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Supported liquid membrane extraction of nickel using stable composite SPEEK/PVDF support impregnated with a sustainable liquid membrane

Sulaiman RNR, Jusoh N, Othman N, Noah NFM, Rosly MB, Rahman HA

J Hazard Mater, 2019 12 15;380:120895.
PMID: 31351388 DOI: 10.1016/j.jhazmat.2019.120895

A sustainable and stable supported liquid membrane (SLM) extraction of nickel was developed via impregnation of sustainable liquid membrane in the composite membrane support consisting of polyvinylidene fluoride (PVDF) and sulfonated poly (ether ether ketone) (SPEEK). Bis-2-ethylhexyl phosphate (D2EHPA), 1-octanol, refined palm oil and sulfuric acid were employed as extractant, synergist extractant, diluent and strippant, respectively. Variables studied including effect of refined palm oil compositions as well as the configurations and thicknesses of SPEEK. Lifespan of SLM was evaluated by recycling the composite membrane support. Results revealed that upon using 100% refined palm oil, about 100% of nickel was extracted and recovered in 10 and 14 h, respectively. Composite SPEEK/PVDF stabilized SLM by reducing liquid membrane loss from 47 to 23% upon applying SPEEK at the feed side of PVDF support. High permeability and flux values were obtained at 9.26 x 10-4 cms-1 and 6.48 x 10-7 molcm-2s-1 when increasing SPEEK thickness from 0.025 to 0.055 mm, respectively. The lifespan of SLM was extended up to ninth cycles with low weight loss percentage of the impregnated composite membrane (8%). In conclusion, the SPEEK/PVDF impregnated with refined palm oil has improved the stability of SLM extraction of nickel ions from industrial wastewater.

Matched MeSH terms: Polyvinyls
Effects of Crude Palm Oil and Crude Palm Kernel Oil Upon Wax Inhibition

Ragunathan T, Husin H, Wood CD

ACS Omega, 2020 Aug 11;5(31):19342-19349.
PMID: 32803027 DOI: 10.1021/acsomega.0c00753

The ever-increasing demand for the finite source of oil has led oil production companies to produce and transport the produced crude oil as efficiently and economically as possible. One of the major concerns especially in waters like the South China Sea is the deposition of wax on the walls of the pipeline or wellbore, constricting and hindering the hydrocarbon flow. This is due to the low seabed temperatures, which can be below the wax appearance temperature (WAT), leading to the deposition of wax out of waxy crude oil through the molecular dispersion mechanism. Currently, many prevention and remedy methods are in place to overcome the problem, but most of the additives possess environmental threat, as most of the chemical solutions used are toxic, nonorganic, and costly. Hence, this paper aims to provide some insights into the effect of palm oil derivatives such as crude palm oil (CPO) and crude palm kernel oil (CPKO) on wax inhibition. The effect of aging time (i.e., immersion time) was also evaluated. A comparison was made between paraffin inhibition efficiency results (PIE %) obtained by CPO, CPKO, poly(ethylene-co-vinyl acetate) (EVA), and triethanolamine (TEA). It was observed that the average efficiency of 81.67% was obtained when 1% CPO was added to heavy crude oil. The wax inhibition performance reached a plateau after 1.5 h of aging time for all of the investigated samples.

Matched MeSH terms: Polyvinyls
Fulltext Investigation of Anti-fouling and UV-Cleaning Properties of PVDF/TiO2 Mixed-Matrix Membrane for Humic Acid Removal

Teow YH, Ooi BS, Ahmad AL, Lim JK

Membranes (Basel), 2020 Dec 24;11(1).
PMID: 33374274 DOI: 10.3390/membranes11010016

Natural organic matters (NOMs) have been found to be the major foulant in the application of ultrafiltration (UF) for treating surface water. Against this background, although hydrophilicity has been demonstrated to aid fouling mitigation, other parameters such as membrane surface morphology may contribute equally to improved fouling resistance. In this work, with humic acid solution as the model substance, the effects of titanium dioxides (TiO2) types (PC-20, P25, and X500) on membrane anti-fouling and defouling properties were comparatively analysed. The aims are (1) to determine the correlation between membrane surface morphology and membrane fouling and (2) to investigate the anti-fouling and UV-cleaning abilities of PVDF/TiO2 mixed-matrix membranes with different membrane topographies and surface energy conditions. The mixed-matrix membrane with P25 TiO2 exhibited the most significant UV-defouling ability, with a high irreversible flux recovery ratio (IFRR(UV)) of 16.56 after 6 h of UV irradiation, whereas that with X500 TiO2 exhibited both superior anti-fouling and defouling properties due to its smoother surface and its highly reactive surface layer.

