Displaying publications 1 - 20 of 220 in total

Abstract:
Sort:
  1. Sheng Y, Lam SS, Wu Y, Ge S, Wu J, Cai L, et al.
    Bioresour Technol, 2021 Mar;324:124631.
    PMID: 33454445 DOI: 10.1016/j.biortech.2020.124631
    The demands of energy sustainability drive efforts to bio-chemical conversion of biomass into biofuels through pretreatment, enzymatic hydrolysis, and microbial fermentation. Pretreatment leads to significant structural changes of the complex lignin polymer that affect yield and productivity of the enzymatic conversion of lignocellulosic biomass. Structural changes of lignin after pretreatment include functional groups, inter unit linkages and compositions. These changes influence non-productive adsorption of enzyme on lignin through hydrophobic interaction and electrostatic interaction as well as hydrogen bonding. This paper reviews the relationships between structural changes of lignin and enzymatic hydrolysis of pretreated lignocellulosic biomass. The formation of pseudo-lignin during dilute acid pretreatment is revealed, and their negative effect on enzymatic hydrolysis is discussed.
    Matched MeSH terms: Lignin*
  2. Yiin CL, Yap KL, Ku AZE, Chin BLF, Lock SSM, Cheah KW, et al.
    Bioresour Technol, 2021 Aug;333:125195.
    PMID: 33932810 DOI: 10.1016/j.biortech.2021.125195
    Biomass wastes exhibit a great potential to be used as a source of non-depleting renewable energy and synthesis of value-added products. The key to the valorization of excess lignocellulosic biomass wastes in the world lies on the pretreatment process to recalcitrant barrier of the lignocellulosic material for the access to useful substrates. A wide range of pretreatment techniques are available and advances in this field is continuously happening, in search for cheap, effective, and environmentally friendly methods. This review starts with an introduction to conventional approaches and green solvents for pretreatment of lignocellulosic biomass. Subsequently, the mechanism of actions along with the advantages and disadvantages of pretreatment techniques were reviewed. The roles of choline chloride (ChCl) in green solvents and their potential applications were also comprehensively reviewed. The collection of ideas in this review serve as an insight for future works or interest on biomass-to-energy conversion using green solvents.
    Matched MeSH terms: Lignin*
  3. Chukwuma OB, Rafatullah M, Tajarudin HA, Ismail N
    PMID: 34204975 DOI: 10.3390/ijerph18116001
    Discovering novel bacterial strains might be the link to unlocking the value in lignocellulosic bio-refinery as we strive to find alternative and cleaner sources of energy. Bacteria display promise in lignocellulolytic breakdown because of their innate ability to adapt and grow under both optimum and extreme conditions. This versatility of bacterial strains is being harnessed, with qualities like adapting to various temperature, aero tolerance, and nutrient availability driving the use of bacteria in bio-refinery studies. Their flexible nature holds exciting promise in biotechnology, but despite recent pointers to a greener edge in the pretreatment of lignocellulose biomass and lignocellulose-driven bioconversion to value-added products, the cost of adoption and subsequent scaling up industrially still pose challenges to their adoption. However, recent studies have seen the use of co-culture, co-digestion, and bioengineering to overcome identified setbacks to using bacterial strains to breakdown lignocellulose into its major polymers and then to useful products ranging from ethanol, enzymes, biodiesel, bioflocculants, and many others. In this review, research on bacteria involved in lignocellulose breakdown is reviewed and summarized to provide background for further research. Future perspectives are explored as bacteria have a role to play in the adoption of greener energy alternatives using lignocellulosic biomass.
    Matched MeSH terms: Lignin*
  4. Sun Q, Chen WJ, Pang B, Sun Z, Lam SS, Sonne C, et al.
    Bioresour Technol, 2021 Dec;341:125807.
