Displaying publications 1 - 20 of 321 in total

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  1. Samsudin MH, Hassan MA, Idris J, Ramli N, Mohd Yusoff MZ, Ibrahim I, et al.
    Waste Manag Res, 2019 May;37(5):551-555.
    PMID: 30727859 DOI: 10.1177/0734242X18823953
    A one-step self-sustained carbonization of coconut shell biomass, carried out in a brick reactor at a relatively low temperature of 300-500°C, successfully produced a biochar-derived adsorbent with 308 m2/g surface area, 2 nm pore diameter, and 0.15 cm3/g total pore volume. The coconut shell biochar qualifies as a nano-adsorbent, supported by scanning electron microscope images, which showed well-developed nano-pores on the surface of the biochar structure, even though there was no separate activation process. This is the first report whereby coconut shell can be converted to biochar-derived nano-adsorbent at a low carbonization temperature, without the need of the activation process. This is superior to previous reports on biochar produced from oil palm empty fruit bunch.
    Matched MeSH terms: Charcoal*
  2. Oh WD, Zaeni JRJ, Lisak G, Lin KA, Leong KH, Choong ZY
    Chemosphere, 2021 Aug;277:130313.
    PMID: 33780679 DOI: 10.1016/j.chemosphere.2021.130313
    Engineered biochar is increasingly regarded as a cost-effective and eco-friendly peroxymonosulfate (PMS) activator. Herein, biochar doped with nitrogen and sulfur moieties was prepared by pyrolysis of wood shavings and doping precursor. The doping precursor consists of either urea, thiourea or 1:1 w/w mixture of urea and thiourea (denoted as NSB-U, NSB-T and NSB-UT, respectively). The physicochemical properties of the NSBs were extensively characterized, revealing that they are of noncrystalline carbon with porous structure. The NSBs were employed as PMS activator to degrade organic pollutants particularly methylene blue (MB). It was found that NSB-UT exhibited higher MB removal rate with kapp = 0.202 min-1 due to its relatively high surface area and favorable intrinsic surface moieties (combination of graphitic N and thiophenic S). The effects of catalyst loading, PMS dosage and initial pH were evaluated. Positive enhancement of the MB removal rate can be obtained by carefully increasing the catalyst loading or PMS dosage. Meanwhile, the MB removal rate is greatly influenced by pH due to electrostatic interactions and pH dependent reactions. The NSB-UT can be reused for several cycles to some extent and its catalytic activity can be restored by thermal treatment. Based on the radical scavenger study and XPS analysis, the nonradical pathway facilitated by the graphitic N and thiophenic S active sites are revealed to be the dominant reaction pathway. Overall, the results of this study show that engineered biochar derived from locally available biowaste can be transformed into PMS activator for environmental applications.
    Matched MeSH terms: Charcoal*
  3. Loy ACM, Alhazmi H, Lock SSM, Yiin CL, Cheah KW, Chin BLF, et al.
    Bioresour Technol, 2021 Dec;341:125796.
    PMID: 34454232 DOI: 10.1016/j.biortech.2021.125796
    The environmental footprints of H2productionviacatalytic gasification of wheat straw using straw-derived biochar catalysts were examined. The functional unit of 1 kg of H2was adopted in the system boundaries, which includes 5 processes namely biomass collection and pre-treatment units (P1), biochar catalyst preparation using fast pyrolysis unit (P2), two-stage pyrolysis-gasification unit (P3), products separation unit (P4), and H2distribution to downstream plants (P5). Based on the life-cycle assessment, the hot spots in this process were identified, the sequence was as follows: P4 > P2 > P1 > P3 > P5. The end-point impacts score for the process was found to be 93.4017 mPt. From benchmarking analysis, the proposed straw-derived biochar catalyst was capable of offering almost similar catalytic performance with other metal-based catalysts with a lower environmental impact.
    Matched MeSH terms: Charcoal*
  4. Yek PNY, Liew RK, Osman MS, Lee CL, Chuah JH, Park YK, et al.
    J Environ Manage, 2019 Apr 15;236:245-253.