Matched MeSH terms: Polyvinyls
Fulltext High Thermal Gradient in Thermo-electrochemical Cells by Insertion of a Poly(Vinylidene Fluoride) Membrane

Hasan SW, Said SM, Sabri MF, Bakar AS, Hashim NA, Hasnan MM, et al.

Sci Rep, 2016 07 06;6:29328.
PMID: 27381946 DOI: 10.1038/srep29328

Thermo-Electrochemical cells (Thermocells/TECs) transform thermal energy into electricity by means of electrochemical potential disequilibrium between electrodes induced by a temperature gradient (ΔT). Heat conduction across the terminals of the cell is one of the primary reasons for device inefficiency. Herein, we embed Poly(Vinylidene Fluoride) (PVDF) membrane in thermocells to mitigate the heat transfer effects - we refer to these membrane-thermocells as MTECs. At a ΔT of 12 K, an improvement in the open circuit voltage (Voc) of the TEC from 1.3 mV to 2.8 mV is obtained by employment of the membrane. The PVDF membrane is employed at three different locations between the electrodes i.e. x = 2 mm, 5 mm, and 8 mm where 'x' defines the distance between the cathode and PVDF membrane. We found that the membrane position at x = 5 mm achieves the closest internal ∆T (i.e. 8.8 K) to the externally applied ΔT of 10 K and corresponding power density is 254 nWcm(-2); 78% higher than the conventional TEC. Finally, a thermal resistivity model based on infrared thermography explains mass and heat transfer within the thermocells.

Matched MeSH terms: Polyvinyls
Pure Cultivation and Morphological Studies of Four Chaetoceros Taxa from the Coastal Waters of Pahang, Malaysia

M.A.M. Fuad, N. Mohammad-Noor, A.K.C. Jalal, B.Y. Kamaruzzaman

Sains Malaysiana, 2015;44:947-955.

This study was conducted to study the morphological features of species under the genus Chaetoceros isolated from the coastal waters of Pahang, Malaysia. The species were isolated, cultivated and viewed under light microscope (LM) and scanning electron microscope (SEM). Four taxa were successfully isolated and cultivated in pure culture, namely Chaetoceros affinis var. affinis, Chaetoceros affinis var. willei, Chaetoceros anastomosans and Chaetoceros baculites. Both varieties of C. affinis were considered as distinct taxa where both strains can be distinguished based on morphological characteristics. C. affinis var. affinis has a thick cell wall compared with C. affinis var. willei. C. anastomosans has special features including a silica bar on the intersection of setae and the production of mucous. The length of the aperture opening is a new record from this study. The new record obtained for C. baculites includes the size of the aperture, the terminal setae, spinal arrangement, the thinness of the cell wall and the location of the species in tropical waters. Detailed data on each species will be added to the taxonomic information for future studies.

Matched MeSH terms: Polyvinyls
Viscosity effects of polyvinyl siloxane impression materials on the accuracy of the stone die produced

Ho W, Lin Seow L, Musawi A

J Clin Transl Res, 2018 May 28;4(1):70-74.
PMID: 30873496

Background: The purpose of the present study was to investigate the effect of different viscosities of polyvinyl siloxane (PVS) impression materials on the accuracy of the stone die produced.
Methods: A three-unit bridge master model was fabricated using cold-cure acrylic resin. Four combinations of different viscosities of PVS impression materials - regular body (monophase) alone, light body with regular body, light body with heavy body, and light body with putty - were used to make an impression of the master model. Ten impressions from each group were taken and Type IV gypsum stone was used to generate the dies. The dies were measured at the inter-abutment distance, occlusogingival length, and shoulder width with a measuring microscope and were compared with the master model using one-way analysis of variance and Tukey (honest significant difference) test.
Results: Differences were found for inter-abutment distance between the master model and the light body with regular body and light body with putty dies (both P < 0.02). A difference was found for shoulder width between the master model and the regular body alone die (P = 0.01). No differences were found for occlusogingival distance (all P > 0.08).
Conclusion: Results suggested inter-abutment distance was most accurate when using a PVS light body combination. Occlusogingival length was accurate using any of the studied PVS combinations, and shoulder width was more accurate when using the regular body PVS.
Relevance for patients: These results should be considered when choosing the viscosity of the PVS to use for producing impressions of high accuracy and fabricating a well-fitting fixed prosthesis.

