifting index (LI) and physiological experience among workers while lifting precast concrete panel with 3300mm x 600mm size and compressive strength of 40MPa. The methods involved include a survey through the Nordic questionnaires, interview sessions, NIOSH lifting index calculation, recommended work limit calculation, Rapid Upper Limb Assessment (RULA) and video recording. The results yielded the MSDs problem. The guidelines of recommended weight limit and lifting index are produced. They benefit workers and increase their awareness on the MSDs issues.
Torrefaction process of biomass material is essential in converting them into biofuel with improved calorific value and physical strength. However, the production of torrefied biomass is loose, powdery, and nonuniform. One method of upgrading this material to improve their handling and combustion properties is by densification into briquettes of higher density than the original bulk density of the material. The effects of critical parameters of briquetting process that includes the type of biomass material used for torrefaction and briquetting, densification temperature, and composition of binder for torrefied biomass are studied and characterized. Starch is used as a binder in the study. The results showed that the briquette of torrefied rubber seed kernel (RSK) is better than torrefied palm oil shell (POS) in both calorific value and compressive strength. The best quality of briquettes is yielded from torrefied RSK at the ambient temperature of briquetting process with the composition of 60% water and 5% binder. The maximum compressive load for the briquettes of torrefied RSK is 141 N and the calorific value is 16 MJ/kg. Based on the economic evaluation analysis, the return of investment (ROI) for the mass production of both RSK and POS briquettes is estimated in 2-year period and the annual profit after payback was approximately 107,428.6 USD.
The tableting properties of Labisia pumila herbal powder, which is well known for its therapeutic benefits was investigated. The herbal powder was compressed into tablets using a stainless steel cylindrical uniaxial die of 13-mm- diameter with compaction pressures ranging from 7 to 25 MPa. Two feed weights, 0.5 and 1.0 g were used to form tablets. Some empirical models were used to describe the compressibility behavior of Labisia pumila tablets. The strength and density of tablets increased with increase in compaction pressure and resulted in reduction in porosity of the tablets. Smaller feeds, higher forces and increase in compaction pressure, contributed to more coherent tablets. These findings can be used to enhance the approach and understanding of tableting properties of Labisia pumila herbal powder tablets.
This paper reports the mechanical properties of cement composite boards made using wood-wool from a lesser known Malaysian timber species. A total of 108 specimens were fabricated using Portland cement (Type I) and wood-wool from Kelampayan (Neolamarckia cadamba). The cement to wood ratio of the specimens was 2 to 1 by weight. The aim of the study was to determine the density; flexural, compressive and tensile strength of wood-wool cement composite boards (WWCCB) by studying boards with wood-wool sized 1.5 mm, 2.5 mm and 3.5 mm and board thickness 25 mm, 50 mm and 75mm. The physical and mechanical properties of the boards were evaluated according to ASTM D 1037-96a (Standard testing method for evaluating properties of wood-based fibre and particle panel materials) and MS934:1986. Results showed that mechanical properties of WWCCB were greatly influenced by the density; as the density decreased, the mechanical strengths also decreased. However, the strength properties of the composite boards did not display a similar trend when subjected to different types of loading conditions. The compressive strength increased with thicker boards (50 mm and 75 mm) but the modulus of elasticity and modulus of rupture declined as the thickness of the board was increased.
Introducing CO2 flux as the carbonate source had an effect on the carbonate content of carbonate apatite (CAp) synthesized by solid state reaction. The reactants were CaCO3 and beta-tricalcium phosphate (β-TCP) and the heat treatment in air was performed at 1250ºC followed by instant cooling in CO2 flux for temperatures ranging from 800ºC room temperature (RT) . The influence of CO2 flux at various temperature drop differences in the cooling process (1250ºC RT, 1250ºC–500ºC, 1250ºC–600ºC, 1250ºC–700ºC, and 1250ºC–800ºC) was tested to optimize the carbonation degree and subsequent effects on the physical and mechanical properties of CAp. Thermally treated samples revealed an increasing degree of carbonation, achieving a maximum of 5.2 wt% at the highest (1250ºC RT) and a minimum of 2.7 wt% at the lowest (1250ºC–800ºC) temperature drop differences, respectively. This showed that the carbonate content was correlated with the increase in exposure to CO2 flux. However, consistent compressive strength, tensile strength, density and porosity were observed against increasing temperature drop differences which indicated that the degree of carbonation exerted no influence on the physical and mechanical properties of CAp. This method enabled the synthesis of solid state CAp simply by exposing calcium phosphate mixtures to CO2 flux. It also allowed the control of carbonate content for desired medical applications.
Coastal accretion and erosion are unavoidable processes as some coastal sediments undergo modification and stabilization. This study was conducted to investigate the geotechnical behavior of soil collected from Bagan Lalang coast and treated with lime, cement, and rice husk ash (RHA) to design a low-cost alternative mixture with environmentally friendly characteristics. Laboratory tests were carried out to analyze the physical properties of the soil (Atterberg limits and compaction properties), together with mechanical characteristics (direct shear and unconfined compressive strength (UCS) tests) to determine the effect of different ratios of stabilizer/pozzolan on the coastal soil and the optimum conditions for each mixture. Part of the purpose of this study was also to analyze the shear behavior of the coastal soil and monitor the maximum axial compressive stress that the treated specimens can bear under zero confining pressure. Compared to the natural soil, the soil treated with lime and rice husk ash (LRHA) in the ratio of 1:2 (8% lime content) showed a tremendous increase in shear stress under the normal stress of 200 kPa. The strength parameters such as the cohesion (c) and internal friction angle (ϕ) values showed a significant increase. Cohesion values increased considerably in samples cured for 90 days compared to specimens cured for 7 days with additional LRHA in the ratio of 1:2 (28%).
Image analysis techniques are gaining popularity in the studies of civil engineering materials. However, the current established image analysis methods often require advanced machinery and strict image acquisition procedures which may be challenging in actual construction practices. In this study, we develop a simplified image analysis technique that uses images with only a digital camera and does not have a strict image acquisition regime. Mortar with 10%, 20%, 30%, and 40% pozzolanic material as cement replacement are prepared for the study. The properties of mortar are evaluated with flow table test, compressive strength test, water absorption test, and surface porosity based on the proposed image analysis technique. The experimental results show that mortar specimens with 20% processed spent bleaching earth (PSBE) achieve the highest 28-day compressive strength and lowest water absorption. The quantified image analysis results show accurate representation of mortar quality with 20% PSBE mortar having the lowest porosity. The regression analysis found strong correlations between all experimental data and the compressive strength. Hence, the developed technique is verified to be feasible as supplementary mortar properties for the study of mortar with pozzolanic material.