Displaying publications 41 - 60 of 532 in total

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  1. Response surface methodology for optimizing methylene blue dye removal by mesoporous activated carbon derived from renewable woody Bambusoideae waste
    Jawad AH, Abdulhameed AS, Khadiran T, ALOthman ZA, Wilson LD, Algburi S
    Int J Phytoremediation, 2024;26(5):727-739.
    PMID: 37817463 DOI: 10.1080/15226514.2023.2262040
    In this study, the focus was on utilizing tropical plant biomass waste, specifically bamboo (BB), as a sustainable precursor for the production of activated carbon (BBAC) via pyrolysis-induced K2CO3 activation. The potential application of BBAC as an effective adsorbent for the removal of methylene blue (MB) dye from aqueous solutions was investigated. Response surface methodology (RSM) was employed to evaluate key adsorption characteristics, which included BBAC dosage (A: 0.02-0.08 g/L), pH (B: 4-10), and time (C: 2-8 min). The adsorption isotherm analysis revealed that the adsorption of MB followed the Freundlich model. Moreover, the kinetic data were well-described by the pseudo-second-order model, suggesting the role of a chemisorption process. The BBAC demonstrated a notable MB adsorption capacity of 195.8 mg/g, highlighting its effectiveness as an adsorbent. Multiple mechanisms were identified as controlling factors in MB adsorption by BBAC, including electrostatic forces, π-π stacking, and H-bonding interactions. The findings of this study indicate that BBAC derived from bamboo has the potential to be a promising adsorbent for the treatment of wastewater containing organic dyes. The employment of sustainable precursors like bamboo for activated carbon production contributes to environmentally friendly waste management practices and offers a solution for the remediation of dye-contaminated wastewater.
    Matched MeSH terms: Waste Water*
  2. Fulltext Nonlinear partial differential equations model related to oxidation pond treatment system: a case study of mpho at taman timor oxidation pond, Johor Bahru
    Amir S. A. Hamzah, Ali H. M. Murid
    MATEMATIKA, 2018;34(2):293-311.
    MyJurnal
    This study presents a mathematical model examining wastewater pollutant removal through
    an oxidation pond treatment system. This model was developed to describe the reaction
    between microbe-based product mPHO (comprising Phototrophic bacteria (PSB)), dissolved
    oxygen (DO) and pollutant namely chemical oxygen demand (COD). It consists
    of coupled advection-diffusion-reaction equations for the microorganism (PSB), DO and
    pollutant (COD) concentrations, respectively. The coupling of these equations occurred
    due to the reactions between PSB, DO and COD to produce harmless compounds. Since
    the model is nonlinear partial differential equations (PDEs), coupled, and dynamic, computational
    algorithm with a specific numerical method, which is implicit Crank-Nicolson
    method, was employed to simulate the dynamical behaviour of the system. Furthermore,
    numerical results revealed that the proposed model demonstrated high accuracy when
    compared to the experimental data.
    Matched MeSH terms: Waste Water
  3. Beta-agonist residues in cattle, chicken and swine livers at the wet market and the environmental impacts of wastewater from livestock farms in Selangor State, Malaysia
    Sakai N, Sakai M, Mohamad Haron DE, Yoneda M, Ali Mohd M
    Chemosphere, 2016 Dec;165:183-190.