Matched MeSH terms: Polyvinyls
Fulltext Lightweight and Durable PVDF-SSPF Composites for Photovoltaics Backsheet Applications: Thermal, Optical and Technical Properties

Alaaeddin MH, Sapuan SM, Zuhri MYM, Zainudin ES, M Al-Oqla F

Materials (Basel), 2019 Jun 29;12(13).
PMID: 31261926 DOI: 10.3390/ma12132104

Photovoltaic module backsheets are characterized according to their thermal, optical, mechanical, and technical properties. This work introduces new fabricated backsheets for PV modules using polyvinylidene fluoride (PVDF) reinforced with short sugar palm fiber (SSPF) composites. The preparation of composites undergoes multiple phases of fabrication. Thermal, optical, and technical investigations of their properties were conducted. Fourier transform infrared spectroscopy (FTIR), Raman spectroscopy, in-situ scanning probe microscopy (SPM), dynamic mechanical analysis (DMA), thermal mechanical analysis (TMA), thermogravimetric analysis (TGA), differential scanning calorimetry (DSC), and prolonged technical testing were accomplished to expansively understand the complex behavior of composites under various conditions. The optical properties of PV backsheets are critical components in determining the reflectance, absorbance, and transmittance of light. The PVDF-SSPF composites exhibited exceptional compatibility and thermal stability, further revealing a homogenous composite structure with enhanced interfacial bonding between the short fiber and polymer matrix.

Matched MeSH terms: Polyvinyls
Size-Controlled and Optical Properties of Platinum Nanoparticles by Gamma Radiolytic Synthesis

Gharibshahi E, Saion E, Ashraf A, Gharibshahi L

Appl Radiat Isot, 2017 Dec;130:211-217.
PMID: 29028581 DOI: 10.1016/j.apradiso.2017.09.012

Gamma radiolytic synthesis was used to produce size-controlled spherical platinum nanoparticles from an aqueous solution containing platinum tetraammine and polyvinyl pyrrolidone. The structural characterizations were performed using X-ray diffraction, and transmission electron microscopy. The transmission electron microscopy was used to determine the average particle diameter, which decreased from 4.4nm at 80kGy to 2.8nm at 120kGy. The UV-visible absorption spectrum was measured and found that platinum nanoparticles exhibit two steady absorption maxima in UV regions due to plasmonic excitation of conduction electrons, which blue shifted to lower wavelengths with a decrease in particle size. We consider the conduction electrons of platinum nanoparticles to follow Thomas-Fermi-Dirac-Weizsacker atomic model that they are not entirely free but weakly bounded to particles at lower-energy states {n = 5, l = 2 or 5d} and {n = 6, l = 0 or 6s}, which upon receiving UV photon energy the electrons make intra-band quantum excitations to higher-energy states allowed by the principles of quantum number that results the absorption maxima. We found an excellent agreement between the experimental and theoretical results, which suggest that the optical absorption of metal nanoparticles could be fundamentally described by a quantum mechanical interpretation, which could be more relevant to photo-catalysis and heterogeneous catalysis.