    PMID: 34474237 DOI: 10.1016/j.biortech.2021.125807
    In recent years, visualization and characterization of lignocellulose at different scales elucidate the modifications of its ultrastructural and chemical features during hydrothermal pretreatment which include degradation and dissolving of hemicelluloses, swelling and partial hydrolysis of cellulose, melting and redepositing a part of lignin in the surface. As a result, cell walls are swollen, deformed and de-laminated from the adjacent layer, lead to a range of revealed droplets that appear on and within cell walls. Moreover, the certain extent morphological changes significantly promote the downstream processing steps, especially for enzymatic hydrolysis and anaerobic fermentation to bioethanol by increasing the contact area with enzymes. However, the formation of pseudo-lignin hinders the accessibility of cellulase to cellulose, which decreases the efficiency of enzymatic hydrolysis. This review is intended to bridge the gap between the microstructure studies and value-added applications of lignocellulose while inspiring more research prospects to enhance the hydrothermal pretreatment process.
    Matched MeSH terms: Lignin*
  5. Tan YT, Chua ASM, Ngoh GC
    Bioresour Technol, 2020 Feb;297:122522.
    PMID: 31818720 DOI: 10.1016/j.biortech.2019.122522
    Since the introduction of deep eutectic solvent (DES) in biomass processing field, the efficiency of DES in lignocellulosic biopolymer model compounds' (cellulose, hemicellulose and lignin) solubilisation and conversion was widely recognized. Nevertheless, DES's potential for biorefinery application can be reflected more accurately through their performance in raw lignocellulosic biomass processing rather than model compound conversion. Therefore, this review examines the studies on raw lignocellulosic biomass fractionation using DES and the subsequent conversion of DES-fractionated products into bio-based products. The review stresses on three key parts: performance of varying types of DESs and pretreatment schemes for biopolymer fractionation, properties and conversion of fractionated saccharides as well as DES-extracted lignin. The prospects and challenges of DES implementation in biomass processing will also be discussed. This review provides a front-to-end view on the DES's performance, starting from pretreatment to DES-fractionated products conversion, which would be helpful in devising a comprehensive biomass utilization process.
    Matched MeSH terms: Lignin*
  6. Yek PNY, Wan Mahari WA, Kong SH, Foong SY, Peng W, Ting H, et al.
    Bioresour Technol, 2022 Mar;347:126687.
    PMID: 35007740 DOI: 10.1016/j.biortech.2022.126687
    Thermal co-processing of lignocellulosic and aquatic biomass, such as algae and shellfish waste, has shown synergistic effects in producing value-added energy products with higher process efficiency than the traditional method, highlighting the importance of scaling up to pilot-scale operations. This article discusses the design and operation of pilot-scale reactors for torrefaction, pyrolysis, and gasification, as well as the key parameters of co-processing biomass into targeted and improved quality products for use as fuel, agricultural application, and environmental remediation. Techno-economic analysis reveals that end product selling price, market dynamics, government policies, and biomass cost are crucial factors influencing the sustainability of thermal co-processing as a feasible approach to utilize the biomass. Because of its simplicity, pyrolysis allows greater energy recovery, while gasification has the highest net present value (profitability). Integration of liquefaction, hydrothermal, and fermentation pre-treatment technology has the potential to increase energy efficiency while reducing process residues.
    Matched MeSH terms: Lignin*
  7. Sohni S, Hassan T, Khan SB, Akhtar K, Bakhsh EM, Hashim R, et al.
    Int J Biol Macromol, 2023 Jan 15;225:1426-1436.
    PMID: 36436599 DOI: 10.1016/j.ijbiomac.2022.11.200
    In this work, facile fabrication of lignin nanoparticles (LNP)-based three-dimensional reduced graphene oxide hydrogel (rGO@LNP) has been demonstrated as a novel strategy for environmental applications. Herein, LNP were facilely synthesized from walnut shell waste through a direct chemical route. These LNP were incorporated into the continuous porous network of rGO network to fabricate rGO@LNP hydrogel. Characterization studies were carried out using various analytical techniques viz. scanning electron microscopy, Fourier transform IR spectroscopy, X-ray diffraction and thermogravimetric analysis. The efficiency of rGO@LNP hydrogel as adsorptive platform was evaluated by employing methylene blue and Pb2+ as model pollutants, whilst the effect of various experimental parameters was ascertained for optimal performance. Furthermore, Agar well diffusion method was used to check the antibacterial activities of the hydrogel using two bacterial pathogenic strains, i.e. Klebsiella pneumoniae (gram negative) and Enterococcus faecalis (gram positive). Results showed that after the inclusion of LNP into rGO hydrogel, there was a marked improvement in pollutant's uptake ability and compared to bare LNP and rGO, the composite hydrogel showed enhanced bactericidal effect. Overall, this approach is outstanding because of the synergy of functional properties of nano-lignin and rGO due to multi-interaction sites in the resulting hydrogel. The results presented herein support the application of rGO@LNP as innovative water filter material for scavenging broad spectrum pollutants and bactericidal properties.
