Displaying publications 21 - 40 of 217 in total

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  1. Haarindraprasad R, Gopinath SCB, Veeradassan P
    Biotechnol Appl Biochem, 2022 Dec;69(6):2698-2712.
    PMID: 34997977 DOI: 10.1002/bab.2316
    A "Janus particle" refers to the production of two materials in a single system and shows a difference in physical characteristics, and two surfaces participate in the formation with different chemistries. This research generated the Janus using a hybrid of zinc oxide (ZnO) and gold (Au) on the sensor surface toward making high-performance DNA sensors. The Janus ZnO/Au-textured film was synthesized via the one-step sol-gel method, which involves a suitable ratio of a mixture of ZnO sol seed solution. The synthesized Janus ZnO/Au-textured film undergoes a low-temperature aqueous hydrothermal route to synthesize quasi-one-dimensional nanowires. The average grain size in the Janus ZnO/Au nanotextured wire was 41.60 nm. The fabricated nanotextured wire was further optimized by tuning the thickness and characterized by XRD and high-resolution microscopy. Electrical characterization was conducted on the Janus ZnO/Au nanotextured wire coupled with an interdigitated electrode sensor to detect the specific leptospirosis DNA strand. The generated device is capable of detecting lower DNA concentration at 1 × 10-13 M with a sensitivity of 8.54 MΩ M-1 cm-2 . The high performance is attained on linear concentrations of 10-6 -10-13 M with the determination coefficient, "I = 135437.63C-3609.07" R2 = 0.9551. A potential strategy is proposed as a base for developing different high-performance sensors.
    Matched MeSH terms: Zinc Oxide*
  2. Talari MK, Abdul Majeed AB, Tripathi DK, Tripathy M
    Chem Pharm Bull (Tokyo), 2012;60(7):818-24.
    PMID: 22790812
    The application of nanomaterials has gained considerable momentum in various fields in recent years due to their high reactivity, excellent surface properties and quantum effects in the nanometer range. The properties of zinc oxide (ZnO) vary with its crystallite size or particle size and often nanocrystalline ZnO is seen to exhibit superior physical and chemical properties due to their higher surface area and modified electronic structure. ZnO nanoparticles are reported to exhibit strong bacterial inhibiting activity and silver (Ag) has been extensively used for its antimicrobial properties since ages. In this study, Ag doped ZnO nanoparticles were synthesized by mechanochemical processing in a high energy ball mill and investigated for antimicrobial activity. The nanocrystalline nature of zinc oxide was established by X-ray diffraction (XRD) studies. It is seen from the XRD data obtained from the samples, that crystallite size of the zinc oxide nanoparticles is seen to decrease with increasing Ag addition. Field emission scanning electron microscopy (FESEM) and transmission electron microscopy (TEM) data also supported the nanoparticle formation during the synthesis. The doped nanoparticles were subjected to antimicrobial investigation and found that both increase in Ag content and decrease in particle size contributed significantly towards antimicrobial efficiency. It was also observed that Ag doped ZnO nanoparticles possess enhanced antimicrobial potential than that of virgin ZnO against the studied microorganisms of Escherichia coli and Staphylococcus aureus.
    Matched MeSH terms: Zinc Oxide/chemistry*
  3. Yusop Ahmad, Nur Haziyanti Mohamad Khalid, Trevor Glen Philip
    MyJurnal
    This study aimed to test the effect of modality imagery training via video tapes and audio tapes to improve the performance of overhead service skills in volleyball. 45 subjects who followed the volleyball professional course in Sultan Idris University of Education (UPSI) were selected for this test and they were randomly divided into three groups: video, audio group and control group. Russel-Lange Volleyball Test was used to obtain data on the overhead service performance. The results showed significant differences in overhead service performance before and after participants were exposed to the methods of video and audio tapes. There were also significant differences in overhead service performance among the video, audio, and control group. The study should that the introduction of audio and video imagery method may helps improve the overhead service skills performance in volley ball.