    PMID: 30735943 DOI: 10.1016/j.jenvman.2019.01.010
    Microwave-steam activation (MSA), an innovative pyrolysis approach combining the use of microwave heating and steam activation, was investigated for its potential production of high grade activated carbon (AC) from waste palm shell (WPS) for methylene blue removal. MSA was performed via pyrolytic carbonization of WPS to produce biochar as the first step followed by steam activation of the biochar using microwave heating to form AC. Optimum yield and adsorption efficiency of methylene blue were obtained using response surface methodology involving several key process parameters. The resulting AC was characterized for its porous characteristics, surface morphology, proximate analysis and elemental compositions. MSA provided a high activation temperature above 500 °C with short process time of 15 min and rapid heating rate (≤150 °C/min). The results from optimization showed that one gram of AC produced from steam activation under 10 min of microwave heating at 550 °C can remove up to 38.5 mg of methylene blue. The AC showed a high and uniform surface porosity consisting high fixed carbon (73 wt%), micropore and BET surface area of 763.1 and 570.8 m2/g respectively, hence suggesting the great potential of MSA as a promising approach to produce high grade adsorbent for dye removal.
    Matched MeSH terms: Charcoal*
  5. Iberahim N, Sethupathi S, Bashir MJK, Kanthasamy R, Ahmad T
    Sci Total Environ, 2022 Jan 20;805:150421.
    PMID: 34818803 DOI: 10.1016/j.scitotenv.2021.150421
    The emission of sulphur dioxide (SO2) gas from power plants and factories to the atmosphere has been an environmental challenge globally. Thus, there is a great interest to control the SO2 gas emission economically and effectively. This study aims to use and convert abundantly available oil palm fiber (OPF) biomass into an adsorbent to adsorb SO2 gas. The preparation of OPF biochar and activated biochar was optimised using the Response Surface Methodology (RSM) based on selected parameters (i.e., pyrolysis temperature, heating rate, holding time, activation temperature, activation time and CO2 flowrate). The best adsorbent was found to be the OPF activated biochar (OPFAB) compared to OPF biochar. OPFAB prepared at 753 °C for 73 min of activation time with 497 ml/min of CO2 flow yields the best adsorption capacity (33.09 mg/g) of SO2. Meanwhile, OPF pyrolysed at 450 °C of heating temperature, 12 °C/min of heating rate and 98 min of holding time yield adsorption capacity at 18.62 mg/g. Various characterisations were performed to investigate the properties and mechanism of the SO2 adsorption process. Thermal regeneration shows the possibilities for the spent adsorbent to be recycled. The findings imply OPFAB as a promising adsorbent for SO2 adsorption.
    Matched MeSH terms: Charcoal*
  6. Gasim MF, Lim JW, Low SC, Lin KA, Oh WD
    Chemosphere, 2022 Jan;287(Pt 4):132458.
    PMID: 34610377 DOI: 10.1016/j.chemosphere.2021.132458
    Over the past decade, there has been a surge of interest in using char (hydrochar or biochar) derived from biomass as persulfate (PS, either peroxymonosulfate or peroxydisulfate) activator for anthropogenic pollutants removal. While extensive investigation showed that char could be used as a PS activator, its sustainability over prolonged application is equivocal. This review provides an assessment of the knowledge gap related to the sustainability of char as a PS activator. The desirable char properties for PS activation are identified, include the high specific surface area and favorable surface chemistry. Various synthesis strategies to obtain the desirable properties during biomass pre-treatment, hydrochar and biochar synthesis, and char post-treatment are discussed. Thereafter, factors related to the sustainability of employing char as a PS activator for anthropogenic pollutants removal are critically evaluated. Among the critical factors include performance uncertainty, competing adsorption process, char stability during PS activation, biomass precursor variation, scalability, and toxic components in char. Finally, some potential research directions are provided. Fulfilling the sustainability factors will provide opportunity to employ char as an economical and efficient catalyst for sustainable environmental remediation.
    Matched MeSH terms: Charcoal*
  7. Yu KL, Lau BF, Show PL, Ong HC, Ling TC, Chen WH, et al.
    Bioresour Technol, 2017 Dec;246:2-11.