    Matched MeSH terms: Lignin/pharmacology
  8. Sun C, Song G, Pan Z, Tu M, Kharaziha M, Zhang X, et al.
    Bioresour Technol, 2023 Jan;368:128356.
    PMID: 36414144 DOI: 10.1016/j.biortech.2022.128356
    The valorization of organosolv pretreatment (OP) is a required approach to the industrialization of the current enzyme-mediated lignocellulosic biorefinery. Recent literature has demonstrated that the solvolysis happening in the OP can modify the soluble components into value-added active compounds, namely organosolv modified lignin (OML) and organosolv modified sugars (OMSs), in addition to protecting them against excessive degradation. Among them, the OML is coincidental with the "lignin-first" strategy that should render a highly reactive lignin enriched with β-O-4 linkages and less condensed structure by organosolv grafting, which is desirable for the transformation into phenolic compounds. The OMSs are valuable glycosidic compounds mainly synthesized by trans-glycosylation, which can find potential applications in cosmetics, foods, and healthcare. Therefore, a state-of-the-art OP holds a big promise of lowering the process cost by the valorization of these active compounds. Recent advances in organosolv modified components are reviewed, and perspectives are made for addressing future challenges.
    Matched MeSH terms: Lignin*
  9. Jayakumar M, Hamda AS, Abo LD, Daba BJ, Venkatesa Prabhu S, Rangaraju M, et al.
    Chemosphere, 2023 Dec;345:140515.
    PMID: 37871877 DOI: 10.1016/j.chemosphere.2023.140515
    Biochar is an ample source of organic carbon prepared by the thermal breakdown of biomass. Lignocellulosic biomass is a promising precursor for biochar production, and has several applications in various industries. In addition, biochar can be applied for environmental revitalization by reducing the negative impacts through intrinsic mechanisms. In addition to its environmentally friendly nature, biochar has several recyclable and inexpensive benefits. Nourishing and detoxification of the environment can be undertaken using biochar by different investigators on account of its excellent contaminant removal capacity. Studies have shown that biochar can be improved by activation to remove toxic pollutants. In general, biochar is produced by closed-loop systems; however, decentralized methods have been proven to be more efficient for increasing resource efficiency in view of circular bio-economy and lignocellulosic waste management. In the last decade, several studies have been conducted to reveal the unexplored potential and to understand the knowledge gaps in different biochar-based applications. However, there is still a crucial need for research to acquire sufficient data regarding biochar modification and management, the utilization of lignocellulosic biomass, and achieving a sustainable paradigm. The present review has been articulated to provide a summary of information on different aspects of biochar, such as production, characterization, modification for improvisation, issues, and remediation have been addressed.
    Matched MeSH terms: Lignin*
  10. Mergbi M, Galloni MG, Aboagye D, Elimian E, Su P, Ikram BM, et al.
    Environ Sci Pollut Res Int, 2023 Jun;30(30):74544-74574.
    PMID: 37227629 DOI: 10.1007/s11356-023-27484-2
    An exponential rise in global pollution and industrialization has led to significant economic and environmental problems due to the insufficient application of green technology for the chemical industry and energy production. Nowadays, the scientific and environmental/industrial communities push to apply new sustainable ways and/or materials for energy/environmental applications through the so-called circular (bio)economy. One of today's hottest topics is primarily valorizing available lignocellulosic biomass wastes into valuable materials for energy or environmentally related applications. This review aims to discuss, from both the chemistry and mechanistic points of view, the recent finding reported on the valorization of biomass wastes into valuable carbon materials. The sorption mechanisms using carbon materials prepared from biomass wastes by emphasizing the relationship between the synthesis route or/and surface modification and the retention performance were discussed towards the removal of organic and heavy metal pollutants from water or air (NOx, CO2, VOCs, SO2, and Hg0). Photocatalytic nanoparticle-coated biomass-based carbon materials have proved to be successful composites for water remediation. The review discusses and simplifies the most raised interfacial, photonic, and physical mechanisms that might take place on the surface of these composites under light irradiation. Finally, the review examines the economic benefits and circular bioeconomy and the challenges of transferring this technology to more comprehensive applications.