    Matched MeSH terms: Zinc Oxide
  4. Teh SJ, Yeoh SL, Lee KM, Lai CW, Abdul Hamid SB, Thong KL
    PMID: 27203568 DOI: 10.1016/j.jphotobiol.2016.05.013
    The immobilization of photocatalyst nanoparticles on a solid substrate is an important aspect for improved post-treatment separation and photocatalyst reactor design. In this study, we report the simple preparation of reduced graphene oxide (rGO)-hybridized zinc oxide (ZnO) thin films using a one-step electrochemical deposition, and investigated the effect of rGO-hybridization on the photoinactivation efficiency of ZnO thin films towards Staphylococcus aureus (S. aureus) and Salmonella enterica serovar Typhi (S. Typhi) as target bacterial pathogens. Field-emission scanning electron microscopy (FESEM) revealed the formation of geometric, hexagonal flakes of ZnO on the ITO glass substrate, as well as the incorporation of rGO with ZnO in the rGO/ZnO thin film. Raman spectroscopy indicated the successful incorporation of rGO with ZnO during the electrodeposition process. Photoluminescence (PL) spectroscopy indicates that rGO hybridization with ZnO increases the amount of oxygen vacancies, evidenced by the shift of visible PL peak at 650 to 500nm. The photoinactivation experiments showed that the thin films were able to reduce the bacterial cell density of Staph. aureus and S. Typhi from an initial concentration of approximately 10(8) to 10(3)CFU/mL within 15min. The rGO/ZnO thin film increased the photoinactivation rate for S. aureus (log[N/No]) from -5.1 (ZnO) to -5.9. In contrast, the application of rGO/ZnO thin film towards the photoinactivation of S. Typhi did not improve its photoinactivation rate, compared to the ZnO thin film. We may summarise that (1) rGO/ZnO was effective to accelerate the photoinactivation of S. aureus but showed no difference to improve the photoinactivation of S. Typhi, in comparison to the performance of ZnO thin films, and (2) the photoinactivation in the presence of ZnO and rGO/ZnO was by ROS damage to the extracellular wall.
    Matched MeSH terms: Zinc Oxide/chemistry*
  5. Ramimoghadam D, Hussein MZ, Taufiq-Yap YH
    Int J Mol Sci, 2012;13(10):13275-93.
    PMID: 23202952 DOI: 10.3390/ijms131013275
    ZnO nanostructures were synthesized by hydrothermal method using different molar ratios of cetyltrimethylammonium bromide (CTAB) and Sodium dodecyl sulfate (SDS) as structure directing agents. The effect of surfactants on the morphology of the ZnO crystals was investigated by field emission scanning electron microscopy (FESEM) and transmission electron microscopy (TEM) techniques. The results indicate that the mixture of cationic-anionic surfactants can significantly modify the shape and size of ZnO particles. Various structures such as flakes, sheets, rods, spheres, flowers and triangular-like particles sized from micro to nano were obtained. In order to examine the possible changes in other properties of ZnO, characterizations like powder X-ray diffraction (PXRD), thermogravimetric and differential thermogravimetric analysis (TGA-DTG), FTIR, surface area and porosity and UV-visible spectroscopy analysis were also studied and discussed.
    Matched MeSH terms: Zinc Oxide/chemistry*
  6. Supramaniam J, Low DYS, Wong SK, Tan LTH, Leo BF, Goh BH, et al.
    Int J Mol Sci, 2021 May 28;22(11).