Matched MeSH terms: Polyvinyls
Fulltext Reflection and transmission coefficient of yttrium iron garnet filled polyvinylidene fluoride composite using rectangular waveguide at microwave frequencies

Soleimani H, Abbas Z, Yahya N, Shameli K, Soleimani H, Shabanzadeh P

Int J Mol Sci, 2012;13(7):8540-8.
PMID: 22942718 DOI: 10.3390/ijms13078540

The sol-gel method was carried out to synthesize nanosized Yttrium Iron Garnet (YIG). The nanomaterials with ferrite structure were heat-treated at different temperatures from 500 to 1000 °C. The phase identification, morphology and functional groups of the prepared samples were characterized by powder X-ray diffraction (PXRD), scanning electron microscopy (SEM) and Fourier transform infrared spectroscopy (FT-IR), respectively. The YIG ferrite nanopowder was composited with polyvinylidene fluoride (PVDF) by a solution casting method. The magnitudes of reflection and transmission coefficients of PVDF/YIG containing 6, 10 and 13% YIG, respectively, were measured using rectangular waveguide in conjunction with a microwave vector network analyzer (VNA) in X-band frequencies. The results indicate that the presence of YIG in polymer composites causes an increase in reflection coefficient and decrease in transmission coefficient of the polymer.

Matched MeSH terms: Polyvinyls/chemistry*
Sensitive voltammetric determination of paracetamol by poly (4-vinylpyridine)/multiwalled carbon nanotubes modified glassy carbon electrode

Ghadimi H, Tehrani RM, Ali AS, Mohamed N, Ab Ghani S

Anal Chim Acta, 2013 Feb 26;765:70-6.
PMID: 23410628 DOI: 10.1016/j.aca.2012.12.039

A novel glassy carbon electrode (GCE) modified with a composite film of poly (4-vinylpyridine) (P4VP) and multiwalled carbon nanotubes (P4VP/MWCNT GCE) was used for the voltammetric determination of paracetamol (PCT). This novel electrode displayed a combined effect of P4VP and MWCNT on the electro-oxidation of PCT in a solution of phosphate buffer at pH 7. Hence, conducting properties of P4VP along with the remarkable physical properties of MWCNTs might have combined effects in enhancing the kinetics of PCT oxidation. The P4VP/MWCNT GCE has also demonstrated excellent electrochemical activity toward PCT oxidation compared to that with bare GCE and MWCNT GCE. The anodic peak currents of PCT on the P4VP/MWCNT GCE were about 300 fold higher than that of the non-modified electrodes. By applying differential pulse voltammetry technique under optimized experimental conditions, a good linear ratio of oxidation peak currents and concentrations of PCT over the range of 0.02-450 μM with a limit of detection of 1.69 nM were achieved. This novel electrode was stable for more than 60 days and reproducible responses were obtained at 99% of the initial current of PCT without any influence of physiologically common interferences such as ascorbic acid and uric acid. The application of this electrode to determine PCT in tablets and urine samples was proposed.

Matched MeSH terms: Polyvinyls/chemistry*
Development of solid dispersion systems of dapivirine to enhance its solubility

Gorajana A, Ying CC, Shuang Y, Fong P, Tan Z, Gupta J, et al.

Curr Drug Deliv, 2013 Jun;10(3):309-16.
PMID: 23360246

Dapivirine, formerly known as TMC 120, is a poorly-water soluble anti-HIV drug, currently being developed as a vaginal microbicide. The clinical use of this drug has been limited due to its poor solubility. The aim of this study was to design solid dispersion systems of Dapivirine to improve its solubility. Solid dispersions were prepared by solvent and fusion methods. Dapivirine release from the solid dispersion system was determined by conducting in-vitro dissolution studies. The physicochemical characteristics of the drug and its formulation were studied using Differential Scanning Calorimetry (DSC), powder X-ray Diffraction (XRD), Fourier-transform Infrared Spectroscopy (FTIR) and Scanning Electron Microscopy (SEM). A significant improvement in drug dissolution rate was observed with the solid dispersion systems. XRD, SEM and DSC results indicated the transformation of pure Dapivirine which exists in crystalline form into an amorphous form in selected solid dispersion formulations. FTIR and HPLC analysis confirmed the absence of drug-excipient interactions. Solid dispersion systems can be used to improve the dissolution rate of Dapivirine. This improvement could be attributed to the reduction or absence of drug crystallinity, existence of drug particles in an amorphous form and improved wettability of the drug.

Matched MeSH terms: Polyvinyls/chemistry
Investigation of interpolymer complexation between Carbopol and various grades of polyvinylpyrrolidone and effects on adhesion strength and swelling properties

Tan YT, Peh KK, Al-Hanba O

J Pharm Pharm Sci, 2001 Jan-Apr;4(1):7-14.
PMID: 11302785

To investigate the interpolymer complexation between Carbopol 934P (CP) and various grades of polyvinylpyrrolidone (PVP) (K90, K32, C15, and VA/S-630).