    Matched MeSH terms: Lignin*
  11. Liao JJ, Latif NHA, Trache D, Brosse N, Hussin MH
    Int J Biol Macromol, 2020 Nov 01;162:985-1024.
    PMID: 32592780 DOI: 10.1016/j.ijbiomac.2020.06.168
    The most critical issues faced by the world nowadays is to provide the sustainability of consumption for energy and natural resources. Lignin is said to be one of the alternative new discoveries best-suited lignocellulosic biomass due to its low cost, sufficient availability and environmentally safe. The valuable properties exhibited by lignin can give broader applications usage such as in composite materials, wood industries, polymer composite industries, pharmaceutical and corrosion inhibitor industries. Many biomass wastes resources, isolation processes and treatments are undergoing development in order to enhance the producing new lignin-based materials on an industrial scale. Therefore, this review discussed on the current knowledge on the structure and chemistry of isolation of lignin from different sources using various common methods, its characterization, properties and its applications.
    Matched MeSH terms: Lignin/isolation & purification*; Lignin/chemistry*
  12. Ahmad Rizal NFA, Ibrahim MF, Zakaria MR, Kamal Bahrin E, Abd-Aziz S, Hassan MA
    Molecules, 2018 Apr 02;23(4).
    PMID: 29614823 DOI: 10.3390/molecules23040811
    The combination of superheated steam (SHS) with ligninolytic enzyme laccase pretreatment together with size reduction was conducted in order to enhance the enzymatic hydrolysis of oil palm biomass into glucose. The oil palm empty fruit bunch (OPEFB) and oil palm mesocarp fiber (OPMF) were pretreated with SHS and ground using a hammer mill to sizes of 2, 1, 0.5 and 0.25 mm before pretreatment using laccase to remove lignin. This study showed that reduction of size from raw to 0.25 mm plays important role in lignin degradation by laccase that removed 38.7% and 39.6% of the lignin from OPEFB and OPMF, respectively. The subsequent saccharification process of these pretreated OPEFB and OPMF generates glucose yields of 71.5% and 63.0%, which represent a 4.6 and 4.8-fold increase, respectively, as compared to untreated samples. This study showed that the combination of SHS with laccase pretreatment together with size reduction could enhance the glucose yield.
    Matched MeSH terms: Lignin/metabolism*
  13. Huang Y, Liu S, Zhang J, Syed-Hassan SSA, Hu X, Sun H, et al.
    Bioresour Technol, 2020 Jul;307:123192.
    PMID: 32220819 DOI: 10.1016/j.biortech.2020.123192
    This study investigated the interactions between volatile and char during biomass pyrolysis at 400 °C, employing a β-5 lignin dimer and amino-modified graphitized carbon nanotube (CNT-NH2) as their models, respectively. The results demonstrated that both -NH2 and its carrier (CNT) facilitated the conversion of the β-5 dimer, which significantly increased from 9.7% (blank run), to 61.6% (with CNT), and to 96.6% (with CNT-NH2). CNT mainly favored the breakage of C-O bond in the feedstock to produce dimers with a yield of 55.5%, while CNT-NH2 promoted the cleavage of both C-O and C-C bonds to yield monomers with a yield up to 63.4%. Such significant changes in the pyrolysis behaviors of the β-5 lignin dimer after the introduction of CNT-NH2 were considered to be mainly caused by hydrogen-bond formations between -NH2 and the dimeric feedstock/products, in addition to the π-π stacking between CNT and aromatic rings.
    Matched MeSH terms: Lignin*
  14. Pocha CKR, Chia SR, Chia WY, Koyande AK, Nomanbhay S, Chew KW
    Chemosphere, 2022 Mar;290:133246.