    PMID: 34071337 DOI: 10.3390/ijms22115781
    Cellulose nanofibers (CNF) isolated from plant biomass have attracted considerable interests in polymer engineering. The limitations associated with CNF-based nanocomposites are often linked to the time-consuming preparation methods and lack of desired surface functionalities. Herein, we demonstrate the feasibility of preparing a multifunctional CNF-zinc oxide (CNF-ZnO) nanocomposite with dual antibacterial and reinforcing properties via a facile and efficient ultrasound route. We characterized and examined the antibacterial and mechanical reinforcement performances of our ultrasonically induced nanocomposite. Based on our electron microscopy analyses, the ZnO deposited onto the nanofibrous network had a flake-like morphology with particle sizes ranging between 21 to 34 nm. pH levels between 8-10 led to the formation of ultrafine ZnO particles with a uniform size distribution. The resultant CNF-ZnO composite showed improved thermal stability compared to pure CNF. The composite showed potent inhibitory activities against Gram-positive (methicillin-resistant Staphylococcus aureus (MRSA)) and Gram-negative Salmonella typhi (S. typhi) bacteria. A CNF-ZnO-reinforced natural rubber (NR/CNF-ZnO) composite film, which was produced via latex mixing and casting methods, exhibited up to 42% improvement in tensile strength compared with the neat NR. The findings of this study suggest that ultrasonically-synthesized palm CNF-ZnO nanocomposites could find potential applications in the biomedical field and in the development of high strength rubber composites.
    Matched MeSH terms: Zinc Oxide/chemistry*
  7. Tang KS
    Life Sci, 2019 Dec 15;239:117011.
    PMID: 31669241 DOI: 10.1016/j.lfs.2019.117011
    Diabetes mellitus (DM) is a multifaceted and costly disease, which requires serious attention. Finding a cheaper anti-diabetic alternative that can act on multiple disease-related targets and pathways is the ultimate treatment goal for DM. Nanotechnology has offered some exciting possibilities in biomedical and drug delivery applications. Zinc oxide nanoparticles (ZnO-NPs), a novel agent to deliver zinc, have great implications in many disease therapies including DM. This review summarizes the pharmacological mechanisms by which ZnO-NPs alleviate DM and diabetic complications. Research implications and future perspectives were also discussed.
    Matched MeSH terms: Zinc Oxide/pharmacology; Zinc Oxide/therapeutic use*
  8. Low SS, Loh HS, Boey JS, Khiew PS, Chiu WS, Tan MTT
    Biosens Bioelectron, 2017 Aug 15;94:365-373.
    PMID: 28319904 DOI: 10.1016/j.bios.2017.02.038
    An efficient electrochemical impedance genosensing platform has been constructed based on graphene/zinc oxide nanocomposite produced via a facile and green approach. Highly pristine graphene was synthesised from graphite through liquid phase sonication and then mixed with zinc acetate hexahydrate for the synthesis of graphene/zinc oxide nanocomposite by solvothermal growth. The as-synthesised graphene/zinc oxide nanocomposite was characterised with scanning electron microscopy (SEM), transmission electron microscopy (TEM), Raman spectroscopy and X-ray diffractometry (XRD) to evaluate its morphology, crystallinity, composition and purity. An amino-modified single stranded DNA oligonucleotide probe synthesised based on complementary Coconut Cadang-Cadang Viroid (CCCVd) RNA sequence, was covalently bonded onto the surface of graphene/zinc oxide nanocomposite by the bio-linker 1-pyrenebutyric acid N-hydroxysuccinimide ester. The hybridisation events were monitored by electrochemical impedance spectroscopy (EIS). Under optimised sensing conditions, the single stranded CCCVd RNA oligonucleotide target could be quantified in a wide range of 1.0×10-11M to 1.0×10-6 with good linearity (R =0.9927), high sensitivity with low detection limit of 4.3×10-12M. Differential pulse voltammetry (DPV) was also performed for the estimation of nucleic acid density on the graphene/zinc oxide nanocomposite-modified sensing platform. The current work demonstrates an important advancement towards the development of a sensitive detection assay for various diseases involving RNA agents such as CCCVd in the future.
    Matched MeSH terms: Zinc Oxide/chemistry
  9. Alomari G, Al-Trad B, Hamdan S, Aljabali AAA, Al Zoubi MS, Al-Batanyeh K, et al.
    IET Nanobiotechnol, 2021 Jul;15(5):473-483.