Matched MeSH terms: Polyvinyls/chemistry*
Effect of Carbopol and polyvinylpyrrolidone on the mechanical, rheological, and release properties of bioadhesive polyethylene glycol gels

Tan YT, Peh KK, Al-Hanbali O

AAPS PharmSciTech, 2000;1(3):E24.
PMID: 14727910

This study examined the mechanical (hardness, compressibility, adhesiveness, and cohesiveness) and rheological (zero-rate viscosity and thixotropy) properties of polyethylene glycol (PEG) gels that contain different ratios of Carbopol 934P (CP) and polyvinylpyrrolidone K90 (PVP). Mechanical properties were examined using a texture analyzer (TA-XT2), and rheological properties were examined using a rheometer (Rheomat 115A). In addition, lidocaine release from gels was evaluated using a release apparatus simulating the buccal condition. The results indicated that an increase in CP concentration significantly increased gel compressibility, hardness, and adhesiveness, factors that affect ease of gel removal from container, ease of gel application onto mucosal membrane, and gel bioadhesion. However, CP concentration was negatively correlated with gel cohesiveness, a factor representing structural reformation. In contrast, PVP concentration was negatively correlated with gel hardness and compressibility, but positively correlated with gel cohesiveness. All PEG gels exhibited pseudoplastic flow with thixotropy, indicating a general loss of consistency with increased shearing stress. Drug release T50% was affected by the flow rate of the simulated saliva solution. A reduction in the flow rate caused a slower drug release and hence a higher T50% value. In addition, drug release was significantly reduced as the concentrations of CP and PVP increased because of the increase in zero-rate viscosity of the gels. Response surfaces and contour plots of the dependent variables further substantiated that various combinations of CP and PVP in the PEG gels offered a wide range of mechanical, rheological, and drug-release characteristics. A combination of CP and PVP with complementary physical properties resulted in a prolonged buccal drug delivery.

Matched MeSH terms: Polyvinyls/chemistry*
Sustainable Dissolution Performance of a Carrier Tailored Electrospun

Teoh XY, Yeoh Y, Yoong LK, Chan SY

Pharm Res, 2020 Jan 07;37(2):28.
PMID: 31912250 DOI: 10.1007/s11095-019-2734-0

PURPOSE: This study aims to conduct an impact investigation in the hydrophobic-hydrophilic balance as an important factor for dissolution improvement of a hydrophilic carrier-based solid dispersion system.
METHODS: Polymeric carriers with different hydrophobic to hydrophilic ratios were used to prepare several electrospun solid dispersion formulations. Physicochemical properties and surface morphology of the samples were assessed using Attenuated Total Reflectance Fourier Transform Infrared (ATR-FTIR), polarized light microscopy, Differential Scanning Calorimetry (DSC), X-ray Powder Diffraction (XRPD) and Scanning Electron Microscopy (SEM). Dissolution study was conducted in a non-sink condition to assess the drug release.
RESULTS: Incorporation of a higher amount of hydrophilic component showed an improvement in formulating a fully amorphous system based on XRPD, yet the dissolution rate increment showed no significant difference from the lower. Hence, the degree of crystallinity is proven not to be the crucial factor contributing to dissolution rate improvement. The presence of a concomitant hydrophobic component, however, showed ability in resisting precipitation and sustaining supersaturation.
CONCLUSION: Hydrophobicity in a binary carrier system plays an important role in achieving and maintaining the supersaturated state particularly for an amorphous solid dispersion. Graphical Abstract.