    PMID: 28844690 DOI: 10.1016/j.biortech.2017.08.009
    Algal biomass is known as a promising sustainable feedstock for the production of biofuels and other valuable products. However, since last decade, massive amount of interests have turned to converting algal biomass into biochar. Due to their high nutrient content and ion-exchange capacity, algal biochars can be used as soil amendment for agriculture purposes or adsorbents in wastewater treatment for the removal of organic or inorganic pollutants. This review describes the conventional (e.g., slow and microwave-assisted pyrolysis) and newly developed (e.g., hydrothermal carbonization and torrefaction) methods used for the synthesis of algae-based biochars. The characterization of algal biochar and a comparison between algal biochar with biochar produced from other feedstocks are also presented. This review aims to provide updated information on the development of algal biochar in terms of the production methods and the characterization of its physical and chemical properties to justify and to expand their potential applications.
    Matched MeSH terms: Charcoal*
  8. Jayakumar M, Hamda AS, Abo LD, Daba BJ, Venkatesa Prabhu S, Rangaraju M, et al.
    Chemosphere, 2023 Dec;345:140515.
    PMID: 37871877 DOI: 10.1016/j.chemosphere.2023.140515
    Biochar is an ample source of organic carbon prepared by the thermal breakdown of biomass. Lignocellulosic biomass is a promising precursor for biochar production, and has several applications in various industries. In addition, biochar can be applied for environmental revitalization by reducing the negative impacts through intrinsic mechanisms. In addition to its environmentally friendly nature, biochar has several recyclable and inexpensive benefits. Nourishing and detoxification of the environment can be undertaken using biochar by different investigators on account of its excellent contaminant removal capacity. Studies have shown that biochar can be improved by activation to remove toxic pollutants. In general, biochar is produced by closed-loop systems; however, decentralized methods have been proven to be more efficient for increasing resource efficiency in view of circular bio-economy and lignocellulosic waste management. In the last decade, several studies have been conducted to reveal the unexplored potential and to understand the knowledge gaps in different biochar-based applications. However, there is still a crucial need for research to acquire sufficient data regarding biochar modification and management, the utilization of lignocellulosic biomass, and achieving a sustainable paradigm. The present review has been articulated to provide a summary of information on different aspects of biochar, such as production, characterization, modification for improvisation, issues, and remediation have been addressed.
    Matched MeSH terms: Charcoal*
  9. Kurniawan TA, Singh D, Avtar R, Othman MHD, Hwang GH, Albadarin AB, et al.
    Chemosphere, 2021 Jul;274:129986.
    PMID: 33979934 DOI: 10.1016/j.chemosphere.2021.129986
    This work investigates the performances of coconut shell waste-based activated carbon (CSWAC) adsorption in batch studies for removal of ammoniacal nitrogen (NH3-N) and refractory pollutants (as indicated by decreasing COD concentration) from landfill leachate. To valorize unused resources, coconut shell, recovered and recycled from agricultural waste, was converted into activated carbon, which can be used for leachate treatment. The ozonation of the CSWAC was conducted to enhance its removal performance for target pollutants. The adsorption mechanisms of refractory pollutants by the adsorbent are proposed. Perspectives on nutrient recovery technologies from landfill leachate from the view-points of downstream processing are presented. Their removal efficiencies for both recalcitrant compounds and ammoniacal nitrogen were compared to those of other techniques reported in previous work. It is found that the ozonated CSWAC substantially removed COD (i.e. 76%) as well as NH3-N (i.e. 75%), as compared to the CSWAC without pretreatment (i.e. COD: 44%; NH3-N: 51%) with NH3-N and COD concentrations of 2750 and 8500 mg/L, respectively. This reveals the need of ozonation for the adsorbent to improve its performance for the removal of COD and NH3-N at optimized reactions: 30 g/L of CSWAC, pH 8, 200 rpm of shaking speed and 20 min of reaction time. Nevertheless, treatment of the leachate samples using the ozonated CSWAC alone was still unable to result in treated effluents that could meet the COD and NH3-N discharge standards below 200 and 5 mg/L, respectively, set by legislative requirements. This reveals that another treatment is necessary to be undertaken to comply with the requirement of their effluent limit.