    PMID: 34694755 DOI: 10.1049/nbt2.12026
    This study examines the effect of nanoparticles with zinc oxides (ZnONPs) on diabetic nephropathy, which is the primary cause of mortality for diabetic patients with end-stage renal disease. Diabetes in adult male rats was induced via intraperitoneal injection of streptozotocin. ZnONPs were intraperitoneally administered to diabetic rats daily for 7 weeks. Diabetes was associated with increases in blood glucose level, 24-h urinary albumin excretion rate, glomerular basement membrane thickness, renal oxidative stress markers, and renal mRNA or protein expression of transforming growth factor-β1, fibronectin, collagen-IV, tumour necrosis factor-α and vascular endothelial growth factor-A. Moreover, the expression of nephrin and podocin, and the mRNA expression of matrix metalloproteinase-9 were decreased in the diabetic group. These changes were not detected in the control group and were significantly prevented by ZnONP treatment. These results provide evidence that ZnONPs ameliorate the renal damage induced in a diabetic rat model of nephropathy through improving renal functionality; inhibiting renal fibrosis, oxidative stress, inflammation and abnormal angiogenesis; and delaying the development of podocyte injury. The present findings may help design the clinical application of ZnONPs for protection against the development of diabetic nephropathy.
    Matched MeSH terms: Zinc Oxide*
  10. Nagai K, Kuwabara T, Ahmad MF, Nakano M, Karakawa M, Taima T, et al.
    Chem Commun (Camb), 2019 Oct 15;55(83):12491-12494.
    PMID: 31573004 DOI: 10.1039/c9cc04759j
    Photoelectrochemical oxidation of thiols was enhanced with a threshold potential of -0.35 V vs. Ag/AgCl by the use of a ZnPc/PCBM:P3HT/ZnO electode, which was prepared by removing the PEDOT:PSS/Au electrode of an inverted OPV device and coating it with ZnPc. A co-photocatalysis property of ZnPc was observed in the photoelectrochemistry and scanning Kelvin probe microscopy.
    Matched MeSH terms: Zinc Oxide
  11. Yeow ST, Shahar A, Abdul Aziz N, Anuar MS, Yusof YA, Taip FS
    Drug Des Devel Ther, 2011;5:465-9.
    PMID: 22162640 DOI: 10.2147/DDDT.S25047
    To investigate the effect of feed preparation characteristics and operational parameters on mixing homogeneity in a convective batch ribbon mixer.
    Matched MeSH terms: Zinc Oxide/chemistry
  12. Gokhan Gunduz, Barbaros Yaman, Seray Ozden, Suleyman Donmez
    Sains Malaysiana, 2013;42:547-552.
    Composite archery bows have been well known and used by Asiatic societies for thousands of years. The Turkish composite bow, made of wood, horn, sinew and glue is one of the most famous and powerful bows in the world. Because of its high draw weight and mechanical efficiency, the Turkish composite bow became a powerful weapon in the Seljuk and the Ottoman empire. In addition to being a powerful weapon of war, at the same time the bow and arrow (archery) continued
    to be a sport of Ottoman (sultans, state officials, janissaries) until the late Ottoman period. In this study of the Ottoman composite archery bows in the collections of Izmir Ethnography Museum, a small wood sample was investigated on the basis of its wood anatomy. The results showed that it was made of maple wood (Acer sp.) and some of its qualitative and quantitative anatomical properties are presented here. One of the key properties for the identification of maple wood is
    the helical thickening throughout the body of the vessel element. Helical thickenings in vessel elements in cutting surfaces of maple-wooden core increase the bonding surface between the wood and sinew-horn. In most of the woods preferred traditionally for bow-making, helical thickenings in tracheids, vessel elements or ground tissue fibres should be taken into account at a hierarchy of cellular structures for elucidating the efficiency of Ottoman composite-wooden bow.
    Matched MeSH terms: Zinc Oxide
  13. Ba-Abbad MM, Kadhum AA, Mohamad AB, Takriff MS, Sopian K
    Chemosphere, 2013 Jun;91(11):1604-11.