    PMID: 34906526 DOI: 10.1016/j.chemosphere.2021.133246
    The ever-growing human population has resulted in the expansion of agricultural activity; evident by the deforestation of rainfoamrests as a means of acquiring fertile land for crops. The crops and fruits produced by such means should be utilized completely; however, there are still losses and under-exploitation of these produces which has resulted in wastes being mounted in landfills. These underutilized agricultural wastes including vegetables and fruits can serve as a potential source for biofuels and green diesel. This paper discusses the main routes (e.g., biological and thermochemical) for producing biofuels such as bioethanol, biodiesel, biogas, bio-oil and green diesel from underutilized crops by emphasizing recent technological innovations for improving biofuels and green diesel yields. The future prospects of a successful production of biofuels and green diesel by this source are also explained. Underutilized lignocelluloses including fruits and vegetables serve as a prospective biofuel and green diesel generation source for the future prosperity of the biofuel industry.
    Matched MeSH terms: Lignin*
  15. Safian MT, Sekeri SH, Yaqoob AA, Serrà A, Jamudin MD, Mohamad Ibrahim MN
    Talanta, 2022 Mar 01;239:123109.
    PMID: 34864531 DOI: 10.1016/j.talanta.2021.123109
    With each passing year, the agriculture and wood processing industries generate increasingly high tonnages of biomass waste, which instead of being burned or left to accumulate should be utilized more sustainably. In parallel, advances in green technology have encouraged large companies and nations to begin using eco-friendly materials, including eco-friendly emulsifiers, which are used in various industries and in bio-based materials. The emulsion-conducive properties of lignocellulosic materials such as cellulose, hemicellulose, and lignin, the building blocks of plant and wood structures, have demonstrated a particular ability to alter the landscape of emulsion technology. Beyond that, the further modification of their structure may improve emulsion stability, which often determines the performance of emulsions. Considering those trends, this review examines the performance of lignocellulosic materials after modification according to their stability, droplet size, and distribution by size, all of which suggest their outstanding potential as materials for emulsifying agents.
    Matched MeSH terms: Lignin*
  16. New EK, Tnah SK, Voon KS, Yong KJ, Procentese A, Yee Shak KP, et al.
    J Environ Manage, 2022 Apr 01;307:114385.
    PMID: 35104699 DOI: 10.1016/j.jenvman.2021.114385
    The high dependence on crude oil for energy utilization leads to a necessity of finding alternative sustainable resources. Solvents are often employed in valorizing the biomass into bioproducts and other value-added chemicals during treatment stages. Unfortunately, despite the effectiveness of conventional solvents, hindrances such as expensive solvents, unfavourable environmental ramifications, and complicated downstream separation systems often occur. Therefore, the scientific community has been actively investigating more cost-effective, environmentally friendly alternatives and possess the excellent dissolving capability for biomass processing. Generally, 'green' solvents are attractive due to their low toxicity, economic value, and biodegradability. Nonetheless, green solvents are not without disadvantages due to their complicated product recovery, recyclability, and high operational cost. This review summarizes and evaluates the recent contributions, including potential advantages, challenges, and drawbacks of green solvents, namely ionic liquids, deep eutectic solvents, water, biomass-derived solvents and carbon dioxide in transforming the lignocellulosic biomass into high-value products. Moreover, research opportunities for future developments and potential upscale implementation of green solvents are also critically discussed.
    Matched MeSH terms: Lignin*
  17. Sankaran R, Parra Cruz RA, Pakalapati H, Show PL, Ling TC, Chen WH, et al.
    Bioresour Technol, 2020 Feb;298:122476.
    PMID: 31810736 DOI: 10.1016/j.biortech.2019.122476
    Microalgal and lignocellulosic biomass is the most sumptuous renewable bioresource raw material existing on earth. Recently, the bioconversion of biomass into biofuels have received significant attention replacing fossil fuels. Pretreatment of biomass is a critical process in the conversion due to the nature and structure of the biomass cell wall that is complex. Although green technologies for biofuel production are advancing, the productivity and yield from these techniques are low. Over the past years, various pretreatment techniques have been developed and successfully employed to improve the technology. This paper presents an in-depth review of the recent advancement of pretreatment methods focusing on microalgal and lignocellulosic biomass. The technological approaches involving physical, chemical, biological and other latest pretreatment methods are reviewed.