    Matched MeSH terms: Charcoal
  10. Ren T, Chen N, Wan Mahari WA, Xu C, Feng H, Ji X, et al.
    Environ Res, 2021 01;192:110273.
    PMID: 33002505 DOI: 10.1016/j.envres.2020.110273
    Pot experiments were conducted to investigate the influence of biochar addition and the mechanisms that alleviate Cd stress in the growth of tobacco plant. Cadmium showed an inhibitory effect on tobacco growth at different post-transplantation times, and this increased with the increase in soil Cd concentration. The growth index decreased by more than 10%, and the photosynthetic pigment and photosynthetic characteristics of the tobacco leaf were significantly reduced, and the antioxidant enzyme activity was enhanced. Application of biochar effectively alleviated the inhibitory effect of Cd on tobacco growth, and the alleviation effect of treatments is more significant to the plants with a higher Cd concentration. The contents of chlorophyll a, chlorophyll b, and carotenoids in the leaves of tobacco plants treated with biochar increased by 9.99%, 12.58%, and 10.32%, respectively, after 60 days of transplantation. The photosynthetic characteristics index of the net photosynthetic rate increased by 11.48%, stomatal conductance increased by 11.44%, and intercellular carbon dioxide concentration decreased to 0.92. Based on the treatments, during the growth period, the antioxidant enzyme activities of tobacco leaves comprising catalase, peroxidase, superoxide dismutase, and malondialdehyde increased by 7.62%, 10.41%, 10.58%, and 12.57%, respectively, after the application of biochar. Our results show that biochar containing functional groups can effectively reduce the effect of Cd stress by intensifying the adsorption or passivation of Cd in the soil, thereby, significantly reducing the Cd content in plant leaves, and providing a theoretical basis and method to alleviate soil Cd pollution and effect soil remediation.
    Matched MeSH terms: Charcoal
  11. Ahmed A, Abu Bakar MS, Hamdani R, Park YK, Lam SS, Sukri RS, et al.
    Environ Res, 2020 07;186:109596.
    PMID: 32361527 DOI: 10.1016/j.envres.2020.109596
    Biochar production from invasive species biomass discarded as waste was studied in a fixed bed reactor pyrolysis system under different temperature conditions for value-added applications. Prior to pyrolysis, the biomass feedstock was characterized by proximate, ultimate, and heating value analyses, while the biomass decomposition behavior was examined by thermogravimetric analysis. The heating values of the feedstock biomass ranged from 18.65 to 20.65 MJ/kg, whereas the volatile matter, fixed carbon, and ash content were 61.54-72.04 wt %, 19.27-26.61 wt % and 1.51-1.86 wt %, respectively. The elemental composition of carbon, hydrogen, and oxygen in the samples was reported to be in the range of 47.41-48.47 wt %, 5.50-5.88 wt % and 46.10-45.18 wt %, respectively, while the nitrogen and sulphur content in the biomass samples were at very low concentrations, making it more useful for valorization from environmental aspects. The biochar yields were reported in the range of 45.36-58.35 wt %, 28.63-44.38 wt % and 22.68-29.42 wt % at a pyrolysis temperature of 400 °C, 500 °C, and 600 °C, respectively. The biochars were characterized from ultimate analysis, heating value, energy densification ratio, energy yield, pH, Fourier transform infrared spectroscopy (FTIR), and scanning electron microscopy and energy dispersive X-ray spectrometry (SEM and EDX), to evaluate their potential for value-added applications. The carbon content, heating value, energy densification ratio, and the porosity of the biochars improved with the increase in pyrolysis temperature, while the energy yield, hydrogen, oxygen, and nitrogen content of the biochars decreased. This study revealed the potential of the valorization of underutilized discarded biomass of invasive species via a pyrolysis process to produce biochar for value-added applications.
    Matched MeSH terms: Charcoal*
  12. Chen WH, Hsu HJ, Kumar G, Budzianowski WM, Ong HC
    Bioresour Technol, 2017 Dec;246:12-19.