Matched MeSH terms: Polyvinyls/chemistry*
Fulltext Formulation development and optimization of sustained release matrix tablet of Itopride HCl by response surface methodology and its evaluation of release kinetics

Bose A, Wong TW, Singh N

Saudi Pharm J, 2013 Apr;21(2):201-13.
PMID: 23960836 DOI: 10.1016/j.jsps.2012.03.006

The objective of this present investigation was to develop and formulate sustained release (SR) matrix tablets of Itopride HCl, by using different polymer combinations and fillers, to optimize by Central Composite Design response surface methodology for different drug release variables and to evaluate drug release pattern of the optimized product. Sustained release matrix tablets of various combinations were prepared with cellulose-based polymers: hydroxy propyl methyl cellulose (HPMC) and polyvinyl pyrolidine (pvp) and lactose as fillers. Study of pre-compression and post-compression parameters facilitated the screening of a formulation with best characteristics that underwent here optimization study by response surface methodology (Central Composite Design). The optimized tablet was further subjected to scanning electron microscopy to reveal its release pattern. The in vitro study revealed that combining of HPMC K100M (24.65 MG) with pvp(20 mg)and use of LACTOSE as filler sustained the action more than 12 h. The developed sustained release matrix tablet of improved efficacy can perform therapeutically better than a conventional tablet.

Matched MeSH terms: Polyvinyls
Fulltext Development of Polyvinylidene Fluoride Membrane by Incorporating Bio-Based Ginger Extract as Additive

Fahrina A, Arahman N, Mulyati S, Aprilia S, Mat Nawi NI, Aqsha A, et al.

Polymers (Basel), 2020 Sep 03;12(9).
PMID: 32899138 DOI: 10.3390/polym12092003

Biofouling on the membrane surface leads to performance deficiencies in membrane filtration. In this study, the application of ginger extract as a bio-based additive to enhance membrane antibiofouling properties was investigated. The extract was dispersed in a dimethyl acetamide (DMAc) solvent together with polyvinylidene fluoride (PVDF) to enhance biofouling resistance of the resulting membrane due to its antibiotic property. The concentrations of the ginger extract in the dope solution were varied in the range of 0-0.1 wt %. The antibacterial property of the resulting membranes was assessed using the Kirby Bauer disc diffusion method. The results show an inhibition zone formed around the PVDF/ginger membrane against Escherichia coli and Staphylococcus aureus demonstrating the efficacy of the residual ginger extract in the membrane matrix to impose the antibiofouling property. The addition of the ginger extract also enhanced the hydrophilicity in the membrane surface by lowering the contact angle from 93° to 85°, which was in good agreement with the increase in the pure water flux of up to 62%.

Matched MeSH terms: Polyvinyls
Fulltext Carnauba Wax/Halloysite Nanotube with Improved Anti-Wetting and Permeability of Hydrophobic PVDF Membrane via DCMD

AbdulKadir WAFW, Ahmad AL, Boon Seng O

Membranes (Basel), 2021 Mar 23;11(3).
PMID: 33807017 DOI: 10.3390/membranes11030228

The hydrophobic membranes have been widely explored to meet the membrane characteristics for the membrane distillation (MD) process. Inorganic metal oxide nanoparticles have been used to improve the membrane hydrophobicity, but limited studies have used nano clay particles. This study introduces halloysite nanotube (HNT) as an alternative material to synthesis a hydrophobic poly(vinylidene fluoride) (PVDF)-HNT membrane. The PVDF membranes were fabricated using functionalized HNTs (e.g., carnauba wax and 1H,1H,2H,2H-perfluorooctyl-trichlorosilane (FOTS)). The results were determined by Fourier transform infrared-attenuated total reflection, scanning electron microscope, goniometer and porometer to determine the desired hydrophobic membrane for direct contact membrane distillation (DCMD). The addition of FOTS-HNT (fs-HNT) and carnauba wax-HNT (fw-HNT) in the PVDF membrane enhanced the water contact angle (CA) to 127° and 137°, respectively. The presence of fw-HNT in the PVDF membrane exhibited higher liquid entry pressure (LEP) (2.64 bar) compared to fs-HNT in the membrane matrix (1.44 bar). The PVDF/fw-HNT membrane (Pfw-HNT) obtained the highest flux of 7.24 L/m2h with 99.9% salt removal. A stable permeability in the Pfw-HNT membrane was obtained throughout 16 h of DCMD. The incorporation of fw-HNT in the PVDF membrane had improved the anti-wetting properties and the membrane performance with the anti-fouling effect.

Matched MeSH terms: Polyvinyls
Fulltext Development of Polyvinylidene Fluoride Membrane via Assembly of Tannic Acid and Polyvinylpyrrolidone for Filtration of Oil/Water Emulsion

Nawi NIM, Ong Amat S, Bilad MR, Nordin NAHM, Shamsuddin N, Prayogi S, et al.