    PMID: 23384541 DOI: 10.1016/j.chemosphere.2012.12.055
    The optical properties of a ZnO photocatalyst were enhanced with various dopant concentrations of Fe(3+). Doped ZnO nanoparticles were synthesized via a sol-gel method without the use of capping agents or surfactants and was then characterized using X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM) and ultraviolet-visible (UV-Vis) spectroscopy. The results showed that ZnO has a wurtzite, hexagonal structure and that the Fe(3+) ions were well incorporated into the ZnO crystal lattice. As the Fe(3+) concentration increased from 0.25 wt.% to 1 wt.%, the crystal size decreased in comparison with the undoped ZnO. The spectral absorption shifts of the visible light region (red shift) and the band gap decreases for each Fe-ZnO sample were investigated. The photocatalytic activities of the ZnO and Fe-ZnO samples were evaluated based on the degradation of 2-chlorophenol in aqueous solution under solar radiation. The samples with a small concentration of Fe(3+) ions showed enhanced photocatalytic activity with an optimal maximum performance at 0.5 wt.%. The results indicated that toxicity removal of 2-chlorophenol at same line of degradation efficiency. Small crystallite size and low band gap were attributed to high activities of Fe-ZnO samples under various concentrations of Fe(3+) ions compared to undoped ZnO.
    Matched MeSH terms: Zinc Oxide/chemical synthesis*; Zinc Oxide/radiation effects*
  14. Ramesh T, Foo KL, R H, Sam AJ, Solayappan M
    Sci Rep, 2019 11 19;9(1):17039.
    PMID: 31745139 DOI: 10.1038/s41598-019-53476-9
    Detection of host integrated viral oncogenes are critical for early and point-of-care molecular diagnostics of virus-induced carcinoma. However, available diagnostic approaches are incapable of combining both cost-efficient medical diagnosis and high analytical performances. To circumvent this, we have developed an improved IDE-based nanobiosensor for biorecognition of HPV-16 infected cervical cancer cells through electrochemical impedance spectroscopy. The system is fabricated by coating gold (Au) doped zinc oxide (ZnO) nanorods interfaced with HPV-16 viral DNA bioreceptors on top of the Interdigitated Electrode (IDE) chips surface. Due to the concurrently improved sensitivity and biocompatibility of the designed nanohybrid film, Au decorated ZnO-Nanorod biosensors demonstrate exceptional detection of HPV-16 E6 oncogene, the cancer biomarker for HPV infected cervical cancers. This sensor displayed high levels of sensitivity by detecting as low as 1fM of viral E6 gene target. The sensor also exhibited a stable functional life span of more than 5 weeks, good reproducibility and high discriminatory properties against HPV-16. Sensor current responses are obtained from cultured cervical cancer cells which are close to clinical cancer samples. Hence, the developed sensor is an adaptable tool with high potential for clinical diagnosis especially useful for economically challenged countries/regions.
    Matched MeSH terms: Zinc Oxide/chemistry
  15. Idris NJ, Bakar SA, Mohamed A, Muqoyyanah M, Othman MHD, Mamat MH, et al.
    Environ Sci Pollut Res Int, 2021 Feb;28(6):6966-6979.
    PMID: 33025441 DOI: 10.1007/s11356-020-10904-y
    In this work, sand/zinc oxide (ZnO)/titanium dioxide (TiO2)-based photocatalysts were hybridized with graphene oxide (GO) and GO_multi-walled carbon nanotubes (MWCNTs) hybrid solution. The novel hybrid was then used in photocatalysis to degrade dye contamination. The nanocomposite photocatalyst was initially fabricated by growing ZnO nanorods (NRs) via sol-gel immersion followed by synthesizing TiO2 NRs for different times (5 and 20 h) using a hydrothermal method on sand as a substrate. Prior to the hybridization, the initial GO was synthesized using electrochemical exfoliation and further mixed with 1 wt% MWCNTs to form GO_MWCNTs hybrid solution. The synthesized GO and GO_MWCNTs hybrid solution were then incorporated onto sand/ZnO/TiO2 nanocomposite-based photocatalysts through immersion. Various sand/ZnO/TiO2-based photocatalysts were then tested for methylene blue (MB) dye degradation within 3 days. On the basis of UV-Vis measurement, the highest MB degradation was achieved by using sand/ZnO NRs/TiO2 NRs (5 h)/GO_MWCNTs (92.60%). The high surface area and high electrical conductivity of GO_MWCNTs prolonged the lifetime of electron/hole separation and thus enhanced the photocatalytic performance.
    Matched MeSH terms: Zinc Oxide*
  16. Singh S, Srivastava B, Gupta K, Gupta N, Singh R, Singh S
    Int J Clin Pediatr Dent, 2020 8 4;13(2):119-123.
    PMID: 32742086 DOI: 10.5005/jp-journals-10005-1718
    Aim and objective: The aim of this study was to evaluate and compare the antifungal efficacy of MTA Fillapex, Metapex, zinc oxide eugenol cement, Endomethasone, and Endoflas against Candida albicans.

    Materials and methods: Root canal exudates of 30 patients were tested against MTA Fillapex (Angelus), Metapex (BioMed), zinc oxide eugenol (Deepak Enterprise), Endomethasone (Septodont), Endoflas FS (Sanlor Laboratories), MTA (Angelus) (positive control), and glycerine (negative control). Children with failed endodontic cases were included in the study. Tube dilution and agar diffusion methods were used to check the antifungal efficacy of the root canal sealers. In tube dilution method, 24-well culture plates containing freshly mixed material along with Candida albicans were used. Wells containing MTA (Angelus) along with Sabouraud dextrose agar and Candida albicans served as positive control while glycerine along with Sabouraud dextrose agar and Candida albicans served as negative control. All plates were incubated at 37°C for 24 hours. Growth of the fungi was monitored after 24 hours by the presence of the turbidity. The samples were recultured to test the experimental material using agar well diffusion method, and the Petri plates were incubated for 24 hours and 72 hours. Zone of inhibition was measured after respective time period. Paired t test was used for the data analysis.

    Results: It was seen in tube dilution method Endomethasone showed least turbidity while maximum was shown by Metapex; similar results were seen in case of agar well diffusion method in which largest zone of inhibition was shown by Endomethasone while smallest was by Metapex.

    Conclusion: It was concluded that Endomethasone showed maximum efficacy against Candida albicans as compared to Metapex.

    How to cite this article: Singh S, Srivastava B, Gupta K, et al. Comparative Evaluation of Antifungal Efficacy of Five Root Canal Sealers against Clinical Isolates of Candida albicans: A Microbiological Study. Int J Clin Pediatr Dent 2020;13(2):119-123.

    Matched MeSH terms: Zinc Oxide; Zinc Oxide-Eugenol Cement
  17. Wong KA, Lam SM, Sin JC
    J Nanosci Nanotechnol, 2019 08 01;19(8):5271-5278.
    PMID: 30913844 DOI: 10.1166/jnn.2019.16816
    Shaped-controlled ZnO architectures including spherical, rod, rice-like and flower-like were fabricated via a reflux method in which the morphology, crystallinity, functional group and optical properties were tailored under different pH values in the precursor solution. The photoactivities of the prepared ZnO were evaluated under UV irradiation and the findings implied that the flower-like ZnO synthesized at pH 12 displayed superior activities on palm oil mil effluent degradation than those of other structures. The photocatalytic enhancement of flower-like ZnO was ascribed to its unique architecture, good crystallinity and superior optical properties. The flower-like ZnO with excellent photocatalytic performance have been confirmed by formation of hydroxyl radicals using a terephthalic acid-photoluminescence test. There was an optimal photocatalyst amount of 1.0 g/L, at which a maximum chemical oxygen demand removal of palm oil mill effluent was achieved under exposure of UV light. The phytotoxicity experiment via mung beans demonstrated a decrease in phytotoxicity.
    Matched MeSH terms: Zinc Oxide
  18. Pratima B, Chandan GD, Nidhi T, Nitish I, Sankriti M, Nagaveni S, et al.
    J Indian Soc Pedod Prev Dent, 2018 9 25;36(3):308-314.
    PMID: 30246755 DOI: 10.4103/JISPPD.JISPPD_1132_17
    Aim: The present study is an attempt to compare and evaluate postoperative assessment of diode laser zinc oxide eugenol (ZOE) pulpotomy and diode laser mineral trioxide aggregate (MTA) pulpotomy procedures in children.

    Materials and Methods: Forty carious primary molars indicated for pulpotomy within the age group of 4-9 years were selected and divided into two groups of 20 each using simple randomization, Group 1: Diode laser MTA and Group 2: Diode laser ZOE pulpotomy. The teeth were evaluated clinically for 1 year at 3, 6, and 12 months interval and radiologically for 6 and 12 months.

    Results: Clinically and radiographically, 100% teeth treated with diode laser MTA and 94% treated with diode laser ZOE were considered successful after 12-month follow-up interval. No significant difference was seen between two groups.

    Conclusion: Despite the success rate, the cost factor of diode laser and MTA could be the limiting factor in its judicious use in pulpotomy procedure.

    Matched MeSH terms: Zinc Oxide-Eugenol Cement/therapeutic use*
  19. Rambabu K, Bharath G, Banat F, Show PL
    J Hazard Mater, 2021 01 15;402:123560.
    PMID: 32759001 DOI: 10.1016/j.jhazmat.2020.123560
    Production of multi-functional zinc oxide nanoparticles (ZnO-NPs) for wastewater treatment through green-approaches is a desirable alternative for conventional synthesis routes. Biomass waste valorization for nanoparticles synthesis has received increased research attention. The present study reports date pulp waste (DPW) utilization as an effective bio-reductant for green-synthesis of ZnO-NPs. A simple and eco-friendly process with low reaction time and calcination temperature was adopted for DPW mediated ZnO-NPs (DP-ZnO-NPs) synthesis. Microscopic investigations of DP-ZnO-NPs confirmed the non-agglomeration and spherical nature of particles with mean diameter of 30 nm. EDX and XPS analysis defined the chemical composition and product purity of DP-ZnO-NPs. UV and photoluminescence studies exhibited surface plasmonic resonance at 381 nm and fluorescent nature of DP-ZnO-NPs. FTIR studies established a formation mechanism outline for DP-ZnO-NPs. XRD and Raman investigations confirmed the crystalline and hexagonal wurtzite phase of DP-ZnO-NPs. DSC/TG analysis displayed the thermal stability of DP-ZnO-NPs with <10 wt% loss upto 700 °C. Photocatalytic degradation of hazardous methylene blue and eosin yellow dyes using DP-ZnO-NPs, showed rapid decomposition rate with 90 % degradation efficiency. Additionally, DP-ZnO-NPs demonstrated significant antibacterial effects on various pathogenic bacteria in terms of zone-of-inhibition measured by disc-diffusion method. Thus, the as-prepared DP-ZnO-NPs is suitable for industrial wastewater treatment.
    Matched MeSH terms: Zinc Oxide*
  20. Ahmad AL, Sugumaran J, Shoparwe NF
    Membranes (Basel), 2018 Dec 14;8(4).
    PMID: 30558199 DOI: 10.3390/membranes8040131
    In this study, the antifouling properties of polyethersulfone (PES) membranes blended with different amounts of ZnO nanoparticles and a fixed ratio of N-methyl-2-pyrrolidone (NMP)-acetone mixture as a solvent were investigated. The properties and performance of the fabricated membranes were examined in terms of hydrophilicity, porosity, pore size, surface and cross-section image using scanning electron microscopy (SEM), surface roughness using atomic force microscopy (AFM), pure water flux, and humic acid filtration. Addition of ZnO as expected was found to improve the hydrophilicity as well as to encourage pore formation. However, the agglomeration of ZnO at a higher concentration cannot be avoided even when dissolved in a mixed solvent. The presence of highly volatile acetone contributed to the tight skin layer of the membrane which shows remarkable antifouling ability with the highest flux recovery ratio and negligible irreversible fouling. ZnO NPs in acetone/NMP mixed solvent shows an improvement in flux and rejection, but, the fouling resistance was moderate compared to the pristine membrane.
    Matched MeSH terms: Zinc Oxide
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