    Matched MeSH terms: Lignin
  18. Chamathka WWDR, Chai TT, Phuah ET, Wong JX, Chen SN, Yassoralipour A
    Int J Biol Macromol, 2024 Mar;260(Pt 2):129637.
    PMID: 38262554 DOI: 10.1016/j.ijbiomac.2024.129637
    The research aimed to explore the potential of palm kernel meal (PKM) as a sustainable source of cellulose nanoparticles (CNPs) for active food packaging. The CNPs were isolated using a combination of chemical techniques, such as alkaline treatment, bleaching, and acid hydrolysis. The characterization of the CNPs was analysed using various techniques, including scanning electron microscopy, Fourier-transform infrared spectroscopy, X-ray diffraction, and UV-visible spectroscopy. The findings revealed that chemical processing effectively removed lignin and hemicellulose from PKM. The SEM morphology confirmed the separation of the CNPs, resulting in the production of 40-100 nm spherical cellulose nanoparticles, while XRD and FTIR analyses confirmed their purity and composition. Moreover, the UV-visible spectroscopy exhibited high transmittance rates, indicating the potential of CNPs as reinforcing agents for polymer matrices. The significance of utilising PKM as a valuable fibre source for extracting CNPs can be recommended for developing active food packaging.
    Matched MeSH terms: Lignin
  19. Mohammed MA, Salmiaton A, Wan Azlina WA, Mohamad Amran MS
    Bioresour Technol, 2012 Apr;110:628-36.
    PMID: 22326334 DOI: 10.1016/j.biortech.2012.01.056
    Empty fruit bunches (EFBs), a waste material from the palm oil industry, were subjected to pyrolysis and gasification. A high content of volatiles (>82%) increased the reactivity of EFBs, and more than 90% decomposed at 700°C; however, a high content of moisture (>50%) and oxygen (>45%) resulted in a low calorific value. Thermogravimetric analysis demonstrated that the higher the heating rate and the smaller the particle size, the higher the peak and final reaction temperatures. The least squares estimation for a first-order reaction model was used to study the degradation kinetics. The values of activation energy increased from 61.14 to 73.76 and from 40.06 to 47.99kJ/mol when the EFB particle size increased from 0.3 to 1.0mm for holocellulose and lignin degradation stages, respectively. The fuel characteristics of EFB are comparable to those of other biomasses and EFB can be considered a good candidate for gasification.
    Matched MeSH terms: Lignin/analysis
  20. Akhtar J, Idris A, Abd Aziz R
    Appl Microbiol Biotechnol, 2014 Feb;98(3):987-1000.
    PMID: 24292125 DOI: 10.1007/s00253-013-5319-6
    Production of succinic acid via separate enzymatic hydrolysis and fermentation (SHF) and simultaneous saccharification and fermentation (SSF) are alternatives and are environmentally friendly processes. These processes have attained considerable positions in the industry with their own share of challenges and problems. The high-value succinic acid is extensively used in chemical, food, pharmaceutical, leather and textile industries and can be efficiently produced via several methods. Previously, succinic acid production via chemical synthesis from petrochemical or refined sugar has been the focus of interest of most reviewers. However, these expensive substrates have been recently replaced by alternative sustainable raw materials such as lignocellulosic biomass, which is cheap and abundantly available. Thus, this review focuses on succinic acid production utilizing lignocellulosic material as a potential substrate for SSF and SHF. SSF is an economical single-step process which can be a substitute for SHF - a two-step process where biomass is hydrolyzed in the first step and fermented in the second step. SSF of lignocellulosic biomass under optimum temperature and pH conditions results in the controlled release of sugar and simultaneous conversion into succinic acid by specific microorganisms, reducing reaction time and costs and increasing productivity. In addition, main process parameters which influence SHF and SSF processes such as batch and fed-batch fermentation conditions using different microbial strains are discussed in detail.
    Matched MeSH terms: Lignin/metabolism*
Filters
Contact Us

Please provide feedback to Administrator (afdal@afpm.org.my)

External Links