Polymers (Basel), 2021 Mar 22;13(6).
PMID: 33810126 DOI: 10.3390/polym13060976

Wastewater containing oil/water emulsion has a serious ecological impact and threatens human health. The impact worsens as its volume increases. Oil/water emulsion needs to be treated before it is discharged or reused again for processing. A membrane-based process is considered attractive in effectively treating oil/water emulsion, but progress has been dampened by the membrane fouling issue. The objective of this study is to develop polyvinylidene fluoride (PVDF) membranes customized for oil/water emulsion separation by incorporating assembly of tannic acid (TA) and polyvinylpyrrolidone (PVP) in the polymer matrix. The results show that the assembly of TA/PVP complexation was achieved as observed from the change in colour during the phase inversion and as also proven from the characterization analyses. Incorporation of the TA/PVP assembly leads to enhanced surface hydrophilicity by lowering the contact angle from 82° to 47°. In situ assembly of the TA/PVP complex also leads to enhanced clean water permeability by a factor of four as a result of enhanced mean flow pore size from 0.2 to 0.9 µm. Owing to enhanced surface chemistry and structural advantages, the optimum hydrophilic PVDF/TA/PVP membrane poses permeability of 540.18 L/(m2 h bar) for oil/water emulsion filtration, three times higher than the pristine PVDF membrane used as the reference.

Matched MeSH terms: Polyvinyls
Fulltext The Impact of Polyvinylpyrrolidone on Properties of Cadmium Oxide Semiconductor Nanoparticles Manufactured by Heat Treatment Technique

Al-Hada NM, Saion E, Talib ZA, Shaari AH

Polymers (Basel), 2016 Apr 08;8(4).
PMID: 30979222 DOI: 10.3390/polym8040113

Cadmium oxide semiconductor nanoparticles were produced using a water based mixture, incorporating cadmium nitrates, polyvinyl pyrrolidone (PVP), and calcination temperature. An X-ray diffraction (XRD) evaluation was conducted to determine the degree of crystallization of the semiconductor nanoparticles. In addition, scanning electron microscopy (SEM) was conducted to identify the morphological features of the nanoparticles. The typical particle sizes and particle dispersal were analyzed via the use of transmission electron microscopy (TEM). The findings provided further support for the XRD outcomes. To determine the composition phase, Fourier transform infrared spectroscopy (FT-IR) was conducted, as it indicated the existence of not only metal oxide ionic band in the selection of samples, but also the efficient removal of organic compounds following calcinations. The optical characteristics were demonstrated, so as to analyze the energy band gap via the use of a UV⁻Vis spectrophotometer. A reduced particle size resulted in diminution of the intensity of photoluminescence, was demonstrated by PL spectra. Plus, the magnetic characteristics were examined using an electron spin resonance (ESR) spectroscopy, which affirmed the existence of unpaired electrons.

Matched MeSH terms: Polyvinyls
Fulltext Conductivity and FTIR studies of low molecular weight polyvinyl chloride-based polymer electrolytes

Ramesh, S., Shanti, R., Chin, S.F.

ASM Science Journal, 2011;5(1):19-26.
MyJurnal

In this present study, a series of polymer electrolyte thin films were synthesized by incorporating different ratios of lithium triflate (LiCF3SO3) in a low molecular weight polyvinyl chloride (PVC) matrix by the solution casting technique. The incorporation of LiCF3SO3 suppressed the high degree of crystallinity in PVC enabling the system to possess an appreciable ionic conductivity. The ionic conductivity of the samples, with different LiCF3SO3 content, was determined by the aid of ac impedance spectroscopy. The highest ionic conductivity of 4.04  10–9 S cm–1 was identified for the composition of PVC: LiCF3SO3 (75:25). Further understanding of the ionic conductivity mechanism was based on temperature-dependent conductivity data which obeyed Arrhenius theory, indicating that the ionic conductivity enhancement was thermally assisted. The possible dipole-dipole interaction between the chemical constituents was confirmed with changes in cage peak, analysed using Fourier transform infrared spectroscopy.

Matched MeSH terms: Polyvinyls

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