    PMID: 28803060 DOI: 10.1016/j.biortech.2017.07.184
    This study focuses on the biochar formation and torrefaction performance of sugarcane bagasse, and they are predicted using the bilinear interpolation (BLI), inverse distance weighting (IDW) interpolation, and regression analysis. It is found that the biomass torrefied at 275°C for 60min or at 300°C for 30min or longer is appropriate to produce biochar as alternative fuel to coal with low carbon footprint, but the energy yield from the torrefaction at 300°C is too low. From the biochar yield, enhancement factor of HHV, and energy yield, the results suggest that the three methods are all feasible for predicting the performance, especially for the enhancement factor. The power parameter of unity in the IDW method provides the best predictions and the error is below 5%. The second order in regression analysis gives a more reasonable approach than the first order, and is recommended for the predictions.
    Matched MeSH terms: Charcoal*
  13. Lam SS, Liew RK, Cheng CK, Rasit N, Ooi CK, Ma NL, et al.
    J Environ Manage, 2018 May 01;213:400-408.
    PMID: 29505995 DOI: 10.1016/j.jenvman.2018.02.092
    Fruit peel, an abundant waste, represents a potential bio-resource to be converted into useful materials instead of being dumped in landfill sites. Palm oil mill effluent (POME) is a harmful waste that should also be treated before it can safely be released to the environment. In this study, pyrolysis of banana and orange peels was performed under different temperatures to produce biochar that was then examined as adsorbent in POME treatment. The pyrolysis generated 30.7-47.7 wt% yield of a dark biochar over a temperature ranging between 400 and 500 °C. The biochar contained no sulphur and possessed a hard texture, low volatile content (≤34 wt%), and high amounts of fixed carbon (≥72 wt%), showing durability in terms of high resistance to chemical reactions such as oxidation. The biochar showed a surface area of 105 m2/g and a porous structure containing mesopores, indicating its potential to provide many adsorption sites for use as an adsorbent. The use of the biochar as adsorbent to treat the POME showed a removal efficiency of up to 57% in reducing the concentration of biochemical oxygen demand (BOD), chemical oxygen demand COD, total suspended solid (TSS) and oil and grease (O&G) of POME to an acceptable level below the discharge standard. Our results indicate that pyrolysis shows promise as a technique to transform banana and orange peel into value-added biochar for use as adsorbent to treat POME. The recovery of biochar from fruit waste also shows advantage over traditional landfill approaches in disposing this waste.
    Matched MeSH terms: Charcoal*
  14. Obayomi KS, Lau SY, Zahir A, Meunier L, Zhang J, Dada AO, et al.
    Chemosphere, 2023 Feb;313:137533.
    PMID: 36528163 DOI: 10.1016/j.chemosphere.2022.137533
    In this present study, silver (Ag) and titanium dioxide (TiO2) nanoparticles were successfully deposited on coconut shell-derived activated carbon (CSAC), to synthesize a novel nanocomposite (CSAC@AgNPs@TiO2NPs) for the adsorption of Methylene Blue (MB) dye from aqueous solution. The fabricated CSAC@AgNPs@TiO2NPs nanocomposite was analyzed by Scanning Electron Microscope (SEM), X-ray Diffraction (XRD), Fourier-Transform Infrared Spectroscopy (FTIR), Transmission Electron Microscope (TEM) equipped with Energy Dispersive X-ray spectroscopy (EDS) detector, X-ray Photoelectron Spectroscope (XPS), and Brunauer-Emmett-Teller (BET). The successful deposition of AgNPs and TiO2NPs on CSAC surface was revealed by the TEM/EDX, SEM, and XPS analysis. The mesopore structure of CSAC@AgNPs@TiO2NPs has a BET surface area of 301 m2/g. The batch adsorption studies were conducted and the influence of different parameters, i.e., adsorbent dose, adsorption time, initial dye concentration, pH and temperature were investigated. The nonlinear isotherm and kinetic modelling demonstrated that adsorption data were best fitted by Sips isotherm and pseudo-second-order models, respectively. The maximum adsorption capacity of MB onto CSAC@AgNPs@TiO2NPs by the Sips model was 184 mg/g. Thermodynamic results revealed that the adsorption was endothermic, spontaneous and physical in nature. CSAC@AgNPs@TiO2NPs revealed that MB absorption by CSAC@AgNPs@TiO2NPs was spontaneous and endothermic. The uptake capacity of MB was influenced significantly by the presence of competing ions including, NO3-, HCO3, Ca2+, and Na+. Repeated tests indicated that the CSAC@AgNPs@TiO2NPs can be regenerated and reused six times before being discarded. The primary separation mechanism between MB dye and CSAC@AgNPs@TiO2NPs was the electrostatic interaction. Thus, CSAC@AgNPs@TiO2NPs was an outstanding material, which displayed good applicability in real water with ≥ 97% removal of MB dye.
    Matched MeSH terms: Charcoal/chemistry
  15. Ajien A, Idris J, Md Sofwan N, Husen R, Seli H
    Waste Manag Res, 2023 Jan;41(1):37-51.
    PMID: 36346183 DOI: 10.1177/0734242X221127167
    The coconut industry generates a relatively large amount of coconut shell and husk biomass, which can be utilized for industrial and environmental purposes. Immense potential for added value when coconut shell and husk biomass are turned into biochar and limited studies are available, making this review paper significant. This paper specifically presents the production and activation technology, economic and financial aspect and application of biochar from coconut shell and husk biomass. Pyrolysis, gasification and self-sustained carbonization are among the production technology discussed to convert this biomass into carbon-rich materials with distinctive characteristics. The surface characteristics of coconut-based biochar, that is, Brunauer-Emmett-Teller (BET) surface area (SBET), pore volume (Vp), pore diameter (dp) and surface functional group can be enhanced by physical and chemical activation and metal impregnation. Due to their favourable characteristics, coconut shell and husk-activated biochar exhibit their potential as valuable adsorption materials for industrial and environmental application including biodiesel production, capacitive deionization, soil amendment, water treatment and carbon sequestration. With the knowledge of the potential, the coconut industry can contribute to both the local and global biocircular economy by producing coconut shell and husk biochar for economic development and environmental remediation. The capital and operating cost for production and activation processes must be taken into account to ensure bioeconomy sustainability, hence coconut shell and husk biomass have a great potential for income generation.
    Matched MeSH terms: Charcoal*
  16. Kurniawan TA, Othman MHD, Liang X, Goh HH, Gikas P, Chong KK, et al.
    J Environ Manage, 2023 Apr 15;332:117429.
    PMID: 36773474 DOI: 10.1016/j.jenvman.2023.117429
    Biochar, derived from unused biomass, is widely considered for its potential to deal with climate change problems. Global interest in biochar is attributed to its ability to sequester carbon in soil and to remediate aquatic environment from water pollution. As soil conditioner and/or adsorbent, biochar offers opportunity through a circular economy (CE) paradigm. While energy transition continues, progress toward low-emissions materials accelerates their advance towards net-zero emissions. However, none of existing works addresses CE-based biochar management to achieve carbon neutrality. To reflect its novelty, this work provides a critical overview of challenges and opportunities for biochar to promote CE and carbon neutrality. This article also offers seminal perspectives about strengthening biomass management through CE and resource recovery paradigms, while exploring how the unused biomass can promote net zero emissions in its applications. By consolidating scattered knowledge in the body of literature into one place, this work uncovers new research directions to close the loops by implementing the circularity of biomass resources in various fields. It is conclusive from a literature survey of 113 articles (2003-2023) that biomass conversion into biochar can promote net zero emissions and CE in the framework of the UN Sustainable Development Goals (SDGs). Depending on their physico-chemical properties, biochar can become a suitable feedstock for CE. Biochar application as soil enrichment offsets 12% of CO2 emissions by land use annually. Adding biochar to soil can improve its health and agricultural productivity, while minimizing about 1/8 of CO2 emissions. Biochar can also sequester CO2 in the long-term and prevent the release of carbon back into the atmosphere after its decomposition. This practice could sequester 2.5 gigatons (Gt) of CO2 annually. With the global biochar market reaching USD 368.85 million by 2028, this work facilitates biochar with its versatile characteristics to promote carbon neutrality and CE applications.
    Matched MeSH terms: Charcoal/chemistry
  17. Zhang Y, Feng Y, Ren Z, Zuo R, Zhang T, Li Y, et al.
    Bioresour Technol, 2023 Apr;374:128746.
    PMID: 36813050 DOI: 10.1016/j.biortech.2023.128746
    The ideal conditions for anaerobic digestion experiments with biochar addition are challenging to thoroughly study due to different experimental purposes. Therefore, three tree-based machine learning models were developed to depict the intricate connection between biochar properties and anaerobic digestion. For the methane yield and maximum methane production rate, the gradient boosting decision tree produced R2 values of 0.84 and 0.69, respectively. According to feature analysis, digestion time and particle size had a substantial impact on the methane yield and production rate, respectively. When particle sizes were in the range of 0.3-0.5 mm and the specific surface area was approximately 290 m2/g, corresponding to a range of O content (>31%) and biochar addition (>20 g/L), the maximum promotion of methane yield and maximum methane production rate were attained. Therefore, this study presents new insights into the effects of biochar on anaerobic digestion through tree-based machine learning.
    Matched MeSH terms: Charcoal*
  18. Ismail IS, Rashidi NA, Yusup S
    Environ Sci Pollut Res Int, 2022 Feb;29(9):12434-12440.
    PMID: 34189693 DOI: 10.1007/s11356-021-15030-x
    Bamboo is the fastest-growing plant and is abundant in Malaysia. It is employed as a starting material for activated carbon production and evaluated for its potential in CO2 capture. A single-stage phosphoric acid (H3PO4) activation is adopted by varying the concentrations of H3PO4 between 50 and 70 wt.% at a constant temperature and holding time of 500°C and 120 min, respectively. The bamboo-based activated carbons are characterized in terms of product yield, surface area, and porosity, as well as surface chemistry properties. Referring to the experimental findings, the prepared activated carbons have BET surface area of >1000 m2 g-1, which implies the effectiveness of the single-stage H3PO4 activation. Furthermore, the prepared activated carbon via 50 wt.% H3PO4 activation shows the highest BET surface area and carbon dioxide (CO2) adsorption capacity of 1.45 mmol g-1 at 25°C/1 bar and 9.0 mmol g-1 at 25°C/30 bar. With respect to both the characterization analysis and CO2 adsorption performance, it is concluded that bamboo waste conversion to activated carbon through H3PO4 activation method is indeed promising.
    Matched MeSH terms: Charcoal*
  19. Ahmad Farid MA, Hassan MA, Roslan AM, Ariffin H, Norrrahim MNF, Othman MR, et al.
    Environ Sci Pollut Res Int, 2021 Jun;28(22):27976-27987.
    PMID: 33527241 DOI: 10.1007/s11356-021-12585-7
    This study provides insight into the decolorization strategy for crude glycerol obtained from biodiesel production using waste cooking oil as raw material. A sequential procedure that includes physico-chemical treatment and adsorption using activated carbon from oil palm biomass was investigated. The results evidenced decolorization and enrichment of glycerol go hand in hand during the treatment, achieving >89% color removal and > 98% increase in glycerol content, turning the glycerol into a clear (colorless) solution. This is attributed to the complete removal of methanol, free fatty acids, and triglycerides, as well as 85% removal of water, and 93% removal of potassium. Properties of the resultant glycerol met the quality standard of BS 2621:1979. The economic aspects of the proposed methods are examined to fully construct a predesign budgetary estimation according to chemical engineering principles. The starting capital is proportionate to the number of physical assets to acquire where both entail a considerable cost at USD 13,200. Having the benefit of sizeable scale production, it reasonably reduces the operating cost per unit product. As productivity sets at 33 m3 per annum, the annual operating costs amount to USD 79,902 in glycerol decolorization. This is translatable to USD 5.38 per liter glycerol, which is ~69% lower compared to using commercial activated carbon.
    Matched MeSH terms: Charcoal*
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