    PMID: 27654221 DOI: 10.1016/j.chemosphere.2016.09.022
    Fourteen beta-agonists were quantitatively analyzed in cattle, chicken and swine liver specimens purchased at 14 wet markets in Selangor State, Malaysia, by liquid chromatography-tandem mass spectrometry (LC-MS/MS). The health risks of ractopamine and clenbuterol residues in the Malaysian population were assessed based on quantitative data and meat consumption statistics in Malaysia. Wastewater samples collected at swine farms (n = 2) and cattle/cow farms (n = 2) in the Kuala Langat district were analyzed for the presence for the 14 compounds. Wastewater in chicken farms was not collected because there was negligible discharge during the breeding period. The environmental impacts caused by beta-agonists discharged from livestock farms were spatially assessed in the Langat River basin using a geographic information system (GIS). As a result, 10 compounds were detected in the liver specimens. Ractopamine, which is a permitted compound for swine in Malaysia, was frequently detected in swine livers; also, 9 other compounds that are prohibited compounds could be illegally abused among livestock farms. The health risks of ractopamine and clenbuterol were assessed to be minimal as their hazard quotients were no more than 7.82 × 10(-4) and 2.71 × 10(-3), respectively. Five beta-agonists were detected in the wastewater samples, and ractopamine in the swine farm resulted in the highest contamination (30.1 μg/L). The environmental impacts of the beta-agonists in the Langat River basin were generally concluded to be minimal, but the ractopamine contamination released from swine farms was localized in coastal areas near the estuary of the Langat River basin because most swine farms were located in that region.
    Matched MeSH terms: Waste Water/analysis*
  4. Co-treatment of landfill leachate and municipal wastewater using the ZELIAC/zeolite constructed wetland system
    Mojiri A, Ziyang L, Tajuddin RM, Farraji H, Alifar N
    J Environ Manage, 2016 Jan 15;166:124-30.
    PMID: 26496842 DOI: 10.1016/j.jenvman.2015.10.020
    Constructed wetland (CW) is a low-cost alternative technology to treat wastewater. This study was conducted to co-treat landfill leachate and municipal wastewater by using a CW system. Typha domingensis was transplanted to CW, which contains two substrate layers of adsorbents, namely, ZELIAC and zeolite. Response surface methodology and central composite design have been utilized to analyze experimental data. Contact time (h) and leachate-to-wastewater mixing ratio (%; v/v) were considered as independent variables. Colour, COD, ammonia, nickel, and cadmium contents were used as dependent variables. At optimum contact time (50.2 h) and leachate-to-wastewater mixing ratio (20.0%), removal efficiencies of colour, COD, ammonia, nickel, and cadmium contents were 90.3%, 86.7%, 99.2%, 86.0%, and 87.1%, respectively. The accumulation of Ni and Cd in the roots and shoots of T. domingensis was also monitored. Translocation factor (TF) was >1 in several runs; thus, Typha is classified as a hyper-accumulator plant.
    Matched MeSH terms: Waste Water
  5. Intelligent optimization for modelling superhydrophobic ceramic membrane oil flux and oil-water separation efficiency: Evidence from wastewater treatment and experimental laboratory
    Usman J, Salami BA, Gbadamosi A, Adamu H, Usman AG, Benaafi M, et al.
    Chemosphere, 2023 Aug;331:138726.
    PMID: 37116721 DOI: 10.1016/j.chemosphere.2023.138726
    Due to the significant energy and economic losses brought on by the global oil spill, there has been an increased interest in oil-water separation. This study presents strong non-linear machine learning models (support vector regression (SVR) and Gaussian process regression (GPR)) with the Response surface method (RSM) to predict the oil flux and oil-water separation efficiency of wastewater using ceramic membrane technology. For the model development and prediction of oil flux (OF) and oil-water separation efficiency (OSE), oil concentration (mg/L), feed flow rate (mL/min), and pH were considered as input variables. The input variables are combined in three combinations to study the most contributing input features to the models' performance. Mean square error (MSE) and Nash-Sutcliffe coefficient efficiency (NSE) were used to assess the prediction performances of the developed models with the different number of input combinations considered in the study. For the two target variables (OF and OSE), GPR and SVR models were used to separately predict them. For OF, the SVR-2 [Combo-2] model (MSE = 0.9255 and NSE = 2.7976) performed better with higher prediction accuracy compared to GPR-2 [Combo-2] model (MSE = 0.763 and NSE = 6.437). In addition, for OSE, the GPR-3 [Combo-3] model (MSE = 0.995 and NSE = 0.5544) performed slightly better than SVR-3 [Combo-3] model (MSE = 0.992 and NSE = 0.8066). The results showed that the SVR model with the combo-2 and GPR-3 models for OF and OSE variables are the proposed models with the best performance and accuracy. This machine learning study will aid in better evaluating the function of materials such as ceramic in membrane performance features such as oil flux and rejection prediction, separation efficiency, water recovery, membrane fouling, and so on. As for academics and manufacturers, this machine learning (ML) strategy will boost performance and allow a better understanding of system governance.
    Matched MeSH terms: Waste Water*
  6. Bio-inspired ZnO NPs synthesized from Citrus sinensis peels extract for Congo red removal from textile wastewater via photocatalysis: Optimization, mechanisms, techno-economic analysis
    Yashni G, Al-Gheethi A, Radin Mohamed RMS, Dai-Viet NV, Al-Kahtani AA, Al-Sahari M, et al.
    Chemosphere, 2021 Oct;281:130661.
    PMID: 34029959 DOI: 10.1016/j.chemosphere.2021.130661
    Textile industry is one of the most environmental unfriendly industrial processes due to the massive generation of colored wastewater contaminated with dyes and other chemical auxiliaries. These contaminants are known to have undesirable consequences to ecosystem. The present study investigated the best operating parameters for the removal of congo red (CR, as the model for dye wastewater) by orange peels extract biosynthesized zinc oxide nanoparticles (ZnO NPs) via photocatalysis in an aqueous solution. The response surface methodology (RSM) with ZnO NPs loadings (0.05-0.20 g), pH (3.00-11.00), and initial CR concentration (5-20 ppm) were used for the optimization process. The applicability of ZnO NPs in the dye wastewater treatment was evaluated based on the techno-economic analysis (TEA). ZnO NPs exhibited hexagonal wurtzite structure with = C-H, C-O, -C-O-C, CC, O-H as the main functional groups. The maximum degradation of CR was more than 96% with 0.171 g of ZnO NPs, at pH 6.43 and 5 ppm of CR and 90% of the R2 coefficient. The specific cost of ZnO NPs production is USD 20.25 per kg. These findings indicated that the biosynthesized ZnO NPs with orange peels extract provides alternative method for treating dye wastewater.
    Matched MeSH terms: Waste Water
  7. Bacterial nanocellulose and its application in heavy metals and dyes removal: a review
    Sahari NS, Shahir S, Ibrahim Z, Hasmoni SH, Altowayti WAH
    Environ Sci Pollut Res Int, 2023 Nov;30(51):110069-110078.
    PMID: 37814051 DOI: 10.1007/s11356-023-30067-w
    This review discusses the application of bacterial nanocellulose (BNC) and modified BNC in treating wastewater containing heavy metals and dye contaminants. It also highlights the challenges and future perspectives of BNC and its composites. Untreated industrial effluents containing toxic heavy metals are systematically discharged into public waters. In particular, lead (Pb), copper (Cu), cadmium (Cd), nickel (Ni), zinc (Zn), and arsenic (As) are very harmful to human health and, in some cases, may lead to death. Several methods such as chemical precipitation, ion exchange, membrane filtration, coagulation, and Fenton oxidation are used to remove these heavy metals from the environment. However, these methods involve the use of numerous chemicals whilst producing high amount of toxic sludge. Meanwhile, the development of the adsorption-based technique has provided an alternative way of treating wastewater using BNC. Bacterial nanocellulose requires less energy for purification and has higher purity than plant cellulose. In general, the optimum growth parameters are crucial in BNC production. Even though native BNC can be used for the removal of heavy metals and dyes, the incorporation of other materials, such as polyethyleneimine, graphene oxide, calcium carbonate and polydopamine can improve sorption efficiencies.
    Matched MeSH terms: Waste Water*
  8. Fulltext Prevalence and risk factors of childhood diarrhea among wastewater irrigating urban farming households in Addis Ababa
    Ali AS, Gari SR, Goodson ML, Walsh CL, Dessie BK, Ambelu A
    PLoS One, 2023;18(11):e0288425.
    PMID: 37939075 DOI: 10.1371/journal.pone.0288425
    INTRODUCTION: Childhood diarrhea is one of the major contributors to the morbidity of under-five children in Ethiopia. Although researchers determine the risk factors varyingly, the exposure route to the pathogens is usually complicated. This study aims to investigate the prevalence and risk factors of diarrhea among children under the age of five among wastewater irrigation farming households in Addis Ababa, Ethiopia.

    METHODS: Cross-sectional study was conducted among 402 farming households from November 2021 to February 2022. Data was collected using a face-to-face interviewer-administered questionnaire. Stata version 14 software was used to analyze data. Factors associated with the prevalence of diarrhea was identified using binary logistic regression. Multivariable analysis was carried out to determine an adjusted odds ratio at a confidence level of 95% and level of significance at 0.05.

    RESULTS: The overall prevalence of under-five children diarrheal cases was 22.3%. The odds of diarrhea are associated with a multitude of variables. Major wastewater-related determinants associated with diarrhea are body washing with irrigation water [AOR: 37.7, 95%CI (3.1, 358)], contaminated cloth with irrigation water [AOR:10.8,95%CI(0.6, 205)], use of protective clothing during farm work [28.9,95%CI (3.9, 215)], use of farm work cloths at home [AOR: 31.7, 95%CI (4.4, 226)], and bringing unwashed farm tools to home [94 (5.7, 1575)].

    CONCLUSION: The high prevalence of under-five children diarrheal disease among wastewater irrigation households was strongly associated with factors related to occupational exposure. Thus, to decrease childhood diarrheal among urban agriculture farmers, appropriate precautions need to be taken.

    Matched MeSH terms: Waste Water*
  9. Fulltext Critical role of Hyssop plant in the possible transmission of SARS-CoV-2 in contaminated human Feces and its implications for the prevention of the virus spread in sewage
    Zahmatkesh S, Klemeš JJ, Bokhari A, Wang C, Sillanpaa M, Hasan M, et al.
    Chemosphere, 2022 Oct;305:135247.
    PMID: 35688196 DOI: 10.1016/j.chemosphere.2022.135247
    The significant issue affecting wastewater treatment is human faeces containing SARS-CoV-2. SARS-CoV-2, as a novel coronavirus, has expanded globally. While the current focus on the COVID-19 epidemic is rightly on preventing direct transmission, the risk of secondary transmission via wastewater should not be overlooked. Many researchers have demonstrated various methods and tools for preventing and declining this virus in wastewater treatment, especially for SARS-CoV-2 in human faeces. This research reports two people tested for 30 d, with written consent, at Mosa-Ebne-Jafar Hospital of Quchan, Iran, from September 1st to October 9th, 2021. The two people's conditions are the same. The Hyssop plant was used, which boosts the immune system's effectiveness and limonene, rosemary, caffeic acids and flavonoids, all biologically active compounds in this plant, cause improved breathing problems, colds, and especially for SARS-CoV-2. As a result, utilising the Hyssop plant can help in reducing SARS-CoV-2 in faeces. This plant's antioxidant properties effectively reduce SARS-CoV-2 in faeces by 30%; nevertheless, depending on the patient's condition. This plant is also beneficial for respiratory and digestive health.
    Matched MeSH terms: Waste Water
  10. Influence of pathogenic bacterial activity on growth of Scenedesmus sp. and removal of nutrients from public market wastewater
    Al-Gheethi AA, Mohamed RM, Jais NM, Efaq AN, Abd Halid A, Wurochekke AA, et al.
    J Water Health, 2017 Oct;15(5):741-756.
    PMID: 29040077 DOI: 10.2166/wh.2017.080
    The present study aims to investigate the influence of Staphylococcus aureus, Escherichia coli and Enterococcus faecalis in public market wastewater on the removal of nutrients in terms of ammonium (NH4-) and orthophosphate (PO43) using Scenedesmus sp. The removal rates of NH4- and orthophosphate PO43- and batch kinetic coefficient of Scenedesmus sp. were investigated. The phycoremediation process was carried out at ambient temperature for 6 days. The results revealed that the pathogenic bacteria exhibited survival potential in the presence of microalgae but they were reduced by 3-4 log at the end of the treatment process. The specific removal rates of NH4- and PO43- have a strong relationship with initial concentration in the public market wastewater (R2 = 0.86 and 0.80, respectively). The kinetic coefficient of NH4- removal by Scenedesmus sp. was determined as k = 4.28 mg NH4- 1 log10 cell mL-1 d-1 and km = 52.01 mg L-1 (R2 = 0.94) while the coefficient of PO43- removal was noted as k = 1.09 mg NH4- 1 log10 cell mL-1 d-1 and km = 85.56 mg L-1 (R2 = 0.92). It can be concluded that Scenedesmus sp. has high competition from indigenous bacteria in the public market wastewater to remove nutrients, with a higher coefficient of removal of NH4- than PO43.
    Matched MeSH terms: Waste Water/analysis*
  11. Fulltext Cadmium (Cd) removal from aqueous solution using Microwave Incinerated Rice Husk Ash (MIRHA)
    Mohamed Hasnain Isa, Shamsul Rahman Mohamed Kutty, Sri Rahayu Mohd Hussin, Nurhidayati Mat Daud, Amirhossein Malakahmad
    Pertanika Journal of Science & Technology, 2012;20(2):339-346.
    MyJurnal
    The presence of heavy metals in aquatic systems has become a serious problem. Heavy metals can haveadverse effects on the environment as well as on human health. As a result, much attention has beengiven to new technologies for removal of heavy metal ions from contaminated waters. In this study,Microwave Incinerated Rice Husk Ash (MIRHA), a locally available agricultural waste, was used for theremoval of Cd (as a representative heavy metal) from synthetic wastewater by batch adsorption process.The effects of pH, initial metal concentration, and contact time on Cd removal efficiency were studied.pH 4 was found to be the optimum. The removal efficiency was found to be correlated with the initialmetal concentration and contact time between adsorbent and adsorbate. Cd adsorption kinetics followedthe pseudo-second-order model and implied chemisorption. The adsorption equilibrium of Cd can bewell described by the Freundlich isotherm model.
    Matched MeSH terms: Waste Water
  12. Microcrystalline cellulose/metal-organic framework hybrid as a sorbent for dispersive micro-solid phase extraction of chlorophenols in water samples
    Ghaemi F, Amiri A
    J Chromatogr A, 2020 Aug 30;1626:461386.
    PMID: 32797858 DOI: 10.1016/j.chroma.2020.461386
    In this study, the microcrystalline cellulose/metal-organic framework 199 hybrid (MCC/MOF-199) was applied as sorbent for the dispersive micro-solid phase-extraction (D-μSPE) of chlorophenols. The D-μSPE method combined with high-performance liquid chromatography- ultraviolet detection (HPLC-UV) was employed to determine of four chlorophenols including 2-chlorophenol (2-CP), 4-chlorophenol (4-CP), 2,3-dichlorophenol (2,3-DCP), and 2,5-dichlorophenol (2,5-DCP) in aqueous. The main parameters of the D-μSPE process that influence the extraction (i.e. the amount of sorbent, elution condition, extraction time, and pH) were investigated and optimized. Based on the outputs, the presence of MCC on the surface of MOF-199 leads to improve the properties of MOF-199 and the MCC/MOF-199 has the highest sorption capacity, durability, and porosity in comparison with MCC and MOF-199. According to the validation study at the optimized conditions, the linearity for the analytes was achieved in the range from 0.1 to 200 ng mL-1 for 2-CP and 4-CP and 0.15 to 200 ng mL-1 for 2,3-DCP and 2,5-DCP with correlation coefficients between 0.9928 and 0.9965. The limits of detection calculated at S/N=3 were in the range of 0.03-0.05 ng mL-1. Besides, the relative standard deviations (RSDs) for three spiking levels (0.2, 10,100 ng mL-1) do not exceed 6.8% and extraction recoveries are between 81.0% and 88.3%. Finally, the D-μSPE-HPLC-UV method was successfully applied to the analysis of CPs in real water samples (mineral, river and wastewater samples) with good recoveries (95.8 to 99.5%) and satisfactory precisions (RSD < 6.8%).
    Matched MeSH terms: Waste Water/analysis
  13. Application of chitosan and its derivatives as adsorbents for dye removal from water and wastewater: a review
    Vakili M, Rafatullah M, Salamatinia B, Abdullah AZ, Ibrahim MH, Tan KB, et al.
    Carbohydr Polym, 2014 Nov 26;113:115-30.
    PMID: 25256466 DOI: 10.1016/j.carbpol.2014.07.007
    Chitosan based adsorbents have received a lot of attention for adsorption of dyes. Various modifications of this polysaccharide have been investigated to improve the adsorption properties as well as mechanical and physical characteristics of chitosan. This review paper discusses major research topics related to chitosan and its derivatives for application in the removal of dyes from water. Modification of chitosan changes the original properties of this material so that it can be more suitable for adsorption of different types of dye. Many chitosan derivatives have been obtained through chemical and physical modifications of raw chitosan that include cross-linking, grafting and impregnation of the chitosan backbone. Better understanding of these varieties and their affinity toward different types of dye can help future research to be properly oriented to address knowledge gaps in this area. This review provides better opportunity for researchers to better explore the potential of chitosan-derived adsorbents for removal of a great variety of dyes.
    Matched MeSH terms: Waste Water*
  14. Oleophilicity and oil-water separation by reduced graphene oxide grafted oil palm empty fruit bunch fibres
    Mohd Shaiful Sajab, Wan Nurmawaddah Wan Abdul Rahman, Chin Hua Chia, Sarani Zakaria, Hatika Kaco, An’amt Mohamed Noor
    Sains Malaysiana, 2018;47:1891-1896.
    Absorption is one of the effective, simple and economical methods to remove oil from oily wastewater. The most widely
    used approach is to utilize lignocellulosic biomass as oil absorbent. However, the hygroscopic of cellulose have limited
    the oil-water separation capability of lignocellulosic fibers. In this study, the surface functionality of oil palm empty
    fruit bunch (EFB) fibers was slightly altered by grafting reduced graphene oxide (rGO). The modified EFB fibers show
    a distinct morphological and chemical characteristics changes as the surface of fibers has been coated with rGO. This
    was supported by FTIR analysis with the diminishing peak of hydroxyl group region of EFB fibers. While the surface
    modification on EFB fibers shows a diminution of a hydrophilic characteristic of 131.6% water absorption in comparison
    with 268.9% of untreated EFB fibers. Moreover, modified fibers demonstrated an oil-water separation increment as well,
    as it shows 89% of oil uptake and improved ~17 times of oil selectivity in oil-water emulsion than untreated EFB fibers.
    Matched MeSH terms: Waste Water
  15. Impacts of pig farming on the water quality of Serin River, Sarawak
    Ling T, Layang H, Then Y, Apun K
    Sains Malaysiana, 2006;35:45-50.
    In Sarawak, pig farm operators are required to treat the wastewater containing pig waste and spilt food in oxidation ponds before discharge. However, information on the impact of this industry on surface water quality is lacking. Therefore, the objective of this study is to determine the impact of pig farm effluent on the water quality of Serin River and its tributaries. Results of analysis show that the tributary that received pond effluent has significantly higher mean of total suspended solids (TSS), biochemical oxygen demand (BOD5) chemical oxygen demand (COD), ammonia-nitrogen (NH3 -N), reactive phosphorus (SRP) and Escherichia coli (E. coli) concentrations when compared to those of the tributary that did not receive pond effluent. Comparisons between the stations upstream and downstream of the discharge point indicated that BOD5 and COD were significantly higher at the downstream station that received pond effluent. Dissolved oxygen (DO) was the lowest at the tributary receiving effluent from pig farms with a mean of 2.40 mg/l. According to the Interim Water Quality Standard of the Department of Environment, water quality at the tributary that received pig farm effluent falls into Class III whereas that of the other stations falls into Class II. It is recommended that further studies be conducted on the management of waste to explore the possibility of turning the waste into a resource so that water quality of rivers can remain pristine for drinking and recreation.
    Matched MeSH terms: Waste Water
  16. Sequential nitrification and denitrification in a novel palm shell granular activated carbon twin-chamber upflow bio-electrochemical reactor for treating ammonium-rich wastewater
    Mousavi S, Ibrahim S, Aroua MK
    Bioresour Technol, 2012 Dec;125:256-66.
    PMID: 23026342 DOI: 10.1016/j.biortech.2012.08.075
    In this study, a twin-chamber upflow bio-electrochemical reactor packed with palm shell granular activated carbon as biocarrier and third electrode was used for sequential nitrification and denitrification of nitrogen-rich wastewater under different operating conditions. The experiments were performed at a constant pH value for the denitrification compartment. The effect of variables, namely, electric current (I) and hydraulic retention time (HRT), on the pH was considered in the nitrification chamber. The response surface methodology was used based on three levels to develop empirical models for the study on the effects of HRT and current values as independent operating variables on NH(4)(+)-N removal. The results showed that ammonium was reduced within the function of an extensive operational range of electric intensity (20-50 mA) and HRT (6-24h). The optimum condition for ammonium oxidation (90%) was determined with an I of 32 mA and HRT of 19.2h.
    Matched MeSH terms: Waste Water/analysis
  17. Fulltext Novel, one-step synthesis of zwitterionic polymer nanoparticles via distillation-precipitation polymerization and its application for dye removal membrane
    Ibrahim GPS, Isloor AM, Inamuddin, Asiri AM, Ismail N, Ismail AF, et al.
    Sci Rep, 2017 Nov 21;7(1):15889.
    PMID: 29162869 DOI: 10.1038/s41598-017-16131-9
    In this work, poly(MBAAm-co-SBMA) zwitterionic polymer nanoparticles were synthesized in one-step via distillation-precipitation polymerization (DPP) and were characterized. [2-(methacryloyloxy)ethyl]dimethyl-(3-sulfopropyl)ammonium hydroxide (SBMA) as monomer and N, N'-methylene bis(acrylamide) (MBAAm) as cross-linker are used for the synthesis of nanoparticles. As  far as our knowledge, this is the first such report on the synthesis of poly(MBAAm-co-SBMA) nanoparticles via DPP. The newly synthesized nanoparticles were further employed for the surface modification of polysulfone (PSF) hollow fiber membranes for dye removal. The modified hollow fiber membrane exhibited the improved permeability (56 L/ m2 h bar) and dye removal (>98% of Reactive Black 5 and >80.7% of Reactive orange 16) with the high permeation of salts. Therefore, the as-prepared membrane can have potential application in textile and industrial wastewater treatment.
    Matched MeSH terms: Waste Water
  18. Fulltext Arsenic, zinc, and aluminium removal from gold mine wastewater effluents and accumulation by submerged aquatic plants (Cabomba piauhyensis, Egeria densa, and Hydrilla verticillata)
    Abu Bakar AF, Yusoff I, Fatt NT, Othman F, Ashraf MA
    Biomed Res Int, 2013;2013:890803.
    PMID: 24102060 DOI: 10.1155/2013/890803
    The potential of three submerged aquatic plant species (Cabomba piauhyensis, Egeria densa, and Hydrilla verticillata) to be used for As, Al, and Zn phytoremediation was tested. The plants were exposed for 14 days under hydroponic conditions to mine waste water effluents in order to assess the suitability of the aquatic plants to remediate elevated multi-metals concentrations in mine waste water. The results show that the E. densa and H. verticillata are able to accumulate high amount of arsenic (95.2%) and zinc (93.7%) and resulted in a decrease of arsenic and zinc in the ambient water. On the other hand, C. piauhyensis shows remarkable aluminium accumulation in plant biomass (83.8%) compared to the other tested plants. The ability of these plants to accumulate the studied metals and survive throughout the experiment demonstrates the potential of these plants to remediate metal enriched water especially for mine drainage effluent. Among the three tested aquatic plants, H. verticillata was found to be the most applicable (84.5%) and suitable plant species to phytoremediate elevated metals and metalloid in mine related waste water.
    Matched MeSH terms: Waste Water/chemistry
  19. Fulltext Field accumulation risks of heavy metals in soil and vegetable crop irrigated with sewage water in western region of Saudi Arabia
    Balkhair KS, Ashraf MA
    Saudi J Biol Sci, 2016 Jan;23(1):S32-44.
    PMID: 26858563 DOI: 10.1016/j.sjbs.2015.09.023
    Wastewater irrigated fields can cause potential contamination with heavy metals to soil and groundwater, thus pose a threat to human beings . The current study was designed to investigate the potential human health risks associated with the consumption of okra vegetable crop contaminated with toxic heavy metals. The crop was grown on a soil irrigated with treated wastewater in the western region of Saudi Arabia during 2010 and 2011. The monitored heavy metals included Cd, Cr, Cu, Pb and Zn for their bioaccumulation factors to provide baseline data regarding environmental safety and the suitability of sewage irrigation in the future. The pollution load index (PLI), enrichment factor (EF) and contamination factor (CF) of these metals were calculated. The pollution load index of the studied soils indicated their level of metal contamination. The concentrations of Ni, Pb, Cd and Cr in the edible portions were above the safe limit in 90%, 28%, 83% and 63% of the samples, respectively. The heavy metals in the edible portions were as follows: Cr > Zn > Ni > Cd > Mn > Pb > Cu > Fe. The Health Risk Index (HRI) was >1 indicating a potential health risk. The EF values designated an enhanced bio-contamination compared to other reports from Saudi Arabia and other countries around the world. The results indicated a potential pathway of human exposure to slow poisoning by heavy metals due to the indirect utilization of vegetables grown on heavy metal-contaminated soil that was irrigated by contaminated water sources. The okra tested was not safe for human use, especially for direct consumption by human beings. The irrigation source was identified as the source of the soil pollution in this study.
    Matched MeSH terms: Waste Water
  20. Using walnut shells as low-cost adsorbent materials in an anaerobic filter medium of a De-centralized wastewater treatment system (DEWATS)
    Zaheer M, Ali MS, Huang N, Ashraf MA
    Chemosphere, 2023 Nov;341:140080.
    PMID: 37678602 DOI: 10.1016/j.chemosphere.2023.140080
    The flow of unprocessed sewage through municipal sewers is a great source of water contamination. This study aims to observe the pollutants removal efficiencies of walnut shells as an efficient low-cost adsorbent material compared to gravel materials as an anaerobic filter medium. Two models of the De-Centralized Wastewater Treatment System (DEWATS) were constructed. The wastewater flowing from toilets and handwashing places was connected to anaerobic filters filled with walnut shells and gravel. The efficiency of both filter media in the removal of biological oxygen demand (BOD), chemical oxygen demand (COD), total suspended solids (TSS), total dissolved solids (TDS), nitrate (NO3), and phosphate (PO43), pH and temperature were observed at the influent of the settler tank and then at the effluent of the collection tank (CT). Temperature and pH were within the acceptable limit of wastewater discharge. The results also indicated that the walnut shells filter media was more efficient at removing organic pollutants (TSS 94%, BOD5 88%, COD 85%, Nitrate 57%, phosphate 46%, and TDS 29%) than the gravel (TSS 81%, BOD5 82%, COD 84%, Nitrate 35%, phosphate 38%, and TDS 26%) at the successive stages. The average removal efficiency of the walnut shell was 88% while in the gravel case, it was 83%. The removal efficiency of walnut shell filters was extensively better over the complete experiment compared to gravel filters for the removal of pollutants, representing the high sorption capability of the walnut shell material. The results of this study show that the walnut shells may be a very useful substitute for other conventional fillers for anaerobic treatment in the anaerobic filter of DEWATS.
    Matched MeSH terms: Waste